TY - JOUR A1 - Burdin, Dmitrii A. A1 - Ekonomov, Nikolai A. A1 - Chashin, Dmitri V. A1 - Fetisov, Leonid Y. A1 - Fetisov, Yuri K. A1 - Shamonin (Chamonine), Mikhail T1 - Temperature Dependence of the Resonant Magnetoelectric Effect in Layered Heterostructures JF - Materials N2 - The dependence of the resonant direct magnetoelectric effect on temperature is studied experimentally in planar composite structures. Samples of rectangular shapes with dimensions of 5 mm x 20 mm employed ferromagnetic layers of either an amorphous (metallic glass) alloy or nickel with a thickness of 20-200 m and piezoelectric layers of single crystalline langatate material or lead zirconate titanate piezoelectric ceramics with a thickness of 500 m. The temperature of the samples was varied in a range between 120 and 390 K by blowing a gaseous nitrogen stream around them. It is shown that the effective characteristics of the magnetoelectric effectsuch as the mechanical resonance frequency f(r), the quality factor Q and the magnitude of the magnetoelectric coefficient (E) at the resonance frequencyare contingent on temperature. The interrelations between the temperature changes of the characteristics of the magnetoelectric effect and the temperature variations of the following material parametersYoung's modulus Y, the acoustic quality factor of individual layers, the dielectric constant epsilon, the piezoelectric modulus d of the piezoelectric layer as well as the piezomagnetic coefficients ((n)) of the ferromagnetic layerare established. The effect of temperature on the characteristics of the nonlinear magnetoelectric effect is observed for the first time. The results can be useful for designing magnetoelectric heterostructures with specified temperature characteristics, in particular, for the development of thermally stabilized magnetoelectric devices. KW - acoustic quality factor KW - composite structure KW - linear KW - magnetoelectric effect KW - magnetoelectric heterostructure KW - magnetostriction KW - nonlinear KW - piezoelectric KW - temperature dependence Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-32185 N1 - corresponding author: Mikhail Shamonin VL - 10 IS - 10 PB - MDPI ER - TY - JOUR A1 - Mayer, Matthias A1 - Rabindranath, Raman A1 - Börner, Juliane A1 - Hörner, Eva A1 - Bentz, Alexander A1 - Salgado, Josefina A1 - Han, Hong A1 - Böse, Holger A1 - Probst, Jörn A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Schlunck, Günther T1 - Ultra-Soft PDMS-Based Magnetoactive Elastomers as Dynamic Cell Culture Substrata JF - PLoS ONE N2 - Mechanical cues such as extracellular matrix stiffness and movement have a major impact on cell differentiation and function. To replicate these biological features in vitro, soft substrata with tunable elasticity and the possibility for controlled surface translocation are desirable. Here we report on the use of ultra-soft (Young’s modulus <100 kPa) PDMS-based magnetoactive elastomers (MAE) as suitable cell culture substrata. Soft non-viscous PDMS (<18 kPa) is produced using a modified extended crosslinker. MAEs are generated by embedding magnetic microparticles into a soft PDMS matrix. Both substrata yield an elasticity-dependent (14 vs. 100 kPa) modulation of α-smooth muscle actin expression in primary human fibroblasts. To allow for static or dynamic control of MAE material properties, we devise low magnetic field (≈40 mT) stimulation systems compatible with cell-culture environments. Magnetic field-instigated stiffening (14 to 200 kPa) of soft MAE enhances the spreading of primary human fibroblasts and decreases PAX-7 transcription in human mesenchymal stem cells. Pulsatile MAE movements are generated using oscillating magnetic fields and are well tolerated by adherent human fibroblasts. This MAE system provides spatial and temporal control of substratum material characteristics and permits novel designs when used as dynamic cell culture substrata or cell culture-coated actuator in tissue engineering applications or biomedical devices. Y1 - 2013 U6 - https://doi.org/10.1371/journal.pone.0076196 VL - 8 IS - 10 PB - PLOS ER - TY - JOUR A1 - Snarskii, Andrei A. A1 - Kalita, Viktor M. A1 - Shamonin (Chamonine), Mikhail T1 - Renormalization of the critical exponent for the shear modulus of magnetoactive elastomers JF - Scientific Reports N2 - It is shown that the critical exponent for the effective shear modulus of a composite medium where a compliant polymer matrix is filled with ferromagnetic particles may significantly depend on the external magnetic field. The physical consequence of this dependence is the critical behavior of the relative magnetorheological effect. Y1 - 2018 U6 - https://doi.org/10.1038/s41598-018-22333-6 N1 - Corresponding author: Mikhail Shamonin VL - 8 SP - 1 EP - 8 PB - Nature ER - TY - JOUR A1 - Dechant, Eduard A1 - Fedulov, Feodor A1 - Fetisov, Leonid Y. A1 - Shamonin (Chamonine), Mikhail T1 - Bandwidth Widening of Piezoelectric Cantilever Beam Arrays by Mass-Tip Tuning for Low-Frequency Vibration Energy Harvesting JF - Applied Science N2 - Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs). The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power. KW - array KW - BAND-PASS FILTERS KW - bandwidth KW - BIMORPH KW - Optimization KW - OUTPUT KW - PERFORMANCE KW - piezoelectric cantilever KW - POWER KW - vibration