TY - JOUR A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Self-assembling structure formation in low-density magnetoactive polymers JF - Journal of Applied Polymer Science N2 - The formation of microstructures in magnetoactive polymers (MAPs) is a recently discovered phenomenon found only with very low filler particle concentrations (less than 3 wt %). Due to the degassing process, filler particles collect around an ascending bubble, which dissolves at a certain point leaving particulate rings within the matrix. The formation of toroidal microstructures commences as filler concentration approaches 1 wt %. The development of coherent parallel aligned rings with a compact order continues as particle concentrations increase toward 2 wt %. Between 2 and 3 wt % capillary doublets develop, while mass percentages higher than 3% result in increasing entropy as the random order of particle agglomeration found in higher concentration MAP dominates. Self-structured samples of different filler material and concentrations between 1 and 3 wt % have been investigated using X-ray tomography, where the emerging structures can be observed and visualized. The ring structures resulting from this research represent microinductivities which can be fabricated in a targeted manner, thus enabling new applications in the high-frequency radio field. Furthermore, these anisotropic, but well-organized, structures have magnetic field-dependent implications for optical, thermal, acoustic, and medical applications. KW - composites KW - ELASTOMERS KW - magnetism and magnetic properties KW - Particle KW - PERMEABILITY KW - self-assembly KW - sensors and actuators KW - VISCOELASTIC PROPERTIES KW - X-ray Y1 - 2019 U6 - https://doi.org/10.1002/app.48291 VL - 137 IS - 3 PB - Wiley ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Diermeier, Andreas A1 - Prem, Nina T1 - The magnetoactive electret JF - smart materials and structures N2 - A magnet which adheres to every surface, not only those of ferromagnetic materials, has hitherto been the domain of science fiction. Now for the first time such a novel device exists. The fusion of a permanently magnetized magnetoactive polymer containing hard magnetic particles and an electret enhanced with ferroelectric particles has resulted in the development of a new smart device-the magnetoactive electret. Magnetoactive electrets can be made to exhibit the usual magnetic properties of permanent magnetism together with the electrostatic properties of electrets. This results in simultaneous magnetoadhesion and electroadhesion forces from the same elastomeric element. The biasing field, needed to avoid discontinuities concerned with transition through the zero point in operating curves, is normally provided by means of either a magnetic or an electric field. This novel technology provides both bias options in a single device. KW - 6D printing KW - electret KW - electroadhesion KW - FLUIDS KW - MAGNETIC-FIELD KW - magnetoactive electret KW - magnetoactive polymer KW - magnetoadhesion KW - Magnetorheological elastomers KW - RHEOLOGY Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/aa738f VL - 26 IS - 7 PB - IOP Publishing ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Szecsey, Tamara T1 - Smart Stiction JF - Robotics & Automation Engineering Journal N2 - Soft robotics could loosely be described as the engineering science of expanded dexterity through controllable flexibility. The exploitation of controllable compliance through the judicious choice of soft flexible members, as opposed to a finite number of rigid kinematic joints, can result in greater dexterity without compromising simplicity. One example is the replacement of segmented mechanical legs with simple compliant material eruciform prolegs. To achieve this in robotics, without introducing additional mechanical joints, mobile surfaces with switchable coefficients of friction is essential. This paper explains how, using silicone based smart materials, the rapid alternation between kinematic and static friction (stiction) may be achieved. Y1 - 2019 U6 - https://doi.org/10.19080/RAEJ.2019.04.555641 N1 - Corresponding author: Gareth J. Monkman VL - 4 IS - 4 PB - Juniper Publishers ER - TY - JOUR A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Structure formation in low concentration magnetoactive polymers JF - AIP advances N2 - This paper concerns recent research into the autonomous formation of micro-structures in low carbonyl iron