@article{KrieglKrenkelShamoninChamonine, author = {Kriegl, Raphael and Krenkel, Lars and Shamonin (Chamonine), Mikhail}, title = {Preservation of wetting ridges using field-induced plasticity of magnetoactive elastomers}, series = {Journal of Colloid and Interface Science}, volume = {683}, journal = {Journal of Colloid and Interface Science}, publisher = {Elsevier}, issn = {0021-9797}, doi = {10.1016/j.jcis.2024.12.132}, pages = {1019 -- 1027}, abstract = {Hypothesis. The presence of a wetting ridge is crucial for many wetting phenomena on soft substrates. Conventional experimental observations of a wetting ridge require permanent presence of a droplet. The magnetic field-induced plasticity effect (FIPE) of soft magnetoative elastomers (MAEs) allows one to overcome this limitation. Depositing a droplet onto an MAE surface and applying a magnetic field fixes the wetting ridge in place due to the FIPE. The droplet can be removed to investigate the ridge with ease using conventional optical methods. Experiments. The wetting ridge is observed on MAEs with different shear moduli and different material thicknesses by confocal laser scanning microscopy (LSM). The preservation quality of the ridge is analyzed for several values of magnetic field from 10 mT to 270 mT. To verify the plausibilty of results obtained, the measured shape is compared to a theoretical model by Style \& Dufresne. Findings. Upon removal of the sessile droplet, the deformation remains embossed onto the MAE surface as long as the magnetic field remains applied. The height of the ridge peak on soft samples (effective shear modulus kPa) is close to the theoretical prediction for a magnetic flux density of 50 mT. The magnitude of the external magnetic field magnifies the height of the wetting ridge.}, language = {en} } @article{KrieglKovalevShamoninChamonineetal., author = {Kriegl, Raphael and Kovalev, Alexander and Shamonin (Chamonine), Mikhail and Gorb, Stanislav}, title = {Tunable contact angle hysteresis on compliant magnetoactive elastomers}, series = {Extreme Mechanics Letters}, volume = {63}, journal = {Extreme Mechanics Letters}, publisher = {Elsevier}, issn = {2352-4316}, doi = {10.1016/j.eml.2023.102049}, abstract = {It is shown that the advancing (ACA) and receding (RCA) contact angles of water on extremely soft (shear modulus of the order of 10 kPa) magnetoactive elastomer (MAE) films significantly depend on the applied magnetic field. The difference between these angles, known as the contact angle hysteresis, is examined. The roles of the filler concentration and material softness are elaborated. The highest change in the contact angle hysteresis (CAH) from 34° in the absence of magnetic field to 76° in a magnetic field of 0.4 T is achieved for the softest sample with the lowest mass fraction of iron particles (70 wt\%). The dependence of the CAH on magnetization history ("magnetic hysteresis") is observed. This magnetic hysteresis is clearly pronounced for the ACA and has little effect on the RCA. Magnetic field-induced changes of the surface roughness exhibit qualitatively the same hysteresis behavior with regard to the external magnetic field as the ACA. The results are promising for the development of smart surfaces for applications where the dynamic wetting has to be controlled.}, language = {en} } @article{JezeršekKrieglKravanjaetal., author = {Jezeršek, Matija and Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Drevenšek-Olenik, Irena and Unold, Heiko and Shamonin (Chamonine), Mikhail}, title = {Control of Droplet Impact through Magnetic Actuation of Surface Microstructures}, series = {Advanced Materials Interfaces}, volume = {10}, journal = {Advanced Materials Interfaces}, number = {11}, publisher = {Wiley}, doi = {10.1002/admi.202202471}, abstract = {An effective method for on-demand control over the impact dynamics of droplets on a magnetoresponsive surface is reported. The surface is comprised of micrometer-sized lamellas from a magnetoactive elastomer on a copper substrate. The surface itself is fabricated using laser micromachining. The orientation of the lamellae is switched from edge-on (orthogonal to the surface) to face-on (parallel to the surface) by changing the direction of a moderate (<250 mT) magnetic field. This simple actuation technique can significantly change the critical velocities of droplet rebound, deposition, and splashing. Rebound and deposition regimes can be switched up to Weber number We < 13 ± 3, while deposition and splashing can be switched in the range of 32 < We < 52. Because a permanent magnet is used, no permanent power supply is required for maintaining the particular regime of droplet impact. The presented technology is highly flexible and enables selective fabrication and actuation of microstructures on complex devices. It has great potential for applications in soft robotics, microfluidics, and advanced thermal management.