@inproceedings{KusterleThumann, author = {Kusterle, Wolfgang and Thumann, Maria}, title = {Pumpability of wet mixsprayed concrete with reduced clinker content}, series = {8th International Symposium on Sprayed Concrete : Modern Use of Wet Mix Sprayed Concrete for Underground Support, 11.- 14.06.2018, Trondheim, Norwegen}, booktitle = {8th International Symposium on Sprayed Concrete : Modern Use of Wet Mix Sprayed Concrete for Underground Support, 11.- 14.06.2018, Trondheim, Norwegen}, editor = {Beck, Thomas and Myren, Synn{\o}ve A. and Engen, Siri}, isbn = {978-82-8208-060-6}, abstract = {The research project „Advanced and Sustainable Shotcrete - ASSpC" aims at the improvement of sprayed concrete mix design regarding durability and sustainability. One possible improvement is to replace part of the clinker content in the binder with different supplementary cementitious materials. It is crucial that new mix designs fulfil the basic technical requirements on site concerning workability and early age development, too. One central issue of the project is to investigate which parameters influence the pumpability of sprayed concrete. Several test methods are used to determine the stability, tendency to segregation, bleeding and of course the consistency of concrete. An essential test method is a concrete sliding pipe rheometer (Sliper). This rheometer determines the pumping characteristics of concrete in the laboratory and on construction site. In comparison to other rheometers, the Sliper evaluates the rheological characteristics of the thin layer of paste which is lubricating the wall of the convey ing pipe. The paper presents the tests procedures in detail as well as first results from lab-tests and from site-tests with different advanced shotcrete mix-designs .}, language = {en} } @inproceedings{ThumannKusterle, author = {Thumann, Maria and Kusterle, Wolfgang}, title = {Durable and Sustainable Shotcrete - Requirements Concerning Workability and Early Strength Development}, series = {Shotcrete for Underground Support XIII : New Developments in Rock Engineering, Tunneling, Underground Space and Deep Excavation [Conference Sept. 3-6, 2017]}, booktitle = {Shotcrete for Underground Support XIII : New Developments in Rock Engineering, Tunneling, Underground Space and Deep Excavation [Conference Sept. 3-6, 2017]}, editor = {M{\"a}hner, Dietmar and Beisler, Matthias and Heimbecher, Frank}, abstract = {Nowadays there is a special need to develop "new" construction materials to reduce the environmental footprint of structures. Investigations focus on durability of constructions and the use of sustainable materials and the reduction of CO2 emission (especially of the binder). Constructions have to be sustainable and durable. This will lead to low maintenance work and costs as well as a good life cycle performance. The aim of the Austrian research project „Advanced and Sustainable Shotcrete - ASSpC" is to improve shotcrete mix design regarding durability and sustainability. There are different ways which may lead to success, one possibility is to replace part of the clinker content in the binder with supplementary cementitious materials. But it is crucial that new mix designs fulfil the technical requirements on site concerning workability and early age strength development, too. One central issue of the research project is to investigate how the pumpability of shotcrete can be determined in lab. At the moment there is no proven method available to measure the pumpability of shotcrete. Several test methods are used to determine the stability, tendency to segregation, bleeding and of course the consistency of concrete. Common test methods like the spread flow table and V-funnel flow time are used as well as two point test methods like the concrete rheometer eBT2 and Sliper. The segregation tendency is evaluated by the