TY - JOUR A1 - Mennicken, Max A1 - Peter, Sophia Katharina A1 - Kaulen, Corinna A1 - Simon, Ulrich A1 - Karthäuser, Silvia T1 - Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes JF - Beilstein journal of nanotechnology N2 - The performance of nanoelectronic and molecular electronic devices relies strongly on the employed functional units and their addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands of gold nanoparticles and contacted by nanoelectrodes. The resulting small-area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport mechanism, that is, thermally activated hopping conduction in the case of Ru-terpyridine wire devices or sequential tunneling in nanoparticle-based devices. Furthermore, the conductance switching of nanoparticle-based devices upon 530 nm irradiation was attributed to plasmon-induced metal-to-ligand charge transfer in the Ru-terpyridine complexes used as switching ligands. Finally, our results reveal a superior device performance of nanoparticle-based devices compared to molecular wire devices based on Ru-terpyridine complexes as functional units. KW - Ru-terpyridine wires KW - conductance switching KW - gold nanoparticles KW - nanoelectronic devices KW - optical addressing Y1 - 2022 U6 - https://doi.org/10.3762/bjnano.13.16 VL - 13 SP - 219 EP - 229 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften ER - TY - JOUR A1 - Hausladen, Matthias A1 - Buchner, Philipp A1 - Bartl, Mathias A1 - Bachmann, Michael A1 - Schreiner, Rupert T1 - Integrated multichip field emission electron source fabricated by laser-micromachining and MEMS technology JF - Journal of Vacuum Science & Technology B N2 - In this work, high-current field emission electron source chips were fabricated using laser-micromachining and MEMS technology. The resulting chips were combined with commercially available printed circuit boards (PCBs) to obtain a multichip electron source. By controlling the separate electron sources using an external current control circuit, we were able to divide the desired total current evenly across the individual chips deployed in the PCB-carrier. In consequence, we were able to show a decreased degradation due to the reduced current load per chip. First, a single electron source chip was measured without current regulation. A steady-state emission current of 1 mA with a high stability of ±1.3% at an extraction voltage of 250 V was observed. At this current level, a mean degradation slope of −0.7 μA/min with a nearly perfect transmission ratio of 99% ± 0.4% was determined. The measurements of a fully assembled multichip PCB-carrier electron source, using a current control circuit for regulation, showed that an even distribution of the desired total current led to a decreased degradation. This was determined by the increase in the required extraction voltage over time. For this purpose, two current levels were applied to the electron source chips of the PCB-carrier using an external current control circuit. First, 300 μA total current was evenly distributed among the individual electron source chips followed by the emission of 300 μA per electron source chip. This allows the observation of the influence of a distributed and nondistributed total current, carried by the electron source chips. Thereby, we obtained an increase in the mean degradation slope from +0.011 V/min (300 μA distributed) to +0.239 V/min (300 μA per chip), which is approximately 21 times higher. Moreover, our current control circuit improved the current stability to under 0.1% for both current levels, 300 μA distributed and 300 μA per chip. KW - MEMS technology KW - Field emitter arrays KW - Electron sources KW - Laser micromachining Y1 - 2024 U6 - https://doi.org/10.1116/6.0003233 VL - 42 IS - 1 PB - AIP Publishing ER - TY - JOUR A1 - Remškar, Maja A1 - Jelenc, Janez A1 - Czepurnyi, Nikolai A1 - Malok, Matjaž A1 - Pirker, Luka A1 - Schreiner, Rupert A1 - Hüttel, Andreas K. T1 - Modulations of the work function and morphology of a single MoS2 nanotube by charge injection JF - Nanoscale Advances N2 - Both the miniaturization of transistor components and the ongoing investigation of material systems with potential for quantum information processing have significantly increased current interest of researchers in semiconducting inorganic nanotubes. Here we report on an additional outstanding aspect of these nanostructures, namely the intrinsic coupling of electronic and mechanical properties. We observe electronic and morphology changes in a single MoS2 nanotube, exposed to charge injections by means of an atomic-force-microscopy tip. An elliptic deformation of the nanotube and helical twisting of the nanotube are visible, consistent with the reverse piezoelectric effect. Work-function changes are found to be dependent on the polarity of the injected carriers. An unexpected long-term persistence of the shape deformations is observed and explained with accumulation of structural defects and the resultant strain, which could cause a memory-like charge confinement and a long lasting modulation of the work function. Y1 - 2024 U6 - https://doi.org/10.1039/d4na00490f SN - 2516-0230 PB - Royal Society of Chemistry (RSC) ER - TY - CHAP A1 - Ali, Md. Wajed A1 - Ahmmed, Tanvir A1 - Al Emran, Md A1 - Roy, Dipon A1 - Refat, Kawsar Ahmed A1 - Khan, Robiul T1 - Driver Fatigue Detection using CWT-Extracted Features and a Deep Learning Approach (CNNLSTM) T2 - 2024 IEEE International Conference on Biomedical Engineering, Computer and Information Technology for Health (BECITHCON), 28-29 Nov. 2024, Dhaka, Bangladesh N2 - Driver fatigue is a leading reason behind traffic accidents globally, resulting in significant threats to public safety and substantial economic costs. Electroencephalography (EEG) has shown to be a critical tool for identifying driver fatigue as it can record brain activity associated with sleepiness, which gives it an advantage over other physiological modalities. Although raw EEG data can provide insightful information, accurate fatigue identification requires strong feature extraction techniques because of the inherent complexity of the data. This emphasizes how urgent it is to investigate revolutionary deep-learning architectures that can successfully extract discriminative features from raw EEG data. This study provides an innovative framework for driver fatigue identification from EEG that combines continuous wavelet transform (CWT) with convolutional neural networks (CNN) and long-short term memory (LSTM). In order to gain the advantage over the drawbacks of manual feature extraction, this study generates time-frequency spectrum representations of EEG data using the CWT. Following extracting information, each channel’s time-frequency images are concatenated and fed into a CNN-LSTM architecture. This combination models the temporal and spatial characteristics of the EEG data and automatically learns discriminative features for identifying drivers’ normal and fatigued states. A publicly available EEG dataset with recordings from twelve subjects is used to evaluate the proposed CWT-CNN-LSTM architecture. The result shows a prominent classification accuracy of 98.34% for both the average of each subject and combined subjects. These findings show how well the CNN-LSTM framework captures EEG patterns associated with fatigue, which may result in more reliable driver fatigue detection systems and improved traffic safety. KW - Accuracy KW - Brain modeling KW - CNN KW - Continuous wavelet transforms KW - Convolutional neural networks KW - CWT KW - Deep learning KW - Deep Learning (DL) KW - Driver Fatigue KW - EEG KW - Electroencephalography KW - Fatigue KW - Feature extraction KW - Long short term memory KW - LSTM KW - Time-frequency analysis Y1 - 2025 UR - https://ieeexplore.ieee.org/document/10962632 SN - 979-8-3315-3435-6 U6 - https://doi.org/10.1109/BECITHCON64160.2024.10962632 SP - 77 EP - 82 PB - IEEE CY - Piscataway, NJ ER - TY - JOUR A1 - Haynack, Alexander A1 - Timothy, Jithender J. A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Analyse des Frost‐Tausalz‐Widerstands zementgebundener Baustoffe mittels 3D‐Laserscanning JF - ce/papers: Proceedings in Civil Engineering N2 - Eine Herausforderung performancebasierter Prüfverfahren zur Bewertung der Dauerhaftigkeit ist die Beschleunigung natürlicher Mechanismen. Dies ist notwendig, um innerhalb kurzer Zeit die Langzeit-Leistungsfähigkeit ermitteln zu können. Die Bestimmung