@article{GamischGadererDawoud, author = {Gamisch, Bernd and Gaderer, Matthias and Dawoud, Belal}, title = {On the Development of Thermochemical Hydrogen Storage: An Experimental Study of the Kinetics of the Redox Reactions under Different Operating Conditions}, series = {Applied Sciences}, volume = {11}, journal = {Applied Sciences}, number = {4}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/app11041623}, pages = {1 -- 15}, abstract = {This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90\% Fe2O3, 10\% stabilizing cement), hydrogen (H2) is applied in different concentrations with nitrogen (N2), as a carrier gas, at temperatures between between 700 ∘C and 900 ∘C, thus simulating the charging phase. The discharge phase is triggered by the flow of a mixture out of steam (H2O) and N2 at different concentrations in the same temperature range, resulting in the oxidizing of the previously reduced pellets. All investigations were carried out in a thermo-gravimetric analyzer (TGA) with a flow rate of 250mL/min. To describe the obtained kinetic results, a simplified analytical model, based on the linear driving force model, was developed. The investigated iron oxide pellets showed a stable redox performance of 23.8\% weight reduction/gain, which corresponds to a volumetric storage density of 2.8kWh/(L bulk), also after the 29 performed redox cycles. Recalling that there is no H2 stored during the storage phase but iron, the introduced hydrogen storage technology is deemed very promising for applications in urban areas as day-night or seasonal storage for green hydrogen.}, language = {en} } @article{PremSindersbergerMonkman, author = {Prem, Nina and Sindersberger, Dirk and Monkman, Gareth J.}, title = {Mini-Extruder for 3D Magnetoactive Polymer Printing}, series = {Advances in Materials Science and Engineering}, journal = {Advances in Materials Science and Engineering}, publisher = {HINDAWI}, doi = {10.1155/2019/8715718}, pages = {1 -- 8}, abstract = {This work describes the development of a new miniature extruder, essential to cavity-free 3D printing of silicone-based smart materials. This makes the 3D printing of magnetoactive and electroactive polymer soft robotic components and devices directly from CAD data possible. The special feature of such an extruder is that it is designed for use with addition-crosslinking RTV-2 silicones, including solid particulate additives. The extruder merges the respective components automatically during extrusion which obviates the need for premixing and vacuum evacuation. Problems associated with inhomogeneities and unwanted cavity production are consequently eliminated. Rheological details necessary to the design, together with some preliminary performance results, are presented.}, language = {en} } @article{Stein, author = {Stein, Oliver}, title = {On analytic properties of the standard zeta function attached to a vector-valued modular form}, series = {Research in Number Theory}, volume = {8}, journal = {Research in Number Theory}, number = {4}, publisher = {Springer Nature}, doi = {10.1007/s40993-022-00368-z}, pages = {1 -- 27}, abstract = {We proof a Garrett-B{\"o}cherer decomposition of a vector-valued Siegel Eisenstein series E2l,0 of genus 2 transforming with the Weil representation of Sp2(Z) on the group ring C[(L′/L)2]. We show that the standard zeta function associated to a vector-valued common eigenform f for the Weil representation can be meromorphically continued to the whole s-plane and that it satisfies a functional equation. The proof is based on an integral representation of this zeta function in terms of f and E2l,0.}, language = {en} } @article{DechantFedulovFetisovetal., author = {Dechant, Eduard and Fedulov, Feodor and Fetisov, Leonid Y. and Shamonin (Chamonine), Mikhail}, title = {Bandwidth Widening of Piezoelectric Cantilever Beam Arrays by Mass-Tip Tuning for Low-Frequency Vibration Energy Harvesting}, series = {Applied Science}, volume = {7}, journal = {Applied Science}, number = {12}, publisher = {MDPI}, organization = {MDPI AG}, doi = {10.3390/app7121324}, abstract = {Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs). The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power.