@misc{RueckBierlLechneretal., author = {R{\"u}ck, Thomas and Bierl, Rudolf and Lechner, Alfred and Graf, Antonia and Dams, Florian and Schreiner, Rupert and Auchter, Eberhard and Kriz, Willy and Deubzer, MIchael and Schiller, Frank and Mottok, J{\"u}rgen and Niemetz, Michael and Margull, Ulrich and Hagel, Georg and Utesch, Matthias and Waldherr, Franz and B{\"o}hm, Matthias and Fraunhoffer, Judith and Gardeia, Armin and Schneider, Ralph and Streubel, Janet and Landes, Dieter and Studt, Reimer and Peuker, Dominik and Scharfenberg, Georg and Hook, Christian and Schuster, Dietwald and Ehrlich, Ingo and Dinnebier, Heinrich and Briem, Ulrich and L{\"a}mmlein, Stephan and Koder, Alexander and Bialek, Adam and Genewsky, Axel and Neumeier, Michael and Schlosser, Philipp and Rabl, Hans-Peter and Paule, Matthias and Galster, Christoph and Schiedermeier, Michael and Zwickel, Andreas and Hobmeier, Christoph and Bischoff, Tobias and Rill, Georg and Schaeffer, Thomas and Arbesmeier, Martin and Groß, Andreas and Schlegl, Thomas and Becker, Mark and Senn, Konrad and Schliekmann, Claus and Scholz, Peter and Sippl, Christian and Grill, Martin}, title = {Forschungsbericht 2011 / Hochschule f{\"u}r Angewandte Wissenschaften - Fachhochschule Regensburg}, editor = {Eckstein, Josef}, address = {Regensburg}, organization = {Hochschule f{\"u}r Angewandte Wissenschaften Regensburg}, issn = {1868-3533}, doi = {10.35096/othr/pub-732}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-7321}, language = {de} } @article{PangerlMuellerRuecketal., author = {Pangerl, Jonas and M{\"u}ller, Max and R{\"u}ck, Thomas and Weigl, Stefan and Bierl, Rudolf}, title = {Characterizing a sensitive compact mid-infrared photoacoustic sensor for methane, ethane and acetylene detection considering changing ambient parameters and bulk composition (N2, O2 and H2O)}, series = {Sensors and Actuators B: Chemical}, volume = {352,1}, journal = {Sensors and Actuators B: Chemical}, publisher = {Elsevier}, doi = {10.1016/j.snb.2021.130962}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-25868}, pages = {1 -- 12}, abstract = {We present a sensitive and compact interband cascade laser (ICL) based photoacoustic setup for the detection of gaseous hydrocarbons and discuss its applicability towards trace gas analysis. We investigated the performance of the sensor for trace concentrations of methane, ethane and acetylene diluted in nitrogen. The excitation of methane and ethane was accomplished using one tunable diode laser, covering a range from 3360 to 3372 nm, which was replaced by a separate ICL at 3025 nm for acetylene detection. The influence of ambient parameters such as temperature, flow rate and pressure as well as potential cross-sensitivities towards O2 and H2O have been examined in terms of methane and acetylene detection. A series of simulations proved several of these influences to be attributed to relaxation effects. With a 3σ limit of detection (LoD) of 6.8 parts per billion (ppbV) in case of methane, 2.3 ppbV regarding ethane and 3.6 ppbV in terms of acetylene, the sensor demonstrates a great potential for applications in the field of trace gas analysis.}, language = {en} } @article{MuellerRueckJobstetal., author = {M{\"u}ller, Max and R{\"u}ck, Thomas and Jobst, Simon and Pangerl, Jonas and Weigl, Stefan and Bierl, Rudolf and Matysik, Frank-Michael}, title = {An Algorithmic Approach to Compute the Effect of Non-Radiative Relaxation Processes in Photoacoustic Spectroscopy}, series = {Photoacoustics}, volume = {26}, journal = {Photoacoustics}, publisher = {Elsevier}, doi = {10.1016/j.pacs.2022.100371}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-39935}, abstract = {Successful transfer of photoacoustic gas sensors from laboratory to real-life applications requires knowledge about potential cross-sensitivities towards environmental and gas matrix changes. Multi-dimensional calibration in case of cross-sensitivities can become very complex or even unfeasible. To address this challenge, we present a novel algorithm to compute the collision based non-radiative efficiency and phase lag of energy relaxation on a molecular level (CoNRad) for photoacoustic signal calculation. This algorithmic approach allows to calculate the entire elaxation cascade of arbitrarily complex systems, yielding a theoretical photoacoustic signal. In this work the influence of varying bulk compositions, i.e. nitrogen (N2), oxygen (O2) and water (H2O) on the photoacoustic signal during methane (CH4) detection is demonstrated. The applicability of the algorithm to other photoacoustic setups is shown exemplary by applying it to the relaxational system investigated in [1]. Hayden et al. examined the effect of water on photoacoustic carbon monoxide (CO) detection.