der Frost-Tausalzbeständigkeit von Beton kann durch den CDF-Test erfolgen, welcher für Betone mit ausreichendem Frost-Tausalz-Widerstand sehr gut funktioniert. Bei Proben mit einer unzureichenden bzw. unbekannten Performance können erhöhte Randabwitterungen auftreten, welche durch das Ablösen des seitlichen Abdichtbands entstehen. Der zunehmende Randeinfluss führt so zu einer Verfälschung der Ergebnisse und zu einer Unterschätzung der tatsächlichen Performance des Bauteils. In diesem Beitrag werden Mörtel- und Betonprobekörper mit unterschiedlichen Abwitterungsraten in Anlehnung an das CDF-Verfahren untersucht. Zusätzlich wird die Oberflächenschädigung der Proben anhand einer neuartigen Messmethode mittels hochauflösendem 3D-Laserscanning ausgewertet. Die Ergebnisse zeigen, dass die Randeffekte mit der Laserscan-Methode umgangen und vergleichbare Ergebnisse zu den CDF-Untersuchungen erzielt werden können. Somit können Betone ohne Randeinflüsse charakterisiert und eine präzise Prognose der Langzeitbeständigkeit getroffen werden. KW - Beton KW - Mörtel KW - Frost-Tausalz-Widerstand KW - Dauerhaftigkeit KW - 3D-Laserscanning Y1 - 2023 U6 - https://doi.org/10.1002/cepa.2951 SN - 2509-7075 VL - 6 IS - 6 SP - 1189 EP - 1196 PB - Ernst & Sohn ER - TY - JOUR A1 - Peter, Daniel A1 - Dalmer, Michael A1 - Lechner, Alfred A1 - Gigler, Alexander M. A1 - Stark, Robert W. A1 - Bensch, Wolfgang T1 - The influence of liquid media on the fracture strength of polysilicon nanostructures JF - Solid State Phenomena N2 - The mechanical stability of nanostructures depends on the surrounding medium. Their stability was probed by lateral force microscopy in liquid media. Previously reported data on water and isopropanol showed an increase in the fracture strength for the latter. Further tests with other alcohols (ethanol, 1-butanol) also showed an increasing strength. The interface between the liquid and the surface is the decisive factor for the influence of the media. When altering the interface with a cationic surfactant or a self-assembled monolayer, an increase of the fracture force by 100 % compared to de-ionized water could be measured. KW - pattern collapse KW - fracture strength KW - damage KW - atomic force microscopy Y1 - 2012 U6 - https://doi.org/10.4028/www.scientific.net/SSP.187.127 VL - 187 SP - 127 EP - 130 PB - Trans Tech Publications ER - TY - CHAP A1 - Escher, Lukas A1 - Rück, Thomas A1 - Jobst, Simon A1 - König, Martin A1 - Bierl, Rudolf T1 - Design and Characterization of a Low-Cost Photoacoustic Sensor for NO2 Using Lateral Illumination and Background Suppression T2 - Imaging and Applied Optics Congress 2022 (3D, AOA, COSI, ISA, pcAOP): 11–15 July 2022, Vancouver, British Columbia, Canada N2 - We introduce a low-cost photoacoustic NO2 sensor based on lateral LED illumination and optical background signal compensation. The 3σ limit of detection (LOD) was identified to be 24 ppbV. Y1 - 2022 SN - 978-1-957171-09-8 U6 - https://doi.org/10.1364/3D.2022.JTu2A.10 PB - Optica Publishing Group ER - TY - INPR A1 - Pangerl, Jonas A1 - Sukul, Pritam A1 - Rück, Thomas A1 - Escher, Lukas A1 - Miekisch, Wolfram A1 - Bierl, Rudolf A1 - Matysik, Frank-Michael T1 - Photoacoustic Trace-Analysis of Breath Isoprene and Acetone Via Interband- and Quantum Cascade Lasers N2 - This research presents two laser-based photoacoustic approaches for analyzing exhaled breath isoprene and acetone. The integration of a PTR-ToF-MS as a reference device ensured the reliability and accuracy of the PAS systems that is based on an ICL for isoprene and a QCL for acetone detection. The calibration yielded limits of detection of 26.9 ppbV and 1.7 ppbV, respectively, and corresponding normalized noise equivalent absorption coefficients (NNEAs) of 5.0E-9 Wcm-1Hz-0.5 and 4.9E-9 Wcm-1Hz-0.5. Laboratory as well as real breath sample measurements from alveolar breath revealed a robust system performance, with only one outlier within the static isoprene measurements. However, discrepancies emerged under dynamic breath sampling conditions, emphasizing the need for further optimization. Especially by knowing the dynamic nature and endogenous origin of exhaled isoprene our findings highlight the potential of breath analysis for non-invasive physio-metabolic and pathophysiological monitoring towards point-of-care devices. KW - photoacoustic spectroscopy KW - breath analysis/profiling KW - real-time mass spectroscopy KW - isoprene KW - acetone Y1 - 2024 U6 - https://doi.org/10.2139/ssrn.4834735 PB - Elsevier / SSRN ER - TY - JOUR A1 - Pangerl, Jonas A1 - Sukul, Pritam A1 - Rück, Thomas A1 - Escher, Lukas A1 - Miekisch, Wolfram A1 - Bierl, Rudolf A1 - Matysik, Frank-Michael T1 - Photoacoustic trace-analysis of breath isoprene and acetone via interband- and Quantum Cascade Lasers JF - Sensors and Actuators: B. Chemical N2 - This research presents two laser-based photoacoustic approaches for analyzing exhaled breath isoprene and acetone. The integration of a PTR-ToF-MS as a reference device ensured the reliability and accuracy of the photoacoustic systems that is based on an ICL for isoprene and a QCL for acetone detection. The calibration yielded limits of detection of 26.9 ppbV and 1.7 ppbV, respectively, and corresponding normalized noise equivalent absorption coefficients (NNEAs) of 5.0E-9 Wcm 1Hz 0.5 and 4.9E-9 Wcm 1Hz 0.5. Laboratory as well as real breath sample measurements from alveolar breath revealed a robust system performance, with only one outlier within the static isoprene measurements. However, discrepancies emerged under dynamic breath sampling conditions, emphasizing the need for further optimization. Especially by knowing the dynamic nature and endogenous origin of exhaled isoprene our findings highlight the potential of breath analysis for non-invasive physio-metabolic and pathophysiological monitoring towards point-of-care devices KW - Photoacoustic spectroscopy KW - Breath analysis/profiling KW - Real-time mass spectrometry KW - Isoprene KW - Acetone Y1 - 2025 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-77024 N1 - Corresponding author der OTH Regensburg: Jonas Pangerl VL - 424 PB - Elsevier ER - TY - CHAP A1 - Escher, Lukas A1 - Müller, Max A1 - Rück, Thomas A1 - Jobst, Simon A1 - Bierl, Rudolf T1 - Digitaler Zwilling photoakustischer Spurengassensoren zur Prozessüberwachung T2 - 16. Dresdner Sensor-Symposium 2022: Vorträge N2 - Stickstoffdioxid (NO2) wird hauptsächlich durch anthropogene Verbrennungsprozesse in Verkehr und Industrie in die Umgebungsluft eingebracht [1]. Die stark reaktive, oxidative Wirkung von NO2 kann bei Exposition mit höheren Konzentrationen Reizungen und allergische Reaktionen in den Atemwegen hervorrufen. Weiter führt NO2 zur Bildung von saurem Regen, Smog und Ozon (O3) die sich ebenso negativ auf die menschliche Gesundheit und Umwelt auswirken [2,3]. Aufgrund dieser Effekte wird die Spurengaskonzentration von NO2 in der Luft in Deutschland an ausgewählten, verkehrsreichen Orten gemessen. Y1 - 2022 SN - 978-3-9819376-7-1 U6 - https://doi.org/10.5162/16dss2022/3.3 PB - AMA (Association for Sensors + Measurement) ER - TY - JOUR A1 - Rück, Thomas A1 - Pangerl, Jonas A1 - Escher, Lukas A1 - Jobst, Simon A1 - Müller, Max A1 - Bierl, Rudolf A1 - Matysik, Frank-Michael T1 - Kinetic cooling in mid-infrared methane photoacoustic spectroscopy: A quantitative analysis via digital twin verification JF - Photoacoustics N2 - This study presents a detailed quantitative analysis of kinetic cooling in methane photoacoustic spectroscopy, leveraging the capabilities of a digital twin model. Using a quantum cascade laser tuned to 1210.01 cm⁻¹, we investigated the effects of varying nitrogen-oxygen matrix compositions on the photoacoustic signals of 15 ppmV methane. Notably, the photoacoustic signal amplitude decreased with increasing oxygen concentration, even falling below the background signal at oxygen levels higher than approximately 6 %V. This phenomenon was attributed to kinetic cooling, where thermal energy is extracted from the surrounding gas molecules rather than added, as validated by complex vector analysis using a previously published digital twin model. The model accurately reproduced complex signal patterns through simulations, providing insights into the underlying molecular mechanisms by quantifying individual collision contributions. These findings underscore the importance of digital twins in understanding the fundamentals of photoacoustic