}, language = {en} } @article{FrikelHaltmeier, author = {Frikel, J{\"u}rgen and Haltmeier, Markus}, title = {Efficient regularization with wavelet sparsity constraints in photoacoustic tomography}, series = {Inverse Problems}, volume = {34}, journal = {Inverse Problems}, number = {2}, doi = {10.1088/1361-6420/aaa0ac}, pages = {1 -- 28}, abstract = {In this paper, we consider the reconstruction problem of photoacoustic tomography (PAT) with a flat observation surface. We develop a direct reconstruction method that employs regularization with wavelet sparsity constraints. To that end, we derive a wavelet-vaguelette decomposition (WVD) for the PAT forward operator and a corresponding explicit reconstruction formula in the case of exact data. In the case of noisy data, we combine the WVD reconstruction formula with soft-thresholding, which yields a spatially adaptive estimation method. We demonstrate that our method is statistically optimal for white random noise if the unknown function is assumed to lie in any Besov-ball. We present generalizations of this approach and, in particular, we discuss the combination of PAT-vaguelette soft-thresholding with a total variation (TV) prior. We also provide an efficient implementation of the PAT-vaguelette transform that leads to fast image reconstruction algorithms supported by numerical results.}, language = {en} } @article{Diamantidis, author = {Diamantidis, Dimitris}, title = {A Critical View on Environmental and Human Risk Acceptance Criteria}, series = {International Journal of Environmental Science and Development}, volume = {8}, journal = {International Journal of Environmental Science and Development}, number = {1}, doi = {10.18178/ijesd.2017.8.1.921}, pages = {62 -- 66}, abstract = {Natural and technological hazards have a major impact on environmental and human safety. Risk assessment plays an essential role in the risk management of the effects of such hazards. This contribution summarizes first the general formulation of risk depending on two parameters: hazard probability and associated consequences. Problems faced in industrial applications based on the experience of the author are discussed. Risk acceptance criteria for the contributors to risk i.e. human, economic and environment are critically reviewed. Resilience based criteria are also included and conclusions for future developments are provided.}, language = {en} } @article{FranzWolfPeriyasamyetal., author = {Franz, Maja and Wolf, Lucas and Periyasamy, Maniraman and Ufrecht, Christian and Scherer, Daniel D. and Plinge, Axel and Mutschler, Christopher and Mauerer, Wolfgang}, title = {Uncovering Instabilities in Variational-Quantum Deep Q-Networks}, series = {Journal of the Franklin Institute}, journal = {Journal of the Franklin Institute}, edition = {In Press, Corrected Proof}, publisher = {Elsevier}, issn = {0016-0032}, doi = {10.1016/j.jfranklin.2022.08.021}, abstract = {Deep Reinforcement Learning (RL) has considerably advanced over the past decade. At the same time, state-of-the-art RL algorithms require a large computational budget in terms of training time to converge. Recent work has started to approach this problem through the lens of quantum computing, which promises theoretical speed-ups for several traditionally hard tasks. In this work, we examine a class of hybrid quantumclassical RL algorithms that we collectively refer to as variational quantum deep Q-networks (VQ-DQN). We show that VQ-DQN approaches are subject to instabilities that cause the learned policy to diverge, study the extent to which this afflicts reproduciblity of established results based on classical simulation, and perform systematic experiments to identify potential explanations for the observed instabilities. Additionally, and in contrast to most existing work on quantum reinforcement learning, we execute RL algorithms on an actual quantum processing unit (an IBM Quantum Device) and investigate differences in behaviour between simulated and physical quantum systems that suffer from implementation deficiencies. Our experiments show that, contrary to opposite claims in the literature, it cannot be conclusively decided if known quantum approaches, even if simulated without physical imperfections, can provide an advantage as compared to classical approaches. Finally, we provide a robust, universal and well-tested implementation of VQ-DQN as a reproducible testbed for future experiments.