TY - JOUR A1 - Braun, Peter A1 - Durner, Bernhard A1 - Rabl, Hans-Peter A1 - Matysik, Frank-Michael T1 - Investigations on the decomposition of AdBlue urea in the liquid phase at low temperatures by an electrochemically induced pH shift JF - Monatshefte für Chemie N2 - Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface. [GRAPHICS] . KW - Ammonia KW - Catalysis KW - CONVERSION KW - Diesel Engine KW - DOPED MN/TIO2 KW - Electrochemistry KW - HYDROLYSIS KW - In situ pH shift KW - NOX KW - OXIDATION KW - PRODUCTS KW - REMOVAL KW - SCR KW - SELECTIVE CATALYTIC-REDUCTION KW - Thermochemistry Y1 - 2019 U6 - https://doi.org/10.1007/s00706-019-02406-6 VL - 150 IS - 9 SP - 1633 EP - 1641 PB - Springer ER - TY - GEN A1 - Weiss, Nils T1 - Vulnerabilities of Connected Cars and beyond T2 - Applied Research Colloquium, 2019, Università Padua, Italy Y1 - 2019 ER - TY - CHAP A1 - Sýkora, Miroslav A1 - Diamantidis, Dimitris A1 - Markova, J. A1 - Masciotta, Maria Giovanna ED - Baričević, Ana ED - Jelčić Rukavina, Marija ED - Damjanović, Domagoi ED - Guadagnini, Maurizio T1 - Optimizing in-situ testing for historic masonry structures: a case study BT - a case study T2 - International Conference on Sustainable Materials, Systems and Structures (SMSS 2019) : Durability, Monitoring and Repair of Structures, 20-22 March 2019, Rovinj, Croatia Y1 - 2019 UR - http://toc.proceedings.com/50441webtoc.pdf SN - 978-1-5108-9296-5 SP - 684 EP - 691 PB - RILEM Publications ER - TY - JOUR A1 - Schwanzer, Peter A1 - Rabl, Hans-Peter A1 - Loders, S. A1 - Seifert, P. A1 - Himmelstoss, S. A1 - Gaderer, Matthias T1 - Difference in the Tailpipe Particle Number by Consideration of Sub-23-nm Particles for Different Injection Settings of a GDI Engine JF - Emission control science and technology N2 - The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50% cutoff (D-50%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50%=10 nm and D-50%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall. KW - DoE KW - GDI KW - Particle number Y1 - 2019 U6 - https://doi.org/10.1007/s40825-019-0114-1 VL - 5 IS - 1 SP - 7 EP - 22 PB - Springer Nature ER - TY - GEN A1 - Altmann, Robert A1 - Rabl, Hans-Peter A1 - Gaderer, Matthias T1 - Phänomenologische Untersuchung des Einspritzverhaltens von Pflanzenölkraftstoff T2 - 3. Tagung der Fuels Joint Research Group (FJRG) "Kraftstoffe für die Mobilität von Morgen" Y1 - 2019 UR - https://www.researchgate.net/publication/335490299_Phanomenologische_Untersuchung_des_Einspritzverhaltens_von_Pflanzenolkraftstoff ER - TY - JOUR A1 - Hansen, B. A1 - Hoebler, Michael A1 - Purr, S. A1 - Meinhardt, J. A1 - Merklein, M. T1 - Basics for inline measurement of tribological conditions in series production of car body parts JF - IOP Conference Series: Materials Science and Engineering N2 - The quality of car body parts in series production is strongly dependent on the tribological behavior. Fluctuating material properties such as the sheet roughness and the amount of lubricant have an influence on the forming process. On the basis of large amounts of data it is possible to investigate the friction behavior in series production and to make process adjustments if required. Therefore, inline measurement systems have a great potential to detect the sheet roughness during the cutting process of blanks in the coil line. Furthermore, contactless systems are advantageous as they do not damage the surface. Nevertheless, the optical measuring is influenced by the lubricant layer on top of the surface. Therefore, the previously unknown impact of the lubricant on the measuring result is investigated. Within this study, stationary optical roughness measurements have been conducted using different amounts of lubricant on hot-dip galvanized EDT steel. The results demonstrate the influence of different amounts of lubricant on the sheet roughness measurement. Hence, it is possible to correct the inline measuring results and gain knowledge of fluctuating surface roughness. In addition, strip drawing test has been carried out to investigate the effect of fluctuating tribological conditions. Y1 - 2019 U6 - https://doi.org/10.1088/1757-899x/651/1/012050 VL - 651 PB - IOP Publishing ER - TY - JOUR A1 - Briem, Ulrich T1 - Biegesteifigkeit von Drahtseilen JF - Technische Logistik Y1 - 2019 IS - 11-12 SP - 24 EP - 25 PB - Huss-Medien CY - Berlin ER - TY - JOUR A1 - Chatzitakis, Paris A1 - Safarov, Javid A1 - Opferkuch, F. A1 - Dawoud, Belal T1 - Experimental investigation of an absorption heat pump with organic working pairs JF - Applied Thermal Engineering N2 - As part of a systematic approach towards the search for alternative absorption heat pump (AHP) working pairs that could potentially provide comparable performance to conventional ones, a previous work performed a detailed theoretical cycle analysis and simulation that revealed concrete correlations between key working fluid thermophysical properties and AHP performance indicators. Following this work, targeted combinations of two organic refrigerants, 2,2,2-trifluoroethanol (TFE) and 2,2,3,3,3-pentafluoropropanol (5FP) and two organic absorbents, 1,3-dimethyl-2-imidazolidinone (DMI) and 2-pyrrolidone (PYR) were tested in a prototype 5 kW AHP, based on a highly compact plate heat exchanger design, which has been previously introduced. The purpose of this effort was to test the findings of the previous work with experimental measurements. The working pair combinations were also subjected to vapor liquid equilibrium (VLE) and viscosity measurements, in order to determine reliable activity coefficient and improve the accuracy of the simulations. The experimental performance data agree well with the COP simulations and show to be consistent with the conclusions derived from the previous theoretical work. KW - Absorption heat pump KW - Coefficient of performance KW - FLUID KW - MIXTURES KW - Organic working pairs KW - Specific solution circulation Y1 - 2019 U6 - https://doi.org/10.1016/j.applthermaleng.2019.114311 VL - 163 IS - December PB - Elsevier ER - TY - CHAP A1 - Sterner, Michael A1 - Thema, Martin ED - Sterner, Michael ED - Stadler, Ingo T1 - Comparison of Storage Systems T2 - Handbook of Energy Storage N2 - There are several approaches to classifying energy storage systems (see Chaps. 1 and 2). Storage systems are used in a large number of different technologies at various stages of development, and in a wide range of application areas (see Chaps. 3 to 5). This chapter compares the capabilities of the different storage systems using the following criteria:This comparison of storage systems also provides a convenient overview of the various storage systems and their capabilities. Y1 - 2019 SN - 978-3-662-55503-3 U6 - https://doi.org/10.1007/978-3-662-55504-0_12 VL - 6 SP - 637 EP - 672 PB - Springer CY - Berlin, Heidelberg ER - TY - JOUR A1 - Keiner, Dominik A1 - Breyer, Christian A1 - Sterner, Michael T1 - Coupling heat and electricity storage technologies for cost and self-consumption optimised residential PV prosumer systems in Germany JF - International Journal of Sustainable Energy Planning and Management N2 - Coupling energy sectors within the emerging residential PV prosumer systems is necessary for an optimised use of the houseowners’ own produced electricity. But the pure availability of different energy technologies in the system is not enough. By optimising the electricity usage as well as the capacities of PV generators, storage technologies, heat pumps and battery electric vehicles, not only the best solution in a technical point of view can be achieved, the need of finding the most financially beneficial system composition for single-family houses and tenements is possible. The study provides a detailed model for average German single-family houses and tenements and results for the energy transition period until 2050 for the optimised energy systems regarding optimised PV and stationary battery capacities and different heat storage capacities. Most noticeable outcomes can be observed by using a vehicle-to-home car, where a car can mostly take over the tasks of a stationary battery and by introducing a solidarity model using this type of car in tenement systems. Y1 - 2019 U6 - https://doi.org/10.5278/ijsepm.2019.21.4 VL - 21 PB - OJS/PKP ER -