filter pressing test and the bucket setting test. Results from lab will be compared to results from site to define threshold values and parameters which describe the pumping characteristics of shotcrete base mix. In addition to that the early age strength development of the shotcrete mix design is investigated with the Minishot System designed by Sika. The shotcrete system is downscaled to a mini spray unit. In opposite to common test methods it is not necessary to mix the accelerator into the cement paste or mortar, but it will be added at the nozzle. The paste is sprayed by a downscaled nozzle and thus a realistic shear stress can be achieved. The paste is applied to a pulsment ultrasound spectrometer and the shear modulus development is measured continuously over time. The results can be linked to the strength development of shotcrete. The paper presents the tests procedures mentioned above in detail as well as first results with different shotcrete mix-designs.}, language = {en} } @inproceedings{ThumannKusterle, author = {Thumann, Maria and Kusterle, Wolfgang}, title = {Enhanced durability of shotcrete - Reduced potential for precipitations}, series = {Proceedings of the 11th fib International PhD Symposium in Civil Engineering. - 29.-31.08.2016, Tokyo, Japan}, booktitle = {Proceedings of the 11th fib International PhD Symposium in Civil Engineering. - 29.-31.08.2016, Tokyo, Japan}, editor = {Maekawa, Koichi and Kasuga, Akio and Yamazaki, Jun}, publisher = {Technical University of Tokyo}, isbn = {978-4-9909148-0-6}, pages = {221 -- 228}, abstract = {The contact of underground water with shotcrete leads to leaching of calcium hydroxide and can increase the precipitation of calcite in the secondary drainage system of tunnels under certain conditions. Indeed precipitations in the drainage pipes lead to high maintenance costs. Within a research project the leaching behavior of new and innovative binder compositions was tested in lab tests. One possible change in mix-design is the reduction in clinker content by using a lower amount of Ordinary Portland Cement together with cementitious materials. Successful combinations were further investigated in sprayed mortar and shotcrete tests to examine the influences of the spraying process and the addition of accelerator. The results indicate how shotcrete mix-design can be improved regarding its potential for precipitations and subsequently enhanced durability of shotcrete.}, language = {en} } @inproceedings{ThumannBriendlJuhartetal., author = {Thumann, Maria and Briendl, Lukas G. and Juhart, Joachim and Kusterle, Wolfgang}, title = {Rheologische Untersuchungen an Frischbetonmischungen f{\"u}r Spritzbeton}, series = {Rheologische Messungen an Baustoffen 2019 : Tagungsband zum 28. Workshop und Kolloquium, 13. und 14. M{\"a}rz an der OTH Regensburg}, booktitle = {Rheologische Messungen an Baustoffen 2019 : Tagungsband zum 28. Workshop und Kolloquium, 13. und 14. M{\"a}rz an der OTH Regensburg}, editor = {Teubert, Oliver and Kusterle, Wolfgang and Greim, Markus}, publisher = {tredition}, address = {Hamburg}, isbn = {978-3-7482-4651-0}, pages = {95 ff.}, language = {de} } @inproceedings{SteindlMittermayrThumannetal., author = {Steindl, F. and Mittermayr, Florian and Thumann, Maria and Juhart, Joachim and Galan Garcia, Isabel and Baldermann, Andre and Briendl, Lukas G. and Sakoparnig, Marlene and R{\"o}ck, Rudolf and Kusterle, Wolfgang}, title = {Sulfate resistance of dry mix shotcretes with new binder composition}, series = {ICCC 2019: 15th International Congress on the Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, booktitle = {ICCC 2019: 15th International Congress on the Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, pages = {3527 -- 3872}, abstract = {Improved understanding of the mechanisms underlying deleterious chemical attacks is necessary