@article{SchmidtDenkerDashielletal., author = {Schmidt, Oliver G. and Denker, Ullrich and Dashiell, Michael W. and Jin-Phillipp, Neng Yun and Eberl, Karl and Schreiner, Rupert and Gr{\"a}beldinger, Hedwig and Schweizer, Heinz C. and Christiansen, Silke H. and Ernst, Frank}, title = {Laterally aligned Ge/Si islands: a new concept for faster field-effect transistors}, series = {Materials Science and Engineering B}, volume = {89}, journal = {Materials Science and Engineering B}, number = {1-3}, publisher = {Elsevier}, address = {New York, NY}, issn = {1873-4944}, doi = {10.1016/S0921-5107(01)00810-8}, pages = {101 -- 105}, abstract = {Self-assembled and coherently strained Ge dots were grown on a Si/SiGe superlattice, which was deposited on a flat Si(001) substrate surface patterned with a regular array of straight trenches. The superlattice translates the surface modulation of the substrate into a strain-field modulation, which causes the Ge dots on its surface to form along straight lines above the buried trenches. This approach provides self-assembled Ge dots with excellent lateral periodicity, which might be useful for fabricating dot-based field-effect-transistors (DotFETs). Here, we propose the concept of a modulation-doped p-channel DotFET (p-MOD-DotFET). The p-MOD-DotFET relies on embedded Ge-rich nanostructures, which provide p-channels through the Ge-rich dots. A high Ge concentration in the dots is desirable in order to exploit the high hole mobility of Ge-rich material. We show that the commonly observed Si-Ge intermixing during Si capping of Ge dots can be suppressed by overgrowing the islands at low temperature.}, language = {en} } @article{KoeckStrieglKrausetal., author = {K{\"o}ck, Hannah and Striegl, Birgit and Kraus, Annalena and Zborilova, Magdalena and Christiansen, Silke H. and Sch{\"a}fer, Nicole and Gr{\"a}ssel, Susanne and Hornberger, Helga}, title = {In Vitro Analysis of Human Cartilage Infiltrated by Hydrogels and Hydrogel-Encapsulated Chondrocytes}, series = {Bioengineering}, volume = {10}, journal = {Bioengineering}, publisher = {MDPI}, doi = {10.3390/bioengineering10070767}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-61235}, pages = {1 -- 21}, abstract = {Osteoarthritis (OA) is a degenerative joint disease causing loss of articular cartilage and structural damage in all joint tissues. Given the limited regenerative capacity of articular cartilage, methods to support the native structural properties of articular cartilage are highly anticipated. The aim of this study was to infiltrate zwitterionic monomer solutions into human OA-cartilage explants to replace lost proteoglycans. The study included polymerization and deposition of methacryloyloxyethyl-phosphorylcholine- and a novel sulfobetaine-methacrylate-based monomer solution within ex vivo human OA-cartilage explants and the encapsulation of isolated chondrocytes within hydrogels and the corresponding effects on chondrocyte viability. The results demonstrated that zwitterionic cartilage-hydrogel networks are formed by infiltration. In general, cytotoxic effects of the monomer solutions were observed, as was a time-dependent infiltration behavior into the tissue accompanied by increasing cell death and penetration depth. The successful deposition of zwitterionic hydrogels within OA cartilage identifies the infiltration method as a potential future therapeutic option for the repair/replacement of OA-cartilage extracellular suprastructure. Due to the toxic effects of the monomer solutions, the focus should be on sealing the OA-cartilage surface, instead of complete infiltration. An alternative treatment option for focal cartilage defects could be the usage of monomer solutions, especially the novel generated sulfobetaine-methacrylate-based monomer solution, as bionic for cell-based 3D bioprintable hydrogels.