@article{BraunRablMatysik, author = {Braun, Peter and Rabl, Hans-Peter and Matysik, Frank-Michael}, title = {Investigations on the Liquid-Phase Decomposition of AdBlue Urea for the Selective Catalytic Reduction Process}, series = {Chemie Ingenieur Technik}, volume = {91}, journal = {Chemie Ingenieur Technik}, number = {7}, publisher = {Wiley}, doi = {10.1002/cite.201800055}, pages = {961 -- 968}, abstract = {Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions.}, language = {en} } @article{BraunDurnerRabletal., author = {Braun, Peter and Durner, Bernhard and Rabl, Hans-Peter and Matysik, Frank-Michael}, title = {Investigations on the decomposition of AdBlue urea in the liquid phase at low temperatures by an electrochemically induced pH shift}, series = {Monatshefte f{\"u}r Chemie}, volume = {150}, journal = {Monatshefte f{\"u}r Chemie}, number = {9}, publisher = {Springer}, doi = {10.1007/s00706-019-02406-6}, pages = {1633 -- 1641}, abstract = {Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface. [GRAPHICS] .}, language = {en} } @misc{Weiss, author = {Weiss, Nils}, title = {Vulnerabilities of OBD2 Dongles}, series = {RCAR Annual Conference, 2018, Munich, Germany}, journal = {RCAR Annual Conference, 2018, Munich, Germany}, language = {en} } @misc{Weiss, author = {Weiss, Nils}, title = {Vulnerabilities of Connected Cars and beyond}, series = {Applied Research Colloquium, 2019, Universit{\`a} Padua, Italy}, journal = {Applied Research Colloquium, 2019, Universit{\`a} Padua, Italy}, language = {en} } @inproceedings{MaeuleRabl, author = {M{\"a}ule, Paul and Rabl, Hans-Peter}, title = {Correlation of Oil Emissions with Particulate Emissions of Gasoline Engines}, series = {Internationales AVL-Forum Abgas- und Partikelemissionen, 20. und 21. Februar 2018, Ludwigsburg}, booktitle = {Internationales AVL-Forum Abgas- und Partikelemissionen, 20. und 21. Februar 2018, Ludwigsburg}, publisher = {AVL Deutschland}, address = {Mainz}, pages = {1 -- 9}, abstract = {Recent developments in exhaust gas legislation make it necessary to focus the research at the particulate emissions from gasoline engines and technologies for their reduction. In addition to the particulates resulting from the combustion of the fuel, the oil emissions represent another possible source for particulate emissions. This paper presents a measurement method which can be used to quantify stationary as well as dynamic oil emissions of gasoline engines. Furthermore, the correlation between the oil emissions and the particulate emissions is the focus of the investigations. Conventional methods for the determination of the oil emissions, such as the gravimetric and the volumetric measurement, are unsuitable since they require long engine operation times to provide useful results. These methods therefore do not allow a fast online measurements during the dynamic operation. For this reason, a new measuring method was used, which allows for a time-resolved online measurement of the oil emissions. This measurement method is based on the sulfur tracer method, which uses the sulfur that is naturally contained in the engine oil as a tracer. The sulfur concentration in the exhaust gas is determined by using an Ion-Molecule-Reaction mass spectrometer. The determination of the particulate emissions corresponds to the PMP regulation. The studies carried out under steady state and dynamic conditions show a clear correlation between the oil consumption and the number of particulates in the exhaust gas. In the case of the dynamic measurements it could also be shown that time-resolved measurements of the oil consumption are possible with the used measurement setup. In addition, it was shown that the number of particulates does not influence the measurement of the SO2-concentration. Furthermore, the different effects of burned and unburned oil emissions have been evaluated by the dosing of the oil into the exhaust gas. The overall conclusion of the measurements shows a strong influence of the oil emissions on the particulate emissions. Therefore, it is crucial to reduce the oil emissions. Possible approaches for this reduction can be improved turbocharger sealing concepts, new piston ring designs or more efficient oil separators for the crankcase ventilation system.