energy harvesting Y1 - 2017 U6 - https://doi.org/10.3390/app7121324 N1 - Corresponding Author: Mikhail Shamonin VL - 7 IS - 12 PB - MDPI ER - TY - JOUR A1 - Kreitmeier, Florian A1 - Chashin, Dmitri V. A1 - Fetisov, Yuri K. A1 - Fetisov, Leonid Y. A1 - Schulz, Irene A1 - Monkman, Gareth J. A1 - Shamonin (Chamonine), Mikhail T1 - Nonlinear Magnetoelectric Response of Planar Ferromagnetic-Piezoelectric Structures to Sub-Millisecond Magnetic Pulses JF - Sensors N2 - The magnetoelectric response of bi- and symmetric trilayer composite structures to pulsed magnetic fields is experimentally investigated in detail. The structures comprise layers of commercially available piezoelectric (lead zirconate titanate) and magnetostrictive (permendur or nickel) materials. The magnetic-field pulses have the form of a half-wave sine function with duration of 450 µs and amplitudes ranging from 500 Oe to 38 kOe. The time dependence of the resulting voltage is presented and explained by theoretical estimations. Appearance of voltage oscillations with frequencies much larger than the reciprocal pulse length is observed for sufficiently large amplitudes (~1-10 kOe) of the magnetic-field pulse. The origin of these oscillations is the excitation of bending and planar acoustic oscillations in the structures. Dependencies of the magnetoelectric voltage coefficient on the excitation frequency and the applied magnetic field are calculated by digital signal processing and compared with those obtained by the method of harmonic field modulation. The results are of interest for developing magnetoelectric sensors of pulsed magnetic fields as well as for rapid characterization of magnetoelectric composite structures. Y1 - 2012 U6 - https://doi.org/10.3390/s121114821 N1 - Corresponding author: Mikhail Shamonin VL - 12 IS - 11 SP - 14821 EP - 14837 PB - MDPI CY - Basel ER - TY - JOUR A1 - Apelsmeier, Andreas A1 - Gleixner, Ramona A1 - Mayer, Matthias A1 - Shamonin (Chamonine), Mikhail A1 - Schmauss, Bernhard T1 - Intensity referencing in an extrinsic optical fiber temperature sensor JF - Procedia Engineering N2 - Optical fiber sensors based on intensity measurement require some form of intensity referencing to avoid errors arising from parasitic losses. Known techniques of referencing such as balanced bridge, divided beam systems or two-wavelength referencing are not suitable for low-cost applications since they use relatively complicated optical components such as multiple LED sources, couplers, filters etc. In this work a novel method of referencing in an extrinsic optical fiber sensor system utilizing temperature dependence of absorption edge in a semiconductor crystal is described. The sensor system comprises a single LED source and no optical fiber junctions. The emission spectrum of an LED depends on its temperature. The reference is provided by controlling the temperature of an LED source and transmission measurements with different emission spectra. The entire process is controlled by a microprocessor unit. Performance of a sensor system is investigated and it is shown that the losses in connectors may be compensated for. KW - Extrinsic optical fiber sensor KW - Intensity referencing KW - Temperature measurement KW - Absorption edge KW - Semiconductor KW - Hot-spot measurement Y1 - 2010 U6 - https://doi.org/10.1016/j.proeng.2010.09.301 VL - 5 SP - 1095 EP - 1098 PB - Elsevier ER - TY - JOUR A1 - Snarskii, Andrei A. A1 - Shamonin (Chamonine), Mikhail A1 - Yuskevich, Pavel T1 - Effective medium theory for the elastic properties of composite materials with various percolation thresholds JF - Materials N2 - It is discussed that the classical effective medium theory for the elastic properties of random heterogeneous materials is not congruous with the effective medium theory for the electrical conductivity. In particular, when describing the elastic and electro-conductive properties of a strongly inhomogeneous two-phase composite material, the steep rise of effective parameters occurs at different concentrations. To achieve the logical concordance between the cross-property relations, a modification of the effective medium theory of the elastic properties is introduced. It is shown that the qualitative conclusions of the theory do not change, while a possibility of describing a broader class of composite materials with various percolation thresholds arises. It is determined under what conditions there is an elasticity theory analogue of the Dykhne formula for the effective conductivity. The theoretical results are supported by known experiments and show improvement over the existing approach. The introduction of the theory with the variable percolation threshold paves the way for describing the magnetorheological properties of magnetoactive elastomers. A similar approach has been recently used for the description of magneto-dielectric and magnetic properties. KW - elastic properties KW - effective medium approximation KW - self-consistent KW - random heterogeneous medium KW - two-phase composite material KW - percolation threshold Y1 - 2020 U6 - https://doi.org/10.3390/ma13051243 VL - 13 IS - 5 SP - 1 EP - 19 PB - MPDI CY - Basel ER - TY - JOUR A1 - Kostrov, Sergei A. A1 - Shamonin (Chamonine), Mikhail A1 - Stepanov, Gennady V. A1 - Kramarenko, Elena Yu T1 - Magnetodielectric Response of Soft Magnetoactive