@article{MikhaeilGadererDawoud, author = {Mikhaeil, Makram and Gaderer, Matthias and Dawoud, Belal}, title = {On the application of adsorber plate heat exchangers in thermally driven chillers}, series = {Applied Thermal Engineering}, volume = {220}, journal = {Applied Thermal Engineering}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2022.119713}, abstract = {The effect of both heat and mass transfer characteristic lengths (HTCL, MTCL) of two different adsorber plate heat exchangers (APHE), for application in an adsorption chiller, on the adsorption and desorption kinetics is investigated. Three representative test frames (TF1-TF3) are prepared to examine small-scale adsorbent samples of the microporous silica gel (Siogel of Oker-Chemie, Germany) applying the volumetric large-temperature-jump methodology at different operating conditions. Based on the obtained kinetic data, an analytical model has been developed to predict the specific cooling power (SCP) and the coefficient of performance (COP) of a single-bed adsorption chiller comprising the studied APHEs. It turned out that, within the tested range of HTCL and MTCL, it can be concluded that, the adsorption kinetics are mainly influenced by the MTCL, while the desorption kinetics are dominated by the HTCL of the adsorbent domain. Applying Siogel as loose pellets inside a newly introduced APHE results in of 423.3 and 182.7 W⋅kg-1, at the evaporator temperatures of 15 °C and 5 °C, respectively. Herein, the condenser and adsorber-end temperatures amount to 30 °C and the desorption-end temperature to 90 °C. The corresponding s amount to 0.50 and 0.40, respectively, which represent quite promising results for further design optimizations.}, language = {en} } @article{FrazzicaPalombaDawoud, author = {Frazzica, Andrea and Palomba, Valeria and Dawoud, Belal}, title = {Thermodynamic Performance of Adsorption Working Pairs for Low-Temperature Waste Heat Upgrading in Industrial Applications}, series = {Applied Sciences}, volume = {11}, journal = {Applied Sciences}, number = {8}, publisher = {MDPI}, doi = {10.3390/app11083389}, abstract = {The present work aims at the thermodynamic analysis of different working pairs in adsorption heat transformers (AdHT) for low-temperature waste heat upgrade in industrial processes. Two different AdHT configurations have been simulated, namely with and without heat recovery between the adsorbent beds. Ten working pairs, employing different adsorbent materials and four different refrigerants, have been compared at varying working boundary conditions. The effects of heat recovery and the presence of a temperature gradient for heat transfer between sinks/sources and the AdHT components have been analyzed. The achieved results demonstrate the possibility of increasing the overall performance when internal heat recovery is implemented. They also highlight the relevant role played by the existing temperature gradient between heat transfer fluids and components, that strongly affect the real operating cycle of the AdHT and thus its expected performance. Both extremely low, i.e., 40-50 degrees C, and low (i.e., 80 degrees C) waste heat source temperatures were investigated at variable ambient temperatures, evaluating the achievable COP and specific energy. The main results demonstrate that optimal performance can be achieved when 40-50 K of temperature difference between waste heat source and ambient temperature are guaranteed. Furthermore, composite sorbents demonstrated to be the most promising adsorbent materials for this application, given their high sorption capacity compared to pure adsorbents, which is reflected in much higher achievable specific energy.}, language = {en} } @article{ThemaWeidlichKauletal., author = {Thema, Martin and Weidlich, Tobias and Kaul, Anja and B{\"o}llmann, Andrea and Huber, Harald and Bellack, Annett and Karl, J{\"u}rgen and Sterner, Michael}, title = {Optimized biological CO2-methanation with a pure culture of thermophilic methanogenic archaea in a trickle-bed reactor}, series = {Bioresource Technology}, journal = {Bioresource Technology}, number = {333}, publisher = {Elsevier}, doi = {10.1016/j.biortech.2021.125135}, abstract = {In this study, a fully automated process converting hydrogen and carbon dioxide to methane in a high temperature trickle-bed reactor was developed from lab scale to field test level. The reactor design and system performance was optimized to yield high methane content in the product gas for direct feed-in to the gas grid. The reaction was catalyzed by a pure culture of Methanothermobacter thermoautotrophicus IM5, which formed a biofilm on ceramic packing elements. During 600 h in continuous and semi-continuous operation in countercurrent flow, the 0.05 m3 reactor produced up to 95.3 \% of methane at a methane production rate of 0.35 mCH43mR-3h-1. Adding nitrogen as carrier gas during startup, foam control and dosing of ammonium and sodium sulfide as nitrogen and sulfur source were important factors for process automation.