TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina T1 - Magnetically enhanced photoconductive high voltage control JF - ISSS Journal of Micro and Smart Systems N2 - The recent surge of interest in electrostatic actuators, particularly for soft robotic applications, has placed increasing demands on high voltage control technology. In this respect, optoelectronic bidirectional switching and analogue regulation of high voltages is becoming increasingly important. One common problem is the leakage current due to dark resistance of the material or device used. Another is the physical size of such elements. However, their ability to provide galvanic separation makes them a very attractive alternative to conventional (wired) semiconductor elements. This paper gives an overview of available methods and devices before introducing a concept based on the combination of photoresistive and magnetoresistive effects in Gallium Arsenide that are potentially applicable to other semiconductor materials. KW - GaAs KW - High voltage actuators KW - Magnetoresistance KW - Opto-sensors KW - Photoconduction KW - Soft robotics Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-30606 N1 - Corresponding author: Gareth J. Monkman VL - 11 SP - 317 EP - 328 PB - Springer Nature ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Striegl, Birgit A1 - Prem, Nina A1 - Sindersberger, Dirk T1 - Electrical Properties of Magnetoactive Boron‐Organo‐Silicon Oxide Polymers JF - Macromolecular Chemistry and Physics N2 - The electrical properties of rheopectic magnetoactive composites comprising boron-organo-silicon oxide dielectric matrices containing carbonyl iron microparticles are presented for the first time. The increase in interfacial magnetocapacitance is seen to greatly exceed that experienced when using conventional elastomeric matrices such as polydimethylsiloxane. In addition to the increase in capacitance, a simultaneous and sharp decrease in the parallel electrical resistance over several orders of magnitude is also observed. The effects are time dependent but repeatable. Potential applications include magnetically controlled frequency dependent devices, magnetic sensor systems, weighting elements for neural networks, etc. Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-26488 N1 - Corresponding author: Gareth J. Monkman VL - 221 IS - 4 SP - 1 EP - 8 PB - Wiley ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Infrared spectral analysis of low concentration magnetoactive polymers JF - Journal of Applied Polymer Science N2 - This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366. KW - ELASTOMERS KW - magnetism and magnetic properties KW - sensors and actuators KW - spectroscopy Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-25913 SN - 1097-4628 N1 - Corresponding author: Nina Prem VL - 137 IS - 7 SP - 1 EP - 7 PB - Wiley ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Striegl, Birgit A1 - Böhm, Valter A1 - Monkman, Gareth J. T1 - Shape memory effects using magnetoactive Boron-organo-silicon oxide polymers JF - Macromolecular Chemistry and Physics N2 - Thermomechanical shape memory materials have certain disadvantages when it comes to 3D volumetric reproduction intended for rapid prototyping or robotic prehension. The need to constantly supply energy to counteract elastic retraction forces in order to maintain the required geometry, together with the inability to achieve conformal stability at elevated temperatures, limits the application of thermal shape memory polymers. Form removal also presents problems as most viscoelastic materials do not ensure demolding stability. This work demonstrates how magnetoactive boron−organo−silicon oxide polymers under the influence of an applied magnetic field can be used to achieve energy free sustainable volumetric shape memory effects over extended periods. The rheopectic properties of boron−organo−silicon oxide materials sustain form removal without mold distortion. Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-23205 N1 - Corresponding Author: Gareth J. Monkman VL - 221 IS - 15 SP - 1 EP - 8 PB - Wiley ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Diermeier, Andreas A1 - Prem, Nina T1 - The magnetoactive electret JF - smart materials and structures N2 - A magnet which adheres to every surface, not only those of ferromagnetic materials, has hitherto been the domain of science fiction. Now for the first time such a novel device exists. The fusion of a permanently magnetized magnetoactive polymer containing hard magnetic particles and an electret enhanced with ferroelectric particles has resulted in the development of a new smart device-the magnetoactive electret. Magnetoactive electrets can be made to exhibit the usual magnetic properties of permanent magnetism together with the electrostatic properties of electrets. This results in simultaneous