@article{GamischHuberGadereretal., author = {Gamisch, Bernd and Huber, Lea and Gaderer, Matthias and Dawoud, Belal}, title = {On the Kinetic Mechanisms of the Reduction and Oxidation Reactions of Iron Oxide/Iron Pellets for a Hydrogen Storage Process}, series = {Energies}, volume = {15}, journal = {Energies}, number = {21}, publisher = {MDPI}, doi = {10.3390/en15218322}, abstract = {This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90\% Fe2O3, 10\% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions' kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5\%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71\% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.}, language = {en} } @article{HuberHeindlSchlosseretal., author = {Huber, Lea and Heindl, Melanie and Schlosser, Marc and Pfitzner, Arno and Dawoud, Belal}, title = {On the Cycle Stability and Macroscopic Structure of Iron Oxide Pellets for Thermochemical Hydrogen Storage: Influence of Water Content during the Pelletizing Process}, series = {Applied Sciences}, volume = {13}, journal = {Applied Sciences}, number = {11}, publisher = {MDPI}, address = {16}, doi = {10.3390/app13116408}, abstract = {Hydrogen storage based on the repeated reduction and oxidation (redox) reactions of iron oxide/iron composites represents a promising technology. This work is dedicated to studying the influence of the amount of water added during the pelletizing process on the cycle stability and structure of iron oxide pellets. The storage composites were prepared from iron oxide (Fe2O3) and 10 wt.-\% support material (cement) with different amounts of water (18 and 33 wt.-\%) in a laboratory-scale pelletizing disk. To evaluate the cycle stability of the composites, the kinetics of the redox reactions were experimentally measured at 800 ∘ C in an atmosphere of 50\% N2 and 50\% H2 (reduction) or 50\% steam (oxidation), respectively. Moreover, the structure of the pellets was analyzed by micro-computed tomography scans. It turned out that pellets with higher water contents attained faster kinetics and a higher cycle stability. The sample with the least water content (18 wt.-\%) needed about 26 min and 19 min to reach a conversion rate of 80\% during the reduction and oxidation reactions of the sixth redox cycle, respectively. In contrast, the sample with the highest water content (33 wt.-\%) could achieve the same conversion rate after 18 min (reduction) and 13 min (oxidation) during the ninth redox cycle.}, language = {en} }