}, language = {en} } @article{KravanjaKrieglHribaretal., author = {Kravanja, Gaia and Kriegl, Raphael and Hribar, Luka and Glavan, Gašper and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Magnetically Actuated Surface Microstructures for Efficient Transport and Tunable Separation of Droplets and Solids}, series = {Advanced Engineering Materials}, volume = {25}, journal = {Advanced Engineering Materials}, number = {22}, publisher = {Wiley-VCH}, issn = {1527-2648}, doi = {10.1002/adem.202301000}, pages = {1 -- 11}, abstract = {Efficient transportation of droplets (∽10 ¹ ̶̶̶̶ 10 ² µl) and small solid objects (∽10 ¹ ̶ 10 ² mm ³ ) have important applications in many fields, such as microfluidics, lab-on-a-chip devices, drug delivery, etc. A novel multifunctional surface consisting of a periodic array of micro-lamellae from a soft magnetoactive elastomer (MAE) on a plastic substrate is reported for these purposes. The physical origin of the propulsion is the bending of soft magnetic lamellae in non-uniform magnetic fields, which is also observed in uniform magnetic fields. The magnetoactive surface is fabricated using a facile and rapid method of laser ablation. The propulsion of items is realized using a four-pole rotating magnet. This results in a cyclic lamellar fringe motion over the micro-structured surface and brings an advantage of easy reciprocation of transport by rotation reversal. Two modes of object transportation are identified: "pushing" mode for precise control of droplet and solid positioning and "bouncing" mode for heavier solid objects transportation. A water droplet of 5 μl or a glass sphere with a 2.1 mm diameter can be moved at a maximum speed of 60 mm s ⁻¹ . The multifunctionality of the proposed mechatronic platform is demonstrated on the examples of selective solid-liquid separation and droplet merging.}, language = {en} } @misc{KrieglKravanjaHribaretal., author = {Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Jezeršek, Matija and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail}, title = {Characterization of Wetting Properties of Magnetoactive Elastomer Surfaces}, series = {Proceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS) - 2023, September 11-13, 2023 Austin, Texas, USA}, journal = {Proceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS) - 2023, September 11-13, 2023 Austin, Texas, USA}, publisher = {The American Society of Mechanical Engineers}, address = {New York, USA}, isbn = {978-0-7918-8752-3}, doi = {10.1115/SMASIS2023-110998}, abstract = {Commercially available contact angle (CA) measuring devices usually do not allow for the application of magnetic fields to the sample under test. A setup for measuring the CA of liquids on magnetosensitive surfaces has been developed specifically for investigating the surfaces of magnetoactive elastomers (MAEs). The addition of a programmable linear stage, which moves a permanent magnet, allows for fine control of the magnetic field applied to the MAE without the need for large and power-consuming electromagnets. Paired with a custom control and evaluation software, this measurement setup operates semiautomatically, limiting operator error and increasing precision, speed, as well as repeatability of static and dynamic CA measurements for different magnetoactive materials. The software is equipped with robust droplet fitting algorithms to avoid experimental challenges arising with soft magnetoactive materials, such as the curling of sample edges or diffuse non-reflective surfaces. Several application examples on MAE surfaces, both processed and unprocessed, are presented.}, language = {en} } @article{StrausKokotKravanjaetal., author = {Straus, Izidor and Kokot, Gašper and Kravanja, Gaia and Hribar, Luka and Kriegl, Raphael and Shamonin (Chamonine), Mikhail and Jezeršek, Matija and Drevenšek-Olenik, Irena}, title = {Dynamically tunable lamellar surface structures from magnetoactive elastomers driven by a uniform magnetic field}, series = {Soft Matter}, volume = {Vol. 19}, journal = {Soft Matter}, publisher = {Royal Society of Chemistry}, doi = {10.1039/D3SM00012E}, pages = {3357 -- 3365}, abstract = {Stimuli responsive materials are key ingredients for any application that requires dynamically tunable or on-demand responses. In this work we report experimental and theoretical investigation of magnetic-field driven modifications of soft-magnetic elastomers whose surface was processed by laser ablation into lamellar microstructures that can be manipulated by a uniform magnetic field. We present a minimal hybrid model that elucidates the associated deflection process of the lamellae and explains the lamellar structure frustration in terms of dipolar magnetic forces arising from the neighbouring lamellae. We experimentally determine the magnitude of the deflection as a function of magnetic flux density and explore the dynamic response of lamellae to fast changes in a magnetic field. A relationship between the deflection of lamellae and modifications of the optical reflectance of the lamellar structures is resolved.