TY - JOUR A1 - Loo, Xuyan A1 - Nagaraju, Bhavana A1 - Pathivada, Sai A1 - Bartsch, Alexander A1 - Schratzenstaller, Thomas A1 - Sattler, Robert A1 - Monkman, Gareth J. T1 - Electrical properties of bisphenol-A-free magnetoactive borosilicate polymers JF - AIP Advances N2 - The recent REACH regulations require the elimination of bisphenol-A and titanium dioxide from commercially available boron-based polymers. This has led to changes in some of the mechanical characteristics, which strongly influence the properties of magnetoactive borosilicate polymers. This work delivers results on the electrical properties and discusses some implications for future research using bisphenol-A and titanium-dioxide-free substitutes. KW - Electrical components KW - Electrical properties and parameters KW - Dielectric properties KW - Electrical resistivity KW - Magnetic materials KW - Viscoelasticity KW - Polymers KW - Non Newtonian fluids KW - Magnetic fluids Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-72936 SN - 2158-3226 N1 - Corresponding author der OTH Regensburg: Gareth J. Monkman VL - 14 IS - 5 PB - AIP Publishing ER - TY - JOUR A1 - Klein, Dagmar A1 - Freimuth, Herbert A1 - Monkman, Gareth J. A1 - Egersdörfer, Stefan A1 - Meier, Alexander A1 - Böse, Holger A1 - Baumann, Michael A1 - Ermert, Helmut A1 - Bruhns, Otto T. T1 - Electrorheological Tactile Elements JF - Mechatronics N2 - The use of ultrasound systems for medical examination and diagnosis is nothing new. The extension of ultrasound techniques for real time elastographic analysis purposes represents a more recent development. Nevertheless, as they stand all such techniques rely on the interpretation of two-dimensional visual data displayed on a video screen. In reality however, a medical doctor will make as much use of exploratory touch as he or she does vision, making the simultaneous portrayal of both video and tactile information most desirable [Böse H, Monkman GJ, Freimuth H, Ermert H. Haptisches Sensor-Aktor-System uaf der grundlage der Echtzeitelastographie sowie von elktro- und magnetorheologischen Materialien “HASASEM” [3]. BMBF Antrag 01 IR A14D, Oktober 2000]. This paper discusses the preliminary tests and basic design parameters for single tactels using electrorheological fluids. The final aim is to produce a prototype three-dimensional tactile display comprising electrically switchable micro-machined cells whose mechanical moduli are governed by phase changes experienced by electrorheological fluids. This will be integrated with the latest elastographic ultrasonic sensor systems in order to present the human fingers with controllable surfaces capable of emulating biological tissue, muscle and bone. Y1 - 2005 U6 - https://doi.org/10.1016/j.mechatronics.2004.05.007 VL - 15 IS - 7 SP - 883 EP - 897 PB - Pergamon CY - Oxford ER - TY - JOUR A1 - Klein, Dagmar A1 - Rensink, D. A1 - Freimuth, Herbert A1 - Monkman, Gareth J. A1 - Egersdörfer, Stefan A1 - Böse, Holger A1 - Baumann, Michael T1 - Modelling the Response of a Tactile Array using an Electrorheological Fluids JF - Journal of Physics D: Applied Physics N2 - This paper reports the first step in the development of a tactile array suitable for the presentation of haptic information in virtual reality. The system is based on the electric field dependence of the viscosity of electrorheological fluids. The simulation, as well as the experimental realization of single tactels is described. The mathematical approach is based on the Eckart model (Eckart W 2000 Continuum Mech. Thermodyn. 