signal generation at the molecular level. Y1 - 2024 U6 - https://doi.org/10.1016/j.pacs.2024.100652 VL - 40 PB - Elsevier ER - TY - JOUR A1 - Leonhardt, Carina A1 - Guertler, Katherine T1 - Unearthing Corporate Greenwashing: A Content Analysis of Sustainability Reporting in the Mining Sector JF - Tripodos N2 - Greenwashing is a common form of corporate disinformation that is often challenging for the general public to detect. Companies engage in greenwashing in their reporting to mislead shareholders and stakeholders about their environmental efforts, seeking to enhance legitimacy and gain competitive advantages. While systems for identifying greenwashing exist, they typically focus on advertising, leaving greenwashing in corporate reports underexamined. This study aims to address this gap by conducting a qualitative content analysis of a climate report from a mining and commodity trading company, considering the company’s profile, the report’s target audience, and current research. The findings reveal that the company employs numerous subtle greenwashing strategies to project a more sustainable image through strategic omissions, hedging and vague long-term goals. Moreover, this research broadens the scope of greenwashing analysis to include corporate reporting, which targets a more informed audience, such as shareholders and experts, rather than the general public. The results underscore the need for stricter regulation of sustainability reports and highlight the importance of fostering greater scrutiny among shareholders. KW - climate communication KW - corporate communication KW - greenwashing KW - sustainability reporting Y1 - 2025 U6 - https://doi.org/10.51698/tripodos.2025.57.06 SN - 1138-3305 VL - 2025 IS - 57 SP - 78 EP - 97 PB - Blanquerna School of Communication and International Relations CY - Barcelona ER - TY - CHAP A1 - Mühlberger, Thomas A1 - Schoplocher, Paul Dragos A1 - Steffens, Oliver ED - Fouad, Nabil A. T1 - Thermische Gebäudesimulation: aktuelle Anwendungen und Erweiterungen mittels der Finite‐Elemente‐Methode T2 - Bauphysik-Kalender 2025: Simulationen, BIM und KI N2 - Nach einem kurzen historischen Abriss der Entwicklung der Gebäudesimulation wird die aktuell übliche gleichungsbasierte Kompaktmodell-Simulation beschrieben und deren praktische Anwendung aufgezeigt. Dabei wird auf die Bedeutung der Validierung von Simulationstools und auf etablierte Validierungsstandards eingegangen. Gebäudesimulation dient der Optimierung des Bauens in allen Planungsphasen. Mit Praxisbeispielen vom sommerlichen Wärmeschutz bis hin zur Modellierung innovativer Konstruktionen werden unterschiedliche Einsatzbereiche demonstriert. Im zweiten Teil wird die Verwendung der Finite-Elemente-Methode (FEM) für die bauphysikalische Modellierung vorgestellt. Anhand von Beispielen zeigen wir, dass die (rechenzeitintensive) FEM aufgrund einer detaillierteren Modellierung von Geometrie, Strahlung und Konvektion präzisere Simulationsergebnisse liefert. Zum Abschluss werden Wege vorgeschlagen, wie dies zur Erweiterung der schnelleren Kompaktmodell-Simulation eingesetzt werden kann. KW - Energieeffizienz KW - Finite-Elemente-Methode KW - Gebäudesimulation KW - Kompaktmodelle KW - thermische Bauphysik Y1 - 2025 SN - 9783433034514 U6 - https://doi.org/10.1002/9783433612095.ch12 SP - 435 EP - 468 PB - Ernst & Sohn CY - Berlin ER - TY - JOUR A1 - Jobst, Simon A1 - Recum, Patrick A1 - Écija-Arenas, Ángela A1 - Moser, Elisabeth A1 - Bierl, Rudolf A1 - Hirsch, Thomas T1 - Semi-Selective Array for the Classification of Purines with Surface Plasmon Resonance Imaging and Deep Learning Data Analysis JF - ACS sensors N2 - In process analytics or environmental monitoring, the real-time recording of the composition of complex samples over a long period of time presents a great challenge. Promising solutions are label-free techniques such as surface plasmon resonance (SPR) spectroscopy. They are, however, often limited due to poor reversibility of analyte binding. In this work, we introduce how SPR imaging in combination with a semi-selective functional surface and smart data analysis can identify small and chemically similar molecules. Our sensor uses individual functional spots made from different ratios of graphene oxide and reduced graphene oxide, which generate a unique signal pattern depending on the analyte due to different binding affinities. These patterns allow four purine bases to be distinguished after classification using a convolutional neural network (CNN) at concentrations as low as 50 μM. The validation and test set classification accuracies were constant across multiple measurements on multiple sensors using a standard CNN, which promises to serve as a future method for developing online sensors in complex mixtures. KW - surface plasmon resonance imaging KW - functional surface KW - graphene oxide KW - reduced graphene oxide KW - 2D materials KW - pattern recognition KW - small-molecule sensing Y1 - 2023 U6 - https://doi.org/10.1021/acssensors.3c01114 VL - 8 IS - 9 SP - 3530 EP - 3537 PB - American Chemical Society ER - TY - CHAP A1 - Hausler, Peter A1 - Wunderlich, Lukas A1 - Fischer, Johannes A1 - Pfab, Christina A1 - Heckscher, Simon A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - Surface plasmon resonance imaging for detection of drug metabolites in water T2 - Proceedings of SPIE, Optical Sensors 2019, 1 - 4 April 2019, Prague, Czech Republic N2 - The analysis of surface water, groundwater, drinking water as well as sewage is important to get information about the contamination of the water cycle. Currently, these time-consuming investigations require special equipment, like for example hyphenated mass spectrometry. Surface plasmon resonance (SPR) is a faster alternative as it is highly sensitive to changes in the dielectric medium next to a thin metal layer and makes it a quasi-universal detector. Therefore, and due to the labelfree nature, SPR is a widely used sensing tool for real‐time monitoring of molecular interactions of various analytes. SPR imaging (SPRi) has several advantages to standard surface plasmon resonance, as it allows to observe many analytes in parallel as well as the integration of referencing technologies. However, the homogenous illumination of a large area (several millimeters) with a small light source is challenging and demands new approaches. Allopurinol, a drug used to lower the blood concentration of urate and hence decrease the affection of gout, gets metabolized to oxipurinol in the body and dropped out almost entirely by urinary excretion. After wastewater treatment, concentrations of oxipurinol up to 21.7 μg•L-1 are detected. Further tracking of oxipurinol in the urban water cycle showed its presence in rivers and streams or even in groundwater. Therefore, the high biological stability of oxipurinol allows this molecule to be used as a marker for domestic wastewater in the environment. For the detection of oxipurinol by SPR graphene was used as receptive layer, as the analyte can bind via π-stacking to this surface. An SPRi technique was developed and compared to conventional SPR system for the detection of oxipurinol. Y1 - 2019 U6 - https://doi.org/10.1117/12.2522324 SN - 0277-786X VL - Vol. 11028 ER - TY - CHAP A1 - Hausler, Peter A1 - Roth, Carina A1 - Aumer, F. A1 - Vitzthumecker, Thomas A1 - Genslein, Christa A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - Miniaturisiertes Sensorsystem zur Oberflächenplasmonenresonanzspektroskopie T2 - 118. Jahrestagung der deutschen Gesellschaft für angewandte Optik (DGaO), 6.