TY - JOUR A1 - Steininger, Peter A1 - Gaderer, Matthias A1 - Dawoud, Belal A1 - Gaderer, Matthias T1 - Experimental and numerical study on the solar gain and heat loss of typical existing and refurbished German buildings JF - iCRBE Procedia N2 - This communication introduces an experimental setup for investigating the effect of solar radiation on the reduction of transmission heat losses and the steady state thermal conductance of uninsulated and insulated multi-layer wall samples. The setup consists of two adjacent climatic chambers, which share a common wall, in which the multi-layer wall samples are mounted. A solar simulator is applied within the outdoor air climatic chamber, whose radiation spectrum and radiation intensity are approximately equivalent to those of the sun. The first tests have been carried out on a wall sample with a typical structure of existing buildings from the year 1930 in Germany. In addition, a high-performance insulating plaster layer has been applied on a basic test sample (with existing building structure) to replicate and assess the refurbished scenario. Furthermore, a numerical investigation on the transient heat transfer process is carried out by using the simulation software COMSOL Multiphysics®. The experimental results of both uninsulated and insulated wall samples are validated against 1D and 3D models. As seen, the uninsulated wall, whose thermal conductance was experimentally determined to be equal to 1.79 W/(m²K), absorbs a heat flux of 208 W/m² through its external wall surface over a period of 8 hours. A fraction of 9.8 % of the absorbed heat arrives as a gain on the internal wall and reduces the transmission heat losses by 11.7 % over a period of 55 hours. On the other hand, the thermal conductivity of the insulation layer of the refurbished wall sample with micro hollow glass spheres was estimated by a parameter estimation procedure using the 3D model and the obtained experimental data. Using the estimated thermal conductivity, a thermal conductance of 0.42 W/(m²K) has been obtained for the refurbished wall sample. Y1 - 2020 UR - https://www.scilit.net/article/e45ed49630736c2ed82cd848e55bb69c?action=show-references U6 - https://doi.org/10.32438/icrbe.202035 VL - 1 IS - 1 SP - 75 EP - 93 PB - Weentech ER - TY - JOUR A1 - Gärtner, Sebastian A1 - Marx-Schubach, Thomas A1 - Gaderer, Matthias A1 - Schmitz, Gerhard A1 - Sterner, Michael T1 - Techno-Economic Analysis of Carbon Dioxide Separation for an Innovative Energy Concept towards Low-Emission Glass Melting JF - energies N2 - The currently still high fossil energy demand is forcing the glass industry to search for innovative approaches for the reduction in CO2 emissions and the integration of renewable energy sources. In this paper, a novel power-to-methane concept is presented and discussed for this purpose. A special focus is on methods for the required CO2 capture from typical flue gases in the glass industry, which have hardly been explored to date. To close this research gap, process simulation models are developed to investigate post-combustion CO2 capture by absorption processes, followed by a techno-economic evaluation. Due to reduced flue gas volume, the designed CO2 capture plant is found to be much smaller (40 m3 absorber column volume) than absorption-based CO2 separation processes for power plants (12,560 m3 absorber column volume). As there are many options for waste heat utilization in the glass industry, the waste heat required for CO2 desorption can be generated in a particularly efficient and cost-effective way. The resulting CO2 separation costs range between 41 and 42 EUR/t CO2, depending on waste heat utilization for desorption. These costs are below the values of 50–65 EUR/t CO2 for comparable industrial applications. Despite these promising economic results, there are still some technical restrictions in terms of solvent degradation due to the high oxygen content in flue gas compositions. The results of this study point towards parametric studies for approaching these issues, such as the use of secondary and tertiary amines as solvents, or the optimization of operating conditions such as stripper pressure for further cost reductions potential. KW - economic evaluation KW - CO2-separation KW - glass industry KW - oxyfuel KW - methanation KW - power-to-gas Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-53627 