@article{ZacherlWopperSchwanzeretal., author = {Zacherl, Florian and Wopper, Christoph and Schwanzer, Peter and Rabl, Hans-Peter}, title = {Potential of the Synthetic Fuel Oxymethylene Ether (OME) for the Usage in a Single-Cylinder Non-Road Diesel Engine: Thermodynamics and Emissions}, series = {Energies}, volume = {15}, journal = {Energies}, number = {21}, publisher = {MDPI}, doi = {10.3390/en15217932}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-55350}, pages = {1 -- 26}, abstract = {Non-road sectors, such as agriculture and construction machinery, require high energy densities and flexibility in use, which is why diesel engines are mainly used. The use of climate-neutral fuels, produced from renewable energies, such as Oxymethylene Ether (OME) as a diesel substitute, can significantly reduce CO2 and pollutant emissions in these sectors. In addition to CO2 neutrality, OME also offers improved combustion characteristics compared to diesel fuel, eliminating the soot-NOx trade-off and thus enabling new opportunities in engine design and calibration. In this paper, the combustion of pure OME on a close-to-production, single-cylinder non-road diesel engine with a pump-line-nozzle injection system is analyzed. A variation of the center of combustion at constant power output was performed for diesel and OME at different operating points. Two injectors were investigated with OME. A study on ignition delay and a detailed thermodynamic analysis was carried out. In addition, the exhaust emissions CO, NOx, VOC, as well as particulate-matter, -number and -size distributions were measured. With OME, a significantly shorter ignition delay as well as a shortened combustion duration could be observed, despite a longer injection duration. In addition, the maximum injection pressure increases. VOC and CO emissions are reduced. Particulate matter was reduced by more than 99\% and particle number (>10 nm) was reduced by multiple orders of magnitude. The median of the particle size distribution shifts from 60 to 85 nm (diesel) into a diameter range of sub 23 nm (OME). A significant reduction of NOx emissions with OME enables new degrees of freedom in engine calibration and an efficiency advantage without hardware adaption.}, language = {en} } @article{KoderSchwanzerZacherletal., author = {Koder, Alexander and Schwanzer, Peter and Zacherl, Florian and Rabl, Hans-Peter and Mayer, Wolfgang and Gruber, Georg and Dotzer, Thomas}, title = {Combustion and emission characteristics of a 2.2L common-rail diesel engine fueled with jatropha oil, soybean oil, and diesel fuel at various EGR-rates}, series = {Fuel}, volume = {228}, journal = {Fuel}, number = {September}, publisher = {Elsevier}, doi = {10.1016/j.fuel.2018.04.147}, pages = {23 -- 29}, abstract = {To investigate the combustion and emission behavior of straight vegetable oils (SVO), jatropha oil, soybean oil, and diesel fuel were tested. For this research, a 2.2L common-rail engine with a two-stage turbocharging concept was equipped with a cylinder pressure indication system, an exhaust-gas analyzer, an AVL Micro Soot sensor and a Scanning Mobility Particle Sizer 3936 (SMPS) device to detect the particle-size-distribution (PSD). At a low and mid-load engine-operating point (EOP), the thermodynamic and emissions were investigated under various exhaust gas recirculation (EGR) rates with respect to the PSD. Moreover, the injection behavior of the three test fuels was analyzed separately using an injection rate analyzer. This procedure facilitates the thermodynamic investigations of the engine process and allows the calculation of the hydraulic delay (HD) as well as the ignition delay (ID). The ID of the SVO fuels compared to diesel fuel was found to be lower at all engine-operating modes, while jatropha oil always showed the shortest ID. In the particulate-nitrogen oxide (NOX) trade-off, the SVO fuels showed higher particulate matter (PM) emissions at the low-load EOP, whereas the PM emissions of diesel fuel overtop the SVO fuels at a higher engine load. With increased EGR-rates, a rise in the particle size was observed for all fuels. At the low-load EOP, the SVO fuels showed larger particles for high EGR-rates. This effect also changed by increasing the engine-load to the mid-load EOP, wherein the particle size of the diesel fuel emissions is higher by applying elevated EGR-rates.