}, language = {en} } @inproceedings{SmolareckFaisstSchneider, author = {Smolareck, Elisabeth and Faisst, Holger and Schneider, Ralph}, title = {Modellbasierte Korrektur von Inertialsensor-Signalen - Ein Schritt auf dem Weg zum hochautomatisierten Fahren}, series = {Konferenz: AALE 2018 - 15. Fachkonferenz, Das Forum f{\"u}r Fachleute der Automatisierungstechnik aus Hochschulen und Wirtschaft 01.03.2018 - 02.03.2018 in K{\"o}ln, Deutschland}, booktitle = {Konferenz: AALE 2018 - 15. Fachkonferenz, Das Forum f{\"u}r Fachleute der Automatisierungstechnik aus Hochschulen und Wirtschaft 01.03.2018 - 02.03.2018 in K{\"o}ln, Deutschland}, publisher = {VDE-Verlag}, address = {Berlin}, isbn = {978-3-8007-4522-7}, pages = {1 -- 10}, abstract = {Infolge neuer Zielsetzungen im Automobilbereich, wie z. B. der Weiterentwicklung von Fahrerassistenzsystemen hin zum hochautomatisierten Fahren (HAF), ergeben sich erh{\"o}hte Anforderungen an die Signalg{\"u}te der im Fahrzeug eingesetzten Inertialsensoren f{\"u}r Drehraten und Beschleunigungen. Da deren Erf{\"u}llung {\"u}ber einen hardwarebasierten Ansatz nicht immer m{\"o}glich und sinnvoll ist, strebt die Firma Continental eine Software-L{\"o}sung zur modellbasierten Verbesserung dieser Sensorsignale an.}, language = {de} } @article{GaertnerRablZink, author = {G{\"a}rtner, Uwe and Rabl, Hans-Peter and Zink, Uwe}, title = {Exhaust Gas Aftertreatment of the Future}, series = {MTZ worldwide}, volume = {79}, journal = {MTZ worldwide}, number = {7-8}, publisher = {Springer}, doi = {10.1007/s38313-018-0060-2}, pages = {70 -- 75}, language = {en} } @article{KuepperArtmannPischingeretal., author = {K{\"u}pper, Carsten and Artmann, Christina and Pischinger, Stefan and Rabl, Hans-Peter}, title = {Lube-Oil Dilution of Gasoline Direct-Injection Engines with Ethanol Fuels}, series = {MTZ worldwide}, volume = {74}, journal = {MTZ worldwide}, number = {9}, publisher = {Springer}, address = {Berlin}, doi = {10.1007/s38313-013-0090-8}, pages = {64 -- 69}, language = {en} } @inproceedings{EberhartChungHaumeretal., author = {Eberhart, Philip and Chung, Tek Shan and Haumer, Anton and Kral, Christian}, title = {Open Source Library for the Simulation of Wind Power Plants}, series = {Proceedings of the 11th International Modelica Conference, Versailles, France, September 21-23, 2015}, booktitle = {Proceedings of the 11th International Modelica Conference, Versailles, France, September 21-23, 2015}, address = {Link{\"o}ping}, doi = {10.3384/ecp15118929}, pages = {929 -- 936}, abstract = {This paper presents the new open source Modelica libraryWindPowerPlants. For the economic assessment of either a wind power plant or an entire wind park, the accurate prediction of the energy output is essential. Such prediction is usually performed by means of calculations based on statistical wind data. The proposed WindPowerPlants library is capable of assessing the energy output both for statistical and real wind data based on time domain simulations. In the presented version of the library wind turbine models are modeled with pitch control. The generator models have variable speed and an optional connector to the mains. The entire library is based on power balance conditions and losses are fully neglected. Yet, the library can be extended towards more detailed models considering different types of losses. The structure and components of the library are presented. Simulations examples are shown and compared with reference data. The applicability of the proposed WindPowerPlants library is demonstrated and possible enhancements are discussed.}, language = {en} } @article{KurzweilScheuerpflug, author = {Kurzweil, Peter and Scheuerpflug, Wolfgang}, title = {State-of-charge monitoring and battery diagnosis of different lithium ion chemistries using impedance spectroscopy}, series = {Batteries}, volume = {7}, journal = {Batteries}, number = {1}, doi = {10.3390/batteries7010017}, pages = {16}, abstract = {For lithium iron phosphate batteries (LFP) in aerospace applications, impedance spectroscopy is applicable in the flat region of the voltage-charge curve. The frequency-dependent pseudocapacitance at 0.15 Hz is presented as useful state-of-charge (SOC) and state-of-health (SOH) indicator. For the same battery type, the prediction error of pseudocapacitance is better than 1\% for a quadratic calibration curve, and less than 36\% for a linear model. An approximately linear correlation between pseudocapacitance and Ah battery capacity is observed as long as overcharge and deep discharge are avoided. We verify the impedance method in comparison to the classical constant-current discharge measurements. In the case of five examined lithium-ion chemistries, the linear trend of impedance and SOC is lost if the slope of the discharge voltage curve versus SOC changes. With nickel manganese cobalt (NMC), high impedance modulus correlates with high SOC above 70\%.}, language = {en} } @article{RomeisKostrovKramarenkoetal., author = {Romeis, Dirk and Kostrov, Sergei A. and Kramarenko, Elena Yu and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail and Saphiannikova, M.