-10. Juni 2017, Dresden N2 - Die Oberflächenplasmonenresonanzspektroskopie (SPR) wird aufgrund ihrer Vorzüge der zerstörungs- und markierungsfreien Messung, sowie der hohen Sensitivität sehr erfolgreich im Labormaßstab eingesetzt. Aufgrund der hohen Kosten geschieht dies bislang hauptsächlich in der Bioanalytik und dem Wirkstoffscreening. Gezeigt wird ein Ansatz, mit dem diese Technologie auf ein ultrakompaktes, kostengünstiges Sensorsystem übertragen wird, welches in der Lage ist, hoch-sensitiv Änderungen im Brechungsindex von 10-6 Einheiten (RIU) zu detektieren. Für Wasser bewirkt eine Temperaturschwankung von 1 K bereits eine Änderung von 1 mRIU. Daher wird durch ein integriertes Referenzsystem, sowie die Miniaturisierung erreicht, dass das System gegenüber Temperaturschwankungen, weitestgehend stabil ist. In dem MOEMS wird anstatt der konventionellen 1-Punkt bzw. 2-Punkt Messung ein bildgebendes Verfahren angewendet. Die Sensorfläche von 15 x 15 mm wird dabei mit einem handelsüblichen 4 Mio. Pixel CMOS Sensor ausgewertet. Um verlässliche Datenpunkte zu erhalten benötigt man eine Fläche von 10 x 10 Pixel. Demzufolge können auf dem Sensor theoretisch bis zu 40.000 Sensorspots parallel ausgewertet werden. KW - Messtechnik KW - Optische Systeme KW - Spektroskopie Y1 - 2017 ER - TY - CHAP A1 - Hausler, Peter A1 - Genslein, Christa A1 - Roth, Carina A1 - Vitzthumecker, Thomas A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - Miniaturized Surface Plasmon Resonance based Sensor System T2 - Proceedings of the 6th International Conference on Photonics, Optics and Laser Technology - PHOTOPTICS, Funchal, Madeira, Portugal N2 - We describe the miniaturization of the Surface Plasmon Resonance (SPR) technology which mainly finds its applications in pharmaceutical screening and biotechnology so far. SPR spectroscopy is a label-free, non-destructive and highly sensitive measurement principle detecting changes in the refractive index in striking distance to a gold surface. A transfer of this technology to a miniaturized sensor will broaden the range of possible applications. A promising feature which is included in the miniaturized system is the angle-dependent recording of the SPR signals without moving parts. Commercial SPR assays are mainly working with a small number of sensing spots. In contrast, the SPR imaging system shown here will allow to use an array of many sensing spots. In combination with chemical receptors designed as an artificial nose, the simultaneous detection of many analytes is envisioned for future applications. KW - Surface Plasmon Resonance Spectroscopy KW - Sensor KW - SPR-imaging KW - Miniaturization KW - Micro-Opto-Electro-Mechanical Systems Y1 - 2018 SN - 978-989-758-286-8 U6 - https://doi.org/10.5220/0006555400630066 SP - 63 EP - 66 PB - SciTePress ER - TY - JOUR A1 - Genslein, Christa A1 - Hausler, Peter A1 - Kirchner, Eva-Maria A1 - Bierl, Rudolf A1 - Baeumner, Antje J. A1 - Hirsch, Thomas T1 - Graphene-enhanced plasmonic nanohole arrays for environmental sensing in aqueous samples JF - Beilstein Journal of Nanotechnology N2 - The label-free nature of surface plasmon resonance techniques (SPR) enables a fast, specific, and sensitive analysis of molecular interactions. However, detection of highly diluted concentrations and small molecules is still challenging. It is shown here that in contrast to continuous gold films, gold nanohole arrays can significantly improve the performance of SPR devices in angle-dependent measurement mode, as a signal amplification arises from localized surface plasmons at the nanostructures. This leads consequently to an increased sensing capability of molecules bound to the nanohole array surface. Furthermore, a reduced graphene oxide (rGO) sensor surface was layered over the nanohole array. Reduced graphene oxide is a 2D nanomaterial consisting of sp2-hybridized carbon atoms and is an attractive receptor surface for SPR as it omits any bulk phase and therefore allows fast response times. In fact, it was found that nanohole arrays demonstrated a higher shift in the resonance angle of 250–380% compared to a continuous gold film. At the same time the nanohole array structure as characterized by its diameter-to-periodicity ratio had minimal influence on the binding capacity of the sensor surface. As a simple and environmentally highly relevant model, binding of the plasticizer diethyl phthalate (DEP) via π-stacking was monitored on the rGO gold nanohole array realizing a limit of detection of as low as 20 nM. The concentration-dependent signal change was studied with the best performing rGO-modified nanohole arrays. Compared to continuous gold films a diameter-to-periodicity ratio (D/P) of 0.43 lead to a 12-fold signal enhancement. Finally, the effect of environmental waters on the sensor was evaluated using samples from sea, lake and river waters spiked with analytically relevant amounts of DEP during which significant changes in the SPR signal are observed. It is expected that this concept can be successfully transferred to enhance the sensitivity in SPR sensors. KW - diethyl phthalate KW - environmental sensing KW - nanohole array KW - nanosphere lithography KW - surface plasmon resonance Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:355-epub-398623 IS - 7 SP - 1564 EP - 1573 ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Blome, Christian A1 - Blums, Juris A1 - Dietrich, Clemens A1 - Tarsevitch, Alexander A1 - Horn-von Hoegen, Michael A1 - von der Linde, Dietrich A1 - Cavalleri, Andrea A1 - Kammler, Martin A1 - Uschmann, Ingo A1 - Foerster, Eckhart T1 - Femtosecond X-ray Diffraction Study of Large Amplitude Coherent Optical Phonons in Laser-Excited Bismuth JF - Conference on Lasers and Electro-Optics, 1–6 June 2003, Baltimore, Maryland N2 - Femtosecond time-resolved X-ray diffraction was used to directly study optical phonons in laser-excited Bismuth. A periodic modulation of the diffraction efficiency reveals initially coherent lattice distortions with atomic displacements of nearly 10% of the nearest- neighbor-distance. Y1 - 2003 UR - https://opg.optica.org/abstract.cfm?uri=cleo-2003-CMZ6 PB - Optical Society of America ER - TY - CHAP A1 - Hausler, Peter A1 - Genslein, Christa A1 - Roth, Carina A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - Mikro-Opto-Elektro-Mechanisches Sensorsystem zur Oberflächenplasmonenresonanzspektroskopie T2 - MikroSystemTechnik Kongress 2017 : MEMS, Mikroelektronik, Systeme 23.-25. Oktober 2017 in München N2 - Gezeigt wird die Miniaturisierung eines Messsystems für Oberflächenplasmonenresonanzspektroskopie (SPR), einer markierungs-, sowie zerstörungsfreien als auch hoch sensitiven Technologie. Aufgrund der hohen Kosten klassischer SPR-Geräte wird sie bisher jedoch vornehmlich in der Bio- und Medizintechnik eingesetzt. Das Messprinzip ermöglicht die Erfassung von Brechungsindexänderungen nahe einer Oberfläche. Der Transfer dieser Technologie von Laborgeräten hin zu einem miniaturisierten Sensorsystem senkt die Kosten, macht das System robuster und ermöglicht so ein wesentlich breiteres Anwendungsspektrum. Ein sehr vielversprechendes Merkmal des hier vorgestellten Systems ist die Möglichkeit den SPR-Effekt winkelabhängig zur Lichtquelle ohne bewegliche Bauteile zu verfolgen. The miniaturization of Surface Plasmon Resonance (SPR) technology, which mainly finds its applications in pharmaceutical screening and biotechnology so far, is described. SPR spectroscopy is a label-free, non destructive and highly sensitive measurement principle which is capable of detecting changes in the refractive index in striking distance to a gold surface. A transfer of this technology to a miniaturized sensor will broaden the range of possible applications. A promising feature which is included in the miniaturized system is the angle-dependent recording of the SPR signals without moving parts. KW - Bewegungselement KW - Biotechnik KW - Brechungsindex KW - Goldoberfläche KW - Laborgerät KW - Lichtquelle KW - Medizintechnik KW - Messprinzip KW - Messsystem KW - Miniaturisierung KW - Oberflächenplasmon KW - Oberflächenplasmonenresonanzspektroskopie KW - pharmazeutisches Screening KW - Sensorsystem KW - Spektroskopie Y1 - 2017 SN - 978-3-8007-4491-6 IS - CD-ROM SP - 645 EP - 647 PB - VDE-Verlag CY - Berlin ER - TY - JOUR A1 - Lindner, Matthias A1 - Pipa, Andrei V. A1 - Karpen, Norbert A1 - Hink, Rüdiger A1 - Berndt, Dominik A1 - Foest, Rüdiger A1 - Bonaccurso, Elmar A1 - Weichwald, Robert A1 - Friedberger, Alois A1 - Caspari, Ralf A1 - Brandenburg, Ronny A1 - Schreiner, Rupert T1 - Icing Mitigation by MEMS-Fabricated Surface Dielectric Barrier Discharge JF - Applied Sciences N2 - Avoiding ice accumulation on aerodynamic components is of enormous importance to flight safety. Novel approaches utilizing surface dielectric barrier discharges (SDBDs) are expected to be more efficient and effective than conventional solutions for preventing ice accretion on aerodynamic components. In this work, the realization of SDBDs based on thin-film substrates by means of micro-electro-mechanical-systems (MEMS) technology is presented. The anti-icing performance of the MEMS SDBDs is presented and compared to SDBDs manufactured by printed circuit board (PCB) technology. It was observed that the 35 mu m thick electrodes of the PCB SDBDs favor surface