N1 - Corresponding author: Sebastian Gärtner VL - 16 IS - 5 SP - 1 EP - 25 PB - MDPI CY - Basel ER - TY - GEN A1 - Schwanzer, Peter A1 - Dietrich, Markus A1 - Haft, Gerhard A1 - Gaderer, Matthias A1 - Rabl, Hans-Peter T1 - Oxidation Kinetics Determination of GDI Engine Soot by a Radio-Frequency Sensor T2 - 23rd Conference on Combustion Generated Nanoparticles 2019, June 17-20, Zürich, Switzerland Y1 - 2019 UR - https://www.nanoparticles.ch/archive/2019_Schwanzer_PO.pdf ER - TY - INPR A1 - Gärtner, Sebastian A1 - Marx-Schubach, Thomas A1 - Gaderer, Matthias A1 - Schmitz, Gerhard A1 - Sterner, Michael T1 - Introduction of an Innovative Energy Concept for low Emission Glass Melting based on Carbon Capture and Usage N2 - Due to the very high fossil energy demand, the glass industry is looking for innovative approaches for the reduction of CO2 emissions and the integration of renewable energy sources. In this paper, we present a novel power-to-gas concept, which has no impact on established melting processes and discuss it for this purpose. A special focus is set on the required CO2 capture from typical flue gases in the glass industry, as this process has not been investigated in detail yet. We used a process simulation approach to investigate post-combustion CO2 capture by absorption processes, followed by a techno-economic evaluation. Our investigations found the designed CO2 capture plant to be approx. 400 times smaller than absorption based CO2 separation processes for conventional power plants. Due to the many options for waste heat utilization, the waste heat required for CO2 desorption can be generated in a particularly efficient and cost-effective way. The resulting CO2 avoidance costs range between 41-42 €/t CO2, depending on waste heat utilization for desorption, and thus offer a cost effective way of CO2 removal from glass industry melting processes. These costs are well below the values of 50-65 €/t CO2 described so far for comparable industrial applications. In addition, we describe optimization options, like solvent and process improvements, to enable further cost reductions. These results motivate further research and development on the overall process presented in this work. KW - glass KW - Oxyfuel KW - Methanation KW - Power-to-Gas KW - CO2 capture KW - Economic Analysis Y1 - 2022 U6 - https://doi.org/10.31224/2642 ER - TY - JOUR A1 - Mikhaeil, Makram A1 - Gaderer, Matthias A1 - Dawoud, Belal T1 - Experimental Investigation of the Adsorption and Desorption Kinetics on an Open-Structured Asymmetric Plate Heat Exchanger; Matching Between Small-Scale and Full-Scale Results JF - Frontiers in Energy Research N2 - This paper introduces the results of an experimental study on the adsorption and desorption kinetics of a commercially available, open-structured asymmetric plate heat exchanger adapted to act as an adsorber/desorber for the application in adsorption heat transformation processes. In addition, a volumetric large temperature jump (V-LTJ) kinetic setup was applied to measure the adsorption and desorption kinetics of a small-scale adsorbent sample prepared dedicatedly to be representative for the adsorbent domain inside the investigated adsorber plate heat exchanger (APHE). All kinetic results of the small-scale adsorbent sample and the APHE were fitted into exponential forms with a single characteristic time constant (τ) with a coefficient of determination (R2) better than 0.9531. A very good matching between the small-scale and full-scale adsorption kinetic measurements was obtained, with an average relative deviation of 12.3% in the obtained τ-values. In addition, the kinetic data of the small-scale adsorbent sample were utilized for estimating the expected specific instantaneous and moving average powers of the evaporator/condenser heat exchanger. The average relative deviation (ARD) between the moving average specific evaporator powers obtained from the small-scale and the full-scale measurements amounts between 5.4 and 15.1%. Y1 - 2022 U6 - https://doi.org/10.3389/fenrg.2022.818486 N1 - Corresponding author: Belal Dawoud VL - 10 SP - 1 EP - 15 PB - Frontiers ER - TY - JOUR A1 - Steininger, Peter A1 - Gaderer, Matthias A1 - Steffens, Oliver A1 - Dawoud, Belal T1 - Experimental and Numerical Study on the Heat Transfer Characteristics of a Newly-Developed Solar