TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Kramarenko, Elena Yu T1 - Magnetorheological behavior of magnetoactive elastomers filled with bimodal iron and magnetite particles JF - Smart materials and structures N2 - Magnetoactive elastomers (MAE) based on soft silicone matrices, filled with various proportions of large diameter ( approximately 50 mu m) iron and small diameter ( approximately 0.5 mu m) magnetite particles are synthesized. Their rheological behavior in homogeneous magnetic fields up to 600 mT is studied in detail. The addition of small magnetite particles facilitates fabrication of uniformly distributed magnetic elastomer composites by preventing aggregation and sedimentation of large particles during curing. It is shown that using the proposed bimodal filler particles it is possible to tailor various magnetorheological (MR) properties which can be useful for different target applications. In particular, either absolute or relative magnetorheological effects can be tuned. The value of the damping factor as well as the range of deformation amplitudes for the linear viscoelastic regime can be chosen. The interdependencies between different MR properties of bimodal MAEs are considered. The results are discussed in the model framework of particle network formation under the simultaneous influence of external magnetic fields and mechanical deformation. KW - damping factor KW - DAMPING PROPERTIES KW - FIELD KW - HYDROGELS KW - MAGNETOELASTIC BEHAVIOR KW - Magnetorheological effect KW - magnetorheological elastomer KW - mechanical hysteresis KW - Payne effect Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/26/3/035019 VL - 26 IS - 3 PB - IOP Publishing ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Kramarenko, Elena Yu A1 - Shamonin (Chamonine), Mikhail T1 - Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis JF - POLYMER N2 - Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - composites KW - DIELECTRIC-PROPERTIES KW - hysteresis KW - MAGNETIC-FIELD KW - magnetoactive elastomer KW - magnetodielectric effect KW - Magnetorhelogical elastomer KW - MELT STATE KW - MICROSTRUCTURE KW - POLYMER DEGRADATION KW - PROGRESS KW - Smart material KW - THERMOOXIDATIVE DEGRADATION KW - TIME-RESOLVED RHEOLOGY KW - Transient response Y1 - 2017 U6 - https://doi.org/10.1016/j.polymer.2017.08.056 VL - 127 SP - 119 EP - 128 PB - ELSEVIER ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale? JF - Physical Review E N2 - The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass % of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles. KW - BEHAVIOR KW - composites KW - hysteresis KW - MAGNETIC-FIELD KW - MODEL KW - RHEOLOGY KW - RUBBER KW - SENSITIVE ELASTOMERS KW - VISCOELASTIC PROPERTIES Y1 - 2017 U6 - https://doi.org/10.1103/PhysRevE.95.062501 VL - 95 IS - 6 PB - Amer Physical Soc ER -