}, language = {en} } @article{GaertnerRankHeberletal., author = {G{\"a}rtner, Sebastian and Rank, Daniel and Heberl, Michael and Gaderer, Matthias and Dawoud, Belal and Haumer, Anton and Sterner, Michael}, title = {Simulation and Techno-Economic Analysis of a Power-to-Hydrogen Process for Oxyfuel Glass Melting}, series = {Energies}, volume = {14}, journal = {Energies}, number = {24}, publisher = {MDPI}, doi = {10.3390/en14248603}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-22713}, abstract = {As an energy-intensive industry sector, the glass industry is strongly affected by the increasingly stringent climate protection targets. As established combustion-based production systems ensure high process stability and glass quality, an immediate switch to low greenhouse gas emission processes is difficult. To approach these challenges, this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study indicate, that the proposed system can reduce specific carbon dioxide emissions by up to 60\%, while increasing specific energy demand by a maximum of 25\%. Investigations of the impact of altered combustion and furnace properties like adiabatic flame temperature (+25 °C), temperature efficiency (∆ξ = -0.003) and heat capacity flow ratio (∆zHL = -0.009) indicate that pure hydrogen-oxygen combustion has less impact on melting properties than assumed so far. Within the case study, high CO2 abatement costs of 295 €/t CO2-eq. were determined. This is mainly due to the insufficient performance of renewable energy sources. The correlations between process scaling and economic parameters presented in this study show promising potential for further economic optimization of the proposed energy system in the future.}, language = {en} } @article{SchorrZentnerZimmermannetal., author = {Schorr, Philipp and Zentner, Lena and Zimmermann, Klaus and B{\"o}hm, Valter}, title = {Jumping locomotion system based on a multistable tensegrity structure}, series = {Mechanical systems and signal processing}, journal = {Mechanical systems and signal processing}, number = {152}, publisher = {Elsevier}, doi = {10.1016/j.ymssp.2020.107384}, abstract = {All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure. (c) 2020 Elsevier Ltd. All rights reserved. All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure.}, language = {en} } @article{EmbergerAltmannGebhardetal., author = {Emberger, Peter and Altmann, Robert and Gebhard, J{\"u}rgen and Thuneke, Klaus and Winkler, Markus and T{\"o}pfer, Georg and Rabl, Hans-Peter and Remmele, Edgar}, title = {Combustion characteristics of pure rapeseed oil fuel after injection in a constant volume combustion chamber with a non-road mobile machinery engine solenoid injector}, series = {Fuel}, journal = {Fuel}, number = {320}, publisher = {Elsevier}, doi = {10.1016/j.fuel.2022.123979}, abstract = {Pure rapeseed oil fuel (R100) according to standard DIN 51605 is a greenhouse gas saving option for the mobility sector. With its high energy density close to diesel fuel, R100 is suitable to operate non-road mobile machinery with a high power demand and long operating time, where electric drives reach their limits. Advantages are indicated for its use in environmentally sensitive areas like agriculture since R100 is highly biodegradable and non-toxic. However, R100 is characterised by differing physical and chemical properties compared to diesel. The objective of the research is to investigate the differences in the ignition and combustion behaviour of R100 compared to diesel fuel (DF). For this purpose, a constant volume combustion chamber is used, which is equipped with a modern solenoid injector for engines of non-road mobile machinery. The researched injector shows a different