TY - CHAP A1 - Schneider, Sebastian A1 - Hots, Jan A1 - Luft, Tommy A1 - Rottengruber, Hermann A1 - Verhey, Jesko L. A1 - Rabl, Hans-Peter T1 - Entwicklung einer empirischen Formel zur Bewertung der Tickergeräuschanteile von Motorgeräuschen T2 - DAGA 2019 - 45. Jahrestagung für Akustik, 8.-21. März 2019, Rostock Y1 - 2019 UR - https://pub.dega-akustik.de/DAGA_2019/data/daga19_proceedings.pdf SN - 978-3-939296-14-0 VL - 45 SP - 643 EP - 646 PB - Deutsche Gesellschaft für Akustik e.V. ER - TY - CHAP A1 - Rieger, Anna A1 - Mühlbauer, Christian A1 - Weber, Rainer A1 - Rabl, Hans-Peter T1 - Measures to Address the Dissonance Perception of Multiple Tonal Components in Sounds T2 - DAGA 2019 - 45. Jahrestagung für Akustik, 18.-21. März 2019, Rostock Y1 - 2019 UR - https://pub.dega-akustik.de/DAGA_2019/data/articles/000499.pdf VL - 45 SP - 375 EP - 378 PB - Deutsche Gesellschaft für Akustik e.V. ER - TY - GEN A1 - Schwanzer, Peter A1 - Dietrich, Markus A1 - Gaderer, Matthias A1 - Rabl, Hans-Peter T1 - Monitoring von Partikelfiltern für den Einsatz in Fahrzeugen mit direkt- einspritzenden Ottomotoren mit einer Radio-Frequenz (RF-) Antenne T2 - Kolloquium des Bayerischen Wissenschaftsforum Y1 - 2019 UR - https://mobilitaet-verkehr.baywiss.de/fileadmin/verbundkolleg/mobilitaet-verkehr/poster/20190417_Poster_Regensburg_Kolloqium_des_Bayerischen_Wissenschaftsforum_Peter_Schwanzer.pdf ER - TY - GEN A1 - Schwanzer, Peter A1 - Dietrich, Markus A1 - Haft, Gerhard A1 - Gaderer, Matthias A1 - Rabl, Hans-Peter T1 - Oxidation Kinetics Determination of GDI Engine Soot by a Radio-Frequency Sensor T2 - 23rd Conference on Combustion Generated Nanoparticles 2019, June 17-20, Zürich, Switzerland Y1 - 2019 UR - https://www.nanoparticles.ch/archive/2019_Schwanzer_PO.pdf ER - TY - JOUR A1 - Braun, Peter A1 - Rabl, Hans-Peter A1 - Matysik, Frank-Michael T1 - Investigations on the Liquid-Phase Decomposition of AdBlue Urea for the Selective Catalytic Reduction Process JF - Chemie Ingenieur Technik N2 - Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions. KW - AdBlue urea KW - Ammonia KW - DeNO(x) KW - EMISSIONS KW - HYDROLYSIS KW - KINETICS KW - Liquid-phase decomposition KW - LOW-TEMPERATURE SCR KW - MODEL KW - NOX KW - Selective catalytic reduction Y1 - 2019 U6 - https://doi.org/10.1002/cite.201800055 VL - 91 IS - 7 SP - 961 EP - 968 PB - Wiley ER - TY - JOUR A1 - Braun, Peter A1 - Durner, Bernhard A1 - Rabl, Hans-Peter A1 - Matysik, Frank-Michael T1 - Investigations on the decomposition of AdBlue urea in the liquid phase at low temperatures by an electrochemically induced pH shift JF - Monatshefte für Chemie N2 - Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface. [GRAPHICS] . KW - Ammonia KW - Catalysis KW - CONVERSION KW - Diesel Engine KW - DOPED MN/TIO2 KW - Electrochemistry KW - HYDROLYSIS KW - In situ pH shift KW - NOX KW - OXIDATION KW - PRODUCTS KW - REMOVAL KW - SCR KW - SELECTIVE CATALYTIC-REDUCTION KW - Thermochemistry Y1 - 2019 U6 - https://doi.org/10.1007/s00706-019-02406-6 VL - 150 IS - 9 SP - 1633 EP - 1641 PB - Springer ER - TY - JOUR A1 - Schwanzer, Peter A1 - Rabl, Hans-Peter A1 - Loders, S. A1 - Seifert, P. A1 - Himmelstoss, S. A1 - Gaderer, Matthias T1 - Difference in the Tailpipe Particle Number by Consideration of Sub-23-nm Particles for Different Injection Settings of a GDI Engine JF - Emission control science and technology N2 - The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50% cutoff (D-50%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50%=10 nm and D-50%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall. KW - DoE KW - GDI KW - Particle number Y1 - 2019 U6 - https://doi.org/10.1007/s40825-019-0114-1 VL - 5 IS - 1 SP - 7 EP - 22 PB - Springer Nature ER - TY - GEN A1 - Altmann, Robert A1 - Rabl, Hans-Peter A1 - Gaderer, Matthias T1 - Phänomenologische Untersuchung des Einspritzverhaltens von Pflanzenölkraftstoff T2 - 3. Tagung der Fuels Joint Research Group (FJRG) "Kraftstoffe für die Mobilität von Morgen" Y1 - 2019 UR - https://www.researchgate.net/publication/335490299_Phanomenologische_Untersuchung_des_Einspritzverhaltens_von_Pflanzenolkraftstoff ER - TY - GEN A1 - Altmann, Robert A1 - Gebhard, Jürgen T1 - Phänomenologische Untersuchung des Einspritzprozesses eines Injektors aus dem Off-Highway-Segment mit Diesel- und Rapsölkraftstoff T2 - 16. Internationaler Fachkongress "Kraftstoffe der Zukunft 2019", Berlin Y1 - 2019 ER - TY - JOUR A1 - Braun, Peter A1 - Gebhard, Jürgen A1 - Matysik, Frank-Michael A1 - Rabl, Hans-Peter T1 - Potential Technical Approaches for Improving Low-Temperature NOx Conversion of Exhaust Aftertreatment Systems JF - Chemie Ingenieur Technik N2 - Lean-burn engines, such as diesel engines, are widely used in mobile and stationary applications. Operation of lean-burn engines leads to formation of distinct amounts of nitrogen oxides (NO and NO2). Efficient aftertreatment is mandatory to meet legal requirements, especially at low exhaust temperatures, as for the future a decline of the exhaust temperature level can be predicted due to improved engine efficiencies. Within this review, potential technical solutions to enhance the DeNO(x)-aftertreatment efficiency at low exhaust temperatures are presented. KW - DECOMPOSITION KW - Diesel Engine KW - Exhaust aftertreatment KW - IMPACT KW - Low-temperature DeNO(x) KW - NH3 KW - NITRIC-OXIDE KW - Nitrogen oxides KW - OXIDE CATALYST KW - PERFORMANCE KW - PYROLYSIS KW - SCR KW - Selective catalytic reduction KW - SELECTIVE CATALYTIC-REDUCTION KW - UREA HYDROLYSIS Y1 - 2018 U6 - https://doi.org/10.1002/cite.201700122 VL - 90 IS - 6 SP - 762 EP - 773 PB - WILEY-VCH ER -