to better predict the long-term performance and durability of shotcrete in aggressive environments. In the scope of the research project "ASSpC - Advanced and Sustainable Sprayed Concrete", new durable and sustainable shotcretes and new test methods are developed. In order to increase shotcrete durability, the spray cement (specified in Austrian Guideline "Sprayed concrete") used is substituted with supplementary cementitious materials (SCMs). However, in the past SCMs have seen only limited use in the application of dry-mix shotcrete. This contribution presents 6 new mix designs intended to be used for dry-mix shotcrete, each with varying amounts and types of SCMs, and compares their performance and sprayability with a commercially available spray cement. As sulfate attack is one of the major threats to shotcrete (e.g. in tunnelling), the resistance of the new mixes against sulfate attack is tested using a modified version of the Swiss sulfate test according to SIA 262/1:2013. This approach provides new insights into damaging mechanisms of dry mix shotcrete in sulfate-loaded environments}, language = {en} } @inproceedings{BaldermannMittermayrThumannetal., author = {Baldermann, Andre and Mittermayr, Florian and Thumann, Maria and Kusterle, Wolfgang}, title = {Development of shotcrete with increased durability against thaumasite sulfate attack}, series = {ICCC 2019: 15th International Congress on Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, booktitle = {ICCC 2019: 15th International Congress on Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, pages = {3425 -- 3435}, language = {en} } @inproceedings{SakoparnigGalanBaldermanetal., author = {Sakoparnig, Marlene and Galan, Isabel and Balderman, Andre and Steindl, Florian and Dietzel, Martin and Thumann, Maria and Saxer, Andreas and Kusterle, Wolfgang and Mittermayr, Florian}, title = {Experimental Ca leaching of shotcrete \& secondary precipitation}, series = {ICCC 2019: 15th International Congress on the Chemistry of Cement, ICCC 2019, 16.-20.09.2019, Prague, Czech Republik}, booktitle = {ICCC 2019: 15th International Congress on the Chemistry of Cement, ICCC 2019, 16.-20.09.2019, Prague, Czech Republik}, pages = {3488 -- 3495}, language = {en} } @inproceedings{BriendlGalanSteindletal., author = {Briendl, Lukas G. and Galan, Isabel and Steindl, Florian and R{\"o}ck, Rudolf and Thumann, Maria and Juhart, Joachim and Baldermann, Andre and Mittermayr, Florian and Kusterle, Wolfgang}, title = {Hydration processes of accelerated cementitious systems governing early strength development}, series = {ICCC 2019: 15th International Congress on Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, booktitle = {ICCC 2019: 15th International Congress on Chemistry of Cement, 16.-20.09.2019, Prague, Czech Republik}, pages = {714 -- 724}, language = {en} } @inproceedings{JuhartBriendlRoecketal., author = {Juhart, Joachim and Briendl, Lukas G. and R{\"o}ck, Rudolf and Galan, Isabel and Thumann, Maria and Mittermayr, Florian and Kusterle, Wolfgang}, title = {Performance optimization of shotcrete by combined fillers}, series = {ICCC 2019: 15th International Congress on the Chemistry of Cement, ICCC 2019, 16.-20.09.2019, Prague, Czech Republik}, booktitle = {ICCC 2019: 15th International Congress on the Chemistry of Cement, ICCC 2019, 16.-20.09.2019, Prague, Czech Republik}, pages = {1387 -- 3872}, language = {en} } @inproceedings{SakoparnigBaldermannThumannetal., author = {Sakoparnig, Marlene and Baldermann, Andre and Thumann, Maria and Mittermayr, Florian and Kusterle, Wolfgang}, title = {Bestimmung der experimentellen Calcium-Auslaugung an Spritzbetonbohrkernen: Methodenvergleich und Update}, series = {Spritzbeton-Tagung 2018, Alpbach, {\"O}sterreich 11.-12.01.2018}, booktitle = {Spritzbeton-Tagung 2018, Alpbach, {\"O}sterreich 11.