TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Khokhlov, Alexei R. A1 - Kramarenko, Elena Yu T1 - Hysteresis of the viscoelastic properties and the normal force in magnetically and mechanically soft magnetoactive elastomers: Effects of filler composition, strain amplitude and magnetic field JF - Polymer N2 - Hysteresis in dynamic modulus, loss factor and normal forces of magnetoactive elastomers (MAEs) comprising various proportions of small (3-5 mu m) and large (50-60 mu m) ferromagnetic particles are experimentally studied using dynamic torsion performed at a fixed oscillation frequency in varying DC magnetic fields. It is shown that hysteresis is a characteristic feature of MAEs observed both under increasing/decreasing magnetic field strength and increasing/decreasing strain amplitude. This hysteresis is attributed to the specific rearrangement of the magnetic filler network under simultaneously applied magnetic field and shear deformation. Rheological properties of the magnetic filler network formed in the magnetic field and, therefore, the rheological properties of MAEs depend strongly on the filler composition and the magnetic field magnitude. Larger magnetic particles and higher magnetic fields provide stronger magnetic networks. Both factors result in the extension of the linear viscoelastic regime to larger strain amplitudes and lead to higher values of shear storage and loss moduli. It is found that the hysteresis width maximises at an intermediate magnetic field where it is attributed to the balance between elastic and magnetic particle interactions. This is apparently where the most significant restructuring of the magnetic network occurs. The hysteresis width decreases with increasing fraction of large particles in the magnetic filler. The loss factor grows significantly when the magnetic network is physically broken by large strains gamma > 1%. A huge (more than one order of magnitude) increase of normal force at maximum magnetic field strengths is observed. It is predicted that any physical quantity depending on the internal structuring of the magnetic filler should demonstrate hysteresis either with a changing magnetic field and constant deformation amplitude or under variable deformation in a constant magnetic field. (C) 2015 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - COMPRESSION KW - Dynamic modulus KW - GELS KW - hysteresis KW - Magnetorheological elastomers KW - magnetostriction KW - MODULUS KW - PARTICLES KW - POLYMER COMPOSITES KW - shear Y1 - 2015 U6 - https://doi.org/10.1016/j.polymer.2015.08.040 VL - 76 SP - 191 EP - 202 PB - Elsevier ER - TY - JOUR A1 - Kostrov, Sergei A. A1 - Shamonin (Chamonine), Mikhail A1 - Stepanov, Gennady V. A1 - Kramarenko, Elena Yu T1 - Magnetodielectric Response of Soft Magnetoactive Elastomers: Effects of Filler Concentration and Measurement Frequency JF - International Journal of Molecular Sciences N2 - The magnetodielectric response of magnetoactive elastomers (MAEs) in its dependence on filler concentration, magnetic field, and test frequency is studied experimentally. MAEs are synthesized on the basis of a silicone matrix filled with spherical carbonyl iron particles characterized by a mean diameter of 4.5 mu m. The concentration of the magnetic filler within composite materials is equal to 70, 75, and 80 mass%. The effective lossless permittivity epsilon as well as the dielectric loss tan grow significantly when the magnetic field increases. The permittivity increases and the dielectric loss decreases with increasing filler concentration. In the measurement frequency range between 1 kHz and 200 kHz, the frequency hardly affects the values of epsilon and tan in the absence of a magnetic field. However, both parameters decrease considerably with the growing frequency in a constant magnetic field. The more strongly the magnetic field is applied, the larger the change in permittivity and loss tangent at the same test frequency is observed. An equivalent circuit formulation qualitatively describes the main tendencies of the magnetodielectric response. KW - dielectric loss KW - magnetic filler KW - MAGNETIC-FIELD KW - magnetoactive elastomers KW - magnetodielectric effect KW - permittivity Y1 - 2019 U6 - https://doi.org/10.3390/ijms20092230 VL - 20 IS - 9 SP - 1 EP - 13 PB - MDPI CY - Basel ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Ecker, Eva A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Kramarenko, Elena Yu A1 - Khokhlov, Alexei R. T1 - Experimental study of the magnetic field enhanced Payne effect in magnetorheological