12 341–62) and its validity is demonstrated by comparing the resulting yield stress with the experimental results from Wunderlich (2000 Dissertation Universität Erlangen-Nürnberg). Two different tactel designs are realized and the experimental results are compared with numerical simulation. The design of modification B is shown to be applicable for the realization of an actuator array with high spatial resolution. Y1 - 2004 U6 - https://doi.org/10.1088/0022-3727/37/5/023 SN - 1361-6463 SN - 0022-3727 VL - 37 IS - 5 SP - 794 EP - 803 PB - IOP Publ. CY - Bristol ER - TY - CHAP A1 - Diermeier, Andreas A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Magneto-Active Polymer Actuator T2 - Actuator 16 : 15th International Conference on New Actuators & 9th International Exhibition on Smart Actuators and Drive Systems : conference proceedings N2 - Magneto-active Polymers (MAP) are closely related to magneto-rheological fluids in that they contain magnetic micro-particles. However, instead of being freely suspended in a carrier fluid they are physically bound within a highly elastic polymer-matrix. The application of an external magnetic field allows changes in the mechanical properties, such as elastic and shear moduli, of the composite material to be achieved. The colossal magneto-rheological effect has been shown to demonstrate changes in Young's modulus by over 1E6 %. Current research concentrates on controllable compliance and the resulting shape memory properties of MAP. This paper deals with recent advancements in this respect, including tubular magneto-active devices with potential applications in medical and other technology. KW - Formgedächtniseffekt KW - Kompositwerkstoff KW - Konzentrat KW - magnetisches Feld KW - magnetorheologische Flüssigkeit KW - Polymer KW - Schermodul Y1 - 2016 SN - 978-3-933339-26-3 SP - 286 EP - 289 PB - WFB CY - Bremen ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Boody, F. P. T1 - Ein Vergleich verschiedene Master-Programme JF - Die Neue Hochschule Y1 - 2003 IS - 1 SP - 12 EP - 13 PB - DUZ Verlags- und Medienhaus GmbH CY - Berlin ER - TY - JOUR A1 - Dillinger, Andrea Elisabeth A1 - Mayer, Matthias A1 - Schneider, Magdalena A1 - Weber, Gregor R. A1 - Goeppner, Corinna A1 - Tamm, Ernst R. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Fuchshofer, Rudolf T1 - Reactive changes in optic nerve astrocytes are mediated by CTGF, TGF beta 2 and increasing substratum stiffness JF - Investigative ophthalmology & visual science N2 - Purpose: Patients with primary open-angle glaucoma (POAG) show a stiffer peripapillary sclera, reactive astrocytes and a remodeled lamina cribrosa (LC). The changes are thought to be mediated by TGFβ2 and its downstream mediator CTGF. Recently we developed a murine glaucoma model by overexpressing CTGF in the anterior eye (βb1CTGF). In this study we investigated the glial lamina region of βb1CTGF mice, and the changes of astrocytes in response to CTGF and TGFβ2 as well as increasing substratum stiffness. Methods: Tangential sections of the glial LC of 2-month-old βb1CTGF mice and their wild-type littermates (WT) were stained with phalloidin and antibodies against GFAP, CTGF and fibronectin (FN). Murine optic nerve (ON) astrocytes from CD1 mice were isolated, cultured and characterized by GFAP staining. The astrocytes were treated with TGFβ2 (1ng/ml) and CTGF (50ng/ml and 100ng/ml). In addition, the cells were seeded on PDMS substrata with different stiffness (10, 30 and 60 kPa). Treated cells were analyzed by Western blotting, real-time RT-PCR and immunohistochemistry. Wound healing assays were performed to analyze migration rate following growth factor treatment. Results: βb1CTGF mice showed a massive increase in CTGF and GFAP in the glial LC when compared with WT mice. Moreover, an increase in FN staining and phalloidin-labeled actin was observed in the peripapillary sclera. Murine ON astrocytes reacted on increased substrate stiffness by increasing the synthesis of GFAP, vimentin and CTGF. Treatment of the cells with TGFβ2 and CTGF led to an enhanced migration rate. In addition, treatment resulted in an increased expression and synthesis of ECM proteins, including FN, tropoelastin, collagen type I and III. The in vitro findings correlated with those seen in the glaucoma mouse model. Conclusions: We conclude that changes in the ECM of LC and peripapillary sclera alter their biomechanical properties and thereby induce reactive changes in resident astrocytes. The reactive changes induced by higher stiffness of their surrounding ECM give rise to a