}, language = {en} } @article{StrausKravanjaHribaretal., author = {Straus, Izidor and Kravanja, Gaia and Hribar, Luka and Kriegl, Raphael and Jezeršek, Matija and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena and Kokot, Gašper}, title = {Surface Modification of Magnetoactive Elastomers by Laser Micromachining}, series = {Materials}, volume = {2024}, journal = {Materials}, number = {17 / 7}, publisher = {MDPI AG}, address = {Basel, Switzerland}, doi = {10.3390/ma17071550}, pages = {12}, abstract = {It has been recently demonstrated that laser micromachining of magnetoactive elastomers is a very convenient method for fabricating dynamic surface microstructures with magnetically tunable properties, such as wettability and surface reflectivity. In this study, we investigate the impact of the micromachining process on the fabricated material's structural properties and its chemical composition. By employing scanning electron microscopy, we investigate changes in size distribution and spatial arrangement of carbonyl iron microparticles dispersed in the polydimethylsiloxane (PDMS) matrix as a function of laser irradiation. Based on the images obtained by a low vacuum secondary electron detector, we analyze modifications of the surface topography. The results show that most profound modifications occur during the low-exposure (8 J/cm^2) treatment of the surface with the laser beam. Our findings provide important insights for developing theoretical models of functional properties of laser-sculptured microstructures from magnetoactive elastomers.}, language = {en} } @inproceedings{KrieglJezeršekKravanjaetal., author = {Kriegl, Raphael and Jezeršek, Matija and Kravanja, Gaia and Hribar, Luka and Kokot, Gašper and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail}, title = {Characterization of Tunable Rebound Properties of Microstructured Magnetoactive Elastomers}, series = {ASME 2024 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS), September 9-11, 2024, Atlanta, Georgia, USA}, booktitle = {ASME 2024 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS), September 9-11, 2024, Atlanta, Georgia, USA}, publisher = {American Society of Mechanical Engineers}, address = {New York, USA}, isbn = {978-0-7918-8832-2}, doi = {10.1115/SMASIS2024-139154}, abstract = {We present a novel method to control the rebounding behavior of small mm-sized solid balls by employing magnetoactive elastomers (MAEs) with microstructured surfaces. An MAE is a composite material consisting of μm-sized ferromagnetic particles dispersed in a soft elastomer (e.g., polydimethylsiloxane) matrix. In the act of rebounding, the ball hits an MAE surface and bounces back. The MAE samples contained 75 wt.\% of iron. This composite material is known to respond to an applied magnetic field with increased stiffness (due to the magnetorheological effect) and plasticity. To adjust the rebound properties, the top layer of the MAE material was additionally modified by micromachining lamellar structures with different dimensions on the 100 μm scale via laser ablation. Due to the resulting high aspect ratio, these surface structures were sensitive to the magnetic field direction. The lamellas could stand up straight or lay down flat. The rebound behavior was evaluated by using a custom build apparatus that facilitates dropping of the balls in a precise and repeatable manner. A ball was dropped from different heights. The ball trajectory was captured with a high-speed camera to investigate the rebound properties. The recorded video was processed using a custom software written in Python. The experimental procedure and data processing algorithms are presented in detail. The results for the samples with different geometrical dimensions are provided as examples. It is made evident that the magnetic field influences the rebound properties of small non-magnetic balls impinging microstructured MAE surfaces. The change in surface topography is an effective way to control the ball rebound. The fabrication flexibility in geometrical dimensions of surface microstructures opens a convenient way to tune the desired response to magnetic fields. The presented idea may find applications in impact mitigation or small-scale sorting machinery, e.g. for recycling.