@article{KovalevBelyaevavonHofenetal., author = {Kovalev, Alexander and Belyaeva, Inna A. and von Hofen, Christian and Gorb, Stanislav and Shamonin (Chamonine), Mikhail}, title = {Magnetically Switchable Adhesion and Friction of Soft Magnetoactive Elastomers}, series = {Advanced Engineering Materials}, volume = {24}, journal = {Advanced Engineering Materials}, number = {10}, publisher = {WILEY-VCH}, doi = {10.1002/adem.202200372}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-45283}, pages = {1 -- 8}, abstract = {Herein, the effect of an applied moderate (~240 mT) magnetic field on the work of adhesion (WoA) of mechanically soft (the shear modulus ~10 kPa) magnetoactive elastomer (MAE) samples with two different mass fractions (70 and 80 wt\%) of carbonyl iron powder (CIP) is concerned. The unfilled elastomer sample is used for comparison. Due to some sedimentation of filling particles, the concentration of inclusions in thin (~10 μm) subsurface layers is different. It is shown that the WoA increases (up to 1.8-fold) on the particle-enriched side (PES) in the magnetic field and its value is higher for higher filler concentration. On the particle-depleted side (PDS), WoA does not depend on particle concentration and on the magnetic field. Adhesion and friction are coupled in MAEs. No statistically significant difference in the friction coefficient, determined from the extended Amontons´ law, depending on sample side, CIP concentration, or presence of magnetic field is found. However, the PDS in the magnetic field demonstrates significantly higher critical shear stress compared to that for the PES or PDS in the absence of magnetic field. Correlations between different surface properties are discussed. Obtained results are useful for the development of magnetically controllable soft robots.}, language = {en} } @article{BelyaevaKramarenkoStepanovetal., author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Stepanov, Gennady V. and Sorokin, Vladislav V. and Stadler, Dominik and Shamonin (Chamonine), Mikhail}, title = {Transient magnetorheological response of magnetoactive elastomers to step and pyramid excitations}, series = {SOFT MATTER}, volume = {12}, journal = {SOFT MATTER}, number = {11}, publisher = {ROYAL SOC CHEMISTRY}, doi = {10.1039/c5sm02690c}, pages = {2901 -- 2913}, abstract = {Transient rheological response of magnetoactive elastomers is experimentally studied using dynamic torsion at a fixed oscillation frequency in temporally stepwise changing magnetic fields and oscillation amplitudes. For step magnetic-field excitations, at least three exponential functions are required to reasonably describe the time behavior of the storage shear modulus over long time scales (>10(3) s). The deduced characteristic time constants of the corresponding rearrangement processes of the filler network differ approximately by one order of magnitude: tau(1) less than or similar to 10(1) s, tau(2) similar to 10(2) s, and tau(3) similar to 10(3) s. The sudden imposition of the external magnetic field activates a very fast rearrangement process with the characteristic time under 10 s, which cannot be determined more precisely due to the measurement conditions. Even more peculiar transient behavior has been observed during pyramid excitations, when either the external magnetic field was first stepwise increased and then decreased in a staircase manner at a fixed strain amplitude gamma or the strain amplitude gamma was first stepwise increased and then decreased in a staircase manner at a fixed magnetic field. In particular, the so-called "cross-over effect'' has been identified in both dynamical loading programs. This cross-over effect seems to be promoted by the application of the external magnetic field. The experimental results are discussed in the context of the specific rearrangement of the magnetic filler network under the