hydraulic behaviour when using R100 compared to DF in that the injected fuel mass is lower with R100 than with DF. In combination with the 14 \% by mass lower calorific value, less energy output is determined with R100. When varying the injection pressure, the impact on the ignition delay and combustion behaviour is much higher for R100 than for DF. Specifically, an increase of the injection pressure supports mixture preparation and thus partially compensates the differing physical properties of R100. The results of ignition delay measurements and net heat release analysis are as follows: At low load conditions with low injection pressure as well as a low combustion chamber temperature and pressure, R100 ignites later and shows a further delayed combustion compared to diesel. The opposite is observed for medium and high load conditions, where R100 ignites faster and without delayed combustion in comparison to DF. Thus, an adjustment of the heat release of R100 at the same level as for DF is possible by modifying the injection strategy. The research shows that for an optimised combustion of R100 the injection settings must be adjusted for every operation point separately. The results indicate how the injection parameters should be adjusted for different load conditions to realise a high-quality engine calibration for R100.}, language = {en} } @inproceedings{TremmelNaglerKutteretal., author = {Tremmel, Florian and Nagler, O. and Kutter, C. and Holmer, Rainer}, title = {Smart Cantilever Probe with Integrated Force and Acoustic Emission Sensor}, series = {2023 IEEE SENSORS, Vienna, Austria, 10/29/2023 - 11/1/2023}, booktitle = {2023 IEEE SENSORS, Vienna, Austria, 10/29/2023 - 11/1/2023}, publisher = {IEEE}, isbn = {979-8-3503-0387-2}, doi = {10.1109/SENSORS56945.2023.10325021}, pages = {1 -- 4}, abstract = {Acoustic emission (AE) testing recently found its application in the wafer testing sector of the semiconductor industry. To find out the mechanical robustness of semiconductor devices, contact pads on the chip surface are intentionally overstressed with an indenter tip and the appearing oxide cracks are detected with help of the generated AE signals. This is done in a customized test bench with a patented sensor-indenter system. This paper presents an improved version of the measurement setup that solves certain disadvantages of it and can be used in a standard wafer prober. The main components of the developed sensor system are a strain gauge for contact force measurement and a piezoelectric sensor element for AE signal detection. Both components are integrated on a cantilever beam which has an exchangeable indenter tip at its free end. The cantilever probe is electrically conductive to enable electrical tests via the indenter tip. This smart sensor-cantilever combination (SCC) can be mounted with several adapter components on a carrier plate to place it in a wafer prober. For both sensor elements amplifier circuits are developed to enhance their signal-to-noise ratios (SNRs). A prototype setup is shown together with simulated and experimental results to demonstrate its performance. The mechanical properties of the cantilever, as well as the force sensor and the AE crack signals, already fulfill the requirements for an implementation in a wafer prober. To further improve the sensor resolutions and detection limits, several optimizations regarding the design of the SCC are in progress.}, language = {en} } @article{ThemaBauerSterner, author = {Thema, Martin and Bauer, Franz and Sterner, Michael}, title = {Power-to-Gas: Electrolysis and methanation status review}, series = {Renewable and Sustainable Energy Reviews}, volume = {112}, journal = {Renewable and Sustainable Energy Reviews}, number = {7}, publisher = {Elsevier}, doi = {10.1016/j.rser.2019.06.030}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-26238}, pages = {775 -- 787}, abstract = {This review gives a worldwide overview on Power-to-Gas projects producing hydrogen or renewable substitute natural gas focusing projects in central Europe. It deepens and completes the content of previous reviews by including hitherto unreviewed projects and by combining project names with details such as plant location. It is based on data from 153 completed, recent and planned projects since 1988 which were evaluated with regards to plant allocation, installed power