@article{HofrichterRankHeberletal., author = {Hofrichter, Andreas and Rank, Daniel and Heberl, Michael and Sterner, Michael}, title = {Determination of the optimal power ratio between electrolysis and renewable energy to investigate the effects on the hydrogen production costs}, series = {International Journal of Hydrogen Energy}, volume = {48}, journal = {International Journal of Hydrogen Energy}, number = {5}, publisher = {Elsevier}, issn = {0360-3199}, doi = {10.1016/j.ijhydene.2022.09.263}, pages = {1651 -- 1663}, abstract = {Green hydrogen via renewable powered electrolysis has a high relevance in decarbonization and supply security. Achieving economically competitive hydrogen production costs is a major challenge in times of an energy price crisis. Our objective is to show the economically optimal installed capacity of electrolysers in relation to wind and solar power so swift and credible statements can be made regarding the system design. The ratio between renewable generation and electrolysis power as well as scaling effects, operating behaviour and development of costs are considered. Hydrogen production costs are calculated for four exemplary real PV and wind sites and different ratios of electrolysis to renewable power for the year 2020. The ideal ratio for PV systems is between 14\% and 73\% and for wind between 3.3\% and 143\% for low and high full load hours. The lowest hydrogen production costs are identified at 2.53 €/kg for 50 MW wind power and 72 MW electrolysis power. The results provide plant constructors the possibility to create a cost-optimized design via an optimum ratio of electrolysis to renewable capacity. Therefore, the procedures for planning and dimensioning of selected systems can be drastically simplified.}, language = {en} } @article{PalombaNowakDawoudetal., author = {Palomba, Valeria and Nowak, Sebastian and Dawoud, Belal and Frazzica, Andrea}, title = {Dynamic modelling of Adsorption systems: a comprehensive calibrated dataset for heat pump and storage applications}, series = {Journal of energy storage}, volume = {33}, journal = {Journal of energy storage}, publisher = {Elsevier}, doi = {10.1016/j.est.2020.102148}, abstract = {The growing efforts for the development of clean and efficient energy systems require the use of a multi-disciplinary approach and the integration of multiple generation appliances. Among the fields that can be considered enabling technologies, adsorption systems for air conditioning and thermal energy storages, are constantly increasing their maturity. However, for a proper design and integration of such systems, there is the need for a simulation framework that is reliable and computationally convenient. In the present paper, the implementation of a dynamic model for adsorption systems is presented, which includes different components (adsorber, phase changer, sorption materials) and is structured as a library. Modelica language and the commercial software Dymola (R) are used for the analysis. Data for different heat exchangers and working pairs are calibrated using experimental results and the calibrated model is subsequently used for the design of an adsorber based on a plate heat exchanger for thermal energy storage applications. The results proved that the model is fast and can reproduce experimental results with good accuracy, thus being a useful tool for the design and optimization of the different components of sorption systems.}, language = {en} } @article{BruniMeijaardRilletal., author = {Bruni, S. and Meijaard, J. P. and Rill, Georg and Schwab, A. L.}, title = {State-of-the-art and challenges of railway and road vehicle dynamics with multibody dynamics approaches}, series = {Multibody System Dynamics}, volume = {49}, journal = {Multibody System Dynamics}, number = {1}, publisher = {Springer}, doi = {10.1007/s11044-020-09735-z}, pages = {1 -- 32}, abstract = {A review of the current use of multibody dynamics methods in the analysis of the dynamics of vehicles is given. Railway vehicle dynamics as well as road vehicle dynamics are considered, where for the latter the dynamics of cars and trucks and the dynamics of single-track vehicles, in particular motorcycles and bicycles, are reviewed. Commonalities and differences are shown, and open questions and challenges are given as directions for further research in this field.