Elastomers: Effects of Filler Concentration and Measurement Frequency JF - International Journal of Molecular Sciences N2 - The magnetodielectric response of magnetoactive elastomers (MAEs) in its dependence on filler concentration, magnetic field, and test frequency is studied experimentally. MAEs are synthesized on the basis of a silicone matrix filled with spherical carbonyl iron particles characterized by a mean diameter of 4.5 mu m. The concentration of the magnetic filler within composite materials is equal to 70, 75, and 80 mass%. The effective lossless permittivity epsilon as well as the dielectric loss tan grow significantly when the magnetic field increases. The permittivity increases and the dielectric loss decreases with increasing filler concentration. In the measurement frequency range between 1 kHz and 200 kHz, the frequency hardly affects the values of epsilon and tan in the absence of a magnetic field. However, both parameters decrease considerably with the growing frequency in a constant magnetic field. The more strongly the magnetic field is applied, the larger the change in permittivity and loss tangent at the same test frequency is observed. An equivalent circuit formulation qualitatively describes the main tendencies of the magnetodielectric response. KW - dielectric loss KW - magnetic filler KW - MAGNETIC-FIELD KW - magnetoactive elastomers KW - magnetodielectric effect KW - permittivity Y1 - 2019 U6 - https://doi.org/10.3390/ijms20092230 VL - 20 IS - 9 SP - 1 EP - 13 PB - MDPI CY - Basel ER - TY - JOUR A1 - Kurzweil, Peter A1 - Shamonin (Chamonine), Mikhail T1 - State-of-Charge Monitoring by Impedance Spectroscopy during Long-Term Self-Discharge of Supercapacitors and Lithium-Ion Batteries JF - Batteries N2 - Frequency-dependent capacitance C(ω) is a rapid and reliable method for the determination of the state-of-charge (SoC) of electrochemical storage devices. The state-of-the-art of SoC monitoring using impedance spectroscopy is reviewed, and complemented by original 1.5-year long-term electrical impedance measurements of several commercially available supercapacitors. It is found that the kinetics of the self-discharge of supercapacitors comprises at least two characteristic time constants in the range of days and months. The curvature of the Nyquist curve at frequencies above 10 Hz (charge transfer resistance) depends on the available electric charge as well, but it is of little use for applications. Lithium-ion batteries demonstrate a linear correlation between voltage and capacitance as long as overcharge and deep discharge are avoided. KW - aging KW - capacitance KW - self-discharge KW - state-of-charge monitoring KW - supercapacitor Y1 - 2018 U6 - https://doi.org/10.3390/batteries4030035 VL - 4 IS - 3 SP - 1 EP - 13 PB - MPDI ER - TY - JOUR A1 - Nadzharyan, Timur A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Theoretical Modeling of Magnetoactive Elastomers on Different Scales: A State-of-the-Art Review JF - Polymers N2 - A review of the latest theoretical advances in the description of magnetomechanical effects and phenomena observed in magnetoactive elastomers (MAEs), i.e., polymer networks filled with magnetic micro- and/or nanoparticles, under the action of external magnetic fields is presented. Theoretical modeling of magnetomechanical coupling is considered on various spatial scales: from the behavior of individual magnetic particles constrained in an elastic medium to the mechanical properties of an MAE sample as a whole. It is demonstrated how theoretical models enable qualitative and quantitative interpretation of experimental results. The limitations and challenges of current approaches are discussed and some information about the most promising lines of research in this area is provided. The review is aimed at specialists involved in the study of not only the magnetomechanical properties of MAEs, but also a wide range of other physical phenomena occurring in magnetic polymer composites in external magnetic fields. KW - magnetodeformation KW - magnetorheological effect KW - mechanical properties KW - magnetic particles KW - theoretical modeling KW - magnetorheological elastomersn KW - magnetoactive elastomers Y1 - 2022 U6 - https://doi.org/10.3390/polym14194096 VL - 14 IS - 19 SP - 1 EP - 42 PB - MDPI ER - TY - JOUR A1 - Lohmeyer, Manfred A1 - Shamonin (Chamonine), Mikhail A1 - Hertel, Peter T1 - Integrated optical circulator based on radiatively coupled magneto-optic waveguides JF - Optical Engineering N2 - In a three-guide coupler with multimode central waveguide, more than two modes of the entire structure participate in the coupling between the outer waveguides. Using a three-mode approximation we found simple conditions for complete power transfer between the outer waveguides: the device length has to match certain multiples of the con- ventionally defined coupling length. The specific form of the relevant modes allows us to design a magneto-optic isolator or circulator with significantly reduced device length (as compared to the conventional nonreciprocal coupler). The performance of the proposed devices is simulated by propagating-mode calculations. Estimates for admissible fabrication tolerances for the layer thicknesses are presented. KW - integrated optics KW - magneto-optic circulator KW - magneto-optic isolator KW - radiatively coupled waveguides KW - three-guide coupler Y1 - 1997 U6 - https://doi.org/10.1117/1.601255 VL - 36 IS - 3 SP - 889 EP - 895 PB - SPIE ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Klepp, Jürgen A1 - Lemmel, Hartmut A1 - Shamonin (Chamonine), Mikhail T1 - Feasibility of Probing the Filler Restructuring in Magnetoactive Elastomers by Ultra-Small-Angle Neutron Scattering JF - Applied Sciences N2 - Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 x 10(-5) and 1.85 x 10(-4) angstrom(-1). It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered. KW - Anisotropy KW - Ferrofluids KW - hysteresis KW - magnetoactive elastomer KW - magnetorheological elastomer KW - Matrix KW - MIicrostructure KW - restructuring of the filler KW - ultra-small-angle neutron scattering Y1 - 2021 U6 - https://doi.org/10.3390/app11104470 VL - 11 IS - 10 SP - 1 EP - 9 PB - MDPI CY - Basel ER - TY - JOUR A1 - Glavan, Gašper A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail T1 - On the Piezomagnetism of Magnetoactive Elastomeric Cylinders in Uniform Magnetic Fields: Height Modulation in the Vicinity of an Operating Point by Time-Harmonic Fields JF - Polymers N2 - Soft magnetoactive elastomers (MAEs) are currently considered to be promising materials for actuators in soft robotics. Magnetically controlled actuators often operate in the vicinity of a bias point. Their dynamic properties can be characterized by the piezomagnetic strain coefficient, which is a ratio of the time-harmonic strain amplitude to the corresponding magnetic field strength. Herein, the dynamic strain response of a family of MAE cylinders to the time-harmonic (frequency of 0.1-2.5 Hz) magnetic fields of varying amplitude (12.5 kA/m-62.5 kA/m), superimposed on different bias magnetic fields (25-127 kA/m), is systematically investigated for the first time. Strain measurements are based on optical imaging with sub-pixel resolution. It is found that the dynamic strain response of MAEs is considerably different from that in conventional magnetostrictive polymer composites (MPCs), and it cannot be described by the effective piezomagnetic constant from the quasi-static measurements. The obtained maximum values of the piezomagnetic strain coefficient (∼102 nm/A) are one to two orders of magnitude higher than in conventional MPCs, but there is a significant phase lag (35-60°) in the magnetostrictive response with respect to an alternating magnetic field. The experimental dependencies of the characteristics of the alternating strain on the amplitude of the alternating field, bias field, oscillation frequency, and aspect ratio of cylinders are given for several representative examples. It is hypothesized that the main cause of observed peculiarities is the non-linear viscoelasticity of these composite materials. Y1 - 2024 U6 - https://doi.org/10.3390/polym16192706 N1 - Corresponding author der OTH Regensburg: Gašper Glavan VL - 16 IS - 19 ER - TY - JOUR A1 - Jezeršek, Matija A1 - Kriegl, Raphael A1 - Kravanja, Gaia A1 - Hribar, Luka A1 - Drevenšek‐Olenik, Irena A1 - Unold, Heiko A1 - Shamonin (Chamonine), Mikhail T1 - Control of Droplet Impact through Magnetic Actuation of Surface Microstructures JF - Advanced Materials Interfaces N2 - An effective method for on-demand control over the impact dynamics of droplets on a magnetoresponsive surface is reported. The surface is comprised of micrometer-sized lamellas from a magnetoactive elastomer on a copper substrate. The surface itself is fabricated using laser micromachining. The orientation of the lamellae is switched from edge-on (orthogonal to the surface) to face-on (parallel to the surface) by changing the direction of a moderate (<250 mT) magnetic field. This simple actuation technique can significantly change the critical velocities of droplet rebound, deposition, and splashing. Rebound and deposition regimes can be switched up to Weber number We < 13 ± 3, while deposition and splashing can be switched in the range of 32 < We < 52. Because a permanent magnet is used, no permanent power supply is required for maintaining the particular regime of droplet impact. The presented technology is highly flexible and enables selective fabrication and actuation of microstructures on complex devices. It has great potential for applications in soft robotics, microfluidics, and advanced thermal management. Y1 - 2023 U6 - https://doi.org/10.1002/admi.202202471 VL - 10 IS - 11 PB - Wiley ER - TY - JOUR A1 - Glavan, Gašper A1 - Kettl, Wolfgang A1 - Brunhuber, Alexander A1 - Shamonin (Chamonine), Mikhail A1 - Drevenšek‐Olenik, Irena T1 - Effect of Material Composition on Tunable Surface Roughness of Magnetoactive Elastomers JF - Polymers N2 - We investigated magnetic-field-induced modifications of the surface roughness of magnetoactive elastomers (MAEs) with four material compositions incorporating two concentrations of ferromagnetic microparticles (70 wt% and 80 wt%) and exhibiting two shear storage moduli of the resulting composite material (about 10 kPa and 30 kPa). The analysis was primarily based on spread optical reflection measurements. The surfaces of all four materials were found to be very smooth in the absence of magnetic field (RMS roughness below 50 nm). A maximal field-induced roughness modification (approximately 1 m/T) was observed for the softer material with