development, plant size, shares and amounts of hydrogen or substitute natural gas producing examinations and product utilization phases. Cost development for electrolysis and carbon dioxide methanation was analyzed and a projection until 2030 is given with an outlook to 2050. The results show substantial cost reductions for electrolysis as well as for methanation during the recent years and a further price decline to less than 500 euro per kilowatt electric power input for both technologies until 2050 is estimated if cost projection follows the current trend. Most of the projects examined are located in Germany, Denmark, the United States of America and Canada. Following an exponential global trend to increase installed power, today's Power-to-Gas applications are operated at about 39 megawatt. Hydrogen and substitute natural gas were investigated on equal terms concerning the number of projects.}, language = {en} } @article{MonkmanSindersbergerPrem, author = {Monkman, Gareth J. and Sindersberger, Dirk and Prem, Nina}, title = {Magnetically enhanced photoconductive high voltage control}, series = {ISSS Journal of Micro and Smart Systems}, volume = {11}, journal = {ISSS Journal of Micro and Smart Systems}, publisher = {Springer Nature}, doi = {10.1007/s41683-021-00088-z}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-30606}, pages = {317 -- 328}, abstract = {The recent surge of interest in electrostatic actuators, particularly for soft robotic applications, has placed increasing demands on high voltage control technology. In this respect, optoelectronic bidirectional switching and analogue regulation of high voltages is becoming increasingly important. One common problem is the leakage current due to dark resistance of the material or device used. Another is the physical size of such elements. However, their ability to provide galvanic separation makes them a very attractive alternative to conventional (wired) semiconductor elements. This paper gives an overview of available methods and devices before introducing a concept based on the combination of photoresistive and magnetoresistive effects in Gallium Arsenide that are potentially applicable to other semiconductor materials.}, language = {en} } @article{HaugVetter, author = {Haug, Sonja and Vetter, Miriam}, title = {Altersgerechtes Wohnen im Quartier}, series = {Standort - Zeitschrift f{\"u}r angewandte Geographie}, volume = {45}, journal = {Standort - Zeitschrift f{\"u}r angewandte Geographie}, publisher = {Springer Nature}, issn = {1432-220X}, doi = {10.1007/s00548-020-00678-3}, pages = {11 -- 17}, abstract = {Im Alter nimmt das Quartier aufgrund geringerer Aktionsradien an Bedeutung zu. Der Beitrag befasst sich mit der Frage, welche Besonderheiten sich bei Senioren-Haushalten im Hinblick auf Wohnen und soziale Teilhabe zeigen. Aus dem Projekt MAGGIE werden Ergebnisse einer schriftlichen Haushaltsbefragung (N=195) in der Wohngenossenschaft Margaretenau Regensburg dargestellt. Hierbei wird auf die aktuelle und zuk{\"u}nftige Wohnsituation, den Ver{\"a}nderungsbedarf, den Wunsch nach Gemeinschaftsangeboten und die soziale Einbettung eingegangen. Es zeigt sich eine geringe Ver{\"a}nderungsbereitschaft und ein {\"u}berdurchschnittlich hohes Maß an lokalem Sozialkapital. Am Ende werden Schlussfolgerungen f{\"u}r das Sanierungs- und Quartiersmanagement gezogen.}, subject = {Alter}, language = {de} } @article{HofrichterRankHeberletal., author = {Hofrichter, Andreas and Rank, Daniel and Heberl, Michael and Sterner, Michael}, title = {Determination of the optimal power ratio between electrolysis and renewable energy to investigate the effects on the hydrogen production costs}, series = {International Journal of Hydrogen Energy}, volume = {48}, journal = {International Journal of Hydrogen Energy}, number = {5}, publisher = {Elsevier}, issn = {0360-3199}, doi = {10.1016/j.ijhydene.2022.09.263}, pages = {1651 -- 1663}, abstract = {Green hydrogen via renewable powered electrolysis has a high relevance in decarbonization and supply security. Achieving economically competitive hydrogen production costs is a major challenge in times of an energy price crisis. Our objective is to show the economically optimal installed capacity of electrolysers in relation to wind and solar power so swift and credible statements can be made regarding the system design. The ratio between renewable