@article{Dawoud, author = {Dawoud, Belal}, title = {Water vapor adsorption kinetics on small and full scale zeolite coated adsorbers; A comparison}, series = {Applied thermal engineering}, volume = {50}, journal = {Applied thermal engineering}, number = {2}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2011.07.013}, pages = {1645 -- 1651}, abstract = {A possibility to enhance both heat and mass transfer characteristics of an adsorber heat exchanger is to apply the adsorbent directly to its surface in form of a consolidated layer. As the majority of the available publications on the effect of both coating technology and adsorbent layer thickness on the adsorption kinetics deals with small scale adsorbent samples, the results obtained can only represent the best case design of an adsorber heat exchanger. This article presents, therefore, a comparison between the adsorption kinetics of water vapour on small as well as two different full scale coated adsorber heat exchanger types with AQSOA-Z02 layers of Mitsubishi Plastics Incorporation under quasi isobaric conditions of adsorption heat pumps. The small scale coated samples have a zeolite dry mass of 200 mg and layer thicknesses of 200, 300 and 500 μm while the full scale adsorbers have a coated zeolite mass between 1.5 and 2.5 kg and layer thicknesses of 150, 200, 300, 400 and 500 μm. In the investigated adsorption heat pump module, up to 52.7 and 57.3\% of the equilibrium differential water loading measured with the small scale coated substrates have been obtained after an adsorption-evaporation times of 300 and 600 s, respectively.}, language = {en} } @techreport{SternerBauerHofrichteretal., author = {Sterner, Michael and Bauer, Franz and Hofrichter, Andreas and Heberl, Michael}, title = {Systemanalyse und -integration Power-to-X im Kontext von erneuerbarer Elektrizit{\"a}t als Prim{\"a}renergie (SPIKE)}, pages = {87}, abstract = {Durch das in Paris beschlossene Ziel, die globale mittlere Temperatur auf deutlich unter 2 Grad Celsius gegen{\"u}ber dem vorindustriellen Niveau zu begrenzen, ist ein Ausstieg aus der Nutzung fossiler Energietr{\"a}ger und Rohstoffe bis zum Jahr 2050 notwendig (WBGU 2016). Daher hat sich die Bundesregierung das Ziel gesetzt, bis zur Mitte des Jahrhunderts eine weitgehende Treibhausgasneutralit{\"a}t zu erreichen. Hierzu ist neben einer Steigerung der Energieeffizienz in allen Sektoren ein Ausbau erneuerbaren Energien notwendig. Dies beinhaltet haupts{\"a}chlich den Zubau von Wind- und Solarstromanlagen. Somit gewinnt die Sektorkopplung immer mehr an Bedeutung und wird in Zukunft eine tragende Rolle f{\"u}r die Defossilisierung des Energiesystems spielen (BMUB 2016). Als zentrales Element der Sektorkopplung gilt Strom, der {\"u}ber Power-to-X (PtX) sowohl energetisch im W{\"a}rme-, und Verkehrssektor als auch stofflich in der Industrie und vor allem im Chemiesektor eingesetzt werden kann (Ausfelder et al. 2018a). Im Rahmen des P2X-Vorhabens der Kopernikus Forschungsinitiative wird die Sektorkopplung durch die Umwandlung von Strom mittels elektrochemischer Prozesse in stoffliche Ressourcen wie Wasserstoff, Synthesegas oder Kohlenstoffmonoxid untersucht. Der Schwerpunkt liegt auf der Betrachtung der Kopplung von Strom und Verkehr sowie Strom und Chemie und der Untersuchung von Prozessen und Pfaden, die aus {\"o}kologischer, {\"o}konomischer und gesellschaftlicher Sicht vorteilhaft sind. Eine vergleichende Einordnung in den Gesamtkontext der Energiewende mit Abw{\"a}gung zahlreicher Alternativen und Konkurrenztechnologien ist dort allerdings nicht vorgesehen. Zudem werden einige relevante PtX-Technologien wie Power-to-Heat nicht betrachtet. Aus diesem Grund wurden in SPIKE erg{\"a}nzende PtX-Technologiepfade aus systemanalytischer Sicht untersucht. Dies sind Power-to-Heat (PtH) und Power-to-Gas (PtG) {\"u}ber Elektrolyse und optionaler anschließender Methanisierung sowie die Herstellung ausgew{\"a}hlter Pfade der strombasierten Herstellung von Produkten der energieintensiven Industrie. Ziel des Forschungsvorhabens war die Analyse von PtX-Technologien und Pfaden, deren vergleichende Einordnung im Gesamtkontext der Energiewende sowie die Unterst{\"u}tzung des P2X Roadmapping Prozesses und die Ableitung von Handlungsempfehlungen. Ein besonderer Schwerpunkt lag auf dem Einsatz von PtX im Industriesektor. F{\"u}r das Vorhaben wurden Arbeitspakete (AP) erstellt, die Untersuchungen zu Technologie, Potenzial, {\"O}konomie und {\"O}kologie von PtH (AP 1), PtG (AP 2), Power-to-Ammoniak, Power-to-Ethen und Power-to-Propen (AP 3) umfassten. Daraus wurde in AP 4 ein Systemvergleich mit Einordnung von PtX in die Energiewende durchgef{\"u}hrt. Auf dieser Basis und der Identifizierung regulatorischer Rahmenbedingungen f{\"u}r PtX (AP 5) wurde das deutsche Energiesystem samt PtX-Pfaden in einem Energiesystemmodell abgebildet (AP 6). Die Ergebnisse flossen in das Roadmapping ein (AP 7). Zudem erfolgte ein Austausch mit den Projektpartnern und das Verfassen wissenschaftlicher Abhandlungen (AP 8).