TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Infrared spectral analysis of low concentration magnetoactive polymers JF - Journal of Applied Polymer Science N2 - This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366. KW - ELASTOMERS KW - magnetism and magnetic properties KW - sensors and actuators KW - spectroscopy Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-25913 SN - 1097-4628 N1 - Corresponding author: Nina Prem VL - 137 IS - 7 SP - 1 EP - 7 PB - Wiley ER - TY - JOUR A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Self-assembling structure formation in low-density magnetoactive polymers JF - Journal of Applied Polymer Science N2 - The formation of microstructures in magnetoactive polymers (MAPs) is a recently discovered phenomenon found only with very low filler particle concentrations (less than 3 wt %). Due to the degassing process, filler particles collect around an ascending bubble, which dissolves at a certain point leaving particulate rings within the matrix. The formation of toroidal microstructures commences as filler concentration approaches 1 wt %. The development of coherent parallel aligned rings with a compact order continues as particle concentrations increase toward 2 wt %. Between 2 and 3 wt % capillary doublets develop, while mass percentages higher than 3% result in increasing entropy as the random order of particle agglomeration found in higher concentration MAP dominates. Self-structured samples of different filler material and concentrations between 1 and 3 wt % have been investigated using X-ray tomography, where the emerging structures can be observed and visualized. The ring structures resulting from this research represent microinductivities which can be fabricated in a targeted manner, thus enabling new applications in the high-frequency radio field. Furthermore, these anisotropic, but well-organized, structures have magnetic field-dependent implications for optical, thermal, acoustic, and medical applications. KW - composites KW - ELASTOMERS KW - magnetism and magnetic properties KW - Particle KW - PERMEABILITY KW - self-assembly KW - sensors and actuators KW - VISCOELASTIC PROPERTIES KW - X-ray Y1 - 2019 U6 - https://doi.org/10.1002/app.48291 VL - 137 IS - 3 PB - Wiley ER -