the lower filler concentration, and a minimal modification (less than 50 nm/T) was observed for the harder material with the higher filler concentration. All four materials showed a significant decrease in the total optical reflectivity with an increasing magnetic field as well. This effect is attributed to the existence of a distinct surface layer that is depleted of microparticles in the absence of a magnetic field but becomes filled with particles in the presence of the field. We analyzed the temporal response of the reflective properties to the switching on and off of the magnetic field and found switching-on response times of around 0.1 s and switching-off response times in the range of 0.3-0.6 s. These observations provide new insight into the magnetic-field-induced surface restructuring of MAEs and may be useful for the development of magnetically reconfigurable elastomeric optical surfaces. KW - magnetically tunable surface reflectivity KW - magnetically tunable surface roughness KW - magnetorheological elastomer KW - magnetorheological polymers KW - surface properties Y1 - 2019 U6 - https://doi.org/10.3390/polym11040594 N1 - Corresponding author: Gašper Glavan VL - 11 IS - 4 SP - 1 EP - 13 PB - MDPI CY - Basel ER - TY - JOUR A1 - Straus, Izidor A1 - Kravanja, Gaia A1 - Hribar, Luka A1 - Kriegl, Raphael A1 - Jezeršek, Matija A1 - Shamonin (Chamonine), Mikhail A1 - Drevenšek‐Olenik, Irena A1 - Kokot, Gašper T1 - Surface Modification of Magnetoactive Elastomers by Laser Micromachining JF - Materials N2 - It has been recently demonstrated that laser micromachining of magnetoactive elastomers is a very convenient method for fabricating dynamic surface microstructures with magnetically tunable properties, such as wettability and surface reflectivity. In this study, we investigate the impact of the micromachining process on the fabricated material’s structural properties and its chemical composition. By employing scanning electron microscopy, we investigate changes in size distribution and spatial arrangement of carbonyl iron microparticles dispersed in the polydimethylsiloxane (PDMS) matrix as a function of laser irradiation. Based on the images obtained by a low vacuum secondary electron detector, we analyze modifications of the surface topography. The results show that most profound modifications occur during the low-exposure (8 J/cm^2) treatment of the surface with the laser beam. Our findings provide important insights for developing theoretical models of functional properties of laser-sculptured microstructures from magnetoactive elastomers. KW - magnetoactive elastomer KW - MAE KW - laser micromachining KW - particle distributions KW - SEM Y1 - 2024 U6 - https://doi.org/10.3390/ma17071550 N1 - This research was funded by the Slovenian Research Agency (ARRS): research programs P1-0192, P2-0392, and research project J1-3006. The work of R.K. and M.S. in Regensburg was funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation), project number 437391117. VL - 2024 IS - 17 / 7 PB - MDPI AG CY - Basel, Switzerland ER - TY - JOUR A1 - Lovšin, Matija A1 - Brandl, Dominik A1 - Glavan, Gašper A1 - Belyaeva, Inna A. A1 - Cmok, Luka A1 - Coga, Lucija A1 - Kalin, Mitjan A1 - Shamonin (Chamonine), Mikhail A1 - Drevenšek‐Olenik, Irena T1 - Reconfigurable Surface Micropatterns Based on the Magnetic Field-Induced Shape Memory Effect in Magnetoactive Elastomers JF - Polymers N2 - A surface relief grating with a period of 30 mu m is embossed onto the surface of magnetoactive elastomer (MAE) samples in the presence of a moderate magnetic field of about 180 mT. The grating, which is represented as a set of parallel stripes with two different amplitude reflectivity coefficients, is detected via diffraction of a laser beam in the reflection configuration. Due to the magnetic-field-induced plasticity effect, the grating persists on the MAE surface for at least 90 h if the magnetic field remains present. When the magnetic field is removed, the diffraction efficiency vanishes in a few minutes. The described effect is much more pronounced in MAE samples with larger content of iron filler (80 wt%) than in the samples with lower content of iron filler (70 wt%). A simple theoretical model is proposed to describe the observed dependence of the diffraction efficiency on the applied magnetic field. Possible applications of MAEs as magnetically reconfigurable diffractive optical elements are discussed. It is proposed that the described experimental method can be used as a convenient tool for investigations of the dynamics of magnetically induced plasticity of MAEs on the micrometer scale. KW - ADHESION KW - friction KW - magnetoactive elastomers KW - magnetorheological elastomer KW - optical diffraction KW - shape memory effect KW - surface microstructuring KW - TEMPERATURE Y1 - 2021 U6 - https://doi.org/10.3390/polym13244422 VL - 13 IS - 24 PB - MDPI ER - TY - JOUR A1 - Kriegl, Raphael A1 - Kravanja, Gaia A1 - Hribar, Luka A1 - Čoga, Lucija A1 - Drevenšek‐Olenik, Irena A1 - Jezeršek, Matija A1 - Kalin, Mitjan A1 - Shamonin (Chamonine), Mikhail T1 - Microstructured Magnetoactive Elastomers for Switchable Wettability JF - Polymers N2 - We demonstrate the control of wettability of non-structured and microstructured magnetoactive elastomers (MAEs) by magnetic field. The synthesized composite materials have a concentration of carbonyl iron particles of 75 wt.