TY - JOUR A1 - Gärtner, Sebastian A1 - Marx-Schubach, Thomas A1 - Gaderer, Matthias A1 - Schmitz, Gerhard A1 - Sterner, Michael T1 - Techno-Economic Analysis of Carbon Dioxide Separation for an Innovative Energy Concept towards Low-Emission Glass Melting JF - energies N2 - The currently still high fossil energy demand is forcing the glass industry to search for innovative approaches for the reduction in CO2 emissions and the integration of renewable energy sources. In this paper, a novel power-to-methane concept is presented and discussed for this purpose. A special focus is on methods for the required CO2 capture from typical flue gases in the glass industry, which have hardly been explored to date. To close this research gap, process simulation models are developed to investigate post-combustion CO2 capture by absorption processes, followed by a techno-economic evaluation. Due to reduced flue gas volume, the designed CO2 capture plant is found to be much smaller (40 m3 absorber column volume) than absorption-based CO2 separation processes for power plants (12,560 m3 absorber column volume). As there are many options for waste heat utilization in the glass industry, the waste heat required for CO2 desorption can be generated in a particularly efficient and cost-effective way. The resulting CO2 separation costs range between 41 and 42 EUR/t CO2, depending on waste heat utilization for desorption. These costs are below the values of 50–65 EUR/t CO2 for comparable industrial applications. Despite these promising economic results, there are still some technical restrictions in terms of solvent degradation due to the high oxygen content in flue gas compositions. The results of this study point towards parametric studies for approaching these issues, such as the use of secondary and tertiary amines as solvents, or the optimization of operating conditions such as stripper pressure for further cost reductions potential. KW - economic evaluation KW - CO2-separation KW - glass industry KW - oxyfuel KW - methanation KW - power-to-gas Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-53627 N1 - Corresponding author: Sebastian Gärtner VL - 16 IS - 5 SP - 1 EP - 25 PB - MDPI CY - Basel ER - TY - INPR A1 - Gärtner, Sebastian A1 - Marx-Schubach, Thomas A1 - Gaderer, Matthias A1 - Schmitz, Gerhard A1 - Sterner, Michael T1 - Introduction of an Innovative Energy Concept for low Emission Glass Melting based on Carbon Capture and Usage N2 - Due to the very high fossil energy demand, the glass industry is looking for innovative approaches for the reduction of CO2 emissions and the integration of renewable energy sources. In this paper, we present a novel power-to-gas concept, which has no impact on established melting processes and discuss it for this purpose. A special focus is set on the required CO2 capture from typical flue gases in the glass industry, as this process has not been investigated in detail yet. We used a process simulation approach to investigate post-combustion CO2 capture by absorption processes, followed by a techno-economic evaluation. Our investigations found the designed CO2 capture plant to be approx. 400 times smaller than absorption based CO2 separation processes for conventional power plants. Due to the many options for waste heat utilization, the waste heat required for CO2 desorption can be generated in a particularly efficient and cost-effective way. The resulting CO2 avoidance costs range between 41-42 €/t CO2, depending on waste heat utilization for desorption, and thus offer a cost effective way of CO2 removal from glass industry melting processes. These costs are well below the values of 50-65 €/t CO2 described so far for comparable industrial applications. In addition, we describe optimization options, like solvent and process improvements, to enable further cost reductions. These results motivate further research and development on the overall process presented in this work. KW - glass KW - Oxyfuel KW - Methanation KW - Power-to-Gas KW - CO2 capture KW - Economic Analysis Y1 - 2022 U6 - https://doi.org/10.31224/2642 ER -