@inproceedings{PangerlWittmannWeigletal., author = {Pangerl, Jonas and Wittmann, Elisabeth and Weigl, Stefan and M{\"u}ller, Max and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Using a Modulated Quantum Cascade Laser for Photoacoustic Spectra Recording of Exhaled Acetone and Main Breath Components}, series = {Optical Sensors and Sensing Congress 2022 (AIS, LACSEA, Sensors, ES)}, booktitle = {Optical Sensors and Sensing Congress 2022 (AIS, LACSEA, Sensors, ES)}, publisher = {Optica Publishing Group}, doi = {10.1364/AIS.2022.ATu3G.1}, abstract = {Photoacoustic spectra of main breath components together with acetone are presented demonstrating spectral linearity towards different concentrations and compositions. The acetone 3σ detection limit at 1209 cm-1 is 0.28 ppbV}, language = {en} } @inproceedings{BartlBuchnerHausladenetal., author = {Bartl, Mathias and Buchner, Philipp and Hausladen, Matthias and Asgharzadehkhorasani, Ali and Bachmann, Michael and Schreiner, Rupert}, title = {Simulations and Investigations of Silicon Nanowire Field Emitters}, series = {37th International Vacuum Nanoelectronics Conference (IVNC), 15-19 July 2024, Brno, Czech Republic}, booktitle = {37th International Vacuum Nanoelectronics Conference (IVNC), 15-19 July 2024, Brno, Czech Republic}, publisher = {IEEE}, doi = {10.1109/IVNC63480.2024.10652355}, pages = {1 -- 2}, abstract = {The emission behavior of field emission electron sources consisting of a silicon nanowire cathode, an extraction grid electrode and a planar anode was investigated based on a particle tracing simulation using FEM. The focus was on the influence of the grid geometry as well as the positioning of the grid relative to the emitters on the electron transmission. The highest transmission can be achieved with the emitter tips protruding 10 µm trough the extraction grid openings. The transmission decreases more rapidly with increasing distance between the tip and the grid the thicker the grid is.}, language = {en} } @phdthesis{Berndt, author = {Berndt, Dominik}, title = {Thermische Wasserstoffsensoren f{\"u}r den Automobilbereich}, address = {Regensburg}, abstract = {F{\"u}r den sicheren Betrieb eines Brennstoffzellenfahrzeugs sind Sensoren wichtig, welche die Wasserstoffkonzentration im Fahrzeuginterieur kontinuierlich {\"u}berwachen, um m{\"o}glichen Entz{\"u}ndungen bzw. Explosionen vorzubeugen. Daf{\"u}r wurden von verschiedenen nationalen und internationalen Instanzen bestimmte Kriterien definiert, die Wasserstoffsensoren f{\"u}r einen Einsatz in Brennstoffzellenfahrzeugen erf{\"u}llen m{\"u}ssen. Im Jahr 2020gab es noch keinen einzigen kommerziell erh{\"a}ltlichen Sensor, der alle diese Kriterien bedienen konnte. In der vorliegenden Arbeit wurde f{\"u}r zwei verschiedene Sensoren die Eignung des thermischen Wirkprinzips f{\"u}r die Detektion von Wasserstoff im Kontext dieser Sicherheitskriterien untersucht. Dabei wurden mit einem MEMS-Sensor und einem Mikrodrahtsensor zwei vergleichsweise einfache Geometrien herangezogen, welche den eindimensionalen und zylindersymmetrischen Fall abbilden sollen. F{\"u}r zwei dynamische Operationsmodi (gepulste Str{\"o}me und 3ω-Methode) wurden darauf aufbauend analytische Modelle basierend auf vereinfachten Sensorgeometrien entwickelt, um die Temperaturentwicklung des Sensorelements in Abh{\"a}ngigkeit der Zeit zu charakterisieren. Diese Studien wurden anschließend anhand von detaillierteren Modellen mithilfe von FEM-Simulationen erg{\"a}nzt und spezifiziert. Darin konnte gezeigt werden, dass f{\"u}r den gepulsten Betrieb sowohl die Pulsh{\"o}he als auch die Zeitkonstante des gemessenen Widerstands- bzw. Temperaturpulses als Messgr{\"o}ße herangezogen werden kann. Beim 3ω-Betrieb konnte zudem eine starke Frequenzabh{\"a}ngigkeit dieser Widerstands- bzw. Temperaturcharakteristik beobachtet werden. Die analytischen und numerischen Studien wurden anschließend durch experimentelle Ergebnisse best{\"a}tigt. Im Hinblick auf die zuvor definierten Kriterien stellte sich heraus, dass die Auswertung der Zeitkonstante beim gepulsten Betrieb im Hinblick auf Sensitivit{\"a}t und Aufl{\"o}sungsgrenze der Auswertung der Pulsh{\"o}he deutlich unterlegen ist. Beim 3ω-Betrieb k{\"o}nnen durch die hochintegrierte Messumgebung deutlich h{\"o}here Genauigkeiten und Aufl{\"o}sungsgrenzen erzielt werden. F{\"u}r den MEMS-Sensor wurde bei einer Anregungsfrequenz von 1 Hz mit 55 ppm die bislang geringste in der Literatur berichtete Aufl{\"o}sungsgrenze f{\"u}r einen thermischen Wasserstoffsensor erreicht. Der Leistungsverbrauch ist dabei im Vergleich zum Pulsbetrieb entsprechend des jeweiligen Tastgrads leicht bis m{\"a}ßig erh{\"o}ht, die