}, language = {en} } @article{SternerBauer, author = {Sterner, Michael and Bauer, Franz}, title = {Power-to-X im Kontext der Energiewende und des Klimaschutzes in Deutschland}, series = {Chemie-Ingenieur-Technik}, volume = {92}, journal = {Chemie-Ingenieur-Technik}, number = {1-2}, publisher = {Wiley}, issn = {0009-286X}, doi = {10.1002/cite.201900167}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-11669}, pages = {85 -- 90}, abstract = {Um den Einfluss verschiedener Power-to-X-Verfahren auf die Transformation des deutschen Energiesystems und das Erreichen der Klimaschutzziele zu {\"u}berpr{\"u}fen, wurde ein sektor{\"u}bergreifendes Energiesystemmodel entwickelt. Die daraus gewonnenen Ergebnisse zeigen: F{\"u}r eine erfolgreiche Energiewende ist der Einsatz von Power-to-X in Zukunft unverzichtbar. Vor allem in Bereichen und Sektoren, in denen hohe Energiedichten erforderlich und nur wenig andere Optionen zur Defossilisierung vorhanden sind, werden Power-to-X-Technologien zwingend notwendig.}, subject = {Power-to-Gas}, language = {de} } @article{SovacoolCabezaPiselloetal., author = {Sovacool, Benjamin K. and Cabeza, Luisa F. and Pisello, Anna Laura and Colladon, Andrea Fronzetti and Larijani, Hatef Madani and Dawoud, Belal and Martiskainen, Mari}, title = {Decarbonizing household heating: Reviewing demographics, geography and low-carbon practices and preferences in five European countries}, series = {Renewable \& Sustainable Energy Reviews}, journal = {Renewable \& Sustainable Energy Reviews}, number = {139}, publisher = {Elsevier}, doi = {10.1016/j.rser.2020.110703}, pages = {1 -- 28}, abstract = {What commonalities are there in sustainable or unsustainable heating practices in five high-income, high-emitting western European countries? What preferences do a nationally representative sample of the public in these countries hold towards low-carbon options? It is imperative that climate policy researchers and practitioners grapple with the difficulty of decarbonizing heat, which remains the largest single end-use service worldwide and which accounts about half of total final energy consumption. Based on a comparative assessment of five representative national surveys in Germany (N = 2009), Italy (N = 2039), Spain (N = 2038), Sweden (N = 2023), and the United Kingdom (N = 2000), this study explores the demographics and geography of household heat decarbonisation in Europe. By analyzing our country level data as well as our combined sample of 10,109 respondents, it investigates how people conceive of the purposes of low-carbon heat, their preferences for particular forms of heat supply, and their (at times odd) practices of heat consumption and temperature settings. Grounded in its original data, the study organizes its findings inductively across the five themes of literacy (heating knowledge, awareness and control), sustainability (heating practices, dynamics and conflicts), temperature (heating satisfaction and preferences), desirability of change (low-carbon heating priorities, business models and trust), and culture (country and national variation). The study also explores intersections between these dimensions, using multivariate analysis, as well as how preferences differ according to varying types of actors as well as geography and space.}, language = {en} } @article{MikhaeilNowakPalombaetal., author = {Mikhaeil, Makram and Nowak, Sebastian and Palomba, Valeria and Frazzica, Andrea and Gaderer, Matthias and Dawoud, Belal}, title = {Experimental and analytical investigation of applying an asymmetric plate heat exchanger as an evaporator in a thermally driven adsorption appliance}, series = {Applied Thermal Engineering}, journal = {Applied Thermal Engineering}, number = {228}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2023.120525}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-61115}, abstract = {This communication presents an experimental and analytical study on the evaporation mechanism in a closed-structured asymmetric plate heat exchanger (PHE) employed as a stagnant water evaporator for the application in an adsorption heat transformation appliance. To this aim, an experimental unit is constructed, which comprises two identical PHEs, one acting as an vaporator/condenser and the second, as an adsorber/desorber. Two endoscopes are mounted inside the investigated evaporator to visualize the evaporation mechanism when performing adsorption-evaporation processes under different boundary conditions. It turned out that the evaporation mechanism is a partially covered, thin film evaporation. A heat transfer analysis is performed to evaluate the heat transfer coefficient of the thin film evaporation () inside the investigated evaporator, resulting in -values between 1330 and 160 [W∙m-2∙K-1] over the investigated adsorption-evaporation time. Correlating the obtained () to the film thickness and the wetted area results in -values between 0.34 and 0.78 [mm] and wetted to total area ratios of 0.78 to 0.16. Besides, an analytical model has been developed and introduced to correlate the overall evaporator heat transfer coefficient with the adsorption potential and the time rate of change of the water uptake.