}, language = {de} } @techreport{ThemaKaulSterneretal., author = {Thema, Martin and Kaul, Anja and Sterner, Michael and Heberl, Michael}, title = {Optimierung eines Rieselbett-Bioreaktors f{\"u}r die dynamische mikrobielle Biosynthese von Methan mit Archaeen-Mikroorganismen in Power-to-Gas-Anlagen}, doi = {10.2314/KXP:1815321555}, abstract = {Das {\"u}bergeordnete Ziel des Vorhabens war die Entwicklung neuer technologischer M{\"o}glichkeiten f{\"u}r den biologischen Methanisierungsprozess mit Archaeen1 in Power-to-Gas-Anwendungen. Im Gegensatz zur technisch ausgereiften chemisch-katalytischen Methanisierung sind hier noch Potenziale zur Optimierung verfahrenstechnischer und biologischer Prozesse f{\"u}r das Speicherkonzept Power-to-Gas [7] vorhanden. Dabei sollte zum einen ein Rieselbett-Bioreaktor optimiert, simuliert und f{\"u}r die Hochskalierung vorbereitet werden. Zum anderen sollte eine Kombination optimal geeigneter Mikroorganismen und Packungsmaterialien selektiert und deren Verhalten und Eignung im Reaktor analysiert werden. Das Verhalten des entwickelten Systems sollte zun{\"a}chst im Labor- und Technikumsmaßstab und anschließend im Feldtest an einer bestehenden Power-to-Gas-Anlage untersucht werden. Hauptziel w{\"a}hrend des Feldtests war die Produktion von einspeisef{\"a}higem Methan sowie dessen Einspeisung ins Gasnetz. Ein Hauptziel des Projektes war es, die Normung und Standardisierung notwendiger Systemparameter und Semantik zur Beschreibung und Einbindung biologischer Methanisierungseinheiten in Power-to-Gas-Anlagen voranzutreiben. Dies sollte zum einen die Vergleichbarkeit der wissenschaftlichen Erkenntnisse verbessern und zum anderen unterst{\"u}tzend bei der Kommerzialisierung der Technologie wirken. Aus dem Projekt heraus wurde so die neue Normungsreihe VDI 4635 Power-to-X beim Verein Deutscher Ingenieure angestoßen.}, language = {de} } @inproceedings{KlitsmanBruecklEller, author = {Klitsman, Maksym and Br{\"u}ckl, Oliver and Eller, Johannes}, title = {Analysis and simulation of the population driving behaviour and charging processes at different charging station types with electric vehicles}, series = {NEIS 2021, Conference on Sustainable Energy Supply and Energy Storage Systems: 13-14. September 2021, Hamburg}, booktitle = {NEIS 2021, Conference on Sustainable Energy Supply and Energy Storage Systems: 13-14. September 2021, Hamburg}, editor = {Schulz, Detlef}, publisher = {VDE-Verlag}, isbn = {978-3-8007-5651-3}, pages = {254 -- 260}, abstract = {Electric vehicles are one of the important components of the energy transition, which is necessary for the CO2 emission reduction. In order to estimate the influence of electromobility on electric grids at present day and in the future, the generation of realistic charge profiles is necessary. The main objective of this study is the development of an algorithm, which generates realistic charge time series of electric vehicles. The very huge and detailed input surveys enable to define different population groups, representing specific driving behaviour. These groups are then composed and scaled up, according to the statistical population structure of a chosen town or city in Germany, and show typical driving behaviour of all inhabitants. The charge profiles are calculated for several charge station types, based on daily electric vehicle user mobility, day type and household type. In addition, charge process occurrence is evaluated through a model, involving charge infrastructure presence, attractiveness of corresponding charge station type and charge process necessity.}, language = {en} } @article{SavelievFetisovChashinetal., author = {Saveliev, Dmitry V. and Fetisov, Leonid Y. and Chashin, Dmitri V. and Shabin, P. A. and Vyunik, D. A. and Fedulov, Feodor and Kettl, W. and Shamonin (Chamonine), Mikhail}, title = {Method of Measuring Deformations of Magnetoactive Elastomers under the Action of Magnetic Fields}, series = {Russian Technological Journal}, volume = {7}, journal = {Russian Technological Journal}, number = {4}, doi = {10.32362/2500-316x-2019-7-4-81-91}, pages = {81 -- 91}, language = {ru} } @article{GamischHuberGadereretal., author = {Gamisch, Bernd and Huber, Lea and Gaderer, Matthias and Dawoud, Belal}, title = {On the Kinetic Mechanisms of the Reduction and Oxidation Reactions of Iron Oxide/Iron Pellets for a Hydrogen Storage Process}, series = {Energies}, volume = {15}, journal = {Energies}, number = {21}, publisher = {MDPI}, doi = {10.3390/en15218322}, abstract = {This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90\% Fe2O3, 10\% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions' kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5\%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71\% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.