}, title = {Magnetic-field-induced stress in confined magnetoactive elastomers}, series = {Soft Matter}, volume = {16}, journal = {Soft Matter}, number = {39}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, doi = {10.1039/D0SM01337D}, pages = {9047 -- 9058}, abstract = {We present a theoretical approach for calculating the state of stress induced by a uniform magnetic field in confined magnetoactive elastomers of arbitrary shape. The theory explicitly includes the magnetic field generated by magnetizable spherical inclusions in the sample interior assuming a non-linear magnetization behavior. The initial spatial distribution of particles and its change in an external magnetic field are considered. This is achieved by the introduction of an effective demagnetizing factor where both the sample shape and the material microstructure are taken into account. Theoretical predictions are fitted to the stress data measured using a specifically designed experimental setup. It is shown that the theory enables the quantification of the effect of material microstructure upon introducing a specific microstructural factor and its derivative with respect to the extensional strain in the undeformed state. The experimentally observed differences between isotropic and anisotropic samples, compliant and stiff elastomer matrices are explained.}, language = {en} } @article{BelyaevaKramarenkoShamoninChamonine, author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Shamonin (Chamonine), Mikhail}, title = {Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis}, series = {POLYMER}, volume = {127}, journal = {POLYMER}, publisher = {ELSEVIER}, doi = {10.1016/j.polymer.2017.08.056}, pages = {119 -- 128}, abstract = {Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000\%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SorokinBelyaevaShamoninChamonineetal., author = {Sorokin, Vladislav V. and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail and Kramarenko, Elena Yu}, title = {Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale?}, series = {Physical Review E}, volume = {95}, journal = {Physical Review E}, number = {6}, publisher = {Amer Physical Soc}, doi = {10.1103/PhysRevE.95.062501}, abstract = {The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass \% of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles.}, language = {en} } @article{DechantFedulovFetisovetal., author = {Dechant, Eduard and Fedulov, Feodor and Fetisov, Leonid Y. and Shamonin (Chamonine), Mikhail}, title = {Bandwidth Widening of Piezoelectric Cantilever Beam Arrays by Mass-Tip Tuning for Low-Frequency Vibration Energy Harvesting}, series = {Applied Science}, volume = {7}, journal = {Applied Science}, number = {12}, publisher = {MDPI}, organization = {MDPI AG}, doi = {10.3390/app7121324}, abstract = {Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs). The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power.}, language = {en} } @inproceedings{SykoraDiamantidisMarkovaetal., author = {S{\´y}kora, Miroslav and Diamantidis, Dimitris and Markova, J. and Masciotta, Maria Giovanna}, title = {Optimizing in-situ testing for historic masonry structures: a case study}, series = {International Conference on Sustainable Materials, Systems and Structures (SMSS 2019) : Durability, Monitoring and Repair of Structures, 20-22 March 2019, Rovinj, Croatia}, booktitle = {International Conference on Sustainable Materials, Systems and Structures (SMSS 2019) : Durability, Monitoring and Repair of Structures, 20-22 March 2019, Rovinj, Croatia}, editor = {Baričević, Ana and Jelčić Rukavina, Marija and Damjanović, Domagoi and Guadagnini, Maurizio}, publisher = {RILEM Publications}, isbn = {978-1-5108-9296-5}, pages = {684 -- 691}, language = {en} } @article{SchwanzerRablLodersetal., author = {Schwanzer, Peter and Rabl, Hans-Peter and Loders, S. and Seifert, P. and Himmelstoss, S. and Gaderer, Matthias}, title = {Difference in the Tailpipe Particle Number by Consideration of Sub-23-nm Particles for Different Injection Settings of a GDI Engine}, series = {Emission control science and technology}, volume = {5}, journal = {Emission control science and technology}, number = {1}, publisher = {Springer Nature}, doi = {10.1007/s40825-019-0114-1}, pages = {7 -- 22}, abstract = {The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50\% cutoff (D-50\%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50\%=10 nm and D-50\%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall.}, language = {en} } @article{KalitaSnarskiiShamoninChamonineetal., author = {Kalita, Viktor M. and Snarskii, Andrei A. and Shamonin (Chamonine), Mikhail and Zorinets, Denis}, title = {Effect of single-particle magnetostriction on the shear modulus of compliant magnetoactive elastomers}, series = {Physical review E}, volume = {95}, journal = {Physical review E}, number = {3}, publisher = {American Physical Society}, doi = {10.1103/PhysRevE.95.032503}, abstract = {The influence of an external magnetic field on the static shear strain and the effective shear modulus of a magnetoactive elastomer (MAE) is studied theoretically in the framework of a recently introduced approach to the single-particle magnetostriction mechanism [V. M. Kalita et al., Phys. Rev. E 93, 062503 (2016)]. The planar problem of magnetostriction in an MAE with magnetically soft inclusions in the form of a thin disk (platelet) having the magnetic anisotropy in the plane of this disk is solved analytically. An external magnetic field acts with torques on magnetic filler particles, creates mechanical stresses in the vicinity of inclusions, induces shear strain, and increases the effective shear modulus of these composite materials. It is shown that the largest effect of the magnetic field on the effective shear modulus should be expected in MAEs with soft elastomer matrices, where the shear modulus of the matrix is less than the magnetic anisotropy constant of inclusions. It is derived that the effective shear modulus is nonlinearly dependent on the external magnetic field and approaches the saturation value in magnetic fields exceeding the field of particle anisotropy. It is shown that model calculations of the effective shear modulus correspond to a phenomenological definition of effective elastic moduli and magnetoelastic coupling constants. The obtained theoretical results compare well with known experimental data. Determination of effective elastic coefficients in MAEs and their dependence on magnetic field is discussed. The concentration dependence of the effective shear modulus at higher filler concentrations has been estimated using the method of Pade approximants, which predicts that both the absolute and relative changes of the magnetic-field-dependent effective shear modulus will significantly increase with the growing concentration of filler particles.}, language = {en} } @misc{AltmannRablGaderer, author = {Altmann, Robert and Rabl, Hans-Peter and Gaderer, Matthias}, title = {Ph{\"a}nomenologische Untersuchung des Einspritzverhaltens von Pflanzen{\"o}lkraftstoff}, series = {3. Tagung der Fuels Joint Research Group (FJRG) "Kraftstoffe f{\"u}r die Mobilit{\"a}t von Morgen"}, journal = {3. Tagung der Fuels Joint Research Group (FJRG) "Kraftstoffe f{\"u}r die Mobilit{\"a}t von Morgen"}, language = {de} } @misc{AltmannGadererRabl, author = {Altmann, Robert and Gaderer, Matthias and Rabl, Hans-Peter}, title = {Pr{\"u}fstandsuntersuchungen an einem DEUTZ NRMM Motor mit Raps{\"o}lkraftstoff und Optimierung des Betriebs- und Emissionsverhaltens durch statistische Versuchsplanung}, series = {18. Internationaler Fachkongress "Kraftstoffe der Zukunft 2021" - digital \& international vernetzt!, online}, journal = {18. Internationaler Fachkongress "Kraftstoffe der Zukunft 2021" - digital \& international vernetzt!, online}, language = {de} } @article{WalterSchwanzerSteineretal., author = {Walter, Stefanie and Schwanzer, Peter and Steiner, Carsten and Hagen, Gunter and Rabl, Hans-Peter and Dietrich, Markus and Moos, Ralf}, title = {Mixing Rules for an Exact Determination of the Dielectric Properties of Engine Soot Using the Microwave Cavity Perturbation Method and Its Application in Gasoline Particulate Filters}, series = {Sensors}, volume = {22}, journal = {Sensors}, number = {9}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s22093311}, pages = {1 -- 17}, abstract = {In recent years, particulate filters have become mandatory in almost all gasoline-powered vehicles to comply with emission standards regarding particulate number. In contrast to diesel applications, monitoring gasoline particulate filters (GPFs) by differential pressure sensors is challenging due to lower soot masses to be deposited in the GPFs. A different approach to determine the soot loading of GPFs is a radio frequency-based sensor (RF sensor). To facilitate sensor development, in previous work, a simulation model was created to determine the RF signal at arbitrary engine operating points. To ensure accuracy, the exact dielectric properties of the soot need to be known. This work has shown how small samples of soot-loaded filter are sufficient to determine the dielectric properties of soot itself using the microwave cavity perturbation method. For this purpose, mixing rules were determined through simulation and measurement, allowing the air and substrate fraction of the sample to be considered. Due to the different geometry of filter substrates compared to crushed soot samples, a different mixing rule had to be derived to calculate the effective filter properties required for the simulation model. The accuracy of the determined mixing rules and the underlying simulation model could be verified by comparative measurements on an engine test bench.}, language = {en} }