}, language = {en} } @article{SchloplocherEttengruberSteffens, author = {Schloplocher, Paul Dragos and Ettengruber, Stefan and Steffens, Oliver}, title = {Improvements for building-performance simulations by a comparative finite-element method analysis}, series = {Energy and Buildings}, volume = {278}, journal = {Energy and Buildings}, publisher = {Elsevier}, doi = {10.1016/j.enbuild.2022.112563}, pages = {1 -- 12}, abstract = {This paper presents a method to improve building-performance simulations (BPS) by the comparison and analysis of different approaches based on finite-element method (FEM) models. The lumped parameter method (LPM) is used in several BPS programs and tools. It has the advantage of fast computing times and comparably good accuracy for thermal and energy loads. With the help of detailed FEM simulations, it is possible to further improve the degree of detail and accuracy while maintaining the high simulation speed. In this work, we compare time-dependent results for local temperatures in a generic reference room within a given periode of time. In a second step, the differences between the models with respect to various physical effects are analyzed and used to introduce additional equations into the LPM model in order to improve its accuracy. Thus, we discuss potentials for improvement for BPS and demonstrate a method of a practical implementation. The results show minor differences of less than 0.1 K for radiation and heat transfer, so their level of detail in BPS is appropriate. In these terms, no improvements were pursued within the work. However, the FEM simulation is capable of calculating the internal convective heat transfer and thermal bridges more accurately due to the use of computational fluid dynamics (CFD) and the geometrically precise representation of the FEM model. Here, deviations of up to 1 K in room temperature (convective heat transfer) and up to 0.5 K in wall temperatures (thermal bridges) were pointed out. By improving the LPM with equations obtained from the FEM, these deviations can be reduced to less than 0.2 K, which is a considerable improvement in accuracy.}, language = {en} } @article{MaiwaldRoiderSchmidtetal., author = {Maiwald, Frederik and Roider, Clemens and Schmidt, Michael and Hierl, Stefan}, title = {Optical Coherence Tomography for 3D Weld Seam Localization in Absorber-Free Laser Transmission Welding}, series = {Applied Sciences}, volume = {12}, journal = {Applied Sciences}, number = {5}, publisher = {MPDI}, address = {Basel}, doi = {10.3390/app12052718}, pages = {1 -- 11}, abstract = {Quality and reliability are of the utmost importance for manufacturing in the optical and medical industries. Absorber-free laser transmission welding enables the precise joining of identical polymers without additives or adhesives and is well-suited to meet the demands of the aforementioned industries. To attain sufficient absorption of laser energy without absorbent additives, thulium fiber lasers, which emit in the polymers' intrinsic absorption spectrum, are used. Focusing the laser beam with a high numerical aperture provides significant intensity gradients inside the workpiece and enables selective fusing of the internal joining zone without affecting the surface of the device. Because seam size and position are crucial, the high-quality requirements demand internal weld seam monitoring. In this work, we propose a novel method to determine weld seam location and size using optical coherence tomography. Changes in optical material properties because of melting and re-solidification during welding allow for weld seam differentiation from the injection-molded base material. Automatic processing of the optical coherence tomography data enables the identification and measurement of the weld seam geometry. The results from our technique are consistent with microscopic images of microtome sections and demonstrate that weld seam localization in polyamide 6 is possible with an accuracy better than a tenth of a millimeter.}, language = {en} } @article{KreitmeierChashinFetisovetal., author = {Kreitmeier, Florian and Chashin, Dmitri V. and Fetisov, Yuri K. and Fetisov, Leonid Y. and Schulz, Irene and Monkman, Gareth J. and Shamonin (Chamonine), Mikhail}, title = {Nonlinear Magnetoelectric Response of Planar Ferromagnetic-Piezoelectric Structures to Sub-Millisecond Magnetic Pulses}, series = {Sensors}, volume = {12}, journal = {Sensors}, number = {11}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s121114821}, pages = {14821 -- 14837}, abstract = {The magnetoelectric response of bi- and symmetric trilayer composite structures to pulsed magnetic fields is experimentally investigated in detail. The structures comprise layers of commercially available piezoelectric (lead zirconate titanate) and magnetostrictive (permendur or nickel) materials. The magnetic-field pulses have the form of a half-wave sine function with duration of 450 µs and amplitudes ranging from 500 Oe to 38 kOe. The time dependence of the