@article{SorokinStepanovShamoninChamonineetal., author = {Sorokin, Vladislav V. and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail and Monkman, Gareth J. and Khokhlov, Alexei R. and Kramarenko, Elena Yu}, title = {Hysteresis of the viscoelastic properties and the normal force in magnetically and mechanically soft magnetoactive elastomers: Effects of filler composition, strain amplitude and magnetic field}, series = {Polymer}, volume = {76}, journal = {Polymer}, publisher = {Elsevier}, doi = {10.1016/j.polymer.2015.08.040}, pages = {191 -- 202}, abstract = {Hysteresis in dynamic modulus, loss factor and normal forces of magnetoactive elastomers (MAEs) comprising various proportions of small (3-5 mu m) and large (50-60 mu m) ferromagnetic particles are experimentally studied using dynamic torsion performed at a fixed oscillation frequency in varying DC magnetic fields. It is shown that hysteresis is a characteristic feature of MAEs observed both under increasing/decreasing magnetic field strength and increasing/decreasing strain amplitude. This hysteresis is attributed to the specific rearrangement of the magnetic filler network under simultaneously applied magnetic field and shear deformation. Rheological properties of the magnetic filler network formed in the magnetic field and, therefore, the rheological properties of MAEs depend strongly on the filler composition and the magnetic field magnitude. Larger magnetic particles and higher magnetic fields provide stronger magnetic networks. Both factors result in the extension of the linear viscoelastic regime to larger strain amplitudes and lead to higher values of shear storage and loss moduli. It is found that the hysteresis width maximises at an intermediate magnetic field where it is attributed to the balance between elastic and magnetic particle interactions. This is apparently where the most significant restructuring of the magnetic network occurs. The hysteresis width decreases with increasing fraction of large particles in the magnetic filler. The loss factor grows significantly when the magnetic network is physically broken by large strains gamma > 1\%. A huge (more than one order of magnitude) increase of normal force at maximum magnetic field strengths is observed. It is predicted that any physical quantity depending on the internal structuring of the magnetic filler should demonstrate hysteresis either with a changing magnetic field and constant deformation amplitude or under variable deformation in a constant magnetic field. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{KostrovShamoninChamonineStepanovetal., author = {Kostrov, Sergei A. and Shamonin (Chamonine), Mikhail and Stepanov, Gennady V. and Kramarenko, Elena Yu}, title = {Magnetodielectric Response of Soft Magnetoactive Elastomers: Effects of Filler Concentration and Measurement Frequency}, series = {International Journal of Molecular Sciences}, volume = {20}, journal = {International Journal of Molecular Sciences}, number = {9}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/ijms20092230}, pages = {1 -- 13}, abstract = {The magnetodielectric response of magnetoactive elastomers (MAEs) in its dependence on filler concentration, magnetic field, and test frequency is studied experimentally. MAEs are synthesized on the basis of a silicone matrix filled with spherical carbonyl iron particles characterized by a mean diameter of 4.5 mu m. The concentration of the magnetic filler within composite materials is equal to 70, 75, and 80 mass\%. The effective lossless permittivity epsilon as well as the dielectric loss tan grow significantly when the magnetic field increases. The permittivity increases and the dielectric loss decreases with increasing filler concentration. In the measurement frequency range between 1 kHz and 200 kHz, the frequency hardly affects the values of epsilon and tan in the absence of a magnetic field. However, both parameters decrease considerably with the growing frequency in a constant magnetic field. The more strongly the magnetic field is applied, the larger the change in permittivity and loss tangent at the same test frequency is observed. An equivalent circuit formulation qualitatively describes the main tendencies of the magnetodielectric response.}, language = {en} } @article{SorokinEckerStepanovetal., author = {Sorokin, Vladislav V. and Ecker, Eva and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail and Monkman, Gareth J. and Kramarenko, Elena Yu and Khokhlov, Alexei R.