}, language = {en} } @article{KloiberSchultheissSoteloetal., author = {Kloiber, Jessica and Schultheiß, Ulrich and Sotelo, Lamborghini and Sarau, George and Christiansen, Silke and Gavras, Sarkis and Hort, Norbert and Hornberger, Helga}, title = {Corrosion behaviour of electropolished magnesium materials}, series = {Materials Today Communications}, journal = {Materials Today Communications}, edition = {Journal Pre-proof}, publisher = {Elsevier}, doi = {10.1016/j.mtcomm.2023.107983}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-68254}, abstract = {Although magnesium and its alloys are promising candidates as biodegradable implant materials, the tendency for localized corrosion mechanism in physiological environment limit their biomedical application. Electropolishing is an attractive strategy for improving the corrosion behaviour of metals, but it is still largely unexplored in magnesium materials. In this study, the characterization of electropolished surfaces of AM50 and pure magnesium was performed, focussing on their in vitro degradation behaviour in cell medium. Corrosion rates were evaluated using potentiodynamic polarisation. The surface morphology before and after the onset of corrosion was investigated by scanning electron microscopy and confocal laser scanning microscopy. The presented electropolishing process led to improved surface performances, observable by significantly lower corrosion rates (0.08 mm·year-1 in Dulbecco's modified Eagle's medium), lower arithmetical mean height (0.05 µm), lower water contact angle (25-35°) and lower micro hardness (35-50 HV 0.1) compared to mechanically and chemically treated surfaces. MgO/Mg(OH)2 could be detected on electropolished surfaces. The localized corrosion mode could be reduced, but not entirely prevented. Electropolishing shows great potential as post-treatment of magnesium-based components, but detailed tests of the long-term corrosion behaviour are an important area of future research.}, language = {en} } @article{HornbergerMarquisChristiansenetal., author = {Hornberger, Helga and Marquis, Peter M. and Christiansen, Silke H. and Strunk, Horst P.}, title = {Microstructure of a high strength alumina glass composite}, series = {Journal of Materials Research}, volume = {11}, journal = {Journal of Materials Research}, number = {4}, doi = {10.1557/JMR.1996.0104}, pages = {855 -- 858}, abstract = {The morphology and microstructure of an Al2O3 glass composite (trade name In-Ceram, Vita Zahnfabrik) were studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The composite was produced by infiltration of a lanthanum-based glass throughout a porous Al2O3 body. This alumina body was formed by three classes of particles differing in size and shape: faceted particles typically ≤4 μm in diameter, platelets of average diameter 8 μm, 1.5 μm thickness, and small spheres 0.4 μm in diameter. The outstanding strength properties of the composite (600 MPa, ball-on-ring test) are a result of the high wetting capability of the glass phase on the Al2O3 surface. In addition, plastic strain relaxation in the faceted particles by dislocation formation compensates partially for residual stresses and impedes crack formation at the glass/Al2O3 interface.}, language = {en} } @article{HornbergerMarquisChristiansenetal., author = {Hornberger, Helga and Marquis, Peter M. and Christiansen, Silke H. and Albrecht, M. and Strunk, Horst P. and Franks, J.}, title = {Microstructure of a high strength alumina-glass composite combined with a diamond like carbon coating}, series = {Electron Microscopy and Analysis}, journal = {Electron Microscopy and Analysis}, doi = {10.1557/JMR.1996.0244}, pages = {559 -- 562}, abstract = {We investigate the mechanical and microstructural properties of a diamond-like carbon coating (DLC) which is deposited by plasma enhanced chemical vapor deposition (PECVD) onto an alumina/aluminosilicate glass composite used for biomedical applications. Ball-on-ring tests yield a fracture strength that is essentially influenced by the surface topology/roughness. The surface topology of the coating is investigated by atomic force microscopy (AFM). Tribology tests and nanoindentation represent the wear resistance and hardness; these are properties that are mainly influenced by the microstructural properties of the DLC coating. This microstructure is investigated by transmission electron microscopy (TEM) and analyzed by parallel electron energy loss spectroscopy (PEELS). For the general applicability of the coated composite, the interfacial adhesion of the DLC coating on the comparably rough substrate (roughness amplitudes and wavelengths are in the micrometer range) is important. Therefore, we focus on TEM investigations that show the interface to be free of gaps and pores that we, together with a characteristic microstructure adjacent to the interface, relate to the excellent adhesion. The interlayer consists of a high density of SiC grains, part of them directly bound to the substrate, and part of them bound to other SiC grains. This interlayer is followed by an essentially different region of the coating as concerns the microstructure; this region consists of nanocrystalline diamond particles embedded in an amorphous carbon matrix. It is this heterogeneous microstructure to which we attribute (i) the good adhesion based upon the interface stabilizing SiC grains, and (ii) the high hardness and wear resistance based upon the diamond nanocrystals in the coating.