icing with an initial accumulation of supercooled water droplets at the electrode impact edges. This effect was not observed for 0.3 mu m thick MEMS-fabricated electrodes indicating a clear advantage for MEMS-technology SDBDs for anti-icing applications. Titanium was identified as the most suitable material for MEMS electrodes. In addition, an optimization of the MEMS-SDBDs with respect to the dielectric materials as well as SDBD design is discussed. KW - aerospace engineering KW - anti-icing KW - DBD PLASMA ACTUATORS KW - EXCITATION KW - FLOW-CONTROL KW - low-temperature plasma KW - MEMS KW - SEPARATION CONTROL KW - SDBD Y1 - 2021 U6 - https://doi.org/10.3390/app112311106 N1 - Corresponding author: Matthias Lindner VL - 11 IS - 23 SP - 1 EP - 17 PB - MDPI CY - Basel ER - TY - CHAP A1 - Genslein, Christa A1 - Hauser, Peter A1 - Kirchner, Eva-Maria A1 - Bierl, Rudolf A1 - Baeumner, Antje J. A1 - Hirsch, Thomas T1 - Detection of small molecules with surface plasmon resonance by synergistic plasmonic effects of nanostructured surfaces and graphene T2 - SPIE Proceedings, Plasmonics in Biology and Medicine XIV, 2017, San Francisco, California N2 - Surface plasmon resonance depends on the dielectric medium at the vicinity and makes it a quasi-universal detector. Therefore, and due to the label-free nature, SPR is a widely used sensing tool for real‐time monitoring molecular interactions of various analytes. However, detection of highly diluted analytes and small molecules (< 400 Da) is still challenging. Gold nanohole arrays provide plasmonic hotspots with improved surface sensitivity and 2D carbon nanomaterials enable binding near the surface. Both effects together are promising in the development of SPR sensors for the efficient determination of small molecules. Graphene is known for efficient binding of molecules with delocalized aromatic π-systems. Additionally, the electromagnetic field is locally enhanced and modulated by the interaction of graphene photonics with the plasmonics of metal nanostructures. The advantages of chemical vapor deposition (CVD) graphene over reduced graphene oxide (rGO) is illustrated by a proof of concept study. In comparison to substrates consisting of a continuous film the surface sensitivity is enhanced for a nanohole arrays and further improved for CVD graphene functionalization in contrast to rGO. The feasibility of the sensor was demonstrated for the detection of adenine down to a concentration of 0.9 μM. Y1 - 2017 U6 - https://doi.org/10.1117/12.2252256 VL - 10080 IS - 1008001F ER - TY - CHAP A1 - Hausler, Peter A1 - Holler, Sven A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - High integrated miniaturized sensor based on Surface Plasmon Resonance T2 - International Biosensor Conference, 11th Workshop on Biosensors & Bioanalytical Microtechniques in Environmental, Food & Clinical Analysis, BBMEC 11, 26.-30. September 2015, Regensburg, Germany Y1 - 2015 ER - TY - CHAP A1 - Hausler, Peter A1 - Holler, Sven A1 - Hirsch, Thomas A1 - Bierl, Rudolf T1 - Miniaturisierte Oberflächenplasmonenresonanz Sensorplattform T2 - MEMS, Mikroelektronik, Systeme, MikroSystemTechnik Kongress 2015, 26.- 28. Oktober 2015, Karlsruhe, proceedings Y1 - 2015 SN - 978-3-8007-4100-7 PB - VDE Verlag CY - Berlin ER - TY - JOUR A1 - Wall, Simone A1 - Krenzer, Boris A1 - Wippermann, Stefan A1 - Sanna, Simone A1 - Klasing, Friedrich A1 - Hanisch-Blicharski, Anja A1 - Kammler, Martin A1 - Schmidt, Wolf Gero A1 - Horn-von Hoegen, Michael T1 - Atomistic picture of charge density wave formation at surfaces JF - Physical review letters N2 - We used ultrafast electron diffraction and density-functional theory calculations to gain insight into the charge density wave (CDW) formation on In/Si(111). Weak excitation by a femtosecond-laser pulse results in the melting of the CDW. The immediate freezing is hindered by a barrier for the motion of atoms during the phase transition: The melted CDW constitutes a long-lived, supercooled phase and is strong evidence for a first-order transition. The freezing into the CDW is triggered by preexisting adsorbates. Starting at these condensation nuclei, the CDW expands one dimensionally on the In/Si(111) surface, with a constant velocity of more than 80 m/s. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevLett.109.186101 VL - 109 IS - 18 PB - APS ER - TY - JOUR A1 - Frigge, Tim A1 - Kalus, Annika A1 - Klasing, Friedrich A1 - Kammler, Martin A1 - Hanisch-Blicharski, Anja A1 - Horn-von Hoegen, Michael T1 - Nanoscale Heat Transport in Self-Organized Ge Clusters on Si(001) JF - MRS Online Proceedings Library N2 - Ultrafast time resolved transmission electron diffraction (TED) in a reflection geometry was used to study the cooling behavior of self-organized, well defined nanoscale germanium hut and dome clusters on Si(001). The clusters were heated in a pump-probe scheme by fs-laser pulses. The resulting transient temperature rise was then determined from the drop in diffraction intensity caused by the Debye-Waller effect. From a cooling time of τ=177 ps we estimated a strongly reduced heat transfer compared with homogeneous films of equivalent thickness. Y1 - 2012 U6 - https://doi.org/10.1557/opl.2013.148 SP - 45 EP - 50 PB - Springer ER - TY - JOUR A1 - Möllenbeck, Simone A1 - Hanisch-Blicharski, Anja A1 - Schneider, Paul A1 - Ligges, Manuel A1 - Zhou, Ping A1 - Kammler, Martin A1 - Krenzer, Boris A1 - Horn-von Hoegen, Michael T1 - Ultra-fast Time-Resolved Electron Diffraction of Strongly Driven Phase Transitions on Silicon Surfaces JF - MRS Online Proceedings Library N2 - The dynamics of strongly driven phase transitions at surfaces are studied by ultra-fast time-resolved reflection high energy electron diffraction. The surfaces are excited by an intense fs-laser pulse (pump) and probed by an ultra-short electron pulse with variable time delay. The order-disorder phase transition from a c(4 × 2) to a(2 × 1) of the bare Si(001) surface shows a transient decrease of the intensity of the c(4 × 2) spots which recovers on a time scale of a few hundred picoseconds indicating the excitation of the phase transition. On Si(111) a monolayer of Indium induces a (4 × 1) reconstruction which undergoes a Peierls like phase transition to a (8 × "2") reconstruction below 100 K. Upon laser excitation with a fluence of 3.4 mJ/cm 2 at a temperature of 72 K the phase transition was strongly driven. The (8 × "2")-diffraction spots instantaneously disappears, while the intensity of the (4 × 1)-spots increases. This increase of the (4 × 1) spot intensity excludes an explanation by the Debye-Waller-Effect and is evidence for a true structural phase transition at a surface. © 2010 Materials Research Society. Y1 - 2009 U6 - https://doi.org/10.1557/PROC-1230-MM03-09 PB - Springer ER - TY - JOUR A1 - Lu, Wei A1 - Nicoul, Matthieu A1 - Shymanovich, Uladzimir A1 - Tarsevitch, Alexander A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael A1 - von der Linde, Dietrich A1 - Sokolowski-Tinten, Klaus T1 - Extreme Phonon Softening in Laser-excited Bismuth - Towards an Inverse Peierls-transition JF - MRS Online Proceedings Library N2 - Large amplitude coherent optical phonons have been investigated in laser-excited Bismuth by means of femtosecond time-resolved X-ray diffraction. For absorbed laser fluences above 2 mJ/cm2, the experimental data reveal an extreme softening of the excited A1g-mode down to frequencies of about 1 THz, only 1/3 of the unperturbed A1g-frequency. At even stronger excitation the measured diffraction signals no longer exhibit an oscillatory behavior presenting strong indication that upon intense laser-excitation the Peierls-distortion, which defines the equilibrium structure of Bismuth, can be transiently reversed. Y1 - 2009 U6 - https://doi.org/10.1557/PROC-1230-MM03-05 VL - 1230 PB - Springer ER - TY - JOUR A1 - Hanisch-Blicharski, Anja A1 - Krenzer, Boris A1 - Möllenbeck, Simone A1 - Ligges, Manuel A1 - Zhou, Ping A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael T1 - Transient Cooling of Ultrathin Epitaxial Bi(111)-Films on Si(111) Upon Femtosecond Laser Excitation Studied by Ultrafast Reflection High Energy Electron Diffraction JF - MRS Online Proceedings Library N2 - With time resolved ultrafast electron diffraction the cooling process across the interface between a thin film and the underlying substrate was studied after excitation with short laser pulses. From the exponential decay of