}, language = {en} } @article{KrieglKravanjaHribaretal., author = {Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Čoga, Lucija and Drevenšek-Olenik, Irena and Jezeršek, Matija and Kalin, Mitjan and Shamonin (Chamonine), Mikhail}, title = {Microstructured Magnetoactive Elastomers for Switchable Wettability}, series = {Polymers}, volume = {14}, journal = {Polymers}, number = {18}, publisher = {MDPI}, doi = {10.3390/polym14183883}, pages = {1 -- 21}, abstract = {We demonstrate the control of wettability of non-structured and microstructured magnetoactive elastomers (MAEs) by magnetic field. The synthesized composite materials have a concentration of carbonyl iron particles of 75 wt.\% (≈27 vol.\%) and three different stiffnesses of the elastomer matrix. A new method of fabrication of MAE coatings on plastic substrates is presented, which allows one to enhance the response of the apparent contact angle to the magnetic field by exposing the particle-enriched side of MAEs to water. A magnetic field is not applied during crosslinking. The highest variation of the contact angle from (113 ± 1)° in zero field up to (156 ± 2)° at about 400 mT is achieved in the MAE sample with the softest matrix. Several lamellar and pillared MAE structures are fabricated by laser micromachining. The lateral dimension of surface structures is about 50 µm and the depth varies between 3 µm and 60 µm. A systematic investigation of the effects of parameters of laser processing (laser power and the number of passages of the laser beam) on the wetting behavior of these structures in the absence and presence of a magnetic field is performed. In particular, strong anisotropy of the wetting behavior of lamellar structures is observed. The results are qualitatively discussed in the framework of the Wenzel and Cassie-Baxter models. Finally, directions of further research on magnetically controlled wettability of microstructured MAE surfaces are outlined. The obtained results may be useful for the development of magnetically controlled smart surfaces for droplet-based microfluidics.}, language = {en} } @misc{Kriegl, author = {Kriegl, Raphael}, title = {Preservation of wetting ridges using field-induced plasticity of magnetoactive elastomers (Version 3) [Data set]}, doi = {10.5281/zenodo.14502155}, abstract = {How to access data: html: Open in browser to view interactive figure pdf/png: Static figure, open with desired program json: Contains data for figures Open using Python pandas: import pandas as pd data = pd.read_json("filename") data then contains a pandas table. The cells in columns describing x,y data might contain entire arrays. Naming: Figure files are named after their respective ordering (i.e. figure1_*). Data and figure files are always named correspondingly. Zip archives (indiv_3D_*.zip) contain multiple additional figures, one for each surface measurement. There is a zip archive with the static renders and one with the interactive plots.}, language = {en} } @misc{Kriegl, author = {Kriegl, Raphael}, title = {Characterization of Wetting Properties of Magnetoactive Elastomer Surfaces [Data set]}, doi = {10.5281/zenodo.13124610}, language = {en} } @misc{Kriegl, author = {Kriegl, Raphael}, title = {Tunable rebound of millimeter-sized rigid balls by magnetic actuation of elastomer-based surface microstructures [Data set]}, doi = {10.5281/zenodo.10419411}, language = {en} } @article{KrieglJezeršekKravanjaetal., author = {Kriegl, Raphael and Jezeršek, Matija and Kravanja, Gaia and Hribar, Luka and Mukhi, Soham and Kokot, Gašper and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail}, title = {Tunable rebound of millimeter-sized rigid balls by magnetic actuation of elastomer-based surface microstructures}, series = {Smart Materials and Structures}, volume = {33}, journal = {Smart Materials and Structures}, number = {6}, publisher = {IOP Publishing}, doi = {10.1088/1361-665X/ad41a9}, abstract = {A novel method for controlling the rebound behavior of small balls made of Al2O3 with a radius of 2.381 mm is presented. It uses different types of micro-structured surfaces of soft magnetoactive elastomers. These surfaces were fabricated via laser micromachining and include fully ablated surfaces as well as micrometer-sized lamellas with a fixed width of 90 µm, height of 250 µm and three different gap sizes (15, 60 and 105 µm). The lamellas can change their orientation from edge-on to face-on configuration according to the direction of the external magnetic field from a permanent magnet. The orientation of the external magnetic field significantly influences the rebound behavior of the balls, from a coefficient of restitution e of to < 0.1. The highest relative change in the coefficient of restitution between zero field and face-on configuration of is observed for lamellas with a gap of 60 µm. Other characteristics of the ball rebound such as the penetration depth into an Magnetoactive elastomer and the maximum deceleration are investigated as well. The proposed method does not require a constant power supply due to the use of permanent magnets. It may find novel applications in the field of impact engineering.