Ansprechzeit wird bei beiden Operationsmodi maßgeblich durch die Sensorgeometrie beeinflusst. Die geometrischen Parameter der jeweiligen Sensoren haben ferner einen starken Einfluss auf die Sensitivit{\"a}t, womit die Divergenz in der Performance von MEMS-Chip und Drahtsensor erkl{\"a}rt werden kann. Es besteht ferner eine starke Temperatur- und Feuchtigkeitsabh{\"a}ngigkeit des Sensorsignals, welches bei beiden Operationsmodi indirekt proportional zur W{\"a}rmeleitf{\"a}higkeit des betrachteten Gasgemischs ist. Die Abh{\"a}ngigkeit vom definierten Umgebungsdruck ist lediglich f{\"u}r die Zeitkonstante relevant, bei der Pulsh{\"o}he besteht keine Druckabh{\"a}ngigkeit. Es konnte eine grunds{\"a}tzliche Eignung des thermischen Messprinzips f{\"u}r den Einsatz eines Wasserstoffsensors im Automobilbereich festgestellt werden. F{\"u}r eine Anwendung m{\"u}ssen allerdings Referenzsensoren f{\"u}r Temperatur, Feuchtigkeit und Druck implementiert werden und eine Kalibrierung in Abh{\"a}ngigkeit dieser Gr{\"o}ßen erfolgen. Der 3ωBetrieb ist aufgrund der h{\"o}heren Genauigkeit zu bevorzugen. W{\"a}hrend der MEMSSensor im Hinblick auf Sensitivit{\"a}t, Ansprechzeit und Leistungsaufnahme gut abschneidet, liegen die Vorteile des Mikrodrahtsensors in seiner Robustheit und der vergleichsweise einfachen Realisierbarkeit}, subject = {Kraftfahrzeugtechnik}, language = {de} } @article{HausladenBuchnerBartletal., author = {Hausladen, Matthias and Buchner, Philipp and Bartl, Mathias and Bachmann, Michael and Schreiner, Rupert}, title = {Integrated multichip field emission electron source fabricated by laser-micromachining and MEMS technology}, series = {Journal of Vacuum Science \& Technology B}, volume = {42}, journal = {Journal of Vacuum Science \& Technology B}, number = {1}, publisher = {AIP Publishing}, doi = {10.1116/6.0003233}, abstract = {In this work, high-current field emission electron source chips were fabricated using laser-micromachining and MEMS technology. The resulting chips were combined with commercially available printed circuit boards (PCBs) to obtain a multichip electron source. By controlling the separate electron sources using an external current control circuit, we were able to divide the desired total current evenly across the individual chips deployed in the PCB-carrier. In consequence, we were able to show a decreased degradation due to the reduced current load per chip. First, a single electron source chip was measured without current regulation. A steady-state emission current of 1 mA with a high stability of ±1.3\% at an extraction voltage of 250 V was observed. At this current level, a mean degradation slope of -0.7 μA/min with a nearly perfect transmission ratio of 99\% ± 0.4\% was determined. The measurements of a fully assembled multichip PCB-carrier electron source, using a current control circuit for regulation, showed that an even distribution of the desired total current led to a decreased degradation. This was determined by the increase in the required extraction voltage over time. For this purpose, two current levels were applied to the electron source chips of the PCB-carrier using an external current control circuit. First, 300 μA total current was evenly distributed among the individual electron source chips followed by the emission of 300 μA per electron source chip. This allows the observation of the influence of a distributed and nondistributed total current, carried by the electron source chips. Thereby, we obtained an increase in the mean degradation slope from +0.011 V/min (300 μA distributed) to +0.239 V/min (300 μA per chip), which is approximately 21 times higher. Moreover, our current control circuit improved the current stability to under 0.1\% for both current levels, 300 μA distributed and 300 μA per chip.}, language = {en} } @article{RemškarJelencCzepurnyietal., author = {Remškar, Maja and Jelenc, Janez and Czepurnyi, Nikolai and Malok, Matjaž and Pirker, Luka and Schreiner, Rupert and H{\"u}ttel, Andreas K.}, title = {Modulations of the work function and morphology of a single MoS2 nanotube by charge injection}, series = {Nanoscale Advances}, journal = {Nanoscale Advances}, publisher = {Royal Society of Chemistry (RSC)}, issn = {2516-0230}, doi = {10.1039/d4na00490f}, abstract = {Both the miniaturization of transistor components and the ongoing investigation of material systems with potential for quantum information processing have significantly increased current interest of researchers in semiconducting inorganic nanotubes. Here we report on an additional outstanding aspect of these nanostructures, namely the intrinsic coupling of electronic and mechanical properties. We observe electronic and morphology changes in a single MoS2 nanotube, exposed to charge injections by means of an atomic-force-microscopy tip. An elliptic deformation of the nanotube and helical twisting of the nanotube are visible, consistent with the reverse piezoelectric effect. Work-function changes are found to be dependent on the polarity of the injected carriers. An unexpected long-term persistence of the shape deformations is observed and explained with accumulation of structural defects and the resultant strain, which could cause a memory-like charge confinement and a long lasting modulation of the work function.