the surface temperature evolution a thermal boundary conductance of 1430 W/(cm2K) is determined for a 9.7 nm thin Bi(111) film on Si(111). A linear dependence between laser fluence and initial temperature rise was measured for film-thicknesses between 2.5 nm and 34.5 nm. The ratio of initial temperature rise and laser fluence for different film-thicknesses is compared to a model taking multilayer optics into account. The data agree well with this model. Y1 - 2009 U6 - https://doi.org/10.1557/PROC-1172-T04-08 SP - 1 EP - 6 PB - Springer ER - TY - JOUR A1 - Al-Falou, A. A. A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael T1 - Strain state analysis of hetero-epitaxial systems JF - Europhysics Letters N2 - We present a new method to analyze the strain state of epitaxial hetero structures by high-resolution spot profile analysis low-energy electron diffraction. From the variation of the spot profiles with the vertical scattering vector we determine the hetero film roughness, the change of interlayer spacing due to tetragonal distortion, and the variation of the interlayer distance due to partial relaxation of the strained rough film. The practical implementation of this method is simple and can be used to determine the onset of strain-relieving defects during the growth process. Y1 - 2005 U6 - https://doi.org/10.1209/epl/i2004-10399-6 VL - 69 IS - 4 SP - 570 EP - 576 PB - IOP ER - TY - JOUR A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael T1 - Low energy electron diffraction of epitaxial growth of bismuth on Si(111) JF - Surface Science N2 - The epitaxial growth of Bi on Si(1 1 1) studied by spot profile analyzing low energy electron diffraction shows for low coverage rotationally disordered Bi cluster with preferred orientations following the threefold symmetry of the Si substrate. With further deposition the Bi cluster coalesces and the surface orientation changes from the pseudo cubic Bi(1 1 0) surface orientation of the Bi cluster into the hexagonal Bi(1 1 1) surface of the resulting Bi film. KW - Bismuth KW - Epitaxial growth KW - LEED KW - low energy electron diffraction KW - Silicon KW - Structural transition Y1 - 2005 U6 - https://doi.org/10.1016/j.susc.2004.11.033 VL - 576 IS - 1-3 SP - 56 EP - 60 PB - Elsevier ER - TY - CHAP A1 - Siders, C. W. A1 - Cavalleri, Andrea A1 - Tóth, Csaba A1 - Wilson, K. R. A1 - Squier, Jeff A. A1 - Barty, C. P. J. A1 - Kammler, Martin A1 - Sokolowski-Tinten, Klaus A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. T1 - Femtosecond X-ray diffraction of short-pulse irradiated semiconductors T2 - Summaries of Papers Presented at the Lasers and Electro-Optics. CLEO '02. Technical Diges, 24-24 May 2002, Long Beach, CA, USA N2 - Summary form only given, as follow. Ultrafast optical-pump, X-ray diffraction probe experiments are providing new ways to study transient processes including the direct observation of the atomic motion by which many solid-state processes and chemical and biochemical reactions take place. Current table-top-terawatt femtosecond laser systems provide an attractive source of few-hundred femtosecond duration bursts of angstrom-scale X-ray radiation with fluxes comparable to standard rotating anode sources. Their compact size enables time resolved structural dynamics to be studied in the small laboratory with temporal resolution better than typical molecular vibrational periods. Ultrafast structural dynamics in crystalline samples are readily studied with such systems and experiments to be discussed in this talk include ultrafast non-thermal solid-to-liquid transition in thin single-crystal Ge-111 films grown on Si-111 substrates; ultrafast non-thermal solid-to-solid transitions in bulk vanadium dioxide from a low temperature insulating phase to a high temperature metallic phase; and harmonic and anharmonic coherent acoustic dynamics in layered Ge-111/Si-111 and bulk GaAs-111 samples. Future improvements in high-average power short-pulse lasers will enable the study of a wider class of materials such as amorphous solids or liquid-phase dynamics of simple molecules, while proposed 4th generation light sources based upon single-pass X-ray free-electron lasers will permit singleshot structural determination of complex biomolecules. KW - high-speed techniques KW - X-ray diffraction KW - laser beam effects KW - semiconductor materials KW - solid-liquid transformations KW - solid-state phase transformations KW - metal-insulator transition Y1 - 2002 U6 - https://doi.org/10.1109/CLEO.2002.1033997 SP - 297 EP - 298 PB - IEEE ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Blome, Christian A1 - Blums, Juris A1 - Cavalleri, Andrea A1 - Dietrich, Clemens A1 - Tarasevitch, Alexander A1 - Uschmann, Ingo A1 - Förster, Eckhard A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael A1 - von der Linde, Dietrich T1 - Femtosecond X-ray measurement of coherent lattice vibrations near the Lindemann stability limit JF - Nature N2 - The study of phase-transition dynamics in solids beyond a time-averaged kinetic description requires direct measurement of the changes in the atomic configuration along the physical pathways leading to the new phase. The timescale of interest is in the range 10(-14) to 10(-12) s. Until recently, only optical techniques were capable of providing adequate time resolution, albeit with indirect sensitivity to structural arrangement. Ultrafast laser-induced changes of long-range order have recently been directly established for some materials using time-resolved X-ray diffraction. However, the measurement of the atomic displacements within the unit cell, as well as their relationship with the stability limit of a structural phase, has to date remained obscure. Here we report time-resolved X-ray diffraction measurements of the coherent atomic displacement of the lattice atoms in photoexcited bismuth close to a phase transition. Excitation of large-amplitude coherent optical phonons gives rise to a periodic modulation of the X-ray diffraction efficiency. Stronger excitation corresponding to atomic displacements exceeding 10 per cent of the nearest-neighbour distance-near the Lindemann limit-leads to a subsequent loss of long-range order, which is most probably due to melting of the material. Y1 - 2003 U6 - https://doi.org/10.1038/nature01490 VL - 422 IS - 6929 SP - 287 EP - 289 PB - Springer ER - TY - JOUR A1 - Hild, R. A1 - Seifert, C. A1 - Kammler, Martin A1 - Meyer zu Heringdorf, Frank-Joachim A1 - Horn-von Hoegen, Michael A1 - Zhachuk, R.A A1 - Olshanetsky, B.Z T1 - Kinetics of Au induced faceting of vicinal Si(111) JF - Surface Science N2 - Au induced faceting of vicinal Si(1 1 1) has been studied during adsorption at elevated temperature by spot profile analyzing of low energy electron diffraction and after quenching to room temperature by scanning tunneling microscopy. On the surfaces inclined towards five different types of facets form with increasing Au coverage at adsorption temperatures Tads below 800 °C. They are (4 4 3), (7 7 5), (5 5 3), a stepped (2 2 1), and the (3 3 1) facets. Atomic models for the (5 5 3) and (7 7 5) facet planes are proposed on the basis of high resolution STM images. At C we found the formation of an ordered step train which covers the entire surface. With further increasing Au coverage the stepped surface decomposes again into (1 1 1) terraces and step bunches. Driving force is the formation of the Si(1 1 1)-(5×2)–Au reconstruction. KW - Low energy electron diffraction (LEED) KW - Scanning tunneling microscopy KW - Silicon KW - Gold KW - Faceting KW - Adsorption kinetics KW - Step formation and bunching Y1 - 2002 U6 - https://doi.org/10.1016/S0039-6028(02)01666-7 VL - 512 IS - 1-2 SP - 117 EP - 127 PB - Elsevier ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Cavalleri, Andrea A1 - Siders, C. W. A1 - Brown, F. L. H. A1 - Leitner, D. M. A1 - Tóth, Csaba A1 - Squier, Jeff A. A1 - Barty, C. P. J. A1 - Wilson, K. R. A1 - Kammler, Martin T1 - Transient lattice dynamics in fs-laser-excited semiconductors probed by ultrafast X-ray diffraction JF - Journal de Physique IV N2 - A study of lattice dynamics in fs-laser-excited crystalline bulk Ge and Ge/Si-heterostructures, using time-resolved x-ray diffraction, was presented. Fast energy transport deep into the bulk of the material, coherent acoustic phonon dynamics, lattice anharmonicity, and vibrational transport across a buried interfaces were observed. Graphs showing