TY - GEN A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Vasiliev, V. G. A1 - Kramarenko, Elena Yu A1 - Mayer, M. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. T1 - Investigation of Dynamic Modulus and Normal Force of Magnetorheological Elastomers with Soft and Hard Magnetic Fillers T2 - NANO 2014, July 13 – 18, 2014, Moscow ; Section 06 - Polymer, Organic and Other Soft Matter Materials Y1 - 2014 CY - Moscow ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Kramarenko, Elena Yu A1 - Stepanov, Gennady V. A1 - Sorokin, Vladislav V. A1 - Stadler, Dominik A1 - Shamonin (Chamonine), Mikhail T1 - Transient magnetorheological response of magnetoactive elastomers to step and pyramid excitations JF - SOFT MATTER N2 - Transient rheological response of magnetoactive elastomers is experimentally studied using dynamic torsion at a fixed oscillation frequency in temporally stepwise changing magnetic fields and oscillation amplitudes. For step magnetic-field excitations, at least three exponential functions are required to reasonably describe the time behavior of the storage shear modulus over long time scales (>10(3) s). The deduced characteristic time constants of the corresponding rearrangement processes of the filler network differ approximately by one order of magnitude: tau(1) less than or similar to 10(1) s, tau(2) similar to 10(2) s, and tau(3) similar to 10(3) s. The sudden imposition of the external magnetic field activates a very fast rearrangement process with the characteristic time under 10 s, which cannot be determined more precisely due to the measurement conditions. Even more peculiar transient behavior has been observed during pyramid excitations, when either the external magnetic field was first stepwise increased and then decreased in a staircase manner at a fixed strain amplitude gamma or the strain amplitude gamma was first stepwise increased and then decreased in a staircase manner at a fixed magnetic field. In particular, the so-called "cross-over effect'' has been identified in both dynamical loading programs. This cross-over effect seems to be promoted by the application of the external magnetic field. The experimental results are discussed in the context of the specific rearrangement of the magnetic filler network under the simultaneous action of the external magnetic field and shear deformation. Striking similarities of the observed phenomena to the structural relaxation processes in glassy materials and to the jamming transition of granular materials are pointed out. The obtained results are important for fundamental understanding of material behavior in magnetic fields as well as for the development of devices on the basis of magnetoactive elastomeric materials. KW - AMPLITUDE KW - BEHAVIOR KW - DEPENDENCE KW - FLUID KW - HOMOGENEOUS MAGNETIC-FIELD KW - NORMAL FORCE KW - OSCILLATORY SHEAR KW - TIME KW - VISCOELASTIC PROPERTIES Y1 - 2016 U6 - https://doi.org/10.1039/c5sm02690c VL - 12 IS - 11 SP - 2901 EP - 2913 PB - ROYAL SOC CHEMISTRY ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Khokhlov, Alexei R. A1 - Kramarenko, Elena Yu T1 - Hysteresis of the viscoelastic properties and the normal force in magnetically and mechanically soft magnetoactive elastomers: Effects of filler composition, strain amplitude and magnetic field JF - Polymer N2 - Hysteresis in dynamic modulus, loss factor and normal forces of magnetoactive elastomers (MAEs) comprising various proportions of small (3-5 mu m) and large (50-60 mu m) ferromagnetic particles are experimentally studied using dynamic torsion performed at a fixed oscillation frequency in varying DC magnetic fields. It is shown that hysteresis is a characteristic feature of MAEs observed both under increasing/decreasing magnetic field strength and increasing/decreasing strain amplitude. This hysteresis is attributed to the specific rearrangement of the magnetic filler network under simultaneously applied magnetic field and shear deformation. Rheological properties of the magnetic filler network formed in the magnetic field and, therefore, the rheological properties of MAEs depend strongly on the filler composition and the magnetic field magnitude. Larger magnetic particles and higher magnetic fields provide stronger magnetic networks. Both factors result in the extension of the linear viscoelastic regime to larger strain amplitudes and lead to higher values of shear storage and loss moduli. It is found that the hysteresis width maximises at an intermediate magnetic field where it is attributed to the balance between elastic and magnetic particle interactions. This is apparently where the most significant restructuring of the magnetic network occurs. The hysteresis width decreases with increasing fraction of large particles in the magnetic filler. The loss factor grows significantly when the