powder (CIP) concentration magneto active polymers (MAP). Higher concentrations of CIP show an isotropic distribution of magnetic filler throughout the entire sample, while autonomous structure formation is possible at mass concentrations lower than 3%. The formation of micro-toroids commences as CIP concentration approaches 1% wt. Further development of coherent rings with a defined order follow as CIP concentrations increase toward 2% wt, whilst exceeding 3% wt leads to the same isotropic distribution found in higher concentration MAP. Structured samples containing between 1% wt and 3% wt CIP were investigated using X-Ray tomography where solitary structures could clearly be observed. The ring structures represent microinductivities whose geometries can be manipulated during fabrication. In addition, these structures are magnetic field sensitive. This is not only relevant to applications in the GHz and THz areas but recent research has revealed implications for optical, thermal, acoustic and even chemical MAP sensors. (C) 2019 Author(s). Y1 - 2019 U6 - https://doi.org/10.1063/1.5079997 N1 - Corresponding author: Dirk Sindersberger VL - 9 IS - 3 PB - AIP Publishing ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Mini-Extruder for 3D Magnetoactive Polymer Printing JF - Advances in Materials Science and Engineering N2 - This work describes the development of a new miniature extruder, essential to cavity-free 3D printing of silicone-based smart materials. This makes the 3D printing of magnetoactive and electroactive polymer soft robotic components and devices directly from CAD data possible. The special feature of such an extruder is that it is designed for use with addition-crosslinking RTV-2 silicones, including solid particulate additives. The extruder merges the respective components automatically during extrusion which obviates the need for premixing and vacuum evacuation. Problems associated with inhomogeneities and unwanted cavity production are consequently eliminated. Rheological details necessary to the design, together with some preliminary performance results, are presented. Y1 - 2019 U6 - https://doi.org/10.1155/2019/8715718 N1 - Corresponding author: Gareth J. Monkman SP - 1 EP - 8 PB - HINDAWI ER - TY - JOUR A1 - Sindersberger, Dirk A1 - Diermeier, Andreas A1 - Prem, Nina A1 - Monkman, Gareth J. T1 - Printing of hybrid magneto active polymers with 6 degrees of freedom JF - Materials today communications N2 - 3D printing techniques offer a versatile method for the fabrication and structuring of magnetoactive polymer (MAP) components and devices for research prototype development. MAP materials enjoy an advantage in that the particulate content may be manipulated by external magnetic fields during the forming and curing processes. Controlled particle diffusion within the polymer matrix, by means of external fields applied during the printing process, influences a further three spatial dimensions. This permits control of the spatial particle concentration and makes free displacement of particle accumulations possible during the crosslinking phase. Particles which are susceptible to electric or magnetic fields can thereby be shifted into regions previously free of particles. The additional 3 graded dispersion axes effectively results in what can be described as 6 degrees of freedom (6DOF) printing. Electrically conductive polymers combined with non-conductive areas, provide an additional benefit for the production of complex hybrid structures. This may be augmented by the combination of magnetically active thermoplastics as inelastic structural components together with mechanically deformable elastomers. The combination of all fabrication methods in one hybrid printing process makes the production of complex sensor and actuator systems in one manufacturing sequence possible. This far exceeds the capabilities of conventional casting and machining operations and opens new possibilities for the fabrication of soft material elements. KW - 3D printing KW - Conductive polymer KW - Hybrid KW - Magnetoactive KW - Polymer Y1 - 2018 U6 - https://doi.org/10.1016/j.mtcomm.2018.02.032 VL - 15 IS - June SP - 269 EP - 274 PB - Elsevier ER - TY - CHAP A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. A1 - Zimmermann, Klaus ED - Schlaak, Helmut T1 - Self-Sensing Electroadhesive Polymer Gripper with Magnetically Controllable Surface Geometry T2 - Actuator 2021, International Conference and Exhibition on