-12.01.2018}, abstract = {Im Rahmen des FFG-Forschungsprojektes „Entwicklung neuer dauerhafter und nachhaltiger Spritzbetone (Advanced and sustainable sprayed concrete; ASSpC)" werden Methoden zur Pr{\"u}fung der Calcium-Auslaugung von Spritzbeton eingesetzt bzw. weiterentwickelt. Bestimmt wurde daf{\"u}r das Reduzierte Versinterungspotential nach Regelwerken der {\"O}sterreichischen Bautechnik Vereinigung und das Auslaugverhalten von Spritzbeton bei leichtem S{\"a}ureangriff (Salpeters{\"a}ure und Kohlens{\"a}ure), um dauerhaftigkeitsrelevante Parameter im Bereich der Wechselwirkungen von Spritzbeton mit leicht sauren (Kohlens{\"a}ure- und Nitrathaltigen) Oberfl{\"a}chen-, Grund- und Sickerw{\"a}ssern zu untersuchen und potentielle Sch{\"a}digungsmechanismen zu identifizieren und zu quantifizieren. Die Vor- und Nachteile der verwendeten Pr{\"u}fmethoden zum l{\"o}senden Angriff werden in Bezug auf die Dauerhaftigkeit von Spritzbeton diskutiert.}, language = {de} } @inproceedings{KusterleThumannMittermayr, author = {Kusterle, Wolfgang and Thumann, Maria and Mittermayr, Florian}, title = {ASSpC - Ein Forschungsprogramm f{\"u}r den Spritzbeton von morgen}, series = {Tagungs-CD der Spritzbeton-Tagung 2018, 11.-12. Januar 2018, Alpbach, Tirol, CD-ROM}, booktitle = {Tagungs-CD der Spritzbeton-Tagung 2018, 11.-12. Januar 2018, Alpbach, Tirol, CD-ROM}, abstract = {Spritzbeton wird im Tunnelbau als tempor{\"a}re und permanente St{\"u}tz- und Ausbaumaßnahme eingesetzt. Mit der Einf{\"u}hrung der alkalifreien Spritzbeton-Technologie wurde um 2004 ein großer Qualit{\"a}tssprung erzielt. Trotzdem besteht noch Optimierungsbedarf. Alle Bauwerke sollten heute nachhaltig und dauerhaft erstellt werden. Spritzbeton sollte daher aus m{\"o}glichst umweltneutralen Stoffen hergestellt werden und auch in aggressiver Umgebung dauerhaft, ohne ung{\"u}nstige Auswirkungen auf das Gesamtbauwerk, seine Aufgaben erf{\"u}llen. Das kann nur mit optimierten Rezepturen unter Einsatz ausgew{\"a}hlter Ausgangsstoffe realisiert werden. Das von der FFG in {\"O}sterreich gef{\"o}rderte Forschungsprogramm „Entwicklung neuer dauerhafter und nachhaltiger Spritzbetone" (Advanced and Sustainable Sprayed Concrete) setzt genau hier an.}, language = {de} } @inproceedings{MittermayrThumannBaldermannetal., author = {Mittermayr, Florian and Thumann, Maria and Baldermann, Andre and Lindlar, Benedikt and Stenger, Christian and Huber, Helmut and Bauer, Eric and Scheutz, Rudolf and Kusterle, Wolfgang}, title = {Instandsetzung Bosruck-Eisenbahntunnel:Entwicklung von Spritzbeton mit erh{\"o}htem Widerstand gegen Thaumasit-Sulfatangriff}, series = {Spritzbeton-Tagung 2018. Alpbach, Tirol, 11. und 12. Januar 2018. Tagungsbeitr{\"a}ge. CD-ROM}, booktitle = {Spritzbeton-Tagung 2018. Alpbach, Tirol, 11. und 12. Januar 2018. Tagungsbeitr{\"a}ge. CD-ROM}, address = {Oberperfuss}, abstract = {Im Bosruck-Eisenbahntunnel kam es in Folge v on intensivem Sulfatangriff durch Thaumasitbildungen zu erheblichen Betonsch{\"a}den. Bisher sieht das Regelwerk ({\"O}NORM B 4710-1 und {\"O}VBB-RL Spritzbeton) bei Sulfatangriff den Einsatz von C 3A-freien Bindemitteln vor - dies gilt auch f{\"u}r Spritzbeton. Untersuchungen haben gezeigt, dass C 3A-freier Zement keinen wesentlich verbesserten Widerstand gegen den Thaumasit-Sulfatangriff aufweist. Im Zuge der Tunnelinstandsetzung war es das vorrangige Ziel, Spritzbeton mit erh{\"o}htem Widerstand gegen Thaumasit-Sulfatangriff und ausreichender Fr{\"u}hfestigkeit zu entwickeln. In diesem Beitrag werden neu entwickelte Mischungsans{\"a}tze und deren Umsetzung im Labormaßstab vorgestellt. Die mechanischen Kennwerte dieser Rezeptur (z.B. Fr{\"u}hfestigkeitsentwicklung) sowie die Ergebnisse der Dauerhaftigkeitsuntersuchungen zeigen, dass eine Rezeptur mit optimiertem Bindemittelgehalt die hohen Anforderungen im Tunnel erf{\"u}llen kann. Die Erfahrungen aus der praktischen Umsetzung im Zuge der Instandsetzungsarbeiten des Bosruck-Eisenbahntunnels im Jahre 2016 waren positiv.