magnetic network is physically broken by large strains gamma > 1%. A huge (more than one order of magnitude) increase of normal force at maximum magnetic field strengths is observed. It is predicted that any physical quantity depending on the internal structuring of the magnetic filler should demonstrate hysteresis either with a changing magnetic field and constant deformation amplitude or under variable deformation in a constant magnetic field. (C) 2015 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - COMPRESSION KW - Dynamic modulus KW - GELS KW - hysteresis KW - Magnetorheological elastomers KW - magnetostriction KW - MODULUS KW - PARTICLES KW - POLYMER COMPOSITES KW - shear Y1 - 2015 U6 - https://doi.org/10.1016/j.polymer.2015.08.040 VL - 76 SP - 191 EP - 202 PB - Elsevier ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Ecker, Eva A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Kramarenko, Elena Yu A1 - Khokhlov, Alexei R. T1 - Experimental study of the magnetic field enhanced Payne effect in magnetorheological elastomers JF - Soft Matter N2 - The dynamic modulus and the loss factor of magnetorheological elastomers (MREs) of various compositions and anisotropies are studied by dynamic torsion oscillations performed in the absence and in the presence of an external magnetic field. The emphasis is on the Payne effect, i.e. the dependence of the elastomer magnetorheological characteristics on the strain amplitude and their evolution with cyclically increasing and decreasing strain amplitudes. MREs are based on two silicone matrices differing in storage modulus (soft, G' similar to 10(3) Pa, and hard, G' similar to 10(4) Pa, matrices). For each matrix, the concentration of carbonyl iron particles with diameters of 3-5 mu m was equal to 70 and 82 mass% (22 and 35 vol%, respectively) in the composite material. Samples for each filler content, isotropic and aligned-particles, are investigated. It is found that the Payne effect significantly increases in the presence of an external magnetic field and varies with the cyclical loading which reaches saturation after several cycles. The results are interpreted as the processes of formation-destruction-reformation of the internal filler structure under the simultaneously applied mechanical force and magnetic field. Impacts of matrix elasticity and magnetic interactions on the filler alignment are elucidated. KW - BEHAVIOR KW - CARRAGEENAN KW - DAMPERS KW - MODEL KW - SEALS KW - SENSITIVE ELASTOMERS KW - Shear modulus KW - VISCOELASTIC PROPERTIES KW - WIDE-RANGE MODULATION Y1 - 2014 U6 - https://doi.org/10.1039/c4sm01738b VL - 10 IS - 43 SP - 8765 EP - 8776 PB - ROYAL Society of CHEMISTRY ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Kramarenko, Elena Yu T1 - Magnetorheological behavior of magnetoactive elastomers filled with bimodal iron and magnetite particles JF - Smart materials and structures N2 - Magnetoactive elastomers (MAE) based on soft silicone matrices, filled with various proportions of large diameter ( approximately 50 mu m) iron and small diameter ( approximately 0.5 mu m) magnetite particles are synthesized. Their rheological behavior in homogeneous magnetic fields up to 600 mT is studied in detail. The addition of small magnetite particles facilitates fabrication of uniformly distributed magnetic elastomer composites by preventing aggregation and sedimentation of large particles during curing. It is shown that using the proposed bimodal filler particles it is possible to tailor various magnetorheological (MR) properties which can be useful for different target applications. In particular, either absolute or relative magnetorheological effects can be tuned. The value of the damping factor as well as the range of deformation amplitudes for the linear viscoelastic regime can be chosen. The interdependencies between different MR properties of bimodal MAEs are considered. The results are discussed in the model framework of particle network formation under the simultaneous influence of external magnetic fields and mechanical deformation. KW - damping factor KW - DAMPING PROPERTIES KW - FIELD KW - HYDROGELS KW - MAGNETOELASTIC BEHAVIOR KW - Magnetorheological effect KW - magnetorheological elastomer KW - mechanical hysteresis KW - Payne effect Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/26/3/035019 VL - 26 IS - 3 PB - IOP Publishing ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale? JF - Physical Review E N2 - The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass % of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles. KW - BEHAVIOR KW - composites KW - hysteresis KW - MAGNETIC-FIELD KW - MODEL KW - RHEOLOGY KW - RUBBER KW - SENSITIVE ELASTOMERS KW - VISCOELASTIC PROPERTIES Y1 - 2017 U6 - https://doi.org/10.1103/PhysRevE.95.062501 VL - 95 IS - 6 PB - Amer Physical Soc ER -