elastomers JF - Soft Matter N2 - The dynamic modulus and the loss factor of magnetorheological elastomers (MREs) of various compositions and anisotropies are studied by dynamic torsion oscillations performed in the absence and in the presence of an external magnetic field. The emphasis is on the Payne effect, i.e. the dependence of the elastomer magnetorheological characteristics on the strain amplitude and their evolution with cyclically increasing and decreasing strain amplitudes. MREs are based on two silicone matrices differing in storage modulus (soft, G' similar to 10(3) Pa, and hard, G' similar to 10(4) Pa, matrices). For each matrix, the concentration of carbonyl iron particles with diameters of 3-5 mu m was equal to 70 and 82 mass% (22 and 35 vol%, respectively) in the composite material. Samples for each filler content, isotropic and aligned-particles, are investigated. It is found that the Payne effect significantly increases in the presence of an external magnetic field and varies with the cyclical loading which reaches saturation after several cycles. The results are interpreted as the processes of formation-destruction-reformation of the internal filler structure under the simultaneously applied mechanical force and magnetic field. Impacts of matrix elasticity and magnetic interactions on the filler alignment are elucidated. KW - BEHAVIOR KW - CARRAGEENAN KW - DAMPERS KW - MODEL KW - SEALS KW - SENSITIVE ELASTOMERS KW - Shear modulus KW - VISCOELASTIC PROPERTIES KW - WIDE-RANGE MODULATION Y1 - 2014 U6 - https://doi.org/10.1039/c4sm01738b VL - 10 IS - 43 SP - 8765 EP - 8776 PB - ROYAL Society of CHEMISTRY ER - TY - CHAP A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu ED - Domracheva, Natalia ED - Caporali, Maria ED - Rentschler, Eva T1 - Highly Responsive Magnetoactive Elastomers (Chapter 7) T2 - Novel Magnetic Nanostructures N2 - This chapter introduces composite smart materials known as magnetoactive (MAEs) or magnetorheological elastomers. It starts by defining these materials and distinguishing them from relevant magnetorheological fluids and ferrofluids. It then gives the overview of constitutive materials for the polymer matrix and filler particles. Next, the influence of external magnetic field on physical properties of MAEs is discussed. The emphasis is made on mechanical properties, which are the most important for real-world applications. In particular, magnetomechanical effects such as magnetostriction, magnetodeformation, and magnetorheological effect are discussed. The magnetic Payne effect is presented as an example of a nonlinear behavior. Electromagnetic and acoustic properties are also considered. The chapter finishes with the brief discussion of the future prospects in research and development of MAEs. Y1 - 2018 SN - 9780128135945 U6 - https://doi.org/10.1016/B978-0-12-813594-5.00007-2 SP - 221 EP - 245 PB - Elsevier ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Kramarenko, Elena Yu T1 - Magnetorheological behavior of magnetoactive elastomers filled with bimodal iron and magnetite particles JF - Smart materials and structures N2 - Magnetoactive elastomers (MAE) based on soft silicone matrices, filled with various proportions of large diameter ( approximately 50 mu m) iron and small diameter ( approximately 0.5 mu m) magnetite particles are synthesized. Their rheological behavior in homogeneous magnetic fields up to 600 mT is studied in detail. The addition of small magnetite particles facilitates fabrication of uniformly distributed magnetic elastomer composites by preventing aggregation and sedimentation of large particles during curing. It is shown that using the proposed bimodal filler particles it is possible to tailor various magnetorheological (MR) properties which can be useful for different target applications. In particular, either absolute or relative magnetorheological effects can be tuned. The value of the damping factor as well as the range of deformation amplitudes for the linear viscoelastic regime can be chosen. The interdependencies between different MR properties of bimodal MAEs are considered. The results are discussed in the model framework of particle network formation under the simultaneous influence of external magnetic fields and mechanical deformation. KW - damping factor KW - DAMPING PROPERTIES KW - FIELD KW - HYDROGELS KW - MAGNETOELASTIC BEHAVIOR KW - Magnetorheological effect KW - magnetorheological elastomer KW - mechanical hysteresis KW - Payne effect Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/26/3/035019 VL - 26 