TY - JOUR A1 - Kurzweil, Peter A1 - Scheuerpflug, Wolfgang T1 - State-of-charge monitoring and battery diagnosis of different lithium ion chemistries using impedance spectroscopy JF - Batteries N2 - For lithium iron phosphate batteries (LFP) in aerospace applications, impedance spectroscopy is applicable in the flat region of the voltage-charge curve. The frequency-dependent pseudocapacitance at 0.15 Hz is presented as useful state-of-charge (SOC) and state-of-health (SOH) indicator. For the same battery type, the prediction error of pseudocapacitance is better than 1% for a quadratic calibration curve, and less than 36% for a linear model. An approximately linear correlation between pseudocapacitance and Ah battery capacity is observed as long as overcharge and deep discharge are avoided. We verify the impedance method in comparison to the classical constant-current discharge measurements. In the case of five examined lithium-ion chemistries, the linear trend of impedance and SOC is lost if the slope of the discharge voltage curve versus SOC changes. With nickel manganese cobalt (NMC), high impedance modulus correlates with high SOC above 70%. KW - battery life testing KW - capacitance KW - lithium-ion battery KW - state-of-charge determination KW - state-of-health KW - pseudocharge KW - impedance spectroscopy KW - aging Y1 - 2021 U6 - https://doi.org/10.3390/batteries7010017 VL - 7 IS - 1 ER -