resulting voltage is presented and explained by theoretical estimations. Appearance of voltage oscillations with frequencies much larger than the reciprocal pulse length is observed for sufficiently large amplitudes (~1-10 kOe) of the magnetic-field pulse. The origin of these oscillations is the excitation of bending and planar acoustic oscillations in the structures. Dependencies of the magnetoelectric voltage coefficient on the excitation frequency and the applied magnetic field are calculated by digital signal processing and compared with those obtained by the method of harmonic field modulation. The results are of interest for developing magnetoelectric sensors of pulsed magnetic fields as well as for rapid characterization of magnetoelectric composite structures.}, language = {en} } @article{ApelsmeierGleixnerMayeretal., author = {Apelsmeier, Andreas and Gleixner, Ramona and Mayer, Matthias and Shamonin (Chamonine), Mikhail and Schmauss, Bernhard}, title = {Intensity referencing in an extrinsic optical fiber temperature sensor}, series = {Procedia Engineering}, volume = {5}, journal = {Procedia Engineering}, publisher = {Elsevier}, doi = {10.1016/j.proeng.2010.09.301}, pages = {1095 -- 1098}, abstract = {Optical fiber sensors based on intensity measurement require some form of intensity referencing to avoid errors arising from parasitic losses. Known techniques of referencing such as balanced bridge, divided beam systems or two-wavelength referencing are not suitable for low-cost applications since they use relatively complicated optical components such as multiple LED sources, couplers, filters etc. In this work a novel method of referencing in an extrinsic optical fiber sensor system utilizing temperature dependence of absorption edge in a semiconductor crystal is described. The sensor system comprises a single LED source and no optical fiber junctions. The emission spectrum of an LED depends on its temperature. The reference is provided by controlling the temperature of an LED source and transmission measurements with different emission spectra. The entire process is controlled by a microprocessor unit. Performance of a sensor system is investigated and it is shown that the losses in connectors may be compensated for.}, language = {en} } @article{MonkmanSindersbergerPremetal., author = {Monkman, Gareth J. and Sindersberger, Dirk and Prem, Nina and Szecsey, Tamara}, title = {Smart Stiction}, series = {Robotics \& Automation Engineering Journal}, volume = {4}, journal = {Robotics \& Automation Engineering Journal}, number = {4}, publisher = {Juniper Publishers}, doi = {10.19080/RAEJ.2019.04.555641}, abstract = {Soft robotics could loosely be described as the engineering science of expanded dexterity through controllable flexibility. The exploitation of controllable compliance through the judicious choice of soft flexible members, as opposed to a finite number of rigid kinematic joints, can result in greater dexterity without compromising simplicity. One example is the replacement of segmented mechanical legs with simple compliant material eruciform prolegs. To achieve this in robotics, without introducing additional mechanical joints, mobile surfaces with switchable coefficients of friction is essential. This paper explains how, using silicone based smart materials, the rapid alternation between kinematic and static friction (stiction) may be achieved.}, language = {en} } @article{Herrmann, author = {Herrmann, Frank}, title = {Human Experience Versus Rule Decision at Krones AG}, series = {Biomedical Journal of Scientific \& Technical Research}, volume = {42}, journal = {Biomedical Journal of Scientific \& Technical Research}, number = {1}, publisher = {Biomedical Research Network+}, issn = {2574 -1241}, doi = {10.26717/BJSTR.2022.42.006691}, pages = {33255 -- 33260}, abstract = {Final assembly at Krones AG must make the best possible use of its production space and meeting the specified customer due dates is critical. Via a self developed simulation tool, the present scheduling procedure is compared with the one by priority rule shortest slack. As a consequence slack should have a higher importance in the planning}, language = {en} } @article{GoeppelFrikelHaltmeier, author = {G{\"o}ppel, Simon and Frikel, J{\"u}rgen and Haltmeier, Markus}, title = {Data-Proximal Complementary ℓ1-TV Reconstruction for Limited Data Computed Tomography}, series = {Mathematics}, volume = {12}, journal = {Mathematics}, number = {10}, publisher = {MDPI}, issn = {2227-7390}, doi = {10.3390/math12101606}, abstract = {In a number of tomographic applications, data cannot be fully acquired, resulting in severely underdetermined image reconstruction. Conventional methods in such cases lead to reconstructions with significant artifacts. To overcome these artifacts, regularization methods are applied that incorporate additional information. An important example is TV reconstruction, which is known to be efficient in compensating for missing data and reducing reconstruction artifacts. On the other hand, tomographic data are also contaminated by noise, which poses an additional challenge. The use of a single regularizer must therefore account for both the missing data and the noise. A particular regularizer may not be ideal for both tasks. For example, the TV regularizer is a poor choice for noise reduction over multiple scales, in which case ℓ1 curvelet regularization methods are well suited. To address this issue, in this paper, we present a novel variational regularization framework that combines the advantages of different regularizers. The basic idea of our framework is to perform reconstruction in two stages. The first stage is mainly aimed at accurate reconstruction in the presence of noise, and the second stage is aimed at artifact reduction. Both reconstruction stages are connected by a data proximity condition. The proposed method is implemented and tested for limited-view CT using a combined curvelet-TV approach. We define and implement a curvelet transform adapted to the limited-view problem and illustrate the advantages of our approach in numerical experiments.}, language = {en} } @article{MikhaeilGadererDawoud, author = {Mikhaeil, Makram and Gaderer, Matthias and Dawoud, Belal}, title = {On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study}, series = {Energy}, volume = {207}, journal = {Energy}, number = {September}, publisher = {Elsevier}, doi = {10.1016/j.energy.2020.118272}, pages = {1 -- 13}, abstract = {An innovative adsorber plate heat exchanger (APHE), which is developed for application in adsorption heat pumps, chillers and thermal energy storage systems, is introduced. A test frame has been constructed as a representative segment of the introduced APHE for applying loose grains of AQSOA-Z02. Adsorption kinetic measurements have been carried out in a volumetric large-temperature-jump setup under typical operating conditions of adsorption processes. A transient 2-D model is developed for the tested sample inside the setup. The measured temporal uptake variations with time have been fed to the model, through which a micro-pore diffusion coefficient at infinite temperature of 2 E-4 [m2s-1] and an activation energy of 42.1 [kJ mol-1] have been estimated. A 3-D model is developed to simulate the combined heat and mass transfer inside the APHE and implemented in a commercial software. Comparing the obtained results with the literature values for an extruded aluminium adsorber heat exchanger coated with a 500 μm layer of the same adsorbent, the differential water uptake obtained after 300 s of adsorption (8.2 g/100 g) implies a sound enhancement of 310\%. This result proves the great potential of the introduced APHE to remarkably enhance the performance of adsorption heat transformation appliances.}, language = {en} } @article{HuberHeindlSchlosseretal., author = {Huber, Lea and Heindl, Melanie and Schlosser, Marc and Pfitzner, Arno and Dawoud, Belal}, title = {On the Cycle Stability and Macroscopic Structure of Iron Oxide Pellets for Thermochemical Hydrogen Storage: Influence of Water Content during the Pelletizing Process}, series = {Applied Sciences}, volume = {13}, journal = {Applied Sciences}, number = {11}, publisher = {MDPI}, address = {16}, doi = {10.3390/app13116408}, abstract = {Hydrogen storage based on the repeated reduction and oxidation (redox) reactions of iron oxide/iron composites represents a promising technology. This work is dedicated to studying the influence of the amount of water added during the pelletizing process on the cycle stability and structure of iron oxide pellets. The storage composites were prepared from iron oxide (Fe2O3) and 10 wt.-\% support material (cement) with different amounts of water (18 and 33 wt.-\%) in a laboratory-scale pelletizing disk. To evaluate the cycle stability of the composites, the kinetics of the redox reactions were experimentally measured at 800 ∘ C in an atmosphere of 50\% N2 and 50\% H2 (reduction) or 50\% steam (oxidation), respectively. Moreover, the structure of the pellets was analyzed by micro-computed tomography scans. It turned out that pellets with higher water contents attained faster kinetics and a higher cycle stability. The sample with the least water content (18 wt.