}, language = {en} } @book{Galka, author = {Galka, Stefan}, title = {AutoStore - was Nutzer {\"u}ber das System berichten k{\"o}nnen}, address = {Regensburg}, isbn = {978-3-9818209-9-7}, doi = {10.35096/othr/pub-646}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-6463}, publisher = {Ostbayerische Technische Hochschule Regensburg}, subject = {Kleinteil}, language = {de} } @inproceedings{EscherRueckJobstetal., author = {Escher, Lukas and R{\"u}ck, Thomas and Jobst, Simon and K{\"o}nig, Martin and Bierl, Rudolf}, title = {Design and Characterization of a Low-Cost Photoacoustic Sensor for NO2 Using Lateral Illumination and Background Suppression}, series = {Imaging and Applied Optics Congress 2022 (3D, AOA, COSI, ISA, pcAOP): 11-15 July 2022, Vancouver, British Columbia, Canada}, booktitle = {Imaging and Applied Optics Congress 2022 (3D, AOA, COSI, ISA, pcAOP): 11-15 July 2022, Vancouver, British Columbia, Canada}, publisher = {Optica Publishing Group}, isbn = {978-1-957171-09-8}, doi = {10.1364/3D.2022.JTu2A.10}, abstract = {We introduce a low-cost photoacoustic NO2 sensor based on lateral LED illumination and optical background signal compensation. The 3σ limit of detection (LOD) was identified to be 24 ppbV.}, language = {en} } @unpublished{PangerlSukulRuecketal., author = {Pangerl, Jonas and Sukul, Pritam and R{\"u}ck, Thomas and Escher, Lukas and Miekisch, Wolfram and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Photoacoustic Trace-Analysis of Breath Isoprene and Acetone Via Interband- and Quantum Cascade Lasers}, publisher = {Elsevier / SSRN}, doi = {10.2139/ssrn.4834735}, abstract = {This research presents two laser-based photoacoustic approaches for analyzing exhaled breath isoprene and acetone. The integration of a PTR-ToF-MS as a reference device ensured the reliability and accuracy of the PAS systems that is based on an ICL for isoprene and a QCL for acetone detection. The calibration yielded limits of detection of 26.9 ppbV and 1.7 ppbV, respectively, and corresponding normalized noise equivalent absorption coefficients (NNEAs) of 5.0E-9 Wcm-1Hz-0.5 and 4.9E-9 Wcm-1Hz-0.5. Laboratory as well as real breath sample measurements from alveolar breath revealed a robust system performance, with only one outlier within the static isoprene measurements. However, discrepancies emerged under dynamic breath sampling conditions, emphasizing the need for further optimization. Especially by knowing the dynamic nature and endogenous origin of exhaled isoprene our findings highlight the potential of breath analysis for non-invasive physio-metabolic and pathophysiological monitoring towards point-of-care devices.}, language = {en} } @article{PangerlSukulRuecketal., author = {Pangerl, Jonas and Sukul, Pritam and R{\"u}ck, Thomas and Escher, Lukas and Miekisch, Wolfram and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Photoacoustic trace-analysis of breath isoprene and acetone via interband- and Quantum Cascade Lasers}, series = {Sensors and Actuators: B. Chemical}, volume = {424}, journal = {Sensors and Actuators: B. Chemical}, publisher = {Elsevier}, doi = {10.1016/j.snb.2024.136886}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-77024}, pages = {12}, abstract = {This research presents two laser-based photoacoustic approaches for analyzing exhaled breath isoprene and acetone. The integration of a PTR-ToF-MS as a reference device ensured the reliability and accuracy of the photoacoustic systems that is based on an ICL for isoprene and a QCL for acetone detection. The calibration yielded limits of detection of 26.9 ppbV and 1.7 ppbV, respectively, and corresponding normalized noise equivalent absorption coefficients (NNEAs) of 5.0E-9 Wcm 1Hz 0.5 and 4.9E-9 Wcm 1Hz 0.5. Laboratory as well as real breath sample measurements from alveolar breath revealed a robust system performance, with only one outlier within the static isoprene measurements. However, discrepancies emerged under dynamic breath sampling conditions, emphasizing the need for further