}, title = {Experimental study of the magnetic field enhanced Payne effect in magnetorheological elastomers}, series = {Soft Matter}, volume = {10}, journal = {Soft Matter}, number = {43}, publisher = {ROYAL Society of CHEMISTRY}, doi = {10.1039/c4sm01738b}, pages = {8765 -- 8776}, abstract = {The dynamic modulus and the loss factor of magnetorheological elastomers (MREs) of various compositions and anisotropies are studied by dynamic torsion oscillations performed in the absence and in the presence of an external magnetic field. The emphasis is on the Payne effect, i.e. the dependence of the elastomer magnetorheological characteristics on the strain amplitude and their evolution with cyclically increasing and decreasing strain amplitudes. MREs are based on two silicone matrices differing in storage modulus (soft, G' similar to 10(3) Pa, and hard, G' similar to 10(4) Pa, matrices). For each matrix, the concentration of carbonyl iron particles with diameters of 3-5 mu m was equal to 70 and 82 mass\% (22 and 35 vol\%, respectively) in the composite material. Samples for each filler content, isotropic and aligned-particles, are investigated. It is found that the Payne effect significantly increases in the presence of an external magnetic field and varies with the cyclical loading which reaches saturation after several cycles. The results are interpreted as the processes of formation-destruction-reformation of the internal filler structure under the simultaneously applied mechanical force and magnetic field. Impacts of matrix elasticity and magnetic interactions on the filler alignment are elucidated.}, language = {en} } @incollection{ShamoninChamonineKramarenko, author = {Shamonin (Chamonine), Mikhail and Kramarenko, Elena Yu}, title = {Highly Responsive Magnetoactive Elastomers (Chapter 7)}, series = {Novel Magnetic Nanostructures}, booktitle = {Novel Magnetic Nanostructures}, editor = {Domracheva, Natalia and Caporali, Maria and Rentschler, Eva}, publisher = {Elsevier}, isbn = {9780128135945}, doi = {10.1016/B978-0-12-813594-5.00007-2}, pages = {221 -- 245}, abstract = {This chapter introduces composite smart materials known as magnetoactive (MAEs) or magnetorheological elastomers. It starts by defining these materials and distinguishing them from relevant magnetorheological fluids and ferrofluids. It then gives the overview of constitutive materials for the polymer matrix and filler particles. Next, the influence of external magnetic field on physical properties of MAEs is discussed. The emphasis is made on mechanical properties, which are the most important for real-world applications. In particular, magnetomechanical effects such as magnetostriction, magnetodeformation, and magnetorheological effect are discussed. The magnetic Payne effect is presented as an example of a nonlinear behavior. Electromagnetic and acoustic properties are also considered. The chapter finishes with the brief discussion of the future prospects in research and development of MAEs.}, language = {en} } @article{SorokinStepanovShamoninChamonineetal., author = {Sorokin, Vladislav V. and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail and Monkman, Gareth J. and Kramarenko, Elena Yu}, title = {Magnetorheological behavior of magnetoactive elastomers filled with bimodal iron and magnetite particles}, series = {Smart materials and structures}, volume = {26}, journal = {Smart materials and structures}, number = {3}, publisher = {IOP Publishing}, doi = {10.1088/1361-665X/26/3/035019}, abstract = {Magnetoactive elastomers (MAE) based on soft silicone matrices, filled with various proportions of large diameter ( approximately 50 mu m) iron and small diameter ( approximately 0.5 mu m) magnetite particles are synthesized. Their rheological behavior in homogeneous magnetic fields up to 600 mT is studied in detail. The addition of small magnetite particles facilitates fabrication of uniformly distributed magnetic elastomer composites by preventing aggregation and sedimentation of large particles during curing. It is shown that using the proposed bimodal filler particles it is possible to tailor various magnetorheological (MR) properties which can be useful for different target applications. In particular, either absolute or relative magnetorheological effects can be tuned. The value of the damping factor as well as the range of deformation amplitudes for the linear viscoelastic regime can be chosen. The interdependencies between different MR properties of bimodal MAEs are considered. The results are discussed in the model framework of particle network formation under the simultaneous influence of external magnetic fields and mechanical deformation.