@article{LooNagarajuPathivadaetal., author = {Loo, Xuyan and Nagaraju, Bhavana and Pathivada, Sai and Bartsch, Alexander and Schratzenstaller, Thomas and Sattler, Robert and Monkman, Gareth J.}, title = {Electrical properties of bisphenol-A-free magnetoactive borosilicate polymers}, series = {AIP Advances}, volume = {14}, journal = {AIP Advances}, number = {5}, publisher = {AIP Publishing}, issn = {2158-3226}, doi = {10.1063/5.0203017}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-72936}, abstract = {The recent REACH regulations require the elimination of bisphenol-A and titanium dioxide from commercially available boron-based polymers. This has led to changes in some of the mechanical characteristics, which strongly influence the properties of magnetoactive borosilicate polymers. This work delivers results on the electrical properties and discusses some implications for future research using bisphenol-A and titanium-dioxide-free substitutes.}, language = {en} } @article{PutzSchirmerSattleretal., author = {Putz, Christoph and Schirmer, Maximilian and Sattler, Robert and Monkman, Gareth J.}, title = {Fabrication of Bisphenol-free Boron-Siloxane Polymers}, series = {Materials Chemistry and Physics}, journal = {Materials Chemistry and Physics}, edition = {Journal Pre-proof}, publisher = {Elsevier}, doi = {10.1016/j.matchemphys.2025.130567}, abstract = {Interest in the preparation of magnetoactive boron-siloxane polymers (MBP) has been stimulated by recent scientific developments. However, recent regulations have prohibited the inclusion of Bisphenol-A normally employed in the manufacture of commercially available products. In the following publication, two different routes for the preparation of magnetoactive borosiloxane polymers have been taken. First, the possibilities of obtaining homogeneous mixtures of magnetoactive polymers by mixing the magnetic particles with the polymer using solid CO2 (dry ice) and stirring (shearing) are investigated. In the course of the work, an approach for the preparation of reference materials of different viscosities was made to prove the transferability to other elastomers. This is then followed by a brief review of the reaction of the polymer with different solvents in relation to the mixing with particles. In manually kneaded compounds, dispersions ranging from 0.00004 to 0.004 particles per mm3 are common. The process described in this work resulted in agglomerations of no greater than 0.00004 particles per mm3 A possible synthesis route for bisphenol-free boron-siloxanes is then considered, in which for the polymer matrix, polydimethylsilanes (dichloro(methyl)silane), boric acid and iron(III)chloride are used for this purpose by polycondensation.}, language = {en} }