}, language = {en} } @misc{RueckHofmannBierl, author = {R{\"u}ck, Thomas and Hofmann, Matthias and Bierl, Rudolf}, title = {Development of a miniaturized photoacoustic multigas sensing system for trace gas measurement}, series = {17th International Conference on Photoacoustic and Photothermal Phenomena, Oct. 20-24, 2013, Suzhou China}, journal = {17th International Conference on Photoacoustic and Photothermal Phenomena, Oct. 20-24, 2013, Suzhou China}, language = {en} } @misc{RueckMatysikBierl, author = {R{\"u}ck, Thomas and Matysik, Frank-Michael and Bierl, Rudolf}, title = {Development of a miniaturized photoacoustic multigas sensing system for trace gas measurement}, series = {analytica conference 2014, 1. bis 4. April, M{\"u}nchen}, journal = {analytica conference 2014, 1. bis 4. April, M{\"u}nchen}, language = {en} } @misc{RueckMatysikBierl, author = {R{\"u}ck, Thomas and Matysik, Frank-Michael and Bierl, Rudolf}, title = {Comparison of acoustic detectors for use in miniaturized photoacoustic devices designed for nitrogen dioxide trace gas measurement}, series = {ANAKON, 23.-26.3.2015, Graz}, journal = {ANAKON, 23.-26.3.2015, Graz}, language = {en} } @article{PangerlSukulRuecketal., author = {Pangerl, Jonas and Sukul, Pritam and R{\"u}ck, Thomas and Fuchs, Patricia and Weigl, Stefan and Miekisch, Wolfram and Bierl, Rudolf and Matysik, Frank-Michael}, title = {An inexpensive UV-LED photoacoustic based real-time sensor-system detecting exhaled trace-acetone}, series = {Photoacoustics}, volume = {38}, journal = {Photoacoustics}, publisher = {Elsevier}, issn = {2213-5979}, doi = {10.1016/j.pacs.2024.100604}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-71279}, pages = {12}, abstract = {n this research we present a low-cost system for breath acetone analysis based on UV-LED photoacoustic spectroscopy. We considered the end-tidal phase of exhalation, which represents the systemic concentrations of volatile organic compounds (VOCs) - providing clinically relevant information about the human health. This is achieved via the development of a CO2-triggered breath sampling system, which collected alveolar breath over several minutes in sterile and inert containers. A real-time mass spectrometer is coupled to serve as a reference device for calibration measurements and subsequent breath analysis. The new sensor system provided a 3σ detection limit of 8.3 ppbV and an NNEA of 1.4E-9 Wcm 1Hz 0.5. In terms of the performed breath analysis measurements, 12 out of 13 fell within the error margin of the photoacoustic measurement system, demonstrating the reliability of the measurements in the field.}, language = {en} } @article{EscherRueckJobstetal., author = {Escher, Lukas and R{\"u}ck, Thomas and Jobst, Simon and Pangerl, Jonas and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Photodissociation-Driven Photoacoustic Spectroscopy with UV-LEDs for Ozone Detection}, series = {Photoacoustics}, volume = {43}, journal = {Photoacoustics}, publisher = {Elsevier BV}, issn = {2213-5979}, doi = {10.1016/j.pacs.2025.100718}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-80076}, pages = {16}, abstract = {This study presents the development and evaluation of a UV-LED based photoacoustic (PA) measurement system for ozone (O3) detection to demonstrate its potential for low-cost and accurate sensing while for the first time addressing the importance of photodissociation for PA signal generation for O3 in the UV range. With a detection limit of 7.9 ppbV, the system exhibits a significant advancement over state-of-the-art UV-PA O3 detection and is on par with laser-based setups. Following a novel discussion of the PA signal arising from photodissociation and its products, cross-sensitivity effects due to environmental factors such as temperature and gas composition were systematically analyzed. A digital twin driven compensation for these influences was implemented and evaluated. Despite the challenges associated with modeling the effects of H2O and CO2, the PA system shows considerable potential, though further studies in real world applications must be conducted.