time-dependent shifts of the centroid of the measured rocking curves in the Ge-overlayer and in the Si-substrate for different fluences, were presented. Y1 - 2001 U6 - https://doi.org/10.1051/jp4:2001290 VL - 11 IS - Pr2 SP - 473 EP - 477 PB - EDP ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Cavalleri, Andrea A1 - Siders, C. W. A1 - Brown, F. L. H. A1 - Leitner, D. M. A1 - Tóth, Csaba A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Squier, Jeff A. A1 - Barty, C. P. J. A1 - Wilson, K. R. T1 - Time-resolved x-ray diffraction study of ultrafast acoustic phonon dynamics in Ge/Si-heterostructures JF - Chemical Physics N2 - Using time-resolved x-ray diffraction the ultafast strain dynamics in fs-laserexcited Ge/Si-heterostructures has been studied. A fluence dependent, anharmonic damping of the impulsively generated acoustic phonons and vibrational transport across the buried Ge/Si-interface are observed. Y1 - 2001 U6 - https://doi.org/10.1007/978-3-642-56546-5_81 VL - 66 SP - 281 EP - 283 PB - Springer ER - TY - CHAP A1 - Sokolowski-Tinten, Klaus A1 - Blome, Christian A1 - Dietrich, Clemens A1 - Blums, Juris A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Cavalleri, Andrea A1 - Squier, Jeff A. A1 - Kammler, Martin T1 - Structural dynamics in laser-excited solids investigated with femtosecond x-ray diffraction T2 - 2002 Summaries of Papers Presented at the Quantum Electronics and Laser Science Conference, 19-24 May 2002, Long Beach, CA, USA N2 - Summary form only given. Ultrashort x-ray pulses offer a unique combination of atomic-scale spatial and temporal resolution, which permits direct measurements of structural transients on an ultrafast time scale. Using time-resolved X-ray diffraction with femtosecond, multi-keV X-ray pulses we have studied transient lattice dynamics in optically excited semiconductors. Y1 - 2002 U6 - https://doi.org/10.1109/QELS.2002.1031182 SP - 115 EP - 116 PB - IEEE ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Blome, Christian A1 - Dietrich, Clemens A1 - Tarasevitch, A. A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Cavalleri, Andrea A1 - Squier, Jeff A. A1 - Kammler, Martin T1 - Femtosecond x-ray measurement of ultrafast melting and large acoustic transients JF - Physical review letters N2 - Time-resolved x-ray diffraction with ultrashort ( approximately 300 fs), multi-keV x-ray pulses has been used to study the femtosecond laser-induced solid-to-liquid phase transition in a thin crystalline layer of germanium. Nonthermal melting is observed to take place within 300-500 fs. Following ultrafast melting we observe strong acoustic perturbations evolving on a picosecond time scale. Y1 - 2001 U6 - https://doi.org/10.1103/PhysRevLett.87.225701 VL - 87 PB - APS ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Blome, Christian A1 - Dietrich, Clemens A1 - Tarasevitch, A. A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Cavalleri, Andrea A1 - Squier, Jeff A. A1 - Kammler, Martin T1 - Femtosecond time-resolved X-ray diffraction study of ultrafast structural dynamics in laser-excited solids JF - International Conference on Ultrafast Phenomena, 12 May 2002, Vancouver Canada N2 - Time-resolved x-ray diffraction with sub-300 fs, multi-keV x-ray pulses was used to study ultrafast lattice dynamics in laser-irradiated germanium and bismuth. In bismuth strong excitation of optical phonons is observed prior to disordering of the material. Y1 - 2002 U6 - https://doi.org/10.1007/978-3-642-59319-2_10 VL - 71 SP - 36 EP - 38 PB - Optica Publishing Grou ER - TY - INPR A1 - Tringides, Michael C. A1 - Conrad, E. H. A1 - Menzel, Andreas A1 - Voss, Neil R. A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael T1 - Dynamics of atomic steps on Si(001) studied by temporal LEED spectroscopy [Poster] N2 - While surface kinetics measurements for single atom diffusion have proliferated, little work exists attempting to measure surface dynamics under equilibrium conditions. We will present our recent work on developing Temporal LEED Spectroscopy (TLS) as a dynamic probe of surfaces capable of kinetics measurements at both high temperatures and surface coverages. By tuning the diffraction to specific structural entities such as steps, islands, etc., and monitoring the diffracted signal as a function of time, dynamics information about these structures can be obtained. As an example we will present TLS results for the dynamics of step fluctuations on Si(001) [1]. We have measured activation energies and identified step-edge diffusion as the rate limiting process for 950K < T < 1130K. Although this result is in apparent disagreement with earlier work, a careful analysis, considering crossover temperatures between different microscopic processes, can reconcile the differences. 1. M. Kammler, et al., Phys. Rev. B (in press). Y1 - 2002 UR - https://www.researchgate.net/publication/252546721_Dynamics_of_atomic_steps_on_Si001_studied_by_temporal_LEED_spectroscopy_poster ER - TY - JOUR A1 - Horn-von Hoegen, Michael A1 - Meyer zu Heringdorf, Frank-Joachim A1 - Kammler, Martin A1 - Schaeffer, C. A1 - Reinking, D. A1 - Hofmann, K. R. T1 - Bi surfactant mediated epitaxy of Ge on Si(111) JF - Thin Solid Films N2 - We have tested Bi for the surfactant mediated epitaxy of Ge on Si(111). Islanding of Ge is prevented and a 2D layer growth of smooth and continuous Ge films is observed. The lattice mismatch is accommodated by a periodic array of dislocations confined to the Si/Ge interface. The large covalent radius of Bi reduces the binding energy, allowing Very efficient segregation and low doping levels even at low growth temperatures. Unfortunately, this results also in a high Bi desorption flux limiting the possible growth temperatures below 600 degrees C. Consequently the Ge films show a high defect density in the order of 10(8) cm(-2) for stacking faults and 10(9) cm(-2) for dislocations which limit electron Hall mobility to values below 700 cm(2)/V s at room temperature. KW - Hall mobility KW - Heteroepitaxial growth KW - Surfactants KW - Doping KW - Molecular beam epitaxy KW - Silicon KW - Germanium KW - Bismuth KW - Low energy electron diffraction KW - Scanning electron microscopy Y1 - 1999 U6 - https://doi.org/10.1016/S0040-6090(98)01659-9 VL - 343-344 SP - 579 EP - 582 PB - Elsevier ER - TY - JOUR A1 - Cavalleri, Andrea A1 - Siders, C. W. A1 - Brown, F. L. H. A1 - Leitner, D. M. A1 - Tóth, Csaba A1 - Squier, Jeff A. A1 - Barty, C. P. J. A1 - Wilson, K. R. A1 - Sokolowski-Tinten, Klaus A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Kammler, Martin T1 - Anharmonic lattice dynamics in germanium measured with ultrafast x-ray diffraction JF - Physical review letters N2 - Damping of impulsively generated coherent acoustic oscillations in a femtosecond laser-heated thin germanium film is measured as a function of fluence by means of ultrafast x-ray diffraction. By simultaneously measuring picosecond strain dynamics in the film and in the unexcited silicon substrate, we separate anharmonic damping from acoustic transmission through the buried interface. The measured damping rate and its dependence on the calculated temperature of the thermal bath is consistent with estimated four-body, elastic dephasing times (T2) for 7-GHz longitudinal acoustic phonons in germanium. Y1 - 2000 U6 - https://doi.org/10.1103/PhysRevLett.85.586 VL - 85 IS - 3 SP - 586 EP - 589 PB - APS ER - TY - JOUR A1 - Sokolowski-Tinten, Klaus A1 - Horn-von Hoegen, Michael A1 - von der Linde, D. A1 - Cavalleri, Andrea A1 - Siders, C. W. A1 - Brown, F. L. H. A1 - Tóth, Csaba A1 - Squier, Jeff A. A1 - Barty, C. P. J. A1 - Wilson, K. R. A1 - Kammler, Martin T1 - Time-resolved x-ray diffraction study of ultrafast acoustic phonon dynamics in Ge/Si-heterostructures JF - International Conference on Ultrafast Phenomena , 9 July 2000, Charleston N2 - Using time-resolved x-ray diffraction the ultafast strain dynamics in fs-laserexcited Ge/Si-heterostructures has been studied. A fluence dependent, anharmonic damping of the impulsively generated acoustic phonons and vibrational transport across the buried Ge/Si-interface are observed. KW - Acoustic Phonon KW - Acoustic Transmission KW - Carrier Diffusion KW - Homogenous Expansion KW - Lattice Anharmonicity Y1 - 2000 UR - https://opg.optica.org/abstract.cfm?uri=UP-2000-MF43 PB - Optica ER - TY - JOUR A1 - Siders, C. W. A1 - Cavalleri, Andrea A1 - Sokolowski-Tinten, Klaus A1 - Tóth, Csaba A1 - Guo, T. A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael A1 - Wilson, K. R. A1 - von der Linde, D. A1 - Barty, C. P. J. T1 - Detection of nonthermal melting by ultrafast X-ray diffraction JF - Science N2 - Using ultrafast, time-resolved, 1.54 angstrom x-ray diffraction, thermal and ultrafast nonthermal melting of germanium, involving passage through nonequilibrium extreme states of matter, was observed. Such ultrafast, optical-pump, x-ray diffraction probe measurements provide a way to study many other transient processes in physics, chemistry, and biology, including direct observation of the atomic motion by which many solid-state processes and chemical and biochemical reactions take place. Y1 - 1999 U6 - https://doi.org/10.1126/science.286.5443.1340 VL - 286 IS - 5443 SP - 1340 EP - 1342 ER - TY - JOUR A1 - Reinking, D. A1 - Kammler, Martin A1 - Hoffmann, N. A1 - Horn-von Hoegen, Michael A1 - Hofmann, K. R. T1 - Fabrication of high-mobility Ge p-channel MOSFETs on Si substrates JF - Electronics Letters N2 - The first fabrication of Ge p-channel MOSFETs (p-MOSFETs) on Si substrates is reported. A CMOS compatible process based on relaxed Ge layers grown on Si(111) substrates by surfactant mediated epitaxy (SME) was used. The non-optimised low temperature process yielded normally-off Ge p-MOSFETs with record channel drift mobilities of 430 cm2/Vs KW - silicon KW - CMOS integrated circuits KW - germanium KW - carrier mobility KW - epitaxial growth KW - integrated circuit technology KW - elemental semiconductors KW - semiconductor growth KW - MOSFET KW - Insulated gate field effect transistors KW - Thin film growth and epitaxy Y1 - 1999 U6 - https://doi.org/10.1049/el:19990349 VL - 35 IS - 6 SP - 503 EP - 504 PB - IET ER - TY - CHAP A1 - Kuhn, Alexander A1 - Franzius, Jan Niklas A1 - Möller, Dennis A1 - Pralle, Norbert A1 - Reich, Franziska A1 - Hellmuth, René A1 - Tombeil, Anne-Sophie A1 - Wenzel, Günter A1 - Linner, Thomas A1 - Schmailzl, Marc A1 - Hu, Rongbo A1 - Bock, Thomas A1 - Maufroy, Christophe A1 - Kopp, Verena A1 - Bölke, Nico A1 - Daub, Urban T1 - Kompetenzzentrum für Baurobotik im Hochbau (CONSAS) - Förderkennzeichen 16SV8637 T2 - Roboter für Assistenzfunktionen: Konzeptstudien für die Interaktion in der Praxis Y1 - 2023 UR - https://www.researchgate.net/publication/373084211_Kompetenzzentrum_fur_Baurobotik_im_Hochbau_CONSAS_-_Forderkennzeichen_16SV8637 SN - 9783731512448 SP - 169 EP - 207 ER - TY - JOUR A1 - Siders, C. W. A1 - Cavalleri, Andrea A1 - Sokolowski-Tinten, Klaus A1 - Tóth, Csaba A1 - Guo, T. A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael A1 - Wilson, K. R. A1 - von der Linde, D. A1 - Barty, C. P. J. T1 - Direct Observation of Ultrafast Non-thermal Melting by Ultrafast X-ray Diffraction JF - Ultrafast Phenomena XII N2 - Ultrafast nonthermal melting of femtosecond laser-irradiated germanium was observed directly for the first time using sub-picosecond, 1.54-angstrom x-ray diffraction. Such measurements allow the study of transient atomic motion fundamental to many processes in physics, chemistry, and biology. Y1 - 2000 U6 - https://doi.org/10.1007/978-3-642-56546-5_80 VL - 66 SP - 276 EP - 280 PB - Springer ER - TY - CHAP A1 - Sokolowski-Tinten, Klaus A1 - von der Linde, D. A1 - Siders, C. W. A1 - Cavalleri, Andrea A1 - Tóth, Csaba A1 - Guo, T. A1 - Wilson, K. R. A1 - Barty, C. P. J. A1 - Kammler, Martin A1 - Horn-von Hoegen, Michael T1 - Lattice dynamics of femtosecond laser-excited semiconductors probed by ultrafast x-ray diffraction T2 - Applications of High Field and Short Wavelength Sources VIII N2 - The present knowledge of the atomic structure of matter is to a large extent due to x-ray spectroscopies. Y1 - 1999 U6 - https://doi.org/10.1364/HFSW.1999.PD3 PB - Optica ER - TY - CHAP A1 - Buchner, Stefan A1 - Wagner, Marcus A1 - Höller, Christoph T1 - Inverse Acoustic Characterization of Rigid Porous Media using Artificial Neural Networks T2 - Proceedings of DAS|DAGA 2025, 51st Annual Meeting on Acoustics, March 17-20, 2025, Copenhagen N2 - Porous sound absorbers can be described by the isotropic Biot model, and its fluid phase can be represented by the Champoux-Allard model. To apply these models to a given absorber material, the five acoustical and the four mechanical material parameters must be known. The direct measurement of these parameters is complex and requires cost-intensive measurement equipment. Current inverse methods to obtain these material parameters solve an optimization problem, trying to fit the absorption or impedance curve of the material model to the impedance tube measurement data. Solving this optimization problem, i.e. finding the global minimum, is not guaranteed in an acceptable amount of time, as the optimization problem possesses a multitude of local minima. This work proposes an alternative, data driven approach using artificial neural networks to obtain the material parameters necessary for the characterization of open porous materials. The approach only requires the results of standard impedance tube measurements. The characterization of rigid- and elastic frame materials has been investigated. The datasets were generated using the rigid and elastic frame models for porous absorbers. The approach shows good results for impedance curves generated by the analytical models, the validation with real-world impedance tube measurement data is currently under investigation. Y1 - 2025 SN - 978-3-939296-23-2 U6 - https://doi.org/10.71568/dasdaga2025.142 SP - 847 EP - 850 CY - Berlin ER - TY - JOUR A1 - Schmidt, Thomas A1 - Kröger, Roland A1 - Flege, Jan Ingo A1 - Horn-von Hoegen, Michael A1 - Clausen, T. A1 - Falta, J. A1 - Janzen, Andreas A1 - Zahl, P. A1 - Kury, P. A1 - Kammler, Martin T1 - Less strain energy despite fewer misfit dislocations: the impact of ordering JF - Physical review letters N2 - The average strain state of Ge films grown on Si(111) by surfactant mediated epitaxy has been compared to the ordering of the interfacial misfit dislocation network. Surprisingly, a smaller degree of average lattice relaxation was found in films grown at higher temperature. On the other hand, these films exhibit a better ordered dislocation network. This effect energetically compensates the higher strain at higher growth temperature, leading to the conclusion that, apart from the formation of misfit dislocations, their ordering represents an important channel for lattice-strain energy relaxation. Y1 - 2006 U6 - https://doi.org/10.1103/PhysRevLett.96.066101 VL - 96 IS - 6 PB - APS ER - TY - JOUR A1 - Hull, Robert A1 - Gray, J. L. A1 - Kammler, Martin A1 - Vandervelde, T. A1 - Kobayashi, Takeshi A1 - Kumar, P. A1 - Pernell, T. A1 - Bean, J. C. A1 - Floro, J. A. A1 - Ross, Frances M. T1 - Precision placement of heteroepitaxial semiconductor quantum dots JF - Materials Science and Engineering: B N2 - We describe two new approaches to the patterning of Si(1 0 0) surfaces for controlled nucleation of heteroepitaxial Ge semiconductor clusters. In the first method, a Ga ' -focused ion beam in situ to the growth chamber is used to create local regions of enhanced Ga ' concentration and surface topography. It is shown that at low ion doses (Â/10 14 cm (2), implanted Ga causes local nucleation of Ge clusters upon the implanted region. At higher doses (]/10 15 cm (2), a complex surface topography localizes nucleation of Ge clusters. This approach can be used to seed complex patterns of Ge clusters with diameters of tens of nanometers and positional accuracy of sub-100 nm. The second method employs self-assembly of complex strain-stabilized ''quantum quadruplet'' and ''quantum fortress'' structures, whereby cooperative island nucleation around shallow strain-relieving pits is identified during Ge x Si 1(x /Si(1 0 0) heteroepitaxy. These configurations are kinetically limited structures that exist over a range of compositions, growth temperatures, and growth rates, but which are destabilized by strain relaxation (e.g. by the introduction of misfit dislocations) and by growth conditions which provide high adatom surface mobilities. Both methods have broad potential application to nanoelectronic device architectures. 2003 Elsevier Science B.V. All rights reserved. KW - Strained layer epitaxy KW - Strain relaxation KW - Quantum fortress KW - Molecular beam epitaxy KW - Controlled nucleation Y1 - 2003 U6 - https://doi.org/10.1016/S0921-5107(02)00680-3 VL - 101 IS - 1-3 SP - 1 EP - 8 PB - Elsevier ER -