-\%) needed about 26 min and 19 min to reach a conversion rate of 80\% during the reduction and oxidation reactions of the sixth redox cycle, respectively. In contrast, the sample with the highest water content (33 wt.-\%) could achieve the same conversion rate after 18 min (reduction) and 13 min (oxidation) during the ninth redox cycle.}, language = {en} } @article{Schiek, author = {Schiek, Roland}, title = {Nonlinear refractive index in silica glass}, series = {Optical Materials Expres}, volume = {13}, journal = {Optical Materials Expres}, number = {6}, publisher = {Optica}, doi = {10.1364/ome.489520}, pages = {1727 -- 1740}, abstract = {The third-order nonlinear susceptibility of silica glass is measured via self-phase modulation in standard single mode fibers at a wavelength of 1550 nm. To minimize the influence of polarization state changes along the propagation only meter-long fibers were investigated. With pulse durations of picoseconds a quasi-instantaneous nonlinearity with ultrafast electronic and fast nuclear-vibration contributions produces under conditions of negligible dispersion a classic and clean nonlinear phase shift following exactly the shape of the pulse power. The complex pulse envelope was retrieved from frequency optical gating spectrograms. The nonlinear fiber parameter γ could be determined with an accuracy of 3.7 percent. Considering the mode field structure and the doping influence the nonlinear refractive index of silica glass as the fiber base material was found to be n 2 =2.22⋅10 -16 cm 2 W±6.0\% for picosecond-long pulses. Comparing nonlinear phase shifts from linear and circular polarized light a nuclear-vibration contribution to the cubic fiber nonlinearity of 25 percent was estimated.}, language = {en} } @article{RomanoEhrlich, author = {Romano, Marco and Ehrlich, Ingo}, title = {Classification of damping properties of fabric-reinforced flat beam-like specimens by a degree of ondulation implying a mesomechanic kinematic}, series = {Science and Engineering of Composite Materials}, volume = {31}, journal = {Science and Engineering of Composite Materials}, number = {1}, publisher = {Walter de Gruyter GmbH}, issn = {2191-0359}, doi = {10.1515/secm-2024-0019}, abstract = {In order to determine the influence of the ondulations in fabrics on the damping properties of fiber-reinforced plastics, the structural dynamic properties of fabric- and unidirectionally reinforced plastics are investigated. The free decay behavior of flat beam-like specimens is investigated under fixed-free boundary conditions. As the material damping is consistently higher in fabric-reinforced specimens compared to unidirectionally reinforced ones, a contribution of an additionally acting mesomechanic kinematic in fabric weaves is implied. Based on a degree of ondulation, it is possible to classify the enhancement of the material damping and determine the corresponding energy dissipation. The study provides valuable quantitative relations of the additional damping effect due to the mesomechanic kinematic. Compared to the unidirectionally reinforced material, plain weave enhances the material damping by 37…52\% at ˜OPL=0.0133 , whereas twill weave 2/2 enhances it by 31…40\% at ˜OT2=0.0098 . The consideration of the findings contributes to a deeper understanding of the visco-elastic dynamic behavior of fabric-reinforced plastics and allows further applications in research, development, and industry.}, language = {en} } @article{SteiningerGadererDawoud, author = {Steininger, Peter and Gaderer, Matthias and Dawoud, Belal}, title = {Assessment of the Annual Transmission Heat Loss Reduction of a Refurbished Existing Building with an Advanced Solar Selective Thermal Insulation System}, series = {Sustainability}, volume = {13}, journal = {Sustainability}, number = {13}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/su13137336}, pages = {1 -- 19}, abstract = {A numerical parameter sensitivity analysis of the design parameters of the recently published solar selective thermal insulation system (SATIS) has been carried out to enhance its thermal and optical properties. It turned out that the insulation properties of SATIS can be effectively improved by reducing the length of the glass closure element. Increasing the area share of the light conducting elements (LCEs) and decreasing their length-to-diameter (L/D) ratio were