TY - JOUR A1 - Thiel, Charlotte A1 - Kratzer, Johanna A1 - Grimm, Benedikt A1 - Kränkel, Thomas A1 - Gehlen, Christoph T1 - Effect of Internal Moisture and Outer Relative Humidity on Concrete Carbonation JF - CivilEng N2 - With steadily rising CO2 concentrations in the ambient air and fast-changing concretecompositions with reduced clinker contents, the availability of reliable and accelerated concrete car-bonation tests is of crucial importance to design durable structures. This paper focuses on the effectsof moisture under accelerated conditions and the effects of different CO2 exposure conditions. Mor-tar prisms incorporating three different cement types were cured and stored at either 50% or 65%relative humidity (RH). Afterwards, the prisms were carbonated at different ambient humidities(50, 57 and 65%), different CO2 concentrations (0.04, 1 and 3 vol.%) and complemented by a seriesof tests at increased gas pressure (2 barg). High-resolution test methods were used to explain theunderlying carbonation mechanisms. The results show that pre-conditioning for two weeks—ascurrently suggested by the European Standard—seems to be too short because the initial inner mois-ture content severely affects the carbonation rate. Relative humidity during carbonation of 57% ledto higher carbonation rates compared to 50% and 65%. In addition, climate data needs to be period-ically (preferably permanently) recorded in research experiments and in laboratory testing to ensurefair interpretation of experimental results. KW - accelerated carbonation KW - concrete KW - moisture KW - durability KW - relative humidity Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-56091 N1 - Corresponding author: Charlotte Thiel VL - 4 IS - 3 SP - 1039 EP - 1052 PB - MDPI CY - Basel ER - TY - JOUR A1 - Haynack, Alexander A1 - Sekandar, Zadran A1 - Jithender, J. Timothy A1 - Gambarelli, Serena A1 - Kränkel, Thomas A1 - Thiel, Charlotte A1 - Ozbolt, Josko A1 - Gehlen, Christoph T1 - Can a Hend-Held 3D Scanner Capture Temperature-Induced Strain of Mortar Samples? Comparison between Experimental Measurements and Numerical Simulations JF - mathematics N2 - The expected lifespan of cement-based materials, particularly concrete, is at least 50 years. Changes in the pore structure of the material need to be considered due to external influences and associated transport processes. The expansion behaviour of concrete and mortar during freeze–thaw attacks, combined with de-icing salt agents, is crucial for both internal and external damage. It is essential to determine and simulate the expansion behaviour of these materials in the laboratory, as well as detect the slow, long-term expansion in real structures. This study measures the expansion of mortar samples during freeze–thaw loading using a high-resolution hand-held 3D laser scanner. The specimens are prepared with fully or partially saturated pore structures through water storage or drying. During freeze–thaw experiments, the specimens are exposed to pure water or a 3% sodium chloride solution (NaCl). Results show contraction during freezing and subsequent expansion during thawing. Both test solutions exhibit similar expansion behaviour, with differences primarily due to saturation levels. Further investigations are required to explore the changing expansion behaviour caused by increasing microcracking resulting from continuous freeze–thaw cycles. A numerical analysis using a 3D coupled hygro-thermo-mechanical (HTM) model is conducted to examine the freeze–thaw behaviour of the mortar. The model accurately represents the freezing deformation during the freeze–thaw cycle. KW - concrete KW - mortar KW - durability KW - freeze–thaw and de-icing salt resistance KW - strain KW - 3D laser scanning KW - numerical simulation KW - 3D FE numerical model KW - hygro-thermo-mechanical coupling Y1 - 2023 U6 - https://doi.org/10.3390/math11173672 VL - 11 IS - 17 PB - MDPI CY - Basel ER - TY - CHAP A1 - Haynack, Alexander A1 - Schneider, Alexander A1 - Timothy, Jithender J. A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Effect of Chloride Concentration on the Freeze-Thaw Resistance of Concrete T2 - International RILEM Conference on Synergising expertise towards sustainability and robustness of CBMs and concrete structures, SynerCrete’23 - Volume 2 N2 - Performance test methods intend to provide a fast, accurate and precise determination of a particular building material property and thus determine the associated material performance. In concrete, various performance tests are used to classify existing or to approve