generation and electrolysis power as well as scaling effects, operating behaviour and development of costs are considered. Hydrogen production costs are calculated for four exemplary real PV and wind sites and different ratios of electrolysis to renewable power for the year 2020. The ideal ratio for PV systems is between 14\% and 73\% and for wind between 3.3\% and 143\% for low and high full load hours. The lowest hydrogen production costs are identified at 2.53 €/kg for 50 MW wind power and 72 MW electrolysis power. The results provide plant constructors the possibility to create a cost-optimized design via an optimum ratio of electrolysis to renewable capacity. Therefore, the procedures for planning and dimensioning of selected systems can be drastically simplified.}, language = {en} } @article{PalombaNowakDawoudetal., author = {Palomba, Valeria and Nowak, Sebastian and Dawoud, Belal and Frazzica, Andrea}, title = {Dynamic modelling of Adsorption systems: a comprehensive calibrated dataset for heat pump and storage applications}, series = {Journal of energy storage}, volume = {33}, journal = {Journal of energy storage}, publisher = {Elsevier}, doi = {10.1016/j.est.2020.102148}, abstract = {The growing efforts for the development of clean and efficient energy systems require the use of a multi-disciplinary approach and the integration of multiple generation appliances. Among the fields that can be considered enabling technologies, adsorption systems for air conditioning and thermal energy storages, are constantly increasing their maturity. However, for a proper design and integration of such systems, there is the need for a simulation framework that is reliable and computationally convenient. In the present paper, the implementation of a dynamic model for adsorption systems is presented, which includes different components (adsorber, phase changer, sorption materials) and is structured as a library. Modelica language and the commercial software Dymola (R) are used for the analysis. Data for different heat exchangers and working pairs are calibrated using experimental results and the calibrated model is subsequently used for the design of an adsorber based on a plate heat exchanger for thermal energy storage applications. The results proved that the model is fast and can reproduce experimental results with good accuracy, thus being a useful tool for the design and optimization of the different components of sorption systems.}, language = {en} } @article{BruniMeijaardRilletal., author = {Bruni, S. and Meijaard, J. P. and Rill, Georg and Schwab, A. L.}, title = {State-of-the-art and challenges of railway and road vehicle dynamics with multibody dynamics approaches}, series = {Multibody System Dynamics}, volume = {49}, journal = {Multibody System Dynamics}, number = {1}, publisher = {Springer}, doi = {10.1007/s11044-020-09735-z}, pages = {1 -- 32}, abstract = {A review of the current use of multibody dynamics methods in the analysis of the dynamics of vehicles is given. Railway vehicle dynamics as well as road vehicle dynamics are considered, where for the latter the dynamics of cars and trucks and the dynamics of single-track vehicles, in particular motorcycles and bicycles, are reviewed. Commonalities and differences are shown, and open questions and challenges are given as directions for further research in this field.}, language = {en} } @article{SternerBauer, author = {Sterner, Michael and Bauer, Franz}, title = {Power-to-X im Kontext der Energiewende und des Klimaschutzes in Deutschland}, series = {Chemie-Ingenieur-Technik}, volume = {92}, journal = {Chemie-Ingenieur-Technik}, number = {1-2}, publisher = {Wiley}, issn = {0009-286X}, doi = {10.1002/cite.201900167}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-11669}, pages = {85 -- 90}, abstract = {Um den Einfluss verschiedener Power-to-X-Verfahren auf die Transformation des deutschen Energiesystems und das Erreichen der Klimaschutzziele zu {\"u}berpr{\"u}fen, wurde ein sektor{\"u}bergreifendes Energiesystemmodel entwickelt. Die daraus gewonnenen Ergebnisse zeigen: F{\"u}r eine erfolgreiche Energiewende ist der Einsatz von Power-to-X in Zukunft unverzichtbar. Vor allem in Bereichen und Sektoren, in denen hohe Energiedichten erforderlich und nur wenig andere Optionen zur Defossilisierung vorhanden sind, werden Power-to-X-Technologien zwingend notwendig.