identified as key parameters in order to increase the solar gain. Two SATIS variants were compared with the same wall insulation without SATIS in a yearly energetic performance assessment. The SATIS variant with 10 mm length of the closure element, 44.2\% area share of LCE, as well as front and rear diameters of 12 mm/9 mm shows an 11.8\% lower transmission heat loss over the heating period than the wall insulation without SATIS. A new methodology was developed to enable the implementation of the computed solar gains of SATIS in 1D simulation tools. The result is a radiant heat flow map for integration as a heat source in 1D simulation models. A comparison between the 1D and 3D models of the inside wall heat fluxes showed an integral yearly agreement of 98\%.}, language = {en} } @article{SindersbergerPremMonkman, author = {Sindersberger, Dirk and Prem, Nina and Monkman, Gareth J.}, title = {Structure formation in low concentration magnetoactive polymers}, series = {AIP advances}, volume = {9}, journal = {AIP advances}, number = {3}, publisher = {AIP Publishing}, doi = {10.1063/1.5079997}, abstract = {This paper concerns recent research into the autonomous formation of micro-structures in low carbonyl iron powder (CIP) concentration magneto active polymers (MAP). Higher concentrations of CIP show an isotropic distribution of magnetic filler throughout the entire sample, while autonomous structure formation is possible at mass concentrations lower than 3\%. The formation of micro-toroids commences as CIP concentration approaches 1\% wt. Further development of coherent rings with a defined order follow as CIP concentrations increase toward 2\% wt, whilst exceeding 3\% wt leads to the same isotropic distribution found in higher concentration MAP. Structured samples containing between 1\% wt and 3\% wt CIP were investigated using X-Ray tomography where solitary structures could clearly be observed. The ring structures represent microinductivities whose geometries can be manipulated during fabrication. In addition, these structures are magnetic field sensitive. This is not only relevant to applications in the GHz and THz areas but recent research has revealed implications for optical, thermal, acoustic and even chemical MAP sensors. (C) 2019 Author(s).}, language = {en} } @article{SternerBauer, author = {Sterner, Michael and Bauer, Franz}, title = {Power-to-X im Kontext der Energiewende und des Klimaschutzes in Deutschland}, series = {Chemie-Ingenieur-Technik}, volume = {92}, journal = {Chemie-Ingenieur-Technik}, number = {1-2}, publisher = {Wiley}, issn = {0009-286X}, doi = {10.1002/cite.201900167}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-11669}, pages = {85 -- 90}, abstract = {Um den Einfluss verschiedener Power-to-X-Verfahren auf die Transformation des deutschen Energiesystems und das Erreichen der Klimaschutzziele zu {\"u}berpr{\"u}fen, wurde ein sektor{\"u}bergreifendes Energiesystemmodel entwickelt. Die daraus gewonnenen Ergebnisse zeigen: F{\"u}r eine erfolgreiche Energiewende ist der Einsatz von Power-to-X in Zukunft unverzichtbar. Vor allem in Bereichen und Sektoren, in denen hohe Energiedichten erforderlich und nur wenig andere Optionen zur Defossilisierung vorhanden sind, werden Power-to-X-Technologien zwingend notwendig.}, subject = {Power-to-Gas}, language = {de} } @article{KloiberSchultheissSoteloetal., author = {Kloiber, Jessica and Schultheiß, Ulrich and Sotelo, Lamborghini and Sarau, George and Christiansen, Silke H. and Gavras, Sarkis and Hort, Norbert and Hornberger, Helga}, title = {Corrosion behaviour of electropolished magnesium materials}, series = {Materials Today Communications}, journal = {Materials Today Communications}, edition = {Journal Pre-proof}, publisher = {Elsevier}, doi = {10.1016/j.mtcomm.2023.107983}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-68254}, abstract = {Although magnesium and its alloys are promising candidates as biodegradable implant materials, the tendency for localized corrosion mechanism in physiological environment limit their biomedical application. Electropolishing is an attractive strategy for improving the corrosion behaviour of metals, but it is still largely unexplored in magnesium materials. In this study, the characterization of electropolished surfaces of AM50 and pure magnesium was performed, focussing on their in vitro degradation behaviour in cell medium. Corrosion rates were evaluated using potentiodynamic polarisation. The surface morphology before and after the onset of corrosion was investigated by scanning