TY - JOUR A1 - Loo, Xuyan A1 - Nagaraju, Bhavana A1 - Pathivada, Sai A1 - Bartsch, Alexander A1 - Schratzenstaller, Thomas A1 - Sattler, Robert A1 - Monkman, Gareth J. T1 - Electrical properties of bisphenol-A-free magnetoactive borosilicate polymers JF - AIP Advances N2 - The recent REACH regulations require the elimination of bisphenol-A and titanium dioxide from commercially available boron-based polymers. This has led to changes in some of the mechanical characteristics, which strongly influence the properties of magnetoactive borosilicate polymers. This work delivers results on the electrical properties and discusses some implications for future research using bisphenol-A and titanium-dioxide-free substitutes. KW - Electrical components KW - Electrical properties and parameters KW - Dielectric properties KW - Electrical resistivity KW - Magnetic materials KW - Viscoelasticity KW - Polymers KW - Non Newtonian fluids KW - Magnetic fluids Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-72936 SN - 2158-3226 N1 - Corresponding author der OTH Regensburg: Gareth J. Monkman VL - 14 IS - 5 PB - AIP Publishing ER - TY - JOUR A1 - Putz, Christoph A1 - Schirmer, Maximilian A1 - Sattler, Robert A1 - Monkman, Gareth J. T1 - Fabrication of Bisphenol-free Boron-Siloxane Polymers JF - Materials Chemistry and Physics N2 - Interest in the preparation of magnetoactive boron-siloxane polymers (MBP) has been stimulated by recent scientific developments. However, recent regulations have prohibited the inclusion of Bisphenol-A normally employed in the manufacture of commercially available products. In the following publication, two different routes for the preparation of magnetoactive borosiloxane polymers have been taken. First, the possibilities of obtaining homogeneous mixtures of magnetoactive polymers by mixing the magnetic particles with the polymer using solid CO2 (dry ice) and stirring (shearing) are investigated. In the course of the work, an approach for the preparation of reference materials of different viscosities was made to prove the transferability to other elastomers. This is then followed by a brief review of the reaction of the polymer with different solvents in relation to the mixing with particles. In manually kneaded compounds, dispersions ranging from 0.00004 to 0.004 particles per mm3 are common. The process described in this work resulted in agglomerations of no greater than 0.00004 particles per mm3 A possible synthesis route for bisphenol-free boron-siloxanes is then considered, in which for the polymer matrix, polydimethylsilanes (dichloro(methyl)silane), boric acid and iron(III)chloride are used for this purpose by polycondensation. Y1 - 2025 U6 - https://doi.org/10.1016/j.matchemphys.2025.130567 N1 - Corresponding author der OTH Regensburg: Gareth J. Monkman PB - Elsevier ET - Journal Pre-proof ER -