new materials, to compare concrete compositions or to determine causes of damage in existing structures. The challenge of such test methods is to accelerate natural (very slow) mechanisms to determine the material performance precisely within a short time. However, the attack on the material must not be unrealistically intensive, but must represent reality, just in fast motion. The performance tests used to demonstrate the freeze-thaw resistance of concrete employ a 3% NaCl solution, with literature data ranging from 1% to 10% showing that low concentrations can result in higher surface scaling. In this paper, mortar and concrete specimens are tested at 0, 1, 3, 6, and 9% NaCl solution following the CDF procedure (DIN CEN/TS 12390-9:2017-05). The results are discussed against the background of the existing literature and show that the damage is critically dependent on the pore system and thus also on the effect of the micro-ice lens pump. With increasing freeze-thaw exposition, the pessimum in the external damage shifts towards a de-icing salt concentration of 6%. Furthermore, a novel test methodology based on 3D-laserscanning is presented to determine scaling accurately by eliminating side effects that are typically present in current standards. KW - Concrete KW - durability KW - freeze-thaw resistance KW - chloride concentration KW - 3D laser scanning Y1 - 2023 U6 - https://doi.org/10.1007/978-3-031-33187-9_83 SP - 911 EP - 921 PB - Springer CY - Cham ER - TY - CHAP A1 - Grimm, Benedikt A1 - Münchmeyer, Sebastian A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Developing a New Rapid, Relevant, and Reliable (R3) Method for Accelerated Measurement of Carbonation Progress at Gas Overpressure T2 - International RILEM Conference on Synergising expertise towards sustainability and robustness of CBMs and concrete structures, SynerCrete’23 - Volume 1 N2 - The determination of durability-relevant material resistances of concrete is of great importance. They serve as input to engineering models to predict the durability of structures under real environmental conditions. The natural resistances have to be determined in time-consuming experiments, since the processes in nature are very slow. This is particularly important for new materials where long-term experience is not yet available. Thus, accelerated testing is required. Only that way new materials can be evaluated regarding their durability and subsequently be used in practical applications. For carbonation, a new R3 accelerated test method is presented in this contribution. An automated carbonation pressure chamber was developed. It consists of a pressure vessel, automated in such a way that it can apply gas overpressure of various intensities up to 8 bar to mortar and concrete samples. Simultaneously, it can control and regulate the ambient CO2 concentration from 0 to 99.5% in a fully automated and continuously variable procedure. Experiments were carried out with varying combinations of gas overpressure at CO2 concentrations of 3 vol.-% to achieve the most time-efficient carbonation of mortars and concretes. Mortars with different material compositions were used to evaluate the general suitability of the test procedure with the developed equipment. The automated carbonation pressure chamber enables reliable carbonation testing with a total duration under accelerated conditions of only 7 days. KW - Carbonation KW - concrete KW - durability KW - accelerated testing KW - gas overpressure Y1 - 2023 U6 - https://doi.org/10.1007/978-3-031-33211-1_30 SP - 336 EP - 346 PB - Springer ER - TY - JOUR A1 - Haynack, Alexander A1 - Timothy, Jithender J. A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Analyse des Frost‐Tausalz‐Widerstands zementgebundener Baustoffe mittels 3D‐Laserscanning JF - ce/papers: Proceedings in Civil Engineering N2 - Eine Herausforderung performancebasierter Prüfverfahren zur Bewertung der Dauerhaftigkeit ist die Beschleunigung natürlicher Mechanismen. Dies ist notwendig, um innerhalb kurzer Zeit die Langzeit-Leistungsfähigkeit ermitteln zu können. Die Bestimmung der Frost-Tausalzbeständigkeit von Beton kann durch den CDF-Test erfolgen, welcher für Betone mit ausreichendem Frost-Tausalz-Widerstand sehr gut funktioniert. Bei Proben mit einer unzureichenden bzw. unbekannten Performance können erhöhte Randabwitterungen auftreten, welche durch das Ablösen des seitlichen Abdichtbands entstehen. Der zunehmende Randeinfluss führt so zu einer Verfälschung der Ergebnisse und zu einer Unterschätzung der tatsächlichen Performance des Bauteils. In