TY - JOUR A1 - Gärtner, Sebastian A1 - Marx-Schubach, Thomas A1 - Gaderer, Matthias A1 - Schmitz, Gerhard A1 - Sterner, Michael T1 - Techno-Economic Analysis of Carbon Dioxide Separation for an Innovative Energy Concept towards Low-Emission Glass Melting JF - energies N2 - The currently still high fossil energy demand is forcing the glass industry to search for innovative approaches for the reduction in CO2 emissions and the integration of renewable energy sources. In this paper, a novel power-to-methane concept is presented and discussed for this purpose. A special focus is on methods for the required CO2 capture from typical flue gases in the glass industry, which have hardly been explored to date. To close this research gap, process simulation models are developed to investigate post-combustion CO2 capture by absorption processes, followed by a techno-economic evaluation. Due to reduced flue gas volume, the designed CO2 capture plant is found to be much smaller (40 m3 absorber column volume) than absorption-based CO2 separation processes for power plants (12,560 m3 absorber column volume). As there are many options for waste heat utilization in the glass industry, the waste heat required for CO2 desorption can be generated in a particularly efficient and cost-effective way. The resulting CO2 separation costs range between 41 and 42 EUR/t CO2, depending on waste heat utilization for desorption. These costs are below the values of 50–65 EUR/t CO2 for comparable industrial applications. Despite these promising economic results, there are still some technical restrictions in terms of solvent degradation due to the high oxygen content in flue gas compositions. The results of this study point towards parametric studies for approaching these issues, such as the use of secondary and tertiary amines as solvents, or the optimization of operating conditions such as stripper pressure for further cost reductions potential. KW - economic evaluation KW - CO2-separation KW - glass industry KW - oxyfuel KW - methanation KW - power-to-gas Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-53627 N1 - Corresponding author: Sebastian Gärtner VL - 16 IS - 5 SP - 1 EP - 25 PB - MDPI CY - Basel ER - TY - JOUR A1 - Gärtner, Sebastian A1 - Rank, Daniel A1 - Heberl, Michael A1 - Gaderer, Matthias A1 - Dawoud, Belal A1 - Haumer, Anton A1 - Sterner, Michael T1 - Simulation and Techno-Economic Analysis of a Power-to-Hydrogen Process for Oxyfuel Glass Melting JF - Energies N2 - As an energy-intensive industry sector, the glass industry is strongly affected by the increasingly stringent climate protection targets. As established combustion-based production systems ensure high process stability and glass quality, an immediate switch to low greenhouse gas emission processes is difficult. To approach these challenges, this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study indicate, that the proposed system can reduce specific carbon dioxide emissions by up to 60%, while increasing specific energy demand by a maximum of 25%. Investigations of the impact of altered combustion and furnace properties like adiabatic flame temperature (+25 °C), temperature efficiency (∆ξ = −0.003) and heat capacity flow ratio (∆zHL = −0.009) indicate that pure hydrogen-oxygen combustion has less impact on melting properties than assumed so far. Within the case study, high CO2 abatement costs of 295 €/t CO2-eq. were determined. This is mainly due to the insufficient performance of renewable energy sources. The correlations between process scaling and economic parameters presented in this study show promising potential for further economic optimization of the proposed energy system in the future. KW - Power-to-Gas KW - Hydrogen KW - Electrolysis KW - Oxyfuel KW - Glass Industry Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:898-opus4-22713 N1 - Corresponding author: Sebastian Gärtner VL - 14 IS - 24 PB - MDPI ER -