TY - JOUR A1 - Belyaeva, Inna A. A1 - Kramarenko, Elena Yu A1 - Shamonin (Chamonine), Mikhail T1 - Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis JF - POLYMER N2 - Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - composites KW - DIELECTRIC-PROPERTIES KW - hysteresis KW - MAGNETIC-FIELD KW - magnetoactive elastomer KW - magnetodielectric effect KW - Magnetorhelogical elastomer KW - MELT STATE KW - MICROSTRUCTURE KW - POLYMER DEGRADATION KW - PROGRESS KW - Smart material KW - THERMOOXIDATIVE DEGRADATION KW - TIME-RESOLVED RHEOLOGY KW - Transient response Y1 - 2017 U6 - https://doi.org/10.1016/j.polymer.2017.08.056 VL - 127 SP - 119 EP - 128 PB - ELSEVIER ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Belyaeva, Inna A. A1 - Shamonin (Chamonine), Mikhail A1 - Kramarenko, Elena Yu T1 - Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale? JF - Physical Review E N2 - The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass % of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles. KW - BEHAVIOR KW - composites KW - hysteresis KW - MAGNETIC-FIELD KW - MODEL KW - RHEOLOGY KW - RUBBER KW - SENSITIVE ELASTOMERS KW - VISCOELASTIC PROPERTIES Y1 - 2017 U6 - https://doi.org/10.1103/PhysRevE.95.062501 VL - 95 IS - 6 PB - Amer Physical Soc ER - TY - JOUR A1 - Belyaeva, Inna A. A1 - Klepp, Jürgen A1 - Lemmel, Hartmut A1 - Shamonin (Chamonine), Mikhail T1 - Feasibility of Probing the Filler Restructuring in Magnetoactive Elastomers by Ultra-Small-Angle Neutron Scattering JF - Applied Sciences N2 - Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 x 10(-5) and 1.85 x 10(-4) angstrom(-1). It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered. KW - Anisotropy KW - Ferrofluids KW - hysteresis KW - magnetoactive elastomer KW - magnetorheological elastomer KW - Matrix KW - MIicrostructure KW - restructuring of the filler KW - ultra-small-angle neutron scattering Y1 - 2021 U6 - https://doi.org/10.3390/app11104470 VL - 11 IS - 10 SP - 1 EP - 9 PB - MDPI CY - Basel ER - TY - JOUR A1 - Savelev, Dmitrii V. A1 - Belyaeva, Inna A. A1 - Chashin, Dmitri V. A1 - Fetisov, Leonid Y. A1 - Romeis, Dirk A1 - Kettl, Wolfgang A1 - Kramarenko, Elena Yu A1 - Saphiannikova, Marina A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail T1 - Giant extensional strain of magnetoactive elastomeric cylinders in uniform magnetic fields JF - Materials N2 - Elongations of magnetoactive elastomers (MAEs) under ascending–descending uniform magnetic fields were studied experimentally using a laboratory apparatus specifically designed to measure large extensional strains (up to 20%) in compliant MAEs. In the literature, such a phenomenon is usually denoted as giant magnetostriction. The synthesized cylindrical MAE samples were based on polydimethylsiloxane matrices filled with micrometer-sized particles of carbonyl iron. The impact of both the macroscopic shape factor of the samples and their magneto-mechanical characteristics were evaluated. For this purpose, the aspect ratio of the MAE cylindrical samples, the concentration of magnetic particles in MAEs and the effective shear modulus were systematically varied. It was shown that the magnetically induced elongation of MAE cylinders in the maximum magnetic field of about 400 kA/m, applied along the cylinder axis, grew with the increasing aspect ratio. The effect of the sample composition is discussed in terms of magnetic filler rearrangements in magnetic fields and the observed experimental tendencies are rationalized by simple theoretical estimates. The obtained results can be used for the design of new smart materials with magnetic-field-controlled deformation properties, e.g., for soft robotics. KW - magnetostriction KW - magnetoactive elastomer KW - extensional strain KW - hysteresis KW - magnetomechanical effect KW - magnetodeformation Y1 - 2020 U6 - https://doi.org/10.3390/ma13153297 SN - 1996-1944 N1 - Corresponding author: Mikhail Shamonin VL - 13 IS - 15 SP - 1 EP - 17 PB - MDPI CY - Basel ER -