}, language = {en} } @article{WalterSchwanzerSteineretal., author = {Walter, Stefanie and Schwanzer, Peter and Steiner, Carsten and Hagen, Gunter and Rabl, Hans-Peter and Dietrich, Markus and Moos, Ralf}, title = {Mixing Rules for an Exact Determination of the Dielectric Properties of Engine Soot Using the Microwave Cavity Perturbation Method and Its Application in Gasoline Particulate Filters}, series = {Sensors}, volume = {22}, journal = {Sensors}, number = {9}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s22093311}, pages = {1 -- 17}, abstract = {In recent years, particulate filters have become mandatory in almost all gasoline-powered vehicles to comply with emission standards regarding particulate number. In contrast to diesel applications, monitoring gasoline particulate filters (GPFs) by differential pressure sensors is challenging due to lower soot masses to be deposited in the GPFs. A different approach to determine the soot loading of GPFs is a radio frequency-based sensor (RF sensor). To facilitate sensor development, in previous work, a simulation model was created to determine the RF signal at arbitrary engine operating points. To ensure accuracy, the exact dielectric properties of the soot need to be known. This work has shown how small samples of soot-loaded filter are sufficient to determine the dielectric properties of soot itself using the microwave cavity perturbation method. For this purpose, mixing rules were determined through simulation and measurement, allowing the air and substrate fraction of the sample to be considered. Due to the different geometry of filter substrates compared to crushed soot samples, a different mixing rule had to be derived to calculate the effective filter properties required for the simulation model. The accuracy of the determined mixing rules and the underlying simulation model could be verified by comparative measurements on an engine test bench.}, language = {en} } @article{SchwanzerRablLodersetal., author = {Schwanzer, Peter and Rabl, Hans-Peter and Loders, S. and Seifert, P. and Himmelstoss, S. and Gaderer, Matthias}, title = {Difference in the Tailpipe Particle Number by Consideration of Sub-23-nm Particles for Different Injection Settings of a GDI Engine}, series = {Emission control science and technology}, volume = {5}, journal = {Emission control science and technology}, number = {1}, publisher = {Springer Nature}, doi = {10.1007/s40825-019-0114-1}, pages = {7 -- 22}, abstract = {The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50\% cutoff (D-50\%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50\%=10 nm and D-50\%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall.}, language = {en} } @article{SchwanzerSchillingerMieslingeretal., author = {Schwanzer, Peter and Schillinger, Maximilian and Mieslinger, Johann and Walter, Stefanie and Hagen, Gunter and Maerkl, Susanne and Haft, Gerhard and Dietrich, Markus and Moos, Ralf and Gaderer, Matthias and Rabl, Hans-Peter}, title = {A Synthetic Ash-Loading Method for Gasoline Particulate Filters with Active Oil Injection}, series = {SAR International Journal of Engines}, volume = {14}, journal = {SAR International Journal of Engines}, number = {4}, publisher = {SAE International}, issn = {1946-3936}, doi = {10.4271/03-14-04-0029}, pages = {493 -- 506}, abstract = {To reduce particulate emissions, the use of particulate filters in diesel engines is meanwhile state of the art, while the integration of such systems in gasoline engines is now also necessary in order to comply with today's regulations. Over its lifetime, a gasoline particulate filter (GPF) collects ash components of fuel, lubrication oil, and materials originating from the catalytic coating and from engine abrasion. In the development and application process, synthetic ashing from GPFs is challenging. The ash of the lubrication oil can be increased in various ways, like oil-doped fuel, a separate oil burner, or changes in the piston-cylinder system of the engine. However, these methods show major disadvantages. For this reason, an improved approach is presented in this study, which allows a quick response to changes in combustion (e.g., engine knocking) and producing ash, which is more realistic due to its primary particle size and the density of ash plugs, in a shorter time. Therefore, an approach to accelerate ash loading by active oil injection using a multi-point injection (MPI) system is introduced. With the help of this methodology, an ashing capacity of 1.21 g/h is implemented, which is a high rate compared to other investigations. The primary particle size (evaluated by means of a transmission electron microscope), is in the same size range as those detected at the full-load curve during regular operation. A computer tomographic (CT) analysis of the incinerated particulate filter also shows that a very high density of ash plugs can be realized, which has also been found in the literature for real applications. In addition, with the help of a mass spectrometer (MS) and an intermediate weighing of the particulate filter, the current ash loading of the GPF could be determined with an accuracy of 1\%.}, language = {en} } @article{BraunDurnerRabletal., author = {Braun, Peter and Durner, Bernhard and Rabl, Hans-Peter and Matysik, Frank-Michael}, title = {Investigations on the decomposition of AdBlue urea in the liquid phase at low temperatures by an electrochemically induced pH shift}, series = {Monatshefte f{\"u}r Chemie}, volume = {150}, journal = {Monatshefte f{\"u}r Chemie}, number = {9}, publisher = {Springer}, doi = {10.1007/s00706-019-02406-6}, pages = {1633 -- 1641}, abstract = {Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface. [GRAPHICS] .