}, language = {en} } @misc{Kriegl2022, author = {Kriegl, Raphael}, title = {Microstructured Magnetoactive Elastomers for Switchable Wettability [Data set]}, doi = {10.5281/zenodo.13124555}, year = {2022}, language = {en} } @article{StrausKravanjaKriegletal., author = {Straus, Izidor and Kravanja, Gaia and Kriegl, Raphael and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena and Jezeršek, Matija and Kokot, Gašper}, title = {Laser Micromachining for Polymer Surface Topography Designt}, series = {JoVE journal : engineering}, journal = {JoVE journal : engineering}, publisher = {JoVE}, doi = {10.3791/68126}, pages = {15}, abstract = {Soft magnetoactive elastomers (MAEs) are smart materials that respond to external magnetic fields by dynamically altering their mechanical properties. They are composed of magnetically responsive microparticles embedded within a soft polymer matrix, exhibiting an effective shear modulus of up to 100 kPa. In recent decades, MAEs' bulk properties have been successfully exploited for applications such as dynamic vibration damping, vibration sensing, and actuation in soft robotics. Recent research has shifted to their surface properties, revealing promising results on tunable surface features such as roughness, adhesion, and wetting. Even the transport of small solid and fluid objects was demonstrated. The associated surface effects can be significantly enhanced through the precise engineering of surface topography. In this article, an efficient laser micromachining technique, with a resolution of 15 µm, is presented, which enables rapid prototyping of MAE surfaces. It allows the creation of various complex shapes and offers functionality beyond the one achievable with traditional molding techniques. Additionally, the approach is versatile and can be applied to any polymer that sufficiently absorbs the laser light. As an example, a lamellar surface micro-pattern fabrication process and its characterization by optical and scanning electron microscopies are shown. Its response to a magnetic field is demonstrated. The technique provides a flexible and fast solution for optimizing polymer surface design across a wide range of applications.}, language = {en} } @article{GeldofKopačinStrausetal., author = {Geldof, Arne and Kopačin, Jan and Straus, Izidor and Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Jezeršek, Matija and Shamonin, Mikhail and Kokot, Gašper and Drevenšek-Olenik, Irena}, title = {Transfer of Energy and Momentum Between Magnetoactive Surface Microstructure and a Solid Object}, series = {Advanced Engineering Materials}, volume = {28}, journal = {Advanced Engineering Materials}, number = {6}, publisher = {Wiley}, doi = {10.1002/adem.202502369}, pages = {9}, abstract = {Transport systems utilizing magnetic materials are very promising for applications that require contactless operation and compatibility with biological processes. A critical parameter in these systems is the efficiency of energy and momentum transfer between the transporting platform and the objects being transported. We investigate the physical mechanisms driving directional transport of solid objects by microlamellar structures laser-inscribed on the surface of a magnetoactive elastomer (MAE). When subjected to a rotating magnetic field with a magnitude of 175 mT and a time period of 0.4 s, the lamellas reorient within a few milliseconds, reaching angular velocities up to 1100 rad s-1. This rapid motion is crucial for efficient momentum and energy transfer to objects in contact with the lamellas. The analysis of collisions of a single lamella with a lead ball with a 2.2 mm diameter shows that the lamella can transfer around 50 nJ of energy, propelling the ball to a speed of around 35 mm s-1. We show how this value sets the upper limit for the ball's transport speed on microlamellar structures. We also explain the background of three distinct transport regimes (kicking, pushing, and bouncing modes) observed on these magnetically driven "conveyor belts".}, language = {en} } @misc{Kriegl, author = {Kriegl, Raphael}, title = {Sessile droplet fitting (Version v1.0b) [Data set]}, doi = {10.5281/zenodo.7464158}, language = {en} }