}, language = {en} } @article{WeiglWittmannRuecketal., author = {Weigl, Stefan and Wittmann, Elisabeth and R{\"u}ck, Thomas and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Effects of ambient parameters and cross-sensitivities from O2, CO2 and H2O on the photoacoustic detection of acetone in the UV region}, series = {Sensors Actuators B Chemical}, journal = {Sensors Actuators B Chemical}, number = {328}, publisher = {Elsevier}, issn = {0925-4005}, doi = {10.1016/j.snb.2020.129001}, abstract = {We present a sensitive UV LED photoacoustic setup for the detection of gaseous acetone and discuss its applicability towards breath analysis. We investigated the performance of the sensor for low acetone concentrations down to 0.1 parts per million (ppmV). The influences of temperature, flow, pressure, optical power and LED duty cycle on the measured signal have been examined. To gain a better understanding of the different effects on the photoacoustic signal, correlation analysis was applied and feature importance was determined using a large measured dataset. Furthermore, the cross-sensitivities towards O2, CO2 and H2O have been studied extensively. Finally, the sensor's performance to detect acetone between 0.1-1 ppmV within gas mixtures simulating breath exhale conditions has been investigated, too. With a limit of detection (LoD) of 12.5 parts per billion (ppbV) (3σ) measured under typical breath exhale gas mixture conditions, the sensor demonstrated a high potential for the application of acetone detection in human breath analysis.}, language = {en} } @unpublished{PangerlSukulRuecketal., author = {Pangerl, Jonas and Sukul, Pritam and R{\"u}ck, Thomas and Fuchs, Patricia and Weigl, Stefan and Miekisch, Wolfram and Bierl, Rudolf and Matysik, Frank-Michael}, title = {An Inexpensive Uv-Led Photoacoustic Based Real-Time Sensor-System Detecting Exhaled Trace-Acetone}, publisher = {Elsevier}, doi = {10.2139/ssrn.4724198}, abstract = {In this research we present a low-cost system for breath acetone analysis based on UV-LED photoacoustic spectroscopy. We considered the end-tidal phase of exhalation, which represents the systemic concentrations of volatile organic compounds (VOCs) - providing clinically relevant information about the human health. This is achieved via the development of a CO2-triggered breath sampling system, which collected alveolar breath over several minutes in sterile and inert containers. A real-time mass spectrometer is coupled to serve as a reference device for calibration measurements and subsequent breath analysis. The new sensor system provided a 3σ detection limit of 6.4 ppbV and an NNEA of 1.1E-9 Wcm-1Hz-0.5. In terms of the performed breath analysis measurements, 12 out of 13 fell within the error margin of the photoacoustic measurement system, demonstrating the reliability of the measurements in the field.}, language = {en} } @article{RueckBierlMatysik, author = {R{\"u}ck, Thomas and Bierl, Rudolf and Matysik, Frank-Michael}, title = {NO2 trace gas monitoring in air using off-beam quartz enhanced photoacoustic spectroscopy (QEPAS) and interference studies towards CO2, H2O and acoustic noise}, series = {Sensors and Actuators B: Chemical}, volume = {255}, journal = {Sensors and Actuators B: Chemical}, number = {Part 3, February}, publisher = {Elsevier}, doi = {10.1016/j.snb.2017.09.039}, pages = {2462 -- 2471}, abstract = {We present the development and characterization as well as comprehensive interference studies of a photoacoustic NO2 trace gas detection system. The system is based on an off-beam quartz enhanced photoacoustic scheme (off-beam QEPAS) and signal generation was initiated by amplitude modulating a low-cost diode laser emitting at 450 nm. The QEPAS sensor element features double-resonant amplification, still it is only ∼ 5 × 5 × 2.5 mm in size. The individual and combined resonance characteristics were investigated and specified to 52 dB amplification, adding up 15 dB acoustic- and 37 dB mechanical-resonance amplification. The linearity of the photoacoustic signal dependency on the analyte concentration was verified from 200 ppbV to 100 ppmV NO2 in synthetic air. The detection limit (3σ) was determined to 1.8 ppbV using a lock-in time constant of 10 s and an averaging time of 20 s. The normalized noise equivalent absorption coefficient was specified to 2.5·10-8 W cm-1 Hz-0.5. The stability of the signal was investigated over time and a slight drift by 1 per mille was observed after 30 min without temperature stabilizing the photoacoustic cell (PAC). Noise analysis was performed by means of Allan deviation and the inverse dependency of response time and precision of the system on the lock-in time constant was outlined. We performed interference analyses towards N2, O2, CO2, H2O and acoustic noise, respectively. Although neither spectral interferences nor losses due to slow NO2 VT-relaxation were observed, O2 was identified to cause a 15\% signal drop due to VVNO2-O2-relaxation. Changing H2O concentrations were found to cause acoustic detuning, which cannot be compensated by adjusting the frequency of modulation, because of the double-resonant feature of the PAC. However, alternative approaches of compensation were discussed. Finally, we carried out heavy traffic noise simulations and determined the QEPAS setup to be 46 times less susceptible towards ambient noise compared to standard microphone-based photoacoustic setups.}, language = {en} }