Active Thermal Insulation System JF - Buildings N2 - A newly-developed solar active thermal insulation system (SATIS) is introduced with the main objective to accomplish a highly-dependent total solar transmittance on the irradiation angle. SATIS is also designed to obtain the maximum transmittance at a prescribed design irradiation angle and to reduce it remarkably at higher irradiation angles. A purely mineral thermal insulation plaster with micro hollow glass spheres is applied to manufacture the investigated SATIS prototype. Light-conducting elements (LCEs) have been introduced into SATIS and suitable closing elements have been applied. The SATIS prototype has been investigated both experimentally and numerically. It turned out that the contributions of conduction, radiation and convection to the effective thermal conductivity of SATIS, without the closing elements (49 mWmK), amount to 86.2%, 13.2% and 0.6%, respectively. The angle-dependent short-wave radiation exchange within the LCE has been investigated via ray tracing. At the incidence angle of 19% (design angle), 27% of the radiation within the LCE is absorbed by the absorber plate, resulting in measured and computed total solar energy transmittances of 11.2%/11.7%, respectively. For a typical summer irradiation angle of 60%, 98% of the incident radiation is absorbed by the surfaces at the entrance of the LCE. The corresponding total solar energy transmittance amounts to 2.9%. KW - angle-dependent total solar energy transmittance KW - effective thermal conductivity KW - experimental investigation KW - numerical simulation KW - ray tracing KW - solar active thermal insulation system (SATIS) Y1 - 2021 U6 - https://doi.org/10.3390/buildings11030123 N1 - Corresponding author: Belal Dawoud VL - 11 IS - 3 SP - 1 EP - 22 PB - MDPI ER - TY - JOUR A1 - Gamisch, Bernd A1 - Gaderer, Matthias A1 - Dawoud, Belal T1 - On the Development of Thermochemical Hydrogen Storage: An Experimental Study of the Kinetics of the Redox Reactions under Different Operating Conditions JF - Applied Sciences N2 - This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90% Fe2O3, 10% stabilizing cement), hydrogen (H2) is applied in different concentrations with nitrogen (N2), as a carrier gas, at temperatures between between 700 ∘C and 900 ∘C, thus simulating the charging phase. The discharge phase is triggered by the flow of a mixture out of steam (H2O) and N2 at different concentrations in the same temperature range, resulting in the oxidizing of the previously reduced pellets. All investigations were carried out in a thermo-gravimetric analyzer (TGA) with a flow rate of 250mL/min. To describe the obtained kinetic results, a simplified analytical model, based on the linear driving force model, was developed. The investigated iron oxide pellets showed a stable redox performance of 23.8% weight reduction/gain, which corresponds to a volumetric storage density of 2.8kWh/(L bulk), also after the 29 performed redox cycles. Recalling that there is no H2 stored during the storage phase but iron, the introduced hydrogen storage technology is deemed very promising for applications in urban areas as day-night or seasonal storage for green hydrogen. KW - hydrogen storage KW - iron/iron oxide KW - reaction kinetics KW - redox reactions Y1 - 2021 U6 - https://doi.org/10.3390/app11041623 N1 - Corresponding author: Belal Dawoud VL - 11 IS - 4 SP - 1 EP - 15 PB - MDPI CY - Basel ER - TY - JOUR A1 - Mikhaeil, Makram A1 - Gaderer, Matthias A1 - Dawoud, Belal T1 - On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study JF - Energy N2 - An innovative adsorber plate heat exchanger (APHE), which is developed for application in adsorption heat pumps, chillers and thermal energy storage systems, is introduced. A test frame has been constructed as a representative segment of the introduced APHE for applying loose grains of AQSOA-Z02. Adsorption kinetic measurements have been carried out in a volumetric large-temperature-jump setup under typical operating conditions of adsorption processes. A transient 2-D model is developed for the tested sample inside the setup. The measured temporal uptake variations with time have been fed to the model, through which a micro-pore diffusion coefficient at infinite temperature of 2 E−4 [m2s−1] and an activation energy of 42.1 [kJ mol−1] have been estimated. A 