@article{PremSindersbergerMonkman, author = {Prem, Nina and Sindersberger, Dirk and Monkman, Gareth J.}, title = {Infrared spectral analysis of low concentration magnetoactive polymers}, series = {Journal of Applied Polymer Science}, volume = {137}, journal = {Journal of Applied Polymer Science}, number = {7}, publisher = {Wiley}, organization = {WILEY}, issn = {1097-4628}, doi = {10.1002/app.48366}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-25913}, pages = {1 -- 7}, abstract = {This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt\%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt\%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt\% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366.}, language = {en} } @article{SindersbergerPremMonkman, author = {Sindersberger, Dirk and Prem, Nina and Monkman, Gareth J.}, title = {Self-assembling structure formation in low-density magnetoactive polymers}, series = {Journal of Applied Polymer Science}, volume = {137}, journal = {Journal of Applied Polymer Science}, number = {3}, publisher = {Wiley}, doi = {10.1002/app.48291}, abstract = {The formation of microstructures in magnetoactive polymers (MAPs) is a recently discovered phenomenon found only with very low filler particle concentrations (less than 3 wt \%). Due to the degassing process, filler particles collect around an ascending bubble, which dissolves at a certain point leaving particulate rings within the matrix. The formation of toroidal microstructures commences as filler concentration approaches 1 wt \%. The development of coherent parallel aligned rings with a compact order continues as particle concentrations increase toward 2 wt \%. Between 2 and 3 wt \% capillary doublets develop, while mass percentages higher than 3\% result in increasing entropy as the random order of particle agglomeration found in higher concentration MAP dominates. Self-structured samples of different filler material and concentrations between 1 and 3 wt \% have been investigated using X-ray tomography, where the emerging structures can be observed and visualized. The ring structures resulting from this research represent microinductivities which can be fabricated in a targeted manner, thus enabling new applications in the high-frequency radio field. Furthermore, these anisotropic, but well-organized, structures have magnetic field-dependent implications for optical, thermal, acoustic, and medical applications.}, language = {en} }