}, language = {de} } @inproceedings{GalanGarciaStauffacherMittermayretal., author = {Galan Garcia, Isabel and Stauffacher, Anina and Mittermayr, Florian and Thumann, Maria and Kusterle, Wolfgang and Juilland, Patrick and Stenger, Christian and Lindlar, Benedikt}, title = {Estudio de las reacciones de hidrataci{\´o}n temprana en el hormig{\´o}n proyectado}, series = {HAC2018 - V Congreso Iberoamericano de Hormig{\´o}n Autocompactable y Hormigones Especiales ; Valencia 05.03.2018 - 06.03.2018}, booktitle = {HAC2018 - V Congreso Iberoamericano de Hormig{\´o}n Autocompactable y Hormigones Especiales ; Valencia 05.03.2018 - 06.03.2018}, publisher = {Universitat Polit{\`e}cnica Val{\`e}ncia}, isbn = {9788490485910}, doi = {10.4995/hac2018.2018.6907}, abstract = {El hormig{\´o}n proyectado es un tipo de hormig{\´o}n especial utilizado como soporte de rocas durante la construcci{\´o}n de t{\´u}neles y excavaci{\´o}n de minas, entre otras aplicaciones. Las principales caracter{\´i}sticas de este tipo de hormig{\´o}n son el fraguado r{\´a}pido y el desarrollo de una muy alta resistencia mec{\´a}nica a edades tempranas, lo cual permite que el hormig{\´o}n se fije a la base sin necesidad de un soporte extra, endureci{\´e}ndose en pocos minutos. Las reacciones de hidrataci{\´o}n que ocurren en las primeras horas en el hormig{\´o}n proyectado determinan el desarrollo de las propiedades mec{\´a}nicas y su estudio es de crucial importancia para entender y optimizar el comportamiento de este tipo de hormigones. El estudio de estas reacciones, sin embargo, resulta relativamente complicado por varias razones: (i) el hormig{\´o}n proyectado endurece muy r{\´a}pido, lo cual dificulta su manejo durante los ensayos experimentales, y (ii) composiciones similares mezcladas en el laboratorio no se comportan de forma similar a las proyectadas. En este trabajo se presenta una metodolog{\´i}a experimental desarrollada para el estudio de las reacciones de hidrataci{\´o}n que ocurren en el hormig{\´o}n proyectado durante las primeras horas y su correlaci{\´o}n con la resistencia mec{\´a}nica.}, language = {es} } @inproceedings{GalanThumannBriendletal.2018, author = {Galan, Isabel and Thumann, Maria and Briendl, Lukas G. and R{\"o}ck, Rudolf and Steindl, Florian and Juhart, Joachim and Mittermayr, Florian and Kusterle, Wolfgang}, title = {From Lab Scale Spraying to Real Scale Shotcreting and back to the Lab}, series = {8th International Symposium on Sprayed Concrete : Modern Use of Wet Mix Sprayed Concrete for Underground Support - Trondheim, Norwegen. - 11. - 14.06.2018}, booktitle = {8th International Symposium on Sprayed Concrete : Modern Use of Wet Mix Sprayed Concrete for Underground Support - Trondheim, Norwegen. - 11. - 14.06.2018}, editor = {Beck, Thomas and Myren, Synn{\o}ve A. and Engen, Siri}, isbn = {978-82-8208-060-6}, pages = {139 -- 153}, year = {2018}, abstract = {Before new mixes are sprayed in real scale applications, lab experiments have to be carried out to provide a basis for predicting a good performance in real scale. In many cases, to understand the correlations between the behavior in the lab and in real scale spraying, a further set of experiments after the real spraying is required. In this paper we present such a two way process for two new wet mixes, one with a very low tricalcium aluminate Portland cement and the other one with a CEM I with addition of ultra-fine calcite. Calorimetry and Shear-Modulus measurements were used in the lab to monitor hydration evolution. In the real scale spraying compressive strength was measured at periodic intervals up to 24 hours. The hydration of the sprayed samples was stopped at 3, 6 and 24 hours and samples were scanned with X-ray for the identification and quantification of the phases present. The results presented are used to discuss the extent to which lab experiments can predict the behavior of mixes in real scale and how small changes in the raw materials and the mixes can lead to quite different results.