optimization. Especially by knowing the dynamic nature and endogenous origin of exhaled isoprene our findings highlight the potential of breath analysis for non-invasive physio-metabolic and pathophysiological monitoring towards point-of-care devices}, language = {en} } @misc{EsperNosterSchultheissetal., author = {Esper, Lukas and Noster, Ulf and Schultheiss, Ulrich and Bund, Andreas}, title = {Quasi-in-Situ Analysis of Electropolished Additively Manufactured Stainless Steel Surfaces}, series = {ECS Meeting Abstracts, F01: Advances in Industrial Electrochemistry and Electrochemical Engineering}, volume = {MA2023-02}, journal = {ECS Meeting Abstracts, F01: Advances in Industrial Electrochemistry and Electrochemical Engineering}, publisher = {The Electrochemical Society}, issn = {2151-2043}, doi = {10.1149/MA2023-02241342mtgabs}, pages = {1342 -- 1342}, abstract = {Progress in additive manufacturing is leading to the emergence of new areas of application. Laser Powder Bed Fusion (L-PBF) is increasingly used for the development of metallic medical implants, but for high-risk implants like vascular support structures (stents), surface quality is critical to ensure successful implantation without harming the surrounding tissue and ensure the patients' health. Therefore, enhancing the surface quality is crucial. Electropolishing is a method for removing surface roughness by smoothing out micro-peaks and valleys. However, L-PBF structures have a high surface roughness due to metal particles adhering on the surface. To achieve a smooth surface for additively manufactured implants like stents using electropolishing, the removal of these particles needs to be studied in more detail. The objective of this study is to examine the electropolishing mechanism of 316L stainless steel samples additively manufactured through Laser Powder Bed Fusion (L-PBF). The main objective is to investigate the removal properties and surface characteristics during electropolishing. To achieve this, various surfaces were characterized for morphology and roughness during Hull cell experiments. Markings are utilized on the Hull cell sample surfaces to identify points of interest during quasi-in-situ measurements. The surfaces are then analyzed after multiple time steps, applying different currents to investigate particle dissolution. The surface characteristics are analyzed through scanning electron microscopy, and surface roughness is analyzed using laser scanning microscopy. The results show that the electropolishing process preferentially removes the adhering particles present on the surface of the samples. Increasing the current density results in faster particle dissolution and a smoother surface (see Figure 1a and b). The mechanism of material removal of various surface features, as shown in Figure 1 (red circle, yellow arrow and red square), was assessed based on the experimental results of the surface structures seen on the SEM images. It was found that different surface features were removed during the experiment at different polishing times and current densities. The amount of charge flowed was found to correlate with surface morphology. Based on the obtained results, various surface features (such as large adherent particles, agglomerates of smaller particles, and valleys) and their changes with increasing test duration and current density were observed by quasi-in situ analyses. A reduction in the diameter of round particles adhering to the surface was observed at both low and higher current densities (see Figure 1a red circle a). Increasing the polishing time resulted in leveling of both large particles and valleys (see Figure 1b red square). Also, dissolution of agglomerates of smaller particles occurred at different polishing times as a function of current density and polishing time (see Figure 1a yellow arrow) are observed. Smoothed surface structures can be observed in regions with equivalent surface charge density (see Figure 2). As a result, comparable surface morphologies may appear at the same area charge density, irrespective of a specific current density. So, it may be adequate to only consider the amount of charge flowed to describe the electropolishing of additive materials. In conclusion, comprehending the dissolution characteristics of particles on L-PBF surfaces is essential for attaining satisfactory surface finish in electropolishing. The results of this study offer valuable perspectives into the electropolishing mechanism of additively manufactured 316L stainless steel and can guide future investigations on surface finishing and polishing of additive manufactured implants like stents. Figure 1}, language = {en} }