TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Diermeier, Andreas A1 - Szecsey, Tamara T1 - Dielectric behaviour of magnetic hybrid materials JF - Physical Sciences Reviews N2 - The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt% CIP) were also investigated. With filler concentrations lower than 3 wt%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt%. Above 3 wt% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1%–3 wt% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found. KW - cappillary doublet KW - diamagnetic KW - elastomer dielectric KW - FTIR KW - interfacial magnetocapacitance KW - magnetoactive polymer KW - PDMS KW - toroid Y1 - 2021 U6 - https://doi.org/10.1515/psr-2019-0121 N1 - Corresponding author: Gareth J. Monkman VL - 7 IS - 10 SP - 1169 EP - 1185 PB - de Gruyter ER - TY - JOUR A1 - Schmidt, Henrik A1 - Straub, Benedikt B. A1 - Sindersberger, Dirk A1 - Bröckel, Ulrich A1 - Monkman, Gareth J. A1 - Auernhammer, Günter T1 - Collision and separation of nickel particles embedded in a Poly dimethylsiloxan matrix under a rotating magnetic field: A strong magneto active function JF - Colloid and Polymer Science N2 - In order to function as soft actuators, depending on their field of use, magnetorheological elastomers (MREs) must fulfill certain criteria. To name just a few, these can include rapid response to external magnetic fields, mechanical durability, mechanical strength, and/or large deformation. Of particular interest are MREs which produce macroscopic deformation for small external magnetic field variations. This work demonstrates how this can be achieved by just a small change in magnetic field orientation. To achieve this, (super)paramagnetic nickel particles of size ≈ 160 μm were embedded in a non-magnetic polydimethylsiloxan (PDMS) (661–1301 Pa) and their displacement in a stepwise rotated magnetic field (170 mT) recorded using a video microscope. Changes in particle aggregation resulting from very small variations in magnetic field orientation led to the observation of a new strongly magneto-active effect. This configuration is characterized by an interparticle distance in relation to the angle difference between magnetic field and particle axis. This causes a strong matrix deformation which in turn demonstrates hysteresis on relaxation. It is shown that the occurrence strongly depends on the particle size, particle distance, and stiffness of the matrix. Choosing the correct parameter combination, the state can be suppressed and the particle-matrix system demonstrates no displacement or hysteresis. In addition, evidences of non-negligible higher order magnetization effects are experimentally ascertained which is qualitatively in agreement with similar, already theoretically described, particle systems. Even at larger particle geometries, the new strongly magneto-active configuration is preserved and could create macroscopic deformation changes. Y1 - 2021 U6 - https://doi.org/10.1007/s00396-020-04784-4 VL - 299 SP - 955 EP - 967 PB - Springer ER - TY - CHAP A1 - Sefl, Ondrej A1 - Prochazka, Radek A1 - Haller, Rainer A1 - Monkman, Gareth J. T1 - Alternative Approach to Optical Detection of Partial Discharges in Air T2 - 2021 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP): 12-15 Dec. 2021, Vancouver, BC, Canada N2 - This article compares the standard electrical method of partial discharge detection with a novel optical detection method based on silicon photomultipliers. A third, complementary, single-loop antenna method is added to represent the ultra-high frequency method commonly used in gas-insulated switchgear/lines. A trio of air-insulated electrode designs that simulate the fundamental fault/discharge types in gaseous insulation (protrusion – corona discharge, floating conductive particle, surface discharges) are employed. Phase-resolved partial discharge activity patterns are compiled for each electrode design. The patterns are analyzed using spatial statistics and the interpretation of the obtained data trends explained by means of an example. Ultimately, the consistency and reliability of discharge detection by the optical methods for each fault/discharge type are evaluated, and suggestions for improvement are made. KW - gas insulated switchgear KW - loop antennas KW - partial discharges KW - photomultipliers KW - reliability KW - statistical analysis KW - surface discharges Y1 - 2021 SN - 978-1-6654-1907-9 U6 - https://doi.org/10.1109/CEIDP50766.2021.9705350 SN - 2576-2397 SP - 324 EP - 327 PB - IEEE ER - TY - CHAP A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Monkman, Gareth J. A1 - Zimmermann, Klaus ED - Schlaak, Helmut T1 - Self-Sensing Electroadhesive Polymer Gripper with Magnetically Controllable Surface Geometry T2 - Actuator 2021, International Conference and Exhibition on New Actuator Systems and Applications: GMM conference, February 17-19, 2021, online event N2 - Compared to conventional end effectors, electro-adhesive grippers enable the handling of sensitive, soft or air-permeable materials [1]. The prehension force is based on a strong electric field generated by electrodes resulting in a polarisation of the dielectric and the generation of mirror charges in the workpiece. When the electrode supply voltage is deactivated, the electric field drops,but an electrostatic field remains due to remanent polarisation of the dielectric. The residual charge on the gripper surface reduces only slowly and in combination with other influencing factors can prevent the workpieces from being ejected temporarily or completely. In this work a solution to this problem is presented by means of gripper surface deforming caused by the applicat ion of a magnetic field to a magneto- active polymer (MAP) actuator. The in-creased distance between the workpiece and the dielectric enables precise and controlled ejection. In addition to compliance and deformability, the employment of soft smart materials enables the integration of self-sens-ing mechanisms for the measurement of surface deformation. The embedding of electrically conductive flexible electrodes within the soft silicone dielectric sup port such movements and serves as the n ecessary electrodes for electroadhesion. Since the implementation of the end effectoris based entirely on soft materials, the self-sensing magnetically controllable electroadhesive gripper (SMEG) can be produced in a shape deposition manufacturing (SDM) process [2], [3] and is highly applicable to the field of soft robotics. Y1 - 2021 SN - 9783800754540 U6 - https://doi.org/10.1002/macp.201800222 SP - 318 EP - 320 PB - VDE VERLAG CY - Berlin; Offenbach ER - TY - CHAP A1 - Schrimer, M A1 - Putz, Christoph A1 - Monkman, Gareth J. ED - McConnell, Lynn T1 - Boron-Silicone-Oxide Polymers T2 - Boron: advances in research and applications Y1 - 2021 SN - 9781685072315 SN - 1685072313 U6 - https://doi.org/10.52305/AFKU5564 SP - 117 EP - 179 PB - Nova Science Publishers CY - New York, NY ER -