TY - JOUR A1 - Monkman, Gareth J. A1 - Striegl, Birgit A1 - Prem, Nina A1 - Sindersberger, Dirk T1 - Electrical Properties of Magnetoactive Boron‐Organo‐Silicon Oxide Polymers JF - Macromolecular Chemistry and Physics N2 - The electrical properties of rheopectic magnetoactive composites comprising boron-organo-silicon oxide dielectric matrices containing carbonyl iron microparticles are presented for the first time. The increase in interfacial magnetocapacitance is seen to greatly exceed that experienced when using conventional elastomeric matrices such as polydimethylsiloxane. In addition to the increase in capacitance, a simultaneous and sharp decrease in the parallel electrical resistance over several orders of magnitude is also observed. The effects are time dependent but repeatable. Potential applications include magnetically controlled frequency dependent devices, magnetic sensor systems, weighting elements for neural networks, etc. Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-26488 N1 - Corresponding author: Gareth J. Monkman VL - 221 IS - 4 SP - 1 EP - 8 PB - Wiley ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Infrared spectral analysis of low concentration magnetoactive polymers JF - Journal of Applied Polymer Science N2 - This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366. KW - ELASTOMERS KW - magnetism and magnetic properties KW - sensors and actuators KW - spectroscopy Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-25913 SN - 1097-4628 N1 - Corresponding author: Nina Prem VL - 137 IS - 7 SP - 1 EP - 7 PB - Wiley ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Striegl, Birgit A1 - Böhm, Valter A1 - Monkman, Gareth J. T1 - Shape memory effects using magnetoactive Boron-organo-silicon oxide polymers JF - Macromolecular Chemistry and Physics N2 - Thermomechanical shape memory materials have certain disadvantages when it comes to 3D volumetric reproduction intended for rapid prototyping or robotic prehension. The need to constantly supply energy to counteract elastic retraction forces in order to maintain the required geometry, together with the inability to achieve conformal stability at elevated temperatures, limits the application of thermal shape memory polymers. Form removal also presents problems as most viscoelastic materials do not ensure demolding stability. This work demonstrates how magnetoactive boron−organo−silicon oxide polymers under the influence of an applied magnetic field can be used to achieve energy free sustainable volumetric shape memory effects over extended periods. The rheopectic properties of boron−organo−silicon oxide materials sustain form removal without mold distortion. Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-23205 N1 - Corresponding Author: Gareth J. Monkman VL - 221 IS - 15 SP - 1 EP - 8 PB - Wiley ER - TY - JOUR A1 - Chen, Rui A1 - Zhang, Zhuo A1 - Song, Ruizhou A1 - Fang, Cheng A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. A1 - Guo, Jianglong T1 - Time-dependent electroadhesive force degradation JF - Smart Materials and Structures N2 - This paper concerns a comprehensive investigation of time-dependent electroadhesion (EA) force degradation. EA shear force tests on different object materials (a PET, glass, ABS, and wood plate) have shown that force degradation was dominated by residual polarization charges trapped in the EA pad dielectric rather than in the substrate dielectric from which the object to be prehended is made. In order to explain this dynamic physical phenomenon, a model of dielectric polarization and depolarization has been proposed. According to the derived relationship between EA force and discharge time, three different methods intended to mitigate this problem has been compared: (1) the natural discharge method, (2) the high voltage resistor discharge method, and (3) the discharge prior to field polarity reversal method. These methods are useful for generating repeatable and stable EA forces, which are required for the characterization of EA pads and their subsequent employment in material handling, mobile robot crawling and climbing tasks. Y1 - 2020 U6 - https://doi.org/10.1088/1361-665X/ab79b5 VL - 29 IS - 5 PB - IOP Publishing ER - TY - JOUR A1 - Lang, Alexander A1 - Monkman, Gareth J. T1 - An analysis of the electrical capacitance between two conducting spheres JF - Journal of Electrostatics N2 - Many modern composites consist of dielectric polymer matrices containing embedded spherical particles. These particles can be electrically conducting and often have magnetic properties. In order to accurately model and simulate such materials, precise calculation of the electrical capacitance between identically sized spheres is required. This is of particular relevance at microscopic dimensions where many smart material-based micro devices are concerned. This may appear trivial for a small number of particles. However, many methods or their analysis appear to be questionable or not applicable at reduced dimensions. In this work, the various methods of analysis are scrutinized before being compared with both simulation and direct measurements. It is surprising to note that of the many works investigated only 3 are in close agreement with both simulation and measurement. Graphical abstract This paper deals with the precise calculation of the electrical capacitance between two conducting spheres of equal, or near equal size.The calculations have been verified by both experimental measurements and simulation. Algorithms in MatLab (Octave) format have been included in the supporting information. KW - Capacitance between spheres KW - Calculation KW - Simulation Experiment Y1 - 2020 U6 - https://doi.org/10.1016/j.elstat.2020.103518 VL - 108 PB - Elsevier ER - TY - JOUR A1 - Metsch, P. A1 - Schmidt, Henrik A1 - Sindersberger, Dirk A1 - Kalina, K. A. A1 - Brummund, J. A1 - Auernhammer, Günter A1 - Monkman, Gareth J. A1 - Kästner, Markus T1 - Field-Induced Interactions in Magneto-Active Elastomers BT - A Comparison of Experiments and Simulations JF - Smart Materials and Structures N2 - In this contribution, field-induced interactions of magnetizable particles embedded into a soft elastomer matrix are analyzed with regard to the resulting mechanical deformations. By comparing experiments for two-, three- and four-particle systems with the results of finite element simulations, a fully coupled continuum model for magneto-active elastomers is validated with the help of real data for the first time. The model under consideration permits the investigation of magneto-active elastomers with arbitrary particle distances, shapes and volume fractions as well as magnetic and mechanical properties of the individual constituents. It thus represents a basis for future studies on more complex, realistic systems. Our results show a very good agreement between experiments and numerical simulations—the deformation behavior of all systems is captured by the model qualitatively as well as quantitatively. Within a sensitivity analysis, the influence of the initial particle positions on the systems' response is examined. Furthermore, a comparison of the full three-dimensional model with the often used, simplified two-dimensional approach shows the typical overestimation of resulting interactions in magneto-active elastomers. Y1 - 2020 U6 - https://doi.org/10.1088/1361-665X/ab92dc N1 - Corrigendum: Field-induced interactions in magneto-active elastomers—a comparison of experiments and simulations (2020 Smart Mater. Struct. 29 085026); https://doi.org/10.1088/1361-665X/abb98b VL - 29 IS - 8 SP - 1 EP - 10 PB - IOPscience ER -