}, language = {en} } @article{BraunRablMatysik, author = {Braun, Peter and Rabl, Hans-Peter and Matysik, Frank-Michael}, title = {Investigations on the Liquid-Phase Decomposition of AdBlue Urea for the Selective Catalytic Reduction Process}, series = {Chemie Ingenieur Technik}, volume = {91}, journal = {Chemie Ingenieur Technik}, number = {7}, publisher = {Wiley}, doi = {10.1002/cite.201800055}, pages = {961 -- 968}, abstract = {Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions.}, language = {en} } @article{EmbergerAltmannGebhardetal., author = {Emberger, Peter and Altmann, Robert and Gebhard, J{\"u}rgen and Thuneke, Klaus and Winkler, Markus and T{\"o}pfer, Georg and Rabl, Hans-Peter and Remmele, Edgar}, title = {Combustion characteristics of pure rapeseed oil fuel after injection in a constant volume combustion chamber with a non-road mobile machinery engine solenoid injector}, series = {Fuel}, journal = {Fuel}, number = {320}, publisher = {Elsevier}, doi = {10.1016/j.fuel.2022.123979}, abstract = {Pure rapeseed oil fuel (R100) according to standard DIN 51605 is a greenhouse gas saving option for the mobility sector. With its high energy density close to diesel fuel, R100 is suitable to operate non-road mobile machinery with a high power demand and long operating time, where electric drives reach their limits. Advantages are indicated for its use in environmentally sensitive areas like agriculture since R100 is highly biodegradable and non-toxic. However, R100 is characterised by differing physical and chemical properties compared to diesel. The objective of the research is to investigate the differences in the ignition and combustion behaviour of R100 compared to diesel fuel (DF). For this purpose, a constant volume combustion chamber is used, which is equipped with a modern solenoid injector for engines of non-road mobile machinery. The researched injector shows a different hydraulic behaviour when using R100 compared to DF in that the injected fuel mass is lower with R100 than with DF. In combination with the 14 \% by mass lower calorific value, less energy output is determined with R100. When varying the injection pressure, the impact on the ignition delay and combustion behaviour is much higher for R100 than for DF. Specifically, an increase of the injection pressure supports mixture preparation and thus partially compensates the differing physical properties of R100. The results of ignition delay measurements and net heat release analysis are as follows: At low load conditions with low injection pressure as well as a low combustion chamber temperature and pressure, R100 ignites later and shows a further delayed combustion compared to diesel. The opposite is observed for medium and high load conditions, where R100 ignites faster and without delayed combustion in comparison to DF. Thus, an adjustment of the heat release of R100 at the same level as for DF is possible by modifying the injection strategy. The research shows that for an optimised combustion of R100 the injection settings must be adjusted for every operation point separately. The results indicate how the injection parameters should be adjusted for different load conditions to realise a high-quality engine calibration for R100.}, language = {en} } @article{BrockKoderRabletal., author = {Brock, Damian and Koder, Alexander and Rabl, Hans-Peter and Touraud, Didier and Kunz, Werner}, title = {Optimising the biodiesel production process: Implementation of glycerol derivatives into biofuel formulations and their potential to form hydrofuels}, series = {Fuel}, volume = {264}, journal = {Fuel}, number = {March}, publisher = {Elsevier}, doi = {10.1016/j.fuel.2019.116695}, abstract = {A new biofuel concept is developed, enabling the usage of vegetable oils and glycerol derivatives in mixtures with biodiesel. This concept significantly enhances the biodiesel production's profitability and thus strongly contributes to the sustainability of future biofuels. After simple addition reactions with building block chemicals, less hydrophilic glycerol derivatives are obtained, which are compatible with biofuels. Even more, the products of the reactions of glycerol with acetone or butyric acid, referred to as solketal and tributyrin, respectively, lead to promising biofuels in mixtures with rapeseed oil and its biodiesel. Due to their low freezing points, they act as cloud and freezing point depressants, when added to vegetable oil/biodiesel blends. Further, since their viscosity is close to common biodiesel, biofuels containing high amounts of vegetable oil and even more glycerol derivatives than they arise during the biodiesel production can be obtained. Thus, this new class of biofuels enables adaptable compositions depending on the application and also the usage as drop-in fuel without any or just few percent of further additives. After optimising the formulations, ignition delay, exhaust gas recirculation, fuel consumption and combustion process measurements were performed in an unmodified upto-date diesel engine. The experiments showed that the properties of the formulated biofuels are either similar to or even better than diesel. The hydrotropy of the glycerol derivatives in these mixtures enables the potential to implement water into biofuels, so-called hydrofuels, reducing nitrogen oxide emissions and leading to further optimised dropin fuels.