}, subject = {Power-to-Gas}, language = {de} } @article{SovacoolCabezaPiselloetal., author = {Sovacool, Benjamin K. and Cabeza, Luisa F. and Pisello, Anna Laura and Colladon, Andrea Fronzetti and Larijani, Hatef Madani and Dawoud, Belal and Martiskainen, Mari}, title = {Decarbonizing household heating: Reviewing demographics, geography and low-carbon practices and preferences in five European countries}, series = {Renewable \& Sustainable Energy Reviews}, journal = {Renewable \& Sustainable Energy Reviews}, number = {139}, publisher = {Elsevier}, doi = {10.1016/j.rser.2020.110703}, pages = {1 -- 28}, abstract = {What commonalities are there in sustainable or unsustainable heating practices in five high-income, high-emitting western European countries? What preferences do a nationally representative sample of the public in these countries hold towards low-carbon options? It is imperative that climate policy researchers and practitioners grapple with the difficulty of decarbonizing heat, which remains the largest single end-use service worldwide and which accounts about half of total final energy consumption. Based on a comparative assessment of five representative national surveys in Germany (N = 2009), Italy (N = 2039), Spain (N = 2038), Sweden (N = 2023), and the United Kingdom (N = 2000), this study explores the demographics and geography of household heat decarbonisation in Europe. By analyzing our country level data as well as our combined sample of 10,109 respondents, it investigates how people conceive of the purposes of low-carbon heat, their preferences for particular forms of heat supply, and their (at times odd) practices of heat consumption and temperature settings. Grounded in its original data, the study organizes its findings inductively across the five themes of literacy (heating knowledge, awareness and control), sustainability (heating practices, dynamics and conflicts), temperature (heating satisfaction and preferences), desirability of change (low-carbon heating priorities, business models and trust), and culture (country and national variation). The study also explores intersections between these dimensions, using multivariate analysis, as well as how preferences differ according to varying types of actors as well as geography and space.}, language = {en} } @article{MikhaeilNowakPalombaetal., author = {Mikhaeil, Makram and Nowak, Sebastian and Palomba, Valeria and Frazzica, Andrea and Gaderer, Matthias and Dawoud, Belal}, title = {Experimental and analytical investigation of applying an asymmetric plate heat exchanger as an evaporator in a thermally driven adsorption appliance}, series = {Applied Thermal Engineering}, journal = {Applied Thermal Engineering}, number = {228}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2023.120525}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-61115}, abstract = {This communication presents an experimental and analytical study on the evaporation mechanism in a closed-structured asymmetric plate heat exchanger (PHE) employed as a stagnant water evaporator for the application in an adsorption heat transformation appliance. To this aim, an experimental unit is constructed, which comprises two identical PHEs, one acting as an vaporator/condenser and the second, as an adsorber/desorber. Two endoscopes are mounted inside the investigated evaporator to visualize the evaporation mechanism when performing adsorption-evaporation processes under different boundary conditions. It turned out that the evaporation mechanism is a partially covered, thin film evaporation. A heat transfer analysis is performed to evaluate the heat transfer coefficient of the thin film evaporation () inside the investigated evaporator, resulting in -values between 1330 and 160 [W∙m-2∙K-1] over the investigated adsorption-evaporation time. Correlating the obtained () to the film thickness and the wetted area results in -values between 0.34 and 0.78 [mm] and wetted to total area ratios of 0.78 to 0.16. Besides, an analytical model has been developed and introduced to correlate the overall evaporator heat transfer coefficient with the adsorption potential and the time rate of change of the water uptake.