}, language = {en} } @article{NadzharyanShamoninChamonineKramarenko, author = {Nadzharyan, Timur A. and Shamonin (Chamonine), Mikhail and Kramarenko, Elena Yu}, title = {Theoretical Modeling of Magnetoactive Elastomers on Different Scales: A State-of-the-Art Review}, series = {Polymers}, volume = {14}, journal = {Polymers}, number = {19}, publisher = {MDPI}, doi = {10.3390/polym14194096}, pages = {1 -- 42}, abstract = {A review of the latest theoretical advances in the description of magnetomechanical effects and phenomena observed in magnetoactive elastomers (MAEs), i.e., polymer networks filled with magnetic micro- and/or nanoparticles, under the action of external magnetic fields is presented. Theoretical modeling of magnetomechanical coupling is considered on various spatial scales: from the behavior of individual magnetic particles constrained in an elastic medium to the mechanical properties of an MAE sample as a whole. It is demonstrated how theoretical models enable qualitative and quantitative interpretation of experimental results. The limitations and challenges of current approaches are discussed and some information about the most promising lines of research in this area is provided. The review is aimed at specialists involved in the study of not only the magnetomechanical properties of MAEs, but also a wide range of other physical phenomena occurring in magnetic polymer composites in external magnetic fields.}, language = {en} } @article{BelyaevaKramarenkoStepanovetal., author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Stepanov, Gennady V. and Sorokin, Vladislav V. and Stadler, Dominik and Shamonin (Chamonine), Mikhail}, title = {Transient magnetorheological response of magnetoactive elastomers to step and pyramid excitations}, series = {SOFT MATTER}, volume = {12}, journal = {SOFT MATTER}, number = {11}, publisher = {ROYAL SOC CHEMISTRY}, doi = {10.1039/c5sm02690c}, pages = {2901 -- 2913}, abstract = {Transient rheological response of magnetoactive elastomers is experimentally studied using dynamic torsion at a fixed oscillation frequency in temporally stepwise changing magnetic fields and oscillation amplitudes. For step magnetic-field excitations, at least three exponential functions are required to reasonably describe the time behavior of the storage shear modulus over long time scales (>10(3) s). The deduced characteristic time constants of the corresponding rearrangement processes of the filler network differ approximately by one order of magnitude: tau(1) less than or similar to 10(1) s, tau(2) similar to 10(2) s, and tau(3) similar to 10(3) s. The sudden imposition of the external magnetic field activates a very fast rearrangement process with the characteristic time under 10 s, which cannot be determined more precisely due to the measurement conditions. Even more peculiar transient behavior has been observed during pyramid excitations, when either the external magnetic field was first stepwise increased and then decreased in a staircase manner at a fixed strain amplitude gamma or the strain amplitude gamma was first stepwise increased and then decreased in a staircase manner at a fixed magnetic field. In particular, the so-called "cross-over effect'' has been identified in both dynamical loading programs. This cross-over effect seems to be promoted by the application of the external magnetic field. The experimental results are discussed in the context of the specific rearrangement of the magnetic filler network under the simultaneous action of the external magnetic field and shear deformation. Striking similarities of the observed phenomena to the structural relaxation processes in glassy materials and to the jamming transition of granular materials are pointed out. The obtained results are important for fundamental understanding of material behavior in magnetic fields as well as for the development of devices on the basis of magnetoactive elastomeric materials.}, language = {en} } @article{BelyaevaKramarenkoShamoninChamonine, author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Shamonin (Chamonine), Mikhail}, title = {Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis}, series = {POLYMER}, volume = {127}, journal = {POLYMER}, publisher = {ELSEVIER}, doi = {10.1016/j.polymer.2017.08.056}, pages = {119 -- 128}, abstract = {Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000\%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SorokinBelyaevaShamoninChamonineetal., author = {Sorokin, Vladislav V. and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail and Kramarenko, Elena Yu}, title = {Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale?}, series = {Physical Review E}, volume = {95}, journal = {Physical Review E}, number = {6}, publisher = {Amer Physical Soc}, doi = {10.1103/PhysRevE.95.062501}, abstract = {The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass \% of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles.}, language = {en} } @misc{SorokinStepanovVasilievetal., author = {Sorokin, Vladislav V. and Stepanov, Gennady V. and Vasiliev, V. G. and Kramarenko, Elena Yu and Mayer, Matthias and Shamonin (Chamonine), Mikhail and Monkman, Gareth J.}, title = {Investigation of Dynamic Modulus and Normal Force of Magnetorheological Elastomers with Soft and Hard Magnetic Fillers}, series = {NANO 2014, July 13 - 18, 2014, Moscow ; Section 06 - Polymer, Organic and Other Soft Matter Materials}, journal = {NANO 2014, July 13 - 18, 2014, Moscow ; Section 06 - Polymer, Organic and Other Soft Matter Materials}, address = {Moscow}, language = {en} } @article{RomeisKostrovKramarenkoetal., author = {Romeis, Dirk and Kostrov, Sergei A. and Kramarenko, Elena Yu and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail and Saphiannikova, Marina}, title = {Magnetic-field-induced stress in confined magnetoactive elastomers}, series = {Soft Matter}, volume = {16}, journal = {Soft Matter}, number = {39}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, doi = {10.1039/D0SM01337D}, pages = {9047 -- 9058}, abstract = {We present a theoretical approach for calculating the state of stress induced by a uniform magnetic field in confined magnetoactive elastomers of arbitrary shape. The theory explicitly includes the magnetic field generated by magnetizable spherical inclusions in the sample interior assuming a non-linear magnetization behavior. The initial spatial distribution of particles and its change in an external magnetic field are considered. This is achieved by the introduction of an effective demagnetizing factor where both the sample shape and the material microstructure are taken into account. Theoretical predictions are fitted to the stress data measured using a specifically designed experimental setup. It is shown that the theory enables the quantification of the effect of material microstructure upon introducing a specific microstructural factor and its derivative with respect to the extensional strain in the undeformed state. The experimentally observed differences between isotropic and anisotropic samples, compliant and stiff elastomer matrices are explained.}, language = {en} } @article{SavelevBelyaevaChashinetal., author = {Savelev, Dmitrii V. and Belyaeva, Inna A. and Chashin, Dmitri V. and Fetisov, Leonid Y. and Romeis, Dirk and Kettl, Wolfgang and Kramarenko, Elena Yu and Saphiannikova, Marina and Stepanov, Gennady V. and Shamonin (Chamonine), Mikhail}, title = {Giant extensional strain of magnetoactive elastomeric cylinders in uniform magnetic fields}, series = {Materials}, volume = {13}, journal = {Materials}, number = {15}, publisher = {MDPI}, address = {Basel}, issn = {1996-1944}, doi = {10.3390/ma13153297}, pages = {1 -- 17}, abstract = {Elongations of magnetoactive elastomers (MAEs) under ascending-descending uniform magnetic fields were studied experimentally using a laboratory apparatus specifically designed to measure large extensional strains (up to 20\%) in compliant MAEs. In the literature, such a phenomenon is usually denoted as giant magnetostriction. The synthesized cylindrical MAE samples were based on polydimethylsiloxane matrices filled with micrometer-sized particles of carbonyl iron. The impact of both the macroscopic shape factor of the samples and their magneto-mechanical characteristics were evaluated. For this purpose, the aspect ratio of the MAE cylindrical samples, the concentration of magnetic particles in MAEs and the effective shear modulus were systematically varied. It was shown that the magnetically induced elongation of MAE cylinders in the maximum magnetic field of about 400 kA/m, applied along the cylinder axis, grew with the increasing aspect ratio. The effect of the sample composition is discussed in terms of magnetic filler rearrangements in magnetic fields and the observed experimental tendencies are rationalized by simple theoretical estimates. The obtained results can be used for the design of new smart materials with magnetic-field-controlled deformation properties, e.g., for soft robotics.}, language = {en} }