}, language = {en} } @article{HornbergerKisselStriegletal., author = {Hornberger, Helga and Kissel, Hannah and Striegl, Birgit and Kronseder, Matthias and Vollnhals, Florian and Christiansen, Silke H.}, title = {Bioactivity and corrosion behavior of magnesium barrier membranes}, series = {Materials and Corrosion}, volume = {73}, journal = {Materials and Corrosion}, number = {1}, publisher = {Wiley}, doi = {10.1002/maco.202112385}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-24499}, pages = {8 -- 19}, abstract = {In the current research, magnesium and its alloys have been intensively studied as resorbable implant materials. Magnesium materials combine their good mechanical properties with bioactivity, which make them interesting for guided bone regeneration and for the application as barrier membranes. In this study, the in vitro degradation behavior of thin magnesium films was investigated in cell medium and simulated body fluid. Three methods were applied to evaluate corrosion rates: measurements of (i) the gaseous volume evolved during immersion, (ii) volume change after immersion, and (iii) polarization curves. In this comparison, measurements of H2 development in Dulbecco's modified Eagle's medium showed to be the most appropriate method, exhibiting a corrosion rate of 0.5 mm·year-1. Observed oxide and carbon contamination have a high impact on controlled degradation, suggesting that surface treatment of thin foils is necessary. The bioactivity test showed positive results; more detailed tests in this area are of interest.}, language = {en} } @article{ChristiansenAlbrechtStrunketal., author = {Christiansen, Silke H. and Albrecht, M. and Strunk, Horst P. and Hornberger, Helga and Marquis, Peter M. and Franks, J.}, title = {Mechanical properties and microstructural analysis of a diamond-like carbon coating on an alumina/glass composite}, series = {Journal of Materials Research}, volume = {11}, journal = {Journal of Materials Research}, number = {8}, doi = {10.1557/JMR.1996.0244}, pages = {1934 -- 1942}, abstract = {We investigate the mechanical and microstructural properties of a diamond-like carbon coating (DLC) which is deposited by plasma enhanced chemical vapor deposition (PECVD) onto an alumina/aluminosilicate glass composite used for biomedical applications. Ball-on-ring tests yield a fracture strength that is essentially influenced by the surface topology/roughness. The surface topology of the coating is investigated by atomic force microscopy (AFM). Tribology tests and nanoindentation represent the wear resistance and hardness; these are properties that are mainly influenced by the microstructural properties of the DLC coating. This microstructure is investigated by transmission electron microscopy (TEM) and analyzed by parallel electron energy loss spectroscopy (PEELS). For the general applicability of the coated composite, the interfacial adhesion of the DLC coating on the comparably rough substrate (roughness amplitudes and wavelengths are in the micrometer range) is important. Therefore, we focus on TEM investigations that show the interface to be free of gaps and pores that we, together with a characteristic microstructure adjacent to the interface, relate to the excellent adhesion. The interlayer consists of a high density of SiC grains, part of them directly bound to the substrate, and part of them bound to other SiC grains. This interlayer is followed by an essentially different region of the coating as concerns the microstructure; this region consists of nanocrystalline diamond particles embedded in an amorphous carbon matrix. It is this heterogeneous microstructure to which we attribute (i) the good adhesion based upon the interface stabilizing SiC grains, and (ii) the high hardness and wear resistance based upon the diamond nanocrystals in the coating.}, language = {en} }