magnetoadhesion and electroadhesion forces from the same elastomeric element. The biasing field, needed to avoid discontinuities concerned with transition through the zero point in operating curves, is normally provided by means of either a magnetic or an electric field. This novel technology provides both bias options in a single device. KW - 6D printing KW - electret KW - electroadhesion KW - FLUIDS KW - MAGNETIC-FIELD KW - magnetoactive electret KW - magnetoactive polymer KW - magnetoadhesion KW - Magnetorheological elastomers KW - RHEOLOGY Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/aa738f VL - 26 IS - 7 PB - IOP Publishing ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Diermeier, Andreas A1 - Szecsey, Tamara T1 - Dielectric behaviour of magnetic hybrid materials JF - Physical Sciences Reviews N2 - The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt% CIP) were also investigated. With filler concentrations lower than 3 wt%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt%. Above 3 wt% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1%–3 wt% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found. KW - cappillary doublet KW - diamagnetic KW - elastomer dielectric KW - FTIR KW - interfacial magnetocapacitance KW - magnetoactive polymer KW - PDMS KW - toroid Y1 - 2021 U6 - https://doi.org/10.1515/psr-2019-0121 N1 - Corresponding author: Gareth J. Monkman VL - 7 IS - 10 SP - 1169 EP - 1185 PB - de Gruyter ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Mini-Extruder for 3D Magnetoactive Polymer Printing JF - Advances in Materials Science and Engineering N2 - This work describes the development of a new miniature extruder, essential to cavity-free 3D printing of silicone-based smart materials. This makes the 3D printing of magnetoactive and electroactive polymer soft robotic components and devices directly from CAD data possible. The special feature of such an extruder is that it is designed for use with addition-crosslinking RTV-2 silicones, including solid particulate additives. The extruder merges the respective components automatically during extrusion which obviates the need for premixing and vacuum evacuation. Problems associated with inhomogeneities and unwanted cavity production are consequently eliminated. Rheological details necessary to the design, together with some preliminary performance results, are presented. Y1 - 2019 U6 - https://doi.org/10.1155/2019/8715718 N1 - Corresponding author: Gareth J. Monkman SP - 1 EP - 8 PB - HINDAWI ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Szecsey, Tamara T1 - Smart Stiction JF - Robotics & Automation Engineering Journal N2 - Soft robotics could loosely be described as the engineering science of expanded dexterity through controllable flexibility. The exploitation of controllable compliance through the judicious choice of soft flexible members, as opposed to a finite number of rigid kinematic joints, can result in greater dexterity without compromising simplicity. One example is the replacement of segmented mechanical legs with simple compliant material eruciform prolegs. To achieve this in robotics, without introducing additional mechanical joints, mobile surfaces with switchable coefficients of friction is essential. This paper explains how, using silicone based smart materials, the rapid alternation between kinematic and static friction (stiction) may be achieved. Y1 - 2019 U6 - https://doi.org/10.19080/RAEJ.2019.04.555641 N1 - Corresponding author: Gareth J. Monkman VL - 4 IS - 4 PB - Juniper Publishers ER - TY - JOUR A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Structure formation in low concentration magnetoactive polymers JF - AIP advances N2 - This paper concerns recent research into the autonomous formation of micro-structures in low carbonyl iron powder (CIP) concentration magneto active polymers (MAP). Higher concentrations of CIP show an isotropic distribution of magnetic filler throughout the entire sample, while autonomous structure formation is possible at mass concentrations lower than 3%. The formation of micro-toroids commences as CIP concentration approaches 1% wt. Further development of coherent rings with a defined order follow as CIP concentrations increase toward 2% wt, whilst exceeding 3% wt leads to the same isotropic distribution found in higher concentration MAP. Structured samples containing between 1% wt and 3% wt CIP were investigated using X-Ray tomography where solitary structures could clearly be observed. The ring structures represent microinductivities whose geometries can be manipulated during fabrication. In addition, these structures are magnetic field sensitive. This is not only relevant to applications in the GHz and THz areas but recent research has revealed implications for optical, thermal, acoustic and even chemical MAP sensors. (C) 2019 Author(s). Y1 - 2019 U6 - https://doi.org/10.1063/1.5079997 N1 - Corresponding author: Dirk Sindersberger VL - 9 IS - 3 PB - AIP Publishing ER - TY - JOUR A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Self-assembling structure formation in low-density magnetoactive polymers JF - Journal of Applied Polymer Science N2 - The formation of microstructures in magnetoactive polymers (MAPs) is a recently discovered phenomenon found only with very low filler particle concentrations (less than 3 wt %). Due to the degassing process, filler particles collect around an ascending bubble, which dissolves at a certain point leaving particulate rings within the matrix. The formation of toroidal microstructures commences as filler concentration approaches 1 wt %. The development of coherent parallel aligned rings with a compact order continues as particle concentrations increase toward 2 wt %. Between 2 and 3 wt % capillary doublets develop, while mass percentages higher than 3% result in increasing entropy as the random order of particle agglomeration found in higher concentration MAP dominates. Self-structured samples of different filler material and concentrations between 1 and 3 wt % have been investigated using X-ray tomography, where the emerging structures can be observed and visualized. The ring structures resulting from this research represent microinductivities which can be fabricated in a targeted manner, thus enabling new applications in the high-frequency radio field. Furthermore, these anisotropic, but well-organized, structures have magnetic field-dependent implications for optical, thermal, acoustic, and medical applications. KW - composites KW - ELASTOMERS KW - magnetism and magnetic properties KW - Particle KW - PERMEABILITY KW - self-assembly KW - sensors and actuators KW - VISCOELASTIC PROPERTIES KW - X-ray Y1 - 2019 U6 - https://doi.org/10.1002/app.48291 VL - 137 IS - 3 PB - Wiley ER - TY - JOUR A1 - Prem, Nina A1 - Chavez Vega, Jhohan Harvey A1 - Böhm, Valter A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. A1 - Zimmermann, Klaus T1 - Properties of Polydimethylsiloxane and Magnetoactive Polymers with Electroconductive Particles JF - Macromolecular Chemistry and Physics N2 - Magnetoactive polymers are intelligent materials whose mechanical and electrical characteristics are reversibly influenced by external magnetic stimuli. They consist of a highly elastic polymer matrix in which magnetically soft and/or hard particles are distributed by means of special fabrication processes. In addition to ferromagnetic particles such as carbonyl iron powder, electrically conductive particles may also be embedded into the polymer matrix. After characterizing a range of compounds, this work focuses on a comparison of the electrical properties and the suitability of various materials for applications, with particular emphasis on integration into 3D and 6D printing processes. 6D printing is based on the selective positioning of particles in a 3D polymer matrix with a further three degrees of freedom for a graduated dispersion of the particles at certain points and in desired directions. The aim is therefore to ensure that the polymers containing electroconductive tracks have the best possible electrical properties, that is, low resistivity but are still capable of being printed. A comparison between the traditionally used compounds containing graphite and carbon black is made for the first time. This latter is found to be greatly superior both in terms of electrical conductivity and applicability to 3D printing and 6D printing. KW - 3D printing KW - 6D printing KW - carbon black KW - composites KW - electroconductive particles KW - graphite KW - magnetoactive polymers KW - polydimethylsiloxane KW - STRAIN, *MRU Y1 - 2018 U6 - https://doi.org/10.1002/macp.201800222 VL - 219 IS - 18 PB - Wiley ER - TY - JOUR A1 - Zimmermann, Klaus A1 - Böhm, Valter A1 - Becker T.I., A1 - Chavez Vega, Jhohan Harvey A1 - Kaufhold, Tobias A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Diermeier, Andreas A1 - Prem, Nina T1 - Mechanical Characterization of the Field-Dependent Properties of Magnetoactive Polymers and Integrated Electrets for their Application in Soft Robotics JF - International Scientific Journal "Problems of Mechanics" Y1 - 2017 SN - 1512-0740 VL - 69 IS - 4 ER - TY - JOUR A1 - Zimmermann, Klaus A1 - Chavez Vega, Jhohan Harvey A1 - Becker, Tatiana I. A1 - Witte, Hartmut A1 - Schilling, Cornelius A1 - Köhring, Sebastian A1 - Böhm, Valter A1 - Monkman, Gareth J. A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Lutz, I. I. A1 - Merker, Lukas T1 - An approach to a form-adaptive compliant gripper element based on magneto-sensitive elastomers with a bioinspired sensorized surface JF - Problems of Mechanics Y1 - 2019 SN - 1512-0740 VL - 75 IS - 2 SP - 23 EP - 38 PB - Georgian Technical University CY - Tbilisi ER -