}, language = {en} } @inproceedings{StauffacherGalanJuillandetal., author = {Stauffacher, Anina and Galan, Isabel and Juilland, Patrick and Thumann, Maria and Stenger, Christian and Baldermann, Andre and Mittermayr, Florian and Lindlar, Benedikt and Kusterle, Wolfgang}, title = {Einfluss von H{\"u}ttensand und ultrafeinem Kalksteinmehl auf die Hydratation von jungem Spritzbeton}, series = {Spritzbeton-Tagung 2018, Alpbach, Tirol, 11. und 12. Januar 2018. Tagungsbeitr{\"a}ge. CD-ROM}, booktitle = {Spritzbeton-Tagung 2018, Alpbach, Tirol, 11. und 12. Januar 2018. Tagungsbeitr{\"a}ge. CD-ROM}, editor = {Kusterle, Wolfgang}, address = {Oberperfuss}, subject = {Spritzbeton}, language = {de} } @inproceedings{JuhartBriendlMittermayretal., author = {Juhart, Joachim and Briendl, Lukas G. and Mittermayr, Florian and Thumann, Maria and R{\"o}ck, Rudolf and Kusterle, Wolfgang}, title = {Optimierte Eigenschaften von Spritzbeton durch kombinierte Zusatzstoffe}, series = {Tagungs-CD der Spritzbeton-Tagung 2018, 11.-12. Januar 2018, Alpbach, Tirol, CD-ROM}, booktitle = {Tagungs-CD der Spritzbeton-Tagung 2018, 11.-12. Januar 2018, Alpbach, Tirol, CD-ROM}, language = {de} } @inproceedings{ThumannJuhartRoecketal., author = {Thumann, Maria and Juhart, Joachim and R{\"o}ck, Rudolf and Saxer, Andreas and Galan, Isabel and Mittermayr, Florian and Kusterle, Wolfgang}, title = {Entwicklung neuer, dauerhafter und nachhaltiger Spritzbetone}, series = {Kolloquium Forschung \& Entwicklung f{\"u}r Zement und Beton 2018}, booktitle = {Kolloquium Forschung \& Entwicklung f{\"u}r Zement und Beton 2018}, pages = {65 -- 69}, language = {de} } @inproceedings{JuhartBriendlMittermayretal., author = {Juhart, Joachim and Briendl, Lukas G. and Mittermayr, Florian and R{\"o}ck, Rudolf and Thumann, Maria and Kusterle, Wolfgang}, title = {Mischungsentwicklung von nachhaltigem Spritzbeton mit kombinierten Zusatzstoffen}, series = {Beton Graz '18 : 4. Grazer Betonkolloquium : 20./21. September 2018}, booktitle = {Beton Graz '18 : 4. Grazer Betonkolloquium : 20./21. September 2018}, publisher = {Verlag der Technischen Universit{\"a}t Graz}, address = {Graz}, isbn = {978-3-85125-621-5}, pages = {139 -- 152}, abstract = {Spritzbeton ist nachhaltig, wenn er sowohl umweltfreundlich als auch dauerhaft ist. Traditionelle Mischungszusammensetzungen f{\"u}r Spritzbeton enthalten einen hohen Anteil an fein gemahlenem Portlandzement und an Erstarrungsbeschleunigern. Beide Komponenten sind f{\"u}r eine sehr schnelle Festigkeitsentwicklung, aber auch hohe Umweltauswirkungen (wie CO2-Emissionen, Prim{\"a}renergiebedarf) verantwortlich. Portlandzement ist ein hervorragendes Bindemittel, bringt aber ein hohes Versinterungspotenzial und bei normaler Zusammensetzung einen geringen Widerstand gegen chemischen Angriff, wie zum Beispiel den Sulfatangriff aus dem Bergwasser, mit sich. Hingegen k{\"o}nnen latent hydraulische und puzzolanische Zusatzstoffe die Dauerhaftigkeit erh{\"o}hen, sind aber auch f{\"u}r eine langsame Festigkeitsentwicklung bekannt. Im Beitrag wird ein neues Konzept des Mischungsentwurfs vorgestellt, das auf der Auswahl geeigneter Zusatzstoffe (i.e. feinste Kalksteinmehle, die die Hydratation beschleunigen, kombiniert mit gemahlenem H{\"u}ttensand und Puzzolanen), der Optimierung von Packungsdichte und Wasserbedarf sowie einem optimalen Mischungsverh{\"a}ltnis aller Feinstoffe beruht. Es wird an exemplarischen Mischungszusammensetzungen gezeigt, welche Eigenschaften bzw. Leistungsmerkmale in Labortests sowie in großmaßst{\"a}blichen Spritzversuchen erreicht werden k{\"o}nnen.}, language = {de} }