}, language = {en} } @inproceedings{GaertnerRankHeberletal., author = {G{\"a}rtner, Sebastian and Rank, Daniel and Heberl, Michael and Gaderer, Matthias and Sterner, Michael}, title = {Integration of Power-To-Methane into Glass Melting Processes}, series = {Proceedings of the International Renewable Energy Storage Conference (IRES 2022)}, volume = {16}, booktitle = {Proceedings of the International Renewable Energy Storage Conference (IRES 2022)}, publisher = {Atlantis Press}, issn = {2589-4943}, doi = {10.2991/978-94-6463-156-2_12}, pages = {147 -- 161}, abstract = {The glass industry is facing increased challenges regarding climate protection targets and rising energy costs. The integration of renewable energy including conversion and storage is a key for both challenges in this energy-intensive industrial sector, which has been mainly relying on fossil gas so far. The options considered to this point for reducing CO2 emissions and switching to a renewable energy supply involve far-reaching changes of the established melting processes. This entails significant risks in terms of influences on glass quality and stable production volumes. The presented approach for the integration of a Power-to-Methane (PtM) system into the glass industry is a completely new concept and has not been considered in detail before. It allows the use of established oxyfuel melting processes, the integration of fluctuating renewable energy sources and a simultaneous reduction of CO2 emissions by more than 78\%. At the same time, natural gas purchases become obsolete. A techno-economic evaluation of the complete PtM process shows, that 1,76 €/m3 or 1,26 €/kg synthetic natural gas are possible with renewable energy supply. Using electricity from the energy grid would require electricity prices < 0,126 €/kWh to allow cost competitive PtM processes in the glass industry. Such electricity prices could be achieved by electricity market-based optimization and operation of the PtM system. This operation strategy would require AI-based algorithms predicting availabilities and prices on future-based markets.}, language = {en} } @article{KralHaumerGrabner, author = {Kral, Christian and Haumer, Anton and Grabner, Christian}, title = {Consistent Induction Motor Parameters for the Calculation of Partial Load Efficiencies by Means of an Advanced Simulation Model}, series = {Engineering Letters}, volume = {18}, journal = {Engineering Letters}, number = {1}, address = {Hong Kong}, issn = {1816-0948}, abstract = {From the rating plate data of an induction motor the nominal efficiency can be determined. Without detailed knowledge of equivalent circuit parameters, partial load behavior cannot be computed. Therefore, a combined calculation and estimation scheme is presented, where the consistent parameters of an equivalent circuit are elaborated, exactly matching the nominal operating point. From these parameters part load efficiencies can be determined.}, language = {en} } @article{KlenkGalka, author = {Klenk, Eva Marianne and Galka, Stefan}, title = {Analysis of real-time tour building and scheduling strategies for in-plant milk-run systems with volatile transportation demand}, series = {IFAC - PapersOnLine}, volume = {52}, journal = {IFAC - PapersOnLine}, number = {13}, publisher = {Elsevier}, doi = {10.1016/j.ifacol.2019.11.517}, pages = {2110 -- 2115}, abstract = {In modern manufacturing systems, milk run (MR) systems represent route-based, cyclic material-handling systems that are used widely and enable frequent deliveries of containerized parts in small lot sizes from a central storage area to multiple points of use on the factory floor. Usually, deliveries take place at predetermined, constant time intervals. As in real-world MR systems, the number of containers to deliver in each interval varies in the short term, peaks in the number of deliveries may lead to capacity bottlenecks and late deliveries. In this paper, we develop three alternative strategies to determine starting times of MR cycles in real-time based on the current number of delivery orders in the system aiming to better handle variations in the number of orders. We evaluate the three strategies for different system load scenarios with respect to delivery service levels, order lead times, systems utilization and necessary number of MR trains using a discrete-event simulation model.}, language = {en} } @misc{PershinaSavelievGlavanetal., author = {Pershina, K. V. and Saveliev, Dmitry V. and Glavan, Gašper and Chashin, Dmitri V. and Belyaeva, Inna A. and Fetisov, Leonid Y. and Shamonin (Chamonine), Mikhail}, title = {The voltage response of a structure comprising a magnetoactive-elastomer cylinder and a piezoelectric material to magnetic field step excitations}, series = {The 4th International Baltic Conference on Magnetism (IBCM 2021) : Svetlogorsk, Russia August 29 - September 2, 2021 : Book of Abstracts}, journal = {The 4th International Baltic Conference on Magnetism (IBCM 2021) : Svetlogorsk, Russia August 29 - September 2, 2021 : Book of Abstracts}, publisher = {Immanuel Kant Baltic Federal University, Kaliningrad, Russia}, pages = {182}, language = {en} }