}, language = {en} } @article{WalterSchwanzerHagenetal., author = {Walter, Stefanie and Schwanzer, Peter and Hagen, Gunter and Haft, Gerhard and Rabl, Hans-Peter and Dietrich, Markus and Moos, Ralf}, title = {Modelling the Influence of Different Soot Types on the Radio-Frequency-Based Load Detection of Gasoline Particulate Filters}, series = {Sensors}, volume = {20}, journal = {Sensors}, number = {9}, publisher = {MDPI}, doi = {10.3390/s20092659}, pages = {1 -- 19}, abstract = {Gasoline particulate filters (GPFs) are an appropriate means to meet today's emission standards. As for diesel applications, GPFs can be monitored via differential pressure sensors or using a radio-frequency approach (RF sensor). Due to largely differing soot properties and engine operating modes of gasoline compared to diesel engines (e.g., the possibility of incomplete regenerations), the behavior of both sensor systems must be investigated in detail. For this purpose, extensive measurements on engine test benches are usually required. To simplify the sensor development, a simulation model was developed using COMSOL Multiphysics((R)) that not only allowed for calculating the loading and regeneration process of GPFs under different engine operating conditions but also determined the impact on both sensor systems. To simulate the regeneration behavior of gasoline soot accurately, an oxidation model was developed. To identify the influence of different engine operating points on the sensor behavior, various samples generated at an engine test bench were examined regarding their kinetic parameters using thermogravimetric analysis. Thus, this compared the accuracy of soot mass determination using the RF sensor with the differential pressure method. By simulating a typical driving condition with incomplete regenerations, the effects of the soot kinetics on sensor accuracy was demonstrated exemplarily. Thereby, the RF sensor showed an overall smaller mass determination error, as well as a lower dependence on the soot kinetics.}, language = {en} } @article{KasparRablMayer, author = {Kaspar, Marcel and Rabl, Hans-Peter and Mayer, Wolfgang}, title = {Ion-Molecule Reaction for the Selective Detection of Hydrocarbons in Diesel Exhaust Gas}, series = {Chemie Ingenieur Technik}, volume = {90}, journal = {Chemie Ingenieur Technik}, number = {6}, publisher = {WILEY-VCH}, doi = {10.1002/cite.201700075}, pages = {826 -- 834}, abstract = {The hydrocarbons present in the diesel exhaust gas are analyzed. A mass spectrometer is used for the measurements, and it operates on the basis of an ion-molecule reaction. This method is especially suitable because it is selective, is as free of fragments as possible, and is highly sensitive to the species that need to be measured. The study shows that numerous hydrocarbons in diesel exhaust gas can be identified. In particular, three molecules, ethyne, ethene and propene, were analyzed online in-depth on an engine test bench under different engine operating conditions.}, language = {en} } @article{BraunGebhardMatysiketal., author = {Braun, Peter and Gebhard, J{\"u}rgen and Matysik, Frank-Michael and Rabl, Hans-Peter}, title = {Potential Technical Approaches for Improving Low-Temperature NOx Conversion of Exhaust Aftertreatment Systems}, series = {Chemie Ingenieur Technik}, volume = {90}, journal = {Chemie Ingenieur Technik}, number = {6}, publisher = {WILEY-VCH}, doi = {10.1002/cite.201700122}, pages = {762 -- 773}, abstract = {Lean-burn engines, such as diesel engines, are widely used in mobile and stationary applications. Operation of lean-burn engines leads to formation of distinct amounts of nitrogen oxides (NO and NO2). Efficient aftertreatment is mandatory to meet legal requirements, especially at low exhaust temperatures, as for the future a decline of the exhaust temperature level can be predicted due to improved engine efficiencies. Within this review, potential technical solutions to enhance the DeNO(x)-aftertreatment efficiency at low exhaust temperatures are presented.}, language = {en} } @article{GaertnerRablZink, author = {G{\"a}rtner, Uwe and Rabl, Hans-Peter and Zink, Uwe}, title = {Exhaust Gas Aftertreatment of the Future}, series = {MTZ worldwide}, volume = {79}, journal = {MTZ worldwide}, number = {7-8}, publisher = {Springer}, doi = {10.1007/s38313-018-0060-2}, pages = {70 -- 75}, language = {en} }