% (≈27 vol.%) and three different stiffnesses of the elastomer matrix. A new method of fabrication of MAE coatings on plastic substrates is presented, which allows one to enhance the response of the apparent contact angle to the magnetic field by exposing the particle-enriched side of MAEs to water. A magnetic field is not applied during crosslinking. The highest variation of the contact angle from (113 ± 1)° in zero field up to (156 ± 2)° at about 400 mT is achieved in the MAE sample with the softest matrix. Several lamellar and pillared MAE structures are fabricated by laser micromachining. The lateral dimension of surface structures is about 50 µm and the depth varies between 3 µm and 60 µm. A systematic investigation of the effects of parameters of laser processing (laser power and the number of passages of the laser beam) on the wetting behavior of these structures in the absence and presence of a magnetic field is performed. In particular, strong anisotropy of the wetting behavior of lamellar structures is observed. The results are qualitatively discussed in the framework of the Wenzel and Cassie-Baxter models. Finally, directions of further research on magnetically controlled wettability of microstructured MAE surfaces are outlined. The obtained results may be useful for the development of magnetically controlled smart surfaces for droplet-based microfluidics. Y1 - 2022 U6 - https://doi.org/10.3390/polym14183883 N1 - Corresponding authors: Raphael Kriegl und Mikhail Shamonin VL - 14 IS - 18 SP - 1 EP - 21 PB - MDPI ER - TY - JOUR A1 - Savelev, Dmitrii V. A1 - Glavan, Gašper A1 - Belan, Viktoria O. A1 - Belyaeva, Inna A. A1 - Fetisov, Leonid Y. A1 - Shamonin (Chamonine), Mikhail T1 - Resonant Magnetoelectric Effect at Low Frequencies in Layered Polymeric Cantilevers Containing a Magnetoactive Elastomer JF - Applied Sciences N2 - In this work, the resonance enhancement of magnetoelectric (ME) coupling at the two lowest bending resonance frequencies was investigated in layered cantilever structures comprising a magnetoactive elastomer (MAE) slab and a commercially available piezoelectric polymer multilayer. A cantilever was fixed at one end in the horizontal plane and the magnetic field was applied horizontally. Five composite structures, each containing an MAE layer of different thicknesses from 0.85 to 4 mm, were fabricated. The fundamental bending resonance frequency in the absence of a magnetic field varied between roughly 23 and 55 Hz. It decreased with the increasing thickness of the MAE layer, which was explained by a simple theory. The largest ME voltage coefficient of about 7.85 V/A was measured in a sample where the thickness of the MAE layer was ≈2 mm. A significant increase in the bending resonance frequencies in the applied DC magnetic field of 240 kA/m up to 200% was observed. The results were compared with alternative designs for layered multiferroic structures. Directions for future research were also discussed. KW - flexible composite KW - low frequency KW - magnetoactive elastomer KW - magnetoelectric effect KW - piezoelectric polymer Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-30637 N1 - corresponding authors: Dmitry V. Saveliev and Mikhail Shamonin VL - 12 IS - 4 SP - 1 EP - 13 PB - MPDI ER - TY - JOUR A1 - Fetisov, Yuri K. A1 - Chashin, Dmitri V. A1 - Savelev, Dmitrii V. A1 - Fetisov, Leonid Y. A1 - Shamonin (Chamonine), Mikhail T1 - Anisotropic Magnetoelectric Effect in a Planar Heterostructure Comprising Piezoelectric Ceramics and Magnetostrictive Fibrous Composite JF - Materials N2 - The direct magnetoelectric (ME) effect is investigated in a planar structure comprising mechanically coupled layers of a magnetostrictive fibrous composite (MFC) and a piezoelectric ceramics (lead zirconate titanate, PZT). The MFC is an array of Ni-wires with a diameter of 200 mu m that are aligned parallel to each other in a single layer. The wires are separated by a distance of 250 or 500 mu m and fixed in a polyamide matrix. The structure was placed in a tangential constant field H and was excited by an alternating magnetic field h parallel to H, while the voltage generated by the PZT layer was measured. The resulting field dependences of the magnetization M(H) and the magnetostriction lambda(H) were determined by the orientation of the field H in the plane of the structure and the distance between the Ni-wires. The ME coupling coefficient of the structure decreased from 4.8 to 0.25 V/A when the orientation of H was changed from parallel to perpendicular to Ni-wires. With an increase in the excitation field amplitude h, a nonlinear ME effect in the output voltage, namely frequency doubling, was observed. The frequency and field dependences of the efficiency of the ME transduction in the MFC-piezoelectric heterostructure are well described by the existing theory. KW - composite KW - frequency doubling KW - heterostructure KW - magnetoelectric effect KW - magnetostrictive fiber KW - piezoelectric ceramic material Y1 - 2019 U6 - https://doi.org/10.3390/ma12193228 N1 - Corresponding authors: Yuri Fetisov, Mikhail Shamonin VL - 12 IS - 19 SP - 1 EP - 13 PB - MDPI CY - Basel ER - TY - JOUR A1 - Savelev, Dmitrii V. A1 - Chashin, Dmitri V. A1 - Fetisov, Leonid Y. A1 - Shamonin (Chamonine), Mikhail A1 - Fetisov, Yuri K. T1 - Ceramic-Heterostructure-Based Magnetoelectric Voltage Transformer with an Adjustable Transformation Ratio JF - Materials N2 - A voltage transformer employing the magnetoelectric effect in a composite ceramic heterostructure with layers of a magnetostrictive nickel–cobalt ferrite and a piezoelectric lead zirconate–titanate is described. In contrast to electromagnetic and piezoelectric transformers, a unique feature of the presented transformer is the possibility of tuning the voltage transformation ratio K using a dc magnetic field. The dependences of the transformer characteristics on the frequency and the amplitude of the input voltage, the strength of the control magnetic field and the load resistance are investigated. The transformer operates in the voltage range between 0 and 112 V, and the voltage transformation ratio K is tuned between 0 and 14.1 when the control field H changes between 0 and 6.4 kA/m. The power at the transformer output reached 63 mW, and the power conversion efficiency was 34%. The methods for calculation of the frequency response, and the field and load characteristics of the transformer are proposed. The ways to improve performance characteristics of magnetoelectric transformers and their possible application areas are discussed. KW - magnetoelectric effect KW - piezoelectric effect KW - voltage transformer KW - composite material KW - magnetostriction Y1 - 2020 U6 - https://doi.org/10.3390/ma13183981 VL - 13 IS - 18 SP - 1 EP - 13 PB - MDPI ER - TY - JOUR A1 - Glavan, Gašper A1 - Belyaeva, Inna A. A1 - Ruwisch, Kevin A1 - Wollschlaeger, Joachim A1 - Shamonin (Chamonine), Mikhail T1 - Magnetoelectric Response of Laminated Cantilevers Comprising a Magnetoactive Elastomer and a Piezoelectric Polymer, in Pulsed Uniform Magnetic Fields JF - Sensors N2 - The voltage response to pulsed uniform magnetic fields and the accompanying bending deformations of laminated cantilever structures are investigated experimentally in detail. The structures comprise a magnetoactive elastomer (MAE) slab and a commercially available piezoelectric polymer multilayer. The magnetic field is applied vertically and the laminated structures are customarily fixed in the horizontal plane or, alternatively, slightly tilted upwards or downwards. Six different MAE compositions incorporating three concentrations of carbonyl iron particles (70 wt%, 75 wt% and 80 wt%) and two elastomer matrices of different stiffness are used. The dependences of the generated voltage and the cantilever's deflection on the composition of the MAE layer and its thickness are obtained. The appearance of the voltage between the electrodes of a piezoelectric material upon application of a magnetic field is considered as a manifestation of the direct magnetoelectric (ME) effect in a composite laminated structure. The ME voltage response increases with the increasing total quantity of the soft-magnetic filler in the MAE layer. The relationship between the generated voltage and the cantilever's deflection is established. The highest observed peak voltage around 5.5 V is about 8.5-fold higher than previously reported values. The quasi-static ME voltage coefficient for this type of ME heterostructures is about 50 V/A in the magnetic field of approximate to 100 kA/m, obtained for the first time. The results could be useful for the development of magnetic field sensors and energy harvesting devices relying on these novel polymer composites. KW - cantilever KW - composites KW - DEMAGNETIZING FACTORS KW - direct magnetoelectric effect KW - laminated structure KW - magnetic field sensor KW - magnetoactive elastomer KW - piezoelectric polymer Y1 - 2021 U6 - https://doi.org/10.3390/s21196390 N1 - Corresponding authors: Gašper Glavan, Mikhail Shamonin VL - 21 IS - 19 SP - 1 EP - 19 PB - MDPI CY - Basel ER - TY - JOUR A1 - Savelev, Dmitrii V. A1 - Belyaeva, Inna A. A1 - Chashin, Dmitri V. A1 - Fetisov, Leonid Y. A1 - Romeis, Dirk A1 - Kettl, Wolfgang A1 - Kramarenko, Elena Yu A1 - Saphiannikova, Marina A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail T1 - Giant extensional strain of magnetoactive elastomeric cylinders in uniform magnetic fields JF - Materials N2 - Elongations of magnetoactive elastomers (MAEs) under ascending–descending uniform magnetic fields were studied experimentally using a laboratory apparatus specifically designed to measure large extensional strains (up to 20%) in compliant MAEs. In the literature, such a phenomenon is usually denoted as giant magnetostriction. The synthesized cylindrical MAE samples were based on polydimethylsiloxane matrices filled with micrometer-sized particles of carbonyl iron. The impact of both the macroscopic shape factor of the samples and their magneto-mechanical characteristics were evaluated. For this purpose, the aspect ratio of the MAE cylindrical samples, the concentration of magnetic particles in MAEs and the effective shear modulus were systematically varied. It was shown that the magnetically induced elongation of MAE cylinders in the maximum magnetic field of about 400 kA/m, applied along the cylinder axis, grew with the increasing aspect ratio. The effect of the sample composition is discussed in terms of magnetic filler rearrangements in magnetic fields and the observed experimental tendencies are rationalized by simple theoretical