electron microscopy and confocal laser scanning microscopy. The presented electropolishing process led to improved surface performances, observable by significantly lower corrosion rates (0.08 mm·year-1 in Dulbecco's modified Eagle's medium), lower arithmetical mean height (0.05 µm), lower water contact angle (25-35°) and lower micro hardness (35-50 HV 0.1) compared to mechanically and chemically treated surfaces. MgO/Mg(OH)2 could be detected on electropolished surfaces. The localized corrosion mode could be reduced, but not entirely prevented. Electropolishing shows great potential as post-treatment of magnesium-based components, but detailed tests of the long-term corrosion behaviour are an important area of future research.}, language = {en} } @article{ThemaBauerSterner, author = {Thema, Martin and Bauer, Franz and Sterner, Michael}, title = {Power-to-Gas: Electrolysis and methanation status review}, series = {Renewable and Sustainable Energy Reviews}, volume = {112}, journal = {Renewable and Sustainable Energy Reviews}, number = {7}, publisher = {Elsevier}, doi = {10.1016/j.rser.2019.06.030}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-26238}, pages = {775 -- 787}, abstract = {This review gives a worldwide overview on Power-to-Gas projects producing hydrogen or renewable substitute natural gas focusing projects in central Europe. It deepens and completes the content of previous reviews by including hitherto unreviewed projects and by combining project names with details such as plant location. It is based on data from 153 completed, recent and planned projects since 1988 which were evaluated with regards to plant allocation, installed power development, plant size, shares and amounts of hydrogen or substitute natural gas producing examinations and product utilization phases. Cost development for electrolysis and carbon dioxide methanation was analyzed and a projection until 2030 is given with an outlook to 2050. The results show substantial cost reductions for electrolysis as well as for methanation during the recent years and a further price decline to less than 500 euro per kilowatt electric power input for both technologies until 2050 is estimated if cost projection follows the current trend. Most of the projects examined are located in Germany, Denmark, the United States of America and Canada. Following an exponential global trend to increase installed power, today's Power-to-Gas applications are operated at about 39 megawatt. Hydrogen and substitute natural gas were investigated on equal terms concerning the number of projects.}, language = {en} } @article{SternerHofrichterMeisingeretal., author = {Sterner, Michael and Hofrichter, Andreas and Meisinger, Alexander and Bauer, Franz and Pinkwart, Karsten and Maletzko, Annabelle and Dittmar, Felix and Cremers, Carsten}, title = {19 Import options for green hydrogen and derivatives - An overview of efficiencies and technology readiness levels}, series = {International Journal of Hydrogen Energy}, volume = {90}, journal = {International Journal of Hydrogen Energy}, publisher = {Elsevier}, issn = {0360-3199}, doi = {10.1016/j.ijhydene.2024.10.045}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-77756}, pages = {1112 -- 1127}, abstract = {The import of hydrogen and derivatives forms part of many national strategies and is fundamental to achieving climate protection targets. This paper provides an overview and technical comparison of import pathways for hydrogen and derivatives in terms of efficiency, technological maturity and development and construction times with a focus on the period up to 2030. The import of hydrogen via pipeline has the highest system efficiency at 57-67 \% and the highest technological maturity with a technology readiness level (TRL) of 8-9. The import of ammonia and methanol via ship and of SNG via pipeline shows efficiencies in the range of 39-64 \% and a technological maturity of TRL 7 to 9 when using point sources. Liquid hydrogen, LOHC and Fischer-Tropsch products have the lowest efficiency and TRL in comparison. The use of direct air capture (DAC) reduces efficiency and TRL considerably. Reconversion of the derivatives to hydrogen is also associated with high losses and is not achievable for all technologies on an industrial scale up to 2030. In the short to medium term, import routes for derivatives that can utilise existing infrastructures and mature technologies are the most promising for imports. In the long term, the most promising option is hydrogen via pipelines.}, language = {en} }