@article{SteiningerGadererDawoud, author = {Steininger, Peter and Gaderer, Matthias and Dawoud, Belal}, title = {Assessment of the Annual Transmission Heat Loss Reduction of a Refurbished Existing Building with an Advanced Solar Selective Thermal Insulation System}, series = {Sustainability}, volume = {13}, journal = {Sustainability}, number = {13}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/su13137336}, pages = {1 -- 19}, abstract = {A numerical parameter sensitivity analysis of the design parameters of the recently published solar selective thermal insulation system (SATIS) has been carried out to enhance its thermal and optical properties. It turned out that the insulation properties of SATIS can be effectively improved by reducing the length of the glass closure element. Increasing the area share of the light conducting elements (LCEs) and decreasing their length-to-diameter (L/D) ratio were identified as key parameters in order to increase the solar gain. Two SATIS variants were compared with the same wall insulation without SATIS in a yearly energetic performance assessment. The SATIS variant with 10 mm length of the closure element, 44.2\% area share of LCE, as well as front and rear diameters of 12 mm/9 mm shows an 11.8\% lower transmission heat loss over the heating period than the wall insulation without SATIS. A new methodology was developed to enable the implementation of the computed solar gains of SATIS in 1D simulation tools. The result is a radiant heat flow map for integration as a heat source in 1D simulation models. A comparison between the 1D and 3D models of the inside wall heat fluxes showed an integral yearly agreement of 98\%.}, language = {en} } @article{GamischHuberGadereretal., author = {Gamisch, Bernd and Huber, Lea and Gaderer, Matthias and Dawoud, Belal}, title = {On the Kinetic Mechanisms of the Reduction and Oxidation Reactions of Iron Oxide/Iron Pellets for a Hydrogen Storage Process}, series = {Energies}, volume = {15}, journal = {Energies}, number = {21}, publisher = {MDPI}, doi = {10.3390/en15218322}, abstract = {This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90\% Fe2O3, 10\% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions' kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5\%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71\% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.}, language = {en} } @article{MikhaeilNowakPalombaetal., author = {Mikhaeil, Makram and Nowak, Sebastian and Palomba, Valeria and Frazzica, Andrea and Gaderer, Matthias and Dawoud, Belal}, title = {Experimental and analytical investigation of applying an asymmetric plate heat exchanger as an evaporator in a thermally driven adsorption appliance}, series = {Applied Thermal Engineering}, journal = {Applied Thermal Engineering}, number = {228}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2023.120525}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-61115}, abstract = {This communication presents an experimental and analytical study on the evaporation mechanism in a closed-structured asymmetric plate heat exchanger (PHE) employed as a stagnant water evaporator for the application in an adsorption heat transformation appliance. To this aim, an experimental unit is constructed, which comprises two identical PHEs, one acting as an vaporator/condenser and the second, as an adsorber/desorber. Two endoscopes are mounted inside the investigated evaporator to visualize the evaporation mechanism when performing adsorption-evaporation processes under different boundary conditions. It turned out that the evaporation mechanism is a partially covered, thin film evaporation. A heat transfer analysis is performed to evaluate the heat transfer coefficient of the thin film evaporation () inside the investigated evaporator, resulting in -values between 1330 and 160 [W∙m-2∙K-1] over the investigated adsorption-evaporation time. Correlating the obtained () to the film thickness and the wetted area results in -values between 0.34 and 0.78 [mm] and wetted to total area ratios of 0.78 to 0.16. Besides, an analytical model has been developed and introduced to correlate the overall evaporator heat transfer coefficient with the adsorption potential and the time rate of change of the water uptake.}, language = {en} } @article{HuberHeindlSchlosseretal., author = {Huber, Lea and Heindl, Melanie and Schlosser, Marc and Pfitzner, Arno and Dawoud, Belal}, title = {On the Cycle Stability and Macroscopic Structure of Iron Oxide Pellets for Thermochemical Hydrogen Storage: Influence of Water Content during the Pelletizing Process}, series = {Applied Sciences}, volume = {13}, journal = {Applied Sciences}, number = {11}, publisher = {MDPI}, address = {16}, doi = {10.3390/app13116408}, abstract = {Hydrogen storage based on the repeated reduction and oxidation (redox) reactions of iron oxide/iron composites represents a promising technology. This work is dedicated to studying the influence of the amount of water added during the pelletizing process on the cycle stability and structure of iron oxide pellets. The storage composites were prepared from iron oxide (Fe2O3) and 10 wt.-\% support material (cement) with different amounts of water (18 and 33 wt.-\%) in a laboratory-scale pelletizing disk. To evaluate the cycle stability of the composites, the kinetics of the redox reactions were experimentally measured at 800 ∘ C in an atmosphere of 50\% N2 and 50\% H2 (reduction) or 50\% steam (oxidation), respectively. Moreover, the structure of the pellets was analyzed by micro-computed tomography scans. It turned out that pellets with higher water contents attained faster kinetics and a higher cycle stability. The sample with the least water content (18 wt.-\%) needed about 26 min and 19 min to reach a conversion rate of 80\% during the reduction and oxidation reactions of the sixth redox cycle, respectively. In contrast, the sample with the highest water content (33 wt.-\%) could achieve the same conversion rate after 18 min (reduction) and 13 min (oxidation) during the ninth redox cycle.}, language = {en} }