IS - 3 PB - IOP Publishing ER - TY - JOUR A1 - Nadzharyan, Timur A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Theoretical Modeling of Magnetoactive Elastomers on Different Scales: A State-of-the-Art Review JF - Polymers N2 - A review of the latest theoretical advances in the description of magnetomechanical effects and phenomena observed in magnetoactive elastomers (MAEs), i.e., polymer networks filled with magnetic micro- and/or nanoparticles, under the action of external magnetic fields is presented. Theoretical modeling of magnetomechanical coupling is considered on various spatial scales: from the behavior of individual magnetic particles constrained in an elastic medium to the mechanical properties of an MAE sample as a whole. It is demonstrated how theoretical models enable qualitative and quantitative interpretation of experimental results. The limitations and challenges of current approaches are discussed and some information about the most promising lines of research in this area is provided. The review is aimed at specialists involved in the study of not only the magnetomechanical properties of MAEs, but also a wide range of other physical phenomena occurring in magnetic polymer composites in external magnetic fields. KW - magnetodeformation KW - magnetorheological effect KW - mechanical properties KW - magnetic particles KW - theoretical modeling KW - magnetorheological elastomersn KW - magnetoactive elastomers Y1 - 2022 U6 - https://doi.org/10.3390/polym14194096 VL - 14 IS - 19 SP - 1 EP - 42 PB - MDPI ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Kramarenko, Elena Yu A1 - Stepanov, Gennady V. A1 - Sorokin, Vladislav V. A1 - Stadler, Dominik A1 - Shamonin (Chamonine), Mikhail T1 - Transient magnetorheological response of magnetoactive elastomers to step and pyramid excitations JF - SOFT MATTER N2 - Transient rheological response of magnetoactive elastomers is experimentally studied using dynamic torsion at a fixed oscillation frequency in temporally stepwise changing magnetic fields and oscillation amplitudes. For step magnetic-field excitations, at least three exponential functions are required to reasonably describe the time behavior of the storage shear modulus over long time scales (>10(3) s). The deduced characteristic time constants of the corresponding rearrangement processes of the filler network differ approximately by one order of magnitude: tau(1) less than or similar to 10(1) s, tau(2) similar to 10(2) s, and tau(3) similar to 10(3) s. The sudden imposition of the external magnetic field activates a very fast rearrangement process with the characteristic time under 10 s, which cannot be determined more precisely due to the measurement conditions. Even more peculiar transient behavior has been observed during pyramid excitations, when either the external magnetic field was first stepwise increased and then decreased in a staircase manner at a fixed strain amplitude gamma or the strain amplitude gamma was first stepwise increased and then decreased in a staircase manner at a fixed magnetic field. In particular, the so-called "cross-over effect'' has been identified in both dynamical loading programs. This cross-over effect seems to be promoted by the application of the external magnetic field. The experimental results are discussed in the context of the specific rearrangement of the magnetic filler network under the simultaneous action of the external magnetic field and shear deformation. Striking similarities of the observed phenomena to the structural relaxation processes in glassy materials and to the jamming transition of granular materials are pointed out. The obtained results are important for fundamental understanding of material behavior in magnetic fields as well as for the development of devices on the basis of magnetoactive elastomeric materials. KW - AMPLITUDE KW - BEHAVIOR KW - DEPENDENCE KW - FLUID KW - HOMOGENEOUS MAGNETIC-FIELD KW - NORMAL FORCE KW - OSCILLATORY SHEAR KW - TIME KW - VISCOELASTIC PROPERTIES Y1 - 2016 U6 - https://doi.org/10.1039/c5sm02690c VL - 12 IS - 11 SP - 2901 EP - 2913 PB - ROYAL SOC CHEMISTRY ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Kramarenko, Elena Yu A1 - Shamonin (Chamonine), Mikhail T1 - Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis JF - POLYMER N2 - Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - composites KW - DIELECTRIC-PROPERTIES KW - hysteresis KW - MAGNETIC-FIELD KW - magnetoactive elastomer KW - magnetodielectric effect KW - Magnetorhelogical elastomer KW - MELT STATE KW - MICROSTRUCTURE KW - POLYMER DEGRADATION KW - PROGRESS KW - Smart material KW - THERMOOXIDATIVE DEGRADATION KW - TIME-RESOLVED RHEOLOGY KW - Transient response Y1 - 2017 U6 - https://doi.org/10.1016/j.polymer.2017.08.056 VL - 127 SP - 119 EP - 128 PB - ELSEVIER ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale? JF - Physical Review E N2 - The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass % of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles. KW - BEHAVIOR KW - composites KW - hysteresis KW - MAGNETIC-FIELD KW - MODEL KW - RHEOLOGY KW - RUBBER KW - SENSITIVE ELASTOMERS KW - VISCOELASTIC PROPERTIES Y1 - 2017 U6 - https://doi.org/10.1103/PhysRevE.95.062501 VL - 95 IS - 6 PB - Amer Physical Soc ER - TY - GEN A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Vasiliev, V. G. A1 - Kramarenko, Elena Yu A1 - Mayer, Matthias A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. T1 - Investigation of Dynamic Modulus and Normal Force of Magnetorheological Elastomers with Soft and Hard Magnetic Fillers T2 - NANO 2014, July 13 – 18, 2014, Moscow ; Section 06 - Polymer, Organic and Other Soft Matter Materials Y1 - 2014 CY - Moscow ER - TY - JOUR A1 - Romeis, Dirk A1 - Kostrov, Sergei A. A1 - Kramarenko, Elena Yu A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Saphiannikova, Marina T1 - Magnetic-field-induced stress in confined magnetoactive elastomers JF - Soft Matter N2 - We present a theoretical approach for calculating the state of stress induced by a uniform magnetic field in confined magnetoactive elastomers of arbitrary shape. The theory explicitly includes the magnetic field generated by magnetizable spherical inclusions in the sample interior assuming a non-linear magnetization behavior. The initial spatial distribution of particles and its change in an external magnetic field are considered. This is achieved by the introduction of an effective demagnetizing factor where both the sample shape and the material microstructure are taken into account. Theoretical predictions are fitted to the stress data measured using a specifically designed experimental setup. It is shown that the theory enables the quantification of the effect of material microstructure upon introducing a specific microstructural factor and its derivative with respect to the extensional strain in the undeformed state. The experimentally observed differences between isotropic and anisotropic samples, compliant and stiff elastomer matrices are explained. Y1 - 2020 U6 - https://doi.org/10.1039/D0SM01337D VL - 16 IS - 39 SP - 9047 EP - 9058 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Savelev, Dmitrii V. A1 - Belyaeva, Inna A. A1 - Chashin, Dmitri V. A1 - Fetisov, Leonid Y. A1 - Romeis, Dirk A1 - Kettl, Wolfgang A1 - Kramarenko, Elena Yu A1 - Saphiannikova, Marina A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail T1 - Giant extensional strain of magnetoactive elastomeric cylinders in uniform magnetic fields JF - Materials N2 - Elongations of magnetoactive elastomers (MAEs) under ascending–descending uniform magnetic fields were studied experimentally using a laboratory apparatus specifically designed to measure large extensional strains (up to 20%) in compliant MAEs. In the literature, such a phenomenon is usually denoted as giant magnetostriction. The synthesized cylindrical MAE samples were based on polydimethylsiloxane matrices filled with micrometer-sized particles of carbonyl iron. The impact of both the macroscopic shape factor of the samples and their magneto-mechanical characteristics were evaluated. For this purpose, the aspect ratio of the MAE cylindrical samples, the concentration of magnetic particles in MAEs and the effective shear modulus were systematically varied. It was shown that the magnetically induced elongation of MAE cylinders in the maximum magnetic field of about 400 kA/m, applied along the cylinder axis, grew with the increasing aspect ratio. The effect of the sample composition is discussed in terms of magnetic filler rearrangements in magnetic fields and the observed experimental tendencies are rationalized by simple theoretical estimates. The obtained results can be used for the design of new smart materials with magnetic-field-controlled deformation properties, e.g., for soft robotics. KW - magnetostriction KW - magnetoactive elastomer KW - extensional strain KW - hysteresis KW - magnetomechanical effect KW - magnetodeformation Y1 - 2020 U6 - https://doi.org/10.3390/ma13153297 SN - 1996-1944 N1 - Corresponding author: Mikhail Shamonin VL - 13 IS - 15 SP - 1 EP - 17 PB - MDPI CY - Basel ER -