New Actuator Systems and Applications: GMM conference, February 17-19, 2021, online event N2 - Compared to conventional end effectors, electro-adhesive grippers enable the handling of sensitive, soft or air-permeable materials [1]. The prehension force is based on a strong electric field generated by electrodes resulting in a polarisation of the dielectric and the generation of mirror charges in the workpiece. When the electrode supply voltage is deactivated, the electric field drops,but an electrostatic field remains due to remanent polarisation of the dielectric. The residual charge on the gripper surface reduces only slowly and in combination with other influencing factors can prevent the workpieces from being ejected temporarily or completely. In this work a solution to this problem is presented by means of gripper surface deforming caused by the applicat ion of a magnetic field to a magneto- active polymer (MAP) actuator. The in-creased distance between the workpiece and the dielectric enables precise and controlled ejection. In addition to compliance and deformability, the employment of soft smart materials enables the integration of self-sens-ing mechanisms for the measurement of surface deformation. The embedding of electrically conductive flexible electrodes within the soft silicone dielectric sup port such movements and serves as the n ecessary electrodes for electroadhesion. Since the implementation of the end effectoris based entirely on soft materials, the self-sensing magnetically controllable electroadhesive gripper (SMEG) can be produced in a shape deposition manufacturing (SDM) process [2], [3] and is highly applicable to the field of soft robotics. Y1 - 2021 SN - 9783800754540 U6 - https://doi.org/10.1002/macp.201800222 SP - 318 EP - 320 PB - VDE VERLAG CY - Berlin; Offenbach ER - TY - GEN A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Spectroscopic Analysis of Magneto-Active Polymers (MAP) - Poster T2 - DFG-Tagung, Benediktbeuern, September 2017 Y1 - 2017 ER - TY - JOUR A1 - Zimmermann, Klaus A1 - Chavez, Jhohan A1 - Becker, Tatiana I. A1 - Witte, Hartmut A1 - Schilling, Cornelius A1 - Köhring, Sebastian A1 - Böhm, Valter A1 - Monkman, Gareth J. A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Lutz, I. I. A1 - Merker, L. T1 - An approach to a form-adaptive compliant gripper element based on magneto-sensitive elastomers with a bioinspired sensorized surface JF - Problems of Mechanics Y1 - 2019 SN - 1512-0740 VL - 75 IS - 2 SP - 23 EP - 38 PB - Georgian Technical University CY - Tbilisi ER - TY - JOUR A1 - Prem, Nina A1 - Chavez, Jhohan A1 - Böhm, Valter A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. A1 - Zimmermann, Klaus T1 - Properties of Polydimethylsiloxane and Magnetoactive Polymers with Electroconductive Particles JF - Macromolecular Chemistry and Physics N2 - Magnetoactive polymers are intelligent materials whose mechanical and electrical characteristics are reversibly influenced by external magnetic stimuli. They consist of a highly elastic polymer matrix in which magnetically soft and/or hard particles are distributed by means of special fabrication processes. In addition to ferromagnetic particles such as carbonyl iron powder, electrically conductive particles may also be embedded into the polymer matrix. After characterizing a range of compounds, this work focuses on a comparison of the electrical properties and the suitability of various materials for applications, with particular emphasis on integration into 3D and 6D printing processes. 6D printing is based on the selective positioning of particles in a 3D polymer matrix with a further three degrees of freedom for a graduated dispersion of the particles at certain points and in desired directions. The aim is therefore to ensure that the polymers containing electroconductive tracks have the best possible electrical properties, that is, low resistivity but are still capable of being printed. A comparison between the traditionally used compounds containing graphite and carbon black is made for the first time. This latter is found to be greatly superior both in terms of electrical conductivity and applicability to 3D printing and 6D printing. KW - 3D printing KW - 6D printing KW - carbon black KW - composites KW - electroconductive particles KW - graphite KW - magnetoactive polymers KW - polydimethylsiloxane KW - STRAIN, *MRU Y1 - 2018 U6 - https://doi.org/10.1002/macp.201800222 VL - 219 IS - 18 PB - Wiley ER -