self-amplifying process that includes increased TGFβ2/CTGF signaling and leads to synthesis of ECM and cytoskeletal proteins, a process that in turn augments the stiffness at the optic nerve head (ONH). Such a scenario may finally result in a vicious circle as the causative mechanism for ONH deformation in POAG. Y1 - 2015 VL - 56 IS - 7 PB - ASSOC RESEARCH VISION OPHTHALMOLOGY INC ER - TY - JOUR A1 - Sorokin, Vladislav V. A1 - Stepanov, Gennady V. A1 - Shamonin (Chamonine), Mikhail A1 - Monkman, Gareth J. A1 - Khokhlov, Alexei R. A1 - Kramarenko, Elena Yu T1 - Hysteresis of the viscoelastic properties and the normal force in magnetically and mechanically soft magnetoactive elastomers: Effects of filler composition, strain amplitude and magnetic field JF - Polymer N2 - Hysteresis in dynamic modulus, loss factor and normal forces of magnetoactive elastomers (MAEs) comprising various proportions of small (3-5 mu m) and large (50-60 mu m) ferromagnetic particles are experimentally studied using dynamic torsion performed at a fixed oscillation frequency in varying DC magnetic fields. It is shown that hysteresis is a characteristic feature of MAEs observed both under increasing/decreasing magnetic field strength and increasing/decreasing strain amplitude. This hysteresis is attributed to the specific rearrangement of the magnetic filler network under simultaneously applied magnetic field and shear deformation. Rheological properties of the magnetic filler network formed in the magnetic field and, therefore, the rheological properties of MAEs depend strongly on the filler composition and the magnetic field magnitude. Larger magnetic particles and higher magnetic fields provide stronger magnetic networks. Both factors result in the extension of the linear viscoelastic regime to larger strain amplitudes and lead to higher values of shear storage and loss moduli. It is found that the hysteresis width maximises at an intermediate magnetic field where it is attributed to the balance between elastic and magnetic particle interactions. This is apparently where the most significant restructuring of the magnetic network occurs. The hysteresis width decreases with increasing fraction of large particles in the magnetic filler. The loss factor grows significantly when the magnetic network is physically broken by large strains gamma > 1%. A huge (more than one order of magnitude) increase of normal force at maximum magnetic field strengths is observed. It is predicted that any physical quantity depending on the internal structuring of the magnetic filler should demonstrate hysteresis either with a changing magnetic field and constant deformation amplitude or under variable deformation in a constant magnetic field. (C) 2015 Elsevier Ltd. All rights reserved. KW - BEHAVIOR KW - COMPRESSION KW - Dynamic modulus KW - GELS KW - hysteresis KW - Magnetorheological elastomers KW - magnetostriction KW - MODULUS KW - PARTICLES KW - POLYMER COMPOSITES KW - shear Y1 - 2015 U6 - https://doi.org/10.1016/j.polymer.2015.08.040 VL - 76 SP - 191 EP - 202 PB - Elsevier ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Diermeier, Andreas A1 - Prem, Nina T1 - The magnetoactive electret JF - smart materials and structures N2 - A magnet which adheres to every surface, not only those of ferromagnetic materials, has hitherto been the domain of science fiction. Now for the first time such a novel device exists. The fusion of a permanently magnetized magnetoactive polymer containing hard magnetic particles and an electret enhanced with ferroelectric particles has resulted in the development of a new smart device-the magnetoactive electret. Magnetoactive electrets can be made to exhibit the usual magnetic properties of permanent magnetism together with the electrostatic properties of electrets. This results in simultaneous magnetoadhesion and electroadhesion forces from the same elastomeric element. The biasing field, needed to avoid discontinuities concerned with transition through the zero point in operating curves, is normally provided by means of either