3-D model is developed to simulate the combined heat and mass transfer inside the APHE and implemented in a commercial software. Comparing the obtained results with the literature values for an extruded aluminium adsorber heat exchanger coated with a 500 μm layer of the same adsorbent, the differential water uptake obtained after 300 s of adsorption (8.2 g/100 g) implies a sound enhancement of 310%. This result proves the great potential of the introduced APHE to remarkably enhance the performance of adsorption heat transformation appliances. KW - Adsorber heat exchanger KW - Plate heat exchanger KW - Adsorption kinetics KW - Dynamic simulation Y1 - 2020 U6 - https://doi.org/10.1016/j.energy.2020.118272 N1 - Corresponding author: Belal Dawoud VL - 207 IS - September SP - 1 EP - 13 PB - Elsevier ER - TY - JOUR A1 - Steininger, Peter A1 - Gaderer, Matthias A1 - Dawoud, Belal T1 - Assessment of the Annual Transmission Heat Loss Reduction of a Refurbished Existing Building with an Advanced Solar Selective Thermal Insulation System JF - Sustainability N2 - A numerical parameter sensitivity analysis of the design parameters of the recently published solar selective thermal insulation system (SATIS) has been carried out to enhance its thermal and optical properties. It turned out that the insulation properties of SATIS can be effectively improved by reducing the length of the glass closure element. Increasing the area share of the light conducting elements (LCEs) and decreasing their length-to-diameter (L/D) ratio were identified as key parameters in order to increase the solar gain. Two SATIS variants were compared with the same wall insulation without SATIS in a yearly energetic performance assessment. The SATIS variant with 10 mm length of the closure element, 44.2% area share of LCE, as well as front and rear diameters of 12 mm/9 mm shows an 11.8% lower transmission heat loss over the heating period than the wall insulation without SATIS. A new methodology was developed to enable the implementation of the computed solar gains of SATIS in 1D simulation tools. The result is a radiant heat flow map for integration as a heat source in 1D simulation models. A comparison between the 1D and 3D models of the inside wall heat fluxes showed an integral yearly agreement of 98%. KW - effective thermal conductivity KW - parameter sensitivity analysis KW - radiant heat flow map KW - solar selective thermal insulation system (SATIS) KW - total solar energy transmittance KW - yearly energetic performance assessment Y1 - 2021 U6 - https://doi.org/10.3390/su13137336 N1 - Corresponding author: Belal Dawoud VL - 13 IS - 13 SP - 1 EP - 19 PB - MDPI CY - Basel ER - TY - JOUR A1 - Mikhaeil, Makram A1 - Gaderer, Matthias A1 - Dawoud, Belal T1 - On the application of adsorber plate heat exchangers in thermally driven chillers BT - An experimental and analytical study JF - Applied Thermal Engineering N2 - The effect of both heat and mass transfer characteristic lengths (HTCL, MTCL) of two different adsorber plate heat exchangers (APHE), for application in an adsorption chiller, on the adsorption and desorption kinetics is investigated. Three representative test frames (TF1-TF3) are prepared to examine small-scale adsorbent samples of the microporous silica gel (Siogel of Oker-Chemie, Germany) applying the volumetric large-temperature-jump methodology at different operating conditions. Based on the obtained kinetic data, an analytical model has been developed to predict the specific cooling power (SCP) and the coefficient of performance (COP) of a single-bed adsorption chiller comprising the studied APHEs. It turned out that, within the tested range of HTCL and MTCL, it can be concluded that, the adsorption kinetics are mainly influenced by the MTCL, while the desorption kinetics are dominated by the HTCL of the adsorbent domain. Applying Siogel as loose pellets inside a newly introduced APHE results in of 423.3 and 182.7 W⋅kg−1, at the evaporator temperatures of 15 °C and 5 °C, respectively. Herein, the condenser and adsorber-end temperatures amount to 30 °C and the desorption-end temperature to 90 °C. The corresponding s amount to 0.50 and 0.40, respectively, which represent quite promising results for further design optimizations. Y1 - 2023 U6 - https://doi.org/10.1016/j.applthermaleng.2022.119713 VL - 220 PB - Elsevier ER -