}, language = {en} } @article{MonkmanSindersbergerPremetal., author = {Monkman, Gareth J. and Sindersberger, Dirk and Prem, Nina and Diermeier, Andreas and Szecsey, Tamara}, title = {Dielectric behaviour of magnetic hybrid materials}, series = {Physical Sciences Reviews}, volume = {7}, journal = {Physical Sciences Reviews}, number = {10}, publisher = {de Gruyter}, doi = {10.1515/psr-2019-0121}, pages = {1169 -- 1185}, abstract = {The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt\%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt\% CIP) were also investigated. With filler concentrations lower than 3 wt\%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt\% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt\%. Above 3 wt\% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1\%-3 wt\% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt\% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found.}, language = {en} } @article{MikhaeilGadererDawoud, author = {Mikhaeil, Makram and Gaderer, Matthias and Dawoud, Belal}, title = {On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study}, series = {Energy}, volume = {207}, journal = {Energy}, number = {September}, publisher = {Elsevier}, doi = {10.1016/j.energy.2020.118272}, pages = {1 -- 13}, abstract = {An innovative adsorber plate heat exchanger (APHE), which is developed for application in adsorption heat pumps, chillers and thermal energy storage systems, is introduced. A test frame has been constructed as a representative segment of the introduced APHE for applying loose grains of AQSOA-Z02. Adsorption kinetic measurements have been carried out in a volumetric large-temperature-jump setup under typical operating conditions of adsorption processes. A transient 2-D model is developed for the tested sample inside the setup. The measured temporal uptake variations with time have been fed to the model, through which a micro-pore diffusion coefficient at infinite temperature of 2 E-4 [m2s-1] and an activation energy of 42.1 [kJ mol-1] have been estimated. A 3-D model is developed to simulate the combined heat and mass transfer inside the APHE and implemented in a commercial software. Comparing the obtained results with the literature values for an extruded aluminium adsorber heat exchanger coated with a 500 μm layer of the same adsorbent, the differential water uptake obtained after 300 s of adsorption (8.2 g/100 g) implies a sound enhancement of 310\%. This result proves the great potential of the introduced APHE to remarkably enhance the performance of adsorption heat transformation appliances.}, language = {en} } @article{MonkmanStrieglPremetal., author = {Monkman, Gareth J. and Striegl, Birgit and Prem, Nina and Sindersberger, Dirk}, title = {Electrical Properties of Magnetoactive Boron-Organo-Silicon Oxide Polymers}, series = {Macromolecular Chemistry and Physics}, volume = {221}, journal = {Macromolecular Chemistry and Physics}, number = {4}, publisher = {Wiley}, doi = {10.1002/macp.201900342}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-26488}, pages = {1 -- 8}, abstract = {The electrical properties of rheopectic magnetoactive composites comprising boron-organo-silicon oxide dielectric matrices containing carbonyl iron microparticles are presented for the first time. The increase in interfacial magnetocapacitance is seen to greatly exceed that experienced when using conventional elastomeric matrices such as polydimethylsiloxane. In addition to the increase in capacitance, a simultaneous and sharp decrease in the parallel electrical resistance over several orders of magnitude is also observed. The effects are time dependent but repeatable. Potential applications include magnetically controlled frequency dependent devices, magnetic sensor systems, weighting elements for neural networks, etc.}, language = {en} } @article{PremSindersbergerMonkman, author = {Prem, Nina and Sindersberger, Dirk and Monkman, Gareth J.}, title = {Infrared spectral analysis of low concentration magnetoactive polymers}, series = {Journal of Applied Polymer Science}, volume = {137}, journal = {Journal of Applied Polymer Science}, number = {7}, publisher = {Wiley}, organization = {WILEY}, issn = {1097-4628}, doi = {10.1002/app.48366}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-25913}, pages = {1 -- 7}, abstract = {This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt\%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt\%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt\% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366.}, language = {en} }