TY - CHAP A1 - Herdl, Florian A1 - Kueddelsmann, Maximillian J. A1 - Schels, Andreas A1 - Bachmann, Michael A1 - Edler, Simon A1 - Wohlfartsstätter, Dominik A1 - Düsberg, Felix A1 - Prugger, Alexander A1 - Dillig, Michael A1 - Dams, Florian A1 - Schreiner, Rupert A1 - Coileáin, Cormac Ó. A1 - Zimmermann, Stefan A1 - Pahlke, Andreas A1 - Duesberg, Georg S. T1 - Characterization and Operation of Graphene-Oxide-Semiconductor Emitters at Atmospheric Pressure Levels T2 - 2023 IEEE 36th International Vacuum Nanoelectronics Conference (IVNC), 10-13 July 2023, Cambridge, MA, USA N2 - In recent years Graphene-Oxide-Semiconductor (GOS) electron emitters have attracted a lot of interest due to their outstanding durability in modest vacuum conditions. However, the performance at ambient pressure remains largely unexplored. In this study GOS-emitters are characterized in nitrogen and air at atmospheric pressure, and compared with their vacuum characteristics. For this purpose, lifetime and IV-characteristics measurements are shown. Furthermore, the GOS-emitter was operated as an ionization source for ion mobility spectrometry (IMS) at ambient conditions. KW - durability KW - graphene compounds KW - ion mobility KW - semiconductor-insulator boundaries Y1 - 2023 SN - 979-8-3503-0143-4 U6 - https://doi.org/10.1109/IVNC57695.2023.10188974 SP - 14 EP - 16 PB - IEEE ER - TY - JOUR A1 - Haynack, Alexander A1 - Sekandar, Zadran A1 - Jithender, J. Timothy A1 - Gambarelli, Serena A1 - Kränkel, Thomas A1 - Thiel, Charlotte A1 - Ozbolt, Josko A1 - Gehlen, Christoph T1 - Can a Hend-Held 3D Scanner Capture Temperature-Induced Strain of Mortar Samples? Comparison between Experimental Measurements and Numerical Simulations JF - mathematics N2 - The expected lifespan of cement-based materials, particularly concrete, is at least 50 years. Changes in the pore structure of the material need to be considered due to external influences and associated transport processes. The expansion behaviour of concrete and mortar during freeze–thaw attacks, combined with de-icing salt agents, is crucial for both internal and external damage. It is essential to determine and simulate the expansion behaviour of these materials in the laboratory, as well as detect the slow, long-term expansion in real structures. This study measures the expansion of mortar samples during freeze–thaw loading using a high-resolution hand-held 3D laser scanner. The specimens are prepared with fully or partially saturated pore structures through water storage or drying. During freeze–thaw experiments, the specimens are exposed to pure water or a 3% sodium chloride solution (NaCl). Results show contraction during freezing and subsequent expansion during thawing. Both test solutions exhibit similar expansion behaviour, with differences primarily due to saturation levels. Further investigations are required to explore the changing expansion behaviour caused by increasing microcracking resulting from continuous freeze–thaw cycles. A numerical analysis using a 3D coupled hygro-thermo-mechanical (HTM) model is conducted to examine the freeze–thaw behaviour of the mortar. The model accurately represents the freezing deformation during the freeze–thaw cycle. KW - concrete KW - mortar KW - durability KW - freeze–thaw and de-icing salt resistance KW - strain KW - 3D laser scanning KW - numerical simulation KW - 3D FE numerical model KW - hygro-thermo-mechanical coupling Y1 - 2023 U6 - https://doi.org/10.3390/math11173672 VL - 11 IS - 17 PB - MDPI CY - Basel ER - TY - CHAP A1 - Grimm, Benedikt A1 - Münchmeyer, Sebastian A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Developing a New Rapid, Relevant, and Reliable (R3) Method for Accelerated Measurement of Carbonation Progress at Gas Overpressure T2 - International RILEM Conference on Synergising expertise towards sustainability and robustness of CBMs and concrete structures, SynerCrete’23 - Volume 1 N2 - The determination of durability-relevant material resistances of concrete is of great importance. They serve as input to engineering models to predict the durability of structures under real environmental conditions. The natural resistances have to be determined in time-consuming experiments, since the processes in nature are very slow. This is particularly important for new materials where long-term experience is not yet available. Thus, accelerated testing is required. Only that way new materials can be evaluated regarding their durability and subsequently be used in practical applications. For carbonation, a new R3 accelerated test method is presented in this contribution. An automated carbonation pressure chamber was developed. It consists of a pressure vessel, automated in such a way that it can apply gas overpressure of various intensities up to 8 bar to mortar and concrete samples. Simultaneously, it can control and regulate the ambient CO2 concentration from 0 to 99.5% in a fully automated and continuously variable procedure. Experiments were carried out with varying combinations of gas overpressure at CO2 concentrations of 3 vol.-% to achieve the most time-efficient carbonation of mortars and concretes. Mortars with different material compositions were used to evaluate the general suitability of the test procedure with the developed equipment. The automated carbonation pressure chamber enables reliable carbonation testing with a total duration under accelerated conditions of only 7 days. KW - Carbonation KW - concrete KW - durability KW - accelerated testing KW - gas overpressure Y1 - 2023 U6 - https://doi.org/10.1007/978-3-031-33211-1_30 SP - 336 EP - 346 PB - Springer ER - TY - CHAP A1 - Haynack, Alexander A1 - Schneider, Alexander A1 - Timothy, Jithender J. A1 - Kränkel, Thomas A1 - Gehlen, Christoph A1 - Thiel, Charlotte T1 - Effect of Chloride Concentration on the Freeze-Thaw Resistance of Concrete T2 - International RILEM Conference on Synergising expertise towards sustainability and robustness of CBMs and concrete structures, SynerCrete’23 - Volume 2 N2 - Performance test methods intend to provide a fast, accurate and precise determination of a particular building material property and thus determine the associated material performance. In concrete, various performance tests are used to classify existing or to approve new materials, to compare concrete compositions or to determine causes of damage in existing structures. The challenge of such test methods is to accelerate natural (very slow) mechanisms to determine the material performance precisely within a short time. However, the attack on the material must not be unrealistically intensive, but must represent reality, just in fast motion. The performance tests used to demonstrate the freeze-thaw resistance of concrete employ a 3% NaCl solution, with literature data ranging from 1% to 10% showing that low concentrations can result in higher surface scaling. In this paper, mortar and concrete specimens are tested at 0, 1, 3, 6, and 9% NaCl solution following the CDF procedure (DIN CEN/TS 12390-9:2017-05). The results are discussed against the background of the existing literature and show that the damage is critically dependent on the pore system and thus also on the effect of the micro-ice lens pump. With increasing freeze-thaw exposition, the pessimum in the external damage shifts towards a de-icing salt concentration of 6%. Furthermore, a novel test methodology based on 3D-laserscanning is presented to determine scaling accurately by eliminating side effects that are typically present in current standards. KW - Concrete KW - durability KW - freeze-thaw resistance KW - chloride concentration KW - 3D laser scanning Y1 - 2023 U6 - https://doi.org/10.1007/978-3-031-33187-9_83 SP - 911 EP - 921 PB - Springer CY - Cham ER -