a magnetic or an electric field. This novel technology provides both bias options in a single device. KW - 6D printing KW - electret KW - electroadhesion KW - FLUIDS KW - MAGNETIC-FIELD KW - magnetoactive electret KW - magnetoactive polymer KW - magnetoadhesion KW - Magnetorheological elastomers KW - RHEOLOGY Y1 - 2017 U6 - https://doi.org/10.1088/1361-665X/aa738f VL - 26 IS - 7 PB - IOP Publishing ER - TY - JOUR A1 - Monkman, Gareth J. A1 - Sindersberger, Dirk A1 - Prem, Nina A1 - Diermeier, Andreas A1 - Szecsey, Tamara T1 - Dielectric behaviour of magnetic hybrid materials JF - Physical Sciences Reviews N2 - The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt% CIP) were also investigated. With filler concentrations lower than 3 wt%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt%. Above 3 wt% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1%–3 wt% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found. KW - cappillary doublet KW - diamagnetic KW - elastomer dielectric KW - FTIR KW - interfacial magnetocapacitance KW - magnetoactive polymer KW - PDMS KW - toroid Y1 - 2021 U6 - https://doi.org/10.1515/psr-2019-0121 N1 - Corresponding author: Gareth J. Monkman VL - 7 IS - 10 SP - 1169 EP - 1185 PB - de Gruyter ER - TY - JOUR A1 - Prem, Nina A1 - Sindersberger, Dirk A1 - Monkman, Gareth J. T1 - Mini-Extruder for 3D Magnetoactive Polymer Printing JF - Advances in Materials Science and Engineering N2 - This work describes the development of a new miniature extruder, essential to cavity-free 3D printing of silicone-based smart materials. This makes the 3D printing of magnetoactive and electroactive polymer soft robotic components and devices directly from CAD data possible. The special feature of such an extruder is that it is designed for use with addition-crosslinking RTV-2 silicones, including solid particulate additives. The extruder merges the respective components automatically during extrusion which obviates the need for premixing and vacuum evacuation. Problems associated with inhomogeneities and unwanted cavity production are consequently eliminated. Rheological details necessary to the design, together with some preliminary performance results, are presented. Y1 - 2019 U6 - https://doi.org/10.1155/2019/8715718 N1 - Corresponding author: Gareth J. Monkman SP - 1 EP - 8 PB - HINDAWI ER - TY - JOUR A1 - Kreitmeier, Florian A1 - Chashin, Dmitri V. A1 - Fetisov, Yuri K. A1 - Fetisov, Leonid Y. A1 - Schulz, Irene A1 - Monkman, Gareth J. A1 - Shamonin (Chamonine), Mikhail T1 - Nonlinear Magnetoelectric Response of Planar Ferromagnetic-Piezoelectric Structures to Sub-Millisecond Magnetic Pulses JF - Sensors N2 - The magnetoelectric response of bi- and symmetric trilayer composite structures to pulsed magnetic fields is experimentally investigated in detail. The structures comprise layers of commercially available piezoelectric (lead zirconate titanate) and magnetostrictive (permendur or nickel) materials. The magnetic-field pulses have the form of a half-wave sine function with duration of 450 µs and amplitudes ranging from 500 Oe to 38 kOe. The time dependence of the resulting voltage is presented and explained by theoretical estimations. Appearance of voltage oscillations with frequencies much larger than the reciprocal pulse length is observed for sufficiently large amplitudes (~1-10 kOe) of the magnetic-field pulse. The origin of these oscillations is the excitation of bending and planar acoustic oscillations in the structures. Dependencies of the magnetoelectric voltage coefficient on the excitation frequency and the applied magnetic field are calculated by digital signal processing and compared with those obtained by the method of harmonic field modulation. The results are of interest for developing magnetoelectric sensors of pulsed magnetic fields as well as for rapid characterization of magnetoelectric composite structures. Y1 - 2012 U6 - https://doi.org/10.3390/s121114821 N1 - Corresponding author: Mikhail Shamonin VL - 12 IS - 11 SP - 14821 EP - 14837 PB - MDPI CY - Basel ER -