diesem Beitrag werden Mörtel- und Betonprobekörper mit unterschiedlichen Abwitterungsraten in Anlehnung an das CDF-Verfahren untersucht. Zusätzlich wird die Oberflächenschädigung der Proben anhand einer neuartigen Messmethode mittels hochauflösendem 3D-Laserscanning ausgewertet. Die Ergebnisse zeigen, dass die Randeffekte mit der Laserscan-Methode umgangen und vergleichbare Ergebnisse zu den CDF-Untersuchungen erzielt werden können. Somit können Betone ohne Randeinflüsse charakterisiert und eine präzise Prognose der Langzeitbeständigkeit getroffen werden. KW - Beton KW - Mörtel KW - Frost-Tausalz-Widerstand KW - Dauerhaftigkeit KW - 3D-Laserscanning Y1 - 2023 U6 - https://doi.org/10.1002/cepa.2951 SN - 2509-7075 VL - 6 IS - 6 SP - 1189 EP - 1196 PB - Ernst & Sohn ER - TY - JOUR A1 - Grimm, Benedikt A1 - Thiel, Charlotte A1 - Kränkel, Thomas A1 - Gehlen, Christoph T1 - Einfluss der Permeation auf die Carbonatisierung von Beton JF - ce/papers: Proceedings in Civil Engineering N2 - Die Carbonatisierung von Beton kann einerseits zu Schäden bei Stahlbetonbauwerken führen, andererseits kann der Beton so CO2 speichern und damit seinen CO2-Fußabdruck verringern. In diesem Beitrag wird dargestellt, wie eine effiziente Beschleunigung der Carbonatisierung durch Anlegen eines geringen äußeren Drucks erreicht werden kann. Damit wird neben der Diffusion der wesentlich schneller ablaufende Transportmechanismus der Permeation ausgenutzt, der das CO2 tiefer in das Probeninnere transportiert und damit in kurzer Zeit die Bestimmung des Carbonatisierungswiderstand zementgebundener Materialien ermöglicht. Hierzu wurde eine Prüfeinrichtung entwickelt, die es ermöglicht, die CO2-Konzentration und in gewissen Grenzen auch relative Luftfeuchte sowie die Temperatur gezielt einzustellen und zu steuern, um so Mörtel- und Betonproben schnell und präzise zu carbonatisieren. Der Einfluss verschiedener Druckstufen und Wechselzyklen wird dargelegt und die resultierenden chemischen und physikalischen Veränderungen der Proben bestimmt. Als besonders effizient und gleichzeitig realitätsnah erwies sich die konstante CO2-Beaufschlagung mit 3 Vol.-% CO2 mit zusätzlichem, moderatem Gasdruck. Das hier entwickelte Verfahren kann daher genutzt werden, um Betone schnell und effizient in zeitraffenden Materialtests hinsichtlich Carbonatisierungswiderstand zu charakterisieren. KW - Beton KW - Carbonatisierung KW - Prüfverfahren KW - Gasdruck KW - Permeation Y1 - 2023 U6 - https://doi.org/10.1002/cepa.3005 SN - 2509-7075 VL - 6 IS - 6 SP - 1348 EP - 1357 PB - Ernst & Sohn CY - Berlin ER - TY - CHAP A1 - Thiel, Charlotte A1 - Hechtl, C. Maximilian A1 - Gehlen, Christoph A1 - Kränkel, Thomas ED - Lowke, Dirk ED - Freund, Niklas ED - Böhler, David ED - Herding, Friedrich T1 - Sustainability Potential of Additive Manufactured Concrete Structures – Studies on the Life Cycle Assessment and Circularity of an Extruded Exterior Wall T2 - Fourth RILEM International Conference on Concrete and Digital Fabrication (DC 2024), Munich, Germany, September 2024 N2 - The Brundtland Report defined sustainable development as a development that meets the needs of the present without compromising the ability of future generations to meet their own needs. If this definition is applied to the construction sector, a new, circular approach to cementitious materials is required. Additive manufacturing (AM) enables to design material-efficient and monolithic structures that meet physical and chemical requirements of building standards while allowing reuse or high-quality recycling of concrete. Here, the environmental impact as well as the circularity potential of an additively manufactured exterior wall, produced by 3D concrete extrusion, are determined. To classify the results, the additively manufactured exterior wall is compared with a conventional concrete construction. Finally, various options for optimizing the printed wall are considered and evaluated. Additive manufacturing enabled significant material savings compared to conventional construction. The environmental impacts strongly depend on the used concrete composition. For example, greenhouse gas emissions could be reduced by 20% when changing the type of lightweight aggregate. The additively manufactured exterior wall exhibited advantages in terms of circularity. Through further development and research, additive manufacturing of concrete can promote a paradigm shift towards sustainable practices. Y1 - 2024 SN - 978-3-031-70030-9 U6 - https://doi.org/10.1007/978-3-031-70031-6_2 SP - 13 EP - 21 PB - SPRINGER INTERNATIONAL PU ER -