estimates. The obtained results can be used for the design of new smart materials with magnetic-field-controlled deformation properties, e.g., for soft robotics. KW - magnetostriction KW - magnetoactive elastomer KW - extensional strain KW - hysteresis KW - magnetomechanical effect KW - magnetodeformation Y1 - 2020 U6 - https://doi.org/10.3390/ma13153297 SN - 1996-1944 N1 - Corresponding author: Mikhail Shamonin VL - 13 IS - 15 SP - 1 EP - 17 PB - MDPI CY - Basel ER - TY - JOUR A1 - Dillinger, Andrea Elisabeth A1 - Weber, Gregor R. A1 - Mayer, Matthias A1 - Schneider, Magdalena A1 - Göppner, Corinna A1 - Ohlmann, Andreas A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Fuchshofer, Rudolf A1 - Keller, Kate A1 - Lozano, Diana C. A1 - Clark, Abbot T1 - CCN2/CTGF-A Modulator of the Optic Nerve Head Astrocyte JF - Frontiers in cell and developmental biology (Front Cell Dev Biol.) N2 - In primary open-angle glaucoma (POAG), a neurodegenerative disease of the optic nerve (ON) and leading cause of blindness, the optic nerve head (ONH) undergoes marked structural extracellular matrix (ECM) changes, which contribute to its permanent deformation and to degeneration of ON axons. The remodeling process of the ECM causes changes in the biomechanical properties of the ONH and the peripapillary sclera, which is accompanied by an increased reactivity of the resident astrocytes. The molecular factors involved in the remodeling process belong to the Transforming growth factor (TGF)-β superfamily, especially TGF-β2. In previous publications we showed that TGF-β2 induced ECM alterations are mediated by Cellular Communication Network Factor (CCN)2/Connective Tissue Growth Factor (CTGF) and recently we showed that CCN2/CTGF is expressed by astrocytes of the ON under normal conditions. In this study we wanted to get a better understanding of the function of CCN2/CTGF under normal and pathologic conditions. To this end, we analyzed the glial lamina and peripapillary sclera of CCN2/CTGF overexpressing mice and studied the effect of CCN2/CTGF and increasing substratum stiffness on murine ON astrocytes in vitro. We observed enhanced astrocyte reactivity in the ONH, increased ECM protein synthesis in the peripapillary sclera and increased Ccn2/Ctgf expression in the ONH during the pathologic development in situ. CCN2/CTGF treatment of primary murine ON astrocytes induced a higher migration rate, and increase of ECM proteins including fibronectin, elastin and collagen type III. Furthermore, the astrocytes responded to stiffer substratum with increased glial fibrillary acidic protein, vimentin, actin and CCN2/CTGF synthesis. Finally, we observed the reinforced appearance of CCN2/CTGF in the lamina cribrosa of glaucomatous patients. We conclude that reactive changes in ONH astrocytes, induced by the altered biomechanical characteristics of the region, give rise to a self-amplifying process that includes increased TGF-β2/CCN2/CTGF signaling and leads to the synthesis of ECM molecules and cytoskeleton proteins, a process that in turn augments the stiffness at the ONH. Such a scenario may finally result in a vicious circle in the pathogenesis of POAG. The transgenic CTGF-overexpressing mouse model might be an optimal model to study the chronic pathological POAG changes in the ONH. KW - astrocytes KW - extracellar matrix KW - glaucoma KW - glial lamina KW - growth factors KW - optic nerve KW - stiffness Y1 - 2022 U6 - https://doi.org/10.3389/fcell.2022.864433 VL - 10 PB - frontiers ER - TY - JOUR A1 - Glavan, Gašper A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail T1 - Multiferroic Cantilevers Containing a Magnetoactive Elastomer: Magnetoelectric Response to Low-Frequency Magnetic Fields of Triangular and Sinusoidal Waveform JF - Sensors N2 - In this work, multiferroic cantilevers comprise a layer of a magnetoactive elastomer (MAE) and a commercially available piezoelectric polymer-based vibration sensor. The structures are fixed at one end in the horizontal plane and the magnetic field is applied vertically. First, the magnetoelectric (ME) response to uniform, triangle-wave magnetic fields with five different slew rates is investigated experimentally. Time and field dependences of the generated voltage, electric charge, and observed mechanical deflection are obtained and compared for four different thicknesses of the MAE layer. The ME responses to triangular and sinusoidal wave excitations are examined in contrast. Second, the ME response at low frequencies (≤3 Hz) is studied by the standard method of harmonic magnetic field modulation. The highest ME coupling coefficient is observed in the bias magnetic field strength of ≈73 kA/m and it is estimated to be about 3.3 ns/m (ME voltage coefficient ≈ 25 V/A) at theoretically vanishing modulation frequency (f→0 Hz). Presented results demonstrate that the investigated heterostructures are promising for applications as magnetic-field sensors and energy harvesting devices. KW - magnetoactive elastomer KW - piezoelectric polymer KW - multilayer cantilever KW - direct magnetoelectric effect KW - magnetic field sensing Y1 - 2022 U6 - https://doi.org/10.3390/s22103791 N1 - Corresponding authors: Gašper Glavan und Mikhail Shamonin Veröffentlichtes Datenset: https://doi.org/10.5281/zenodo.14651784 VL - 22 IS - 10 SP - 1 EP - 17 PB - MDPI CY - Basel ER -