}, language = {en} } @article{MonkmanSindersbergerPremetal., author = {Monkman, Gareth J. and Sindersberger, Dirk and Prem, Nina and Diermeier, Andreas and Szecsey, Tamara}, title = {Dielectric behaviour of magnetic hybrid materials}, series = {Physical Sciences Reviews}, volume = {7}, journal = {Physical Sciences Reviews}, number = {10}, publisher = {de Gruyter}, doi = {10.1515/psr-2019-0121}, pages = {1169 -- 1185}, abstract = {The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt\%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt\% CIP) were also investigated. With filler concentrations lower than 3 wt\%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt\% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt\%. Above 3 wt\% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1\%-3 wt\% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt\% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found.}, language = {en} } @article{MikhaeilGadererDawoud, author = {Mikhaeil, Makram and Gaderer, Matthias and Dawoud, Belal}, title = {On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study}, series = {Energy}, volume = {207}, journal = {Energy}, number = {September}, publisher = {Elsevier}, doi = {10.1016/j.energy.2020.118272}, pages = {1 -- 13}, abstract = {An innovative adsorber plate heat exchanger (APHE), which is developed for application in adsorption heat pumps, chillers and thermal energy storage systems, is introduced. A test frame has been constructed as a representative segment of the introduced APHE for applying loose grains of AQSOA-Z02. Adsorption kinetic measurements have been carried out in a volumetric large-temperature-jump setup under typical operating conditions of adsorption processes. A transient 2-D model is developed for the tested sample inside the setup. The measured temporal uptake variations with time have been fed to the model, through which a micro-pore diffusion coefficient at infinite temperature of 2 E-4 [m2s-1] and an activation energy of 42.1 [kJ mol-1] have been estimated. A 3-D model is developed to simulate the combined heat and mass transfer inside the APHE and implemented in a commercial software. Comparing the obtained results with the literature values for an extruded aluminium adsorber heat exchanger coated with a 500 μm layer of the same adsorbent, the differential water uptake obtained after 300 s of adsorption (8.2 g/100 g) implies a sound enhancement of 310\%. This result proves the great potential of the introduced APHE to remarkably enhance the performance of adsorption heat transformation appliances.}, language = {en} } @article{MonkmanStrieglPremetal., author = {Monkman, Gareth J. and Striegl, Birgit and Prem, Nina and Sindersberger, Dirk}, title = {Electrical Properties of Magnetoactive Boron-Organo-Silicon Oxide Polymers}, series = {Macromolecular Chemistry and Physics}, volume = {221}, journal = {Macromolecular Chemistry and Physics}, number = {4}, publisher = {Wiley}, doi = {10.1002/macp.201900342}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-26488}, pages = {1 -- 8}, abstract = {The electrical properties of rheopectic magnetoactive composites comprising boron-organo-silicon oxide dielectric matrices containing carbonyl iron microparticles are presented for the first time. The increase in interfacial magnetocapacitance is seen to greatly exceed that experienced when using conventional elastomeric matrices such as polydimethylsiloxane. In addition to the increase in capacitance, a simultaneous and sharp decrease in the parallel electrical resistance over several orders of magnitude is also observed. The effects are time dependent but repeatable. Potential applications include magnetically controlled frequency dependent devices, magnetic sensor systems, weighting elements for neural networks, etc.}, language = {en} } @article{PremSindersbergerMonkman, author = {Prem, Nina and Sindersberger, Dirk and Monkman, Gareth J.}, title = {Infrared spectral analysis of low concentration magnetoactive polymers}, series = {Journal of Applied Polymer Science}, volume = {137}, journal = {Journal of Applied Polymer Science}, number = {7}, publisher = {Wiley}, organization = {WILEY}, issn = {1097-4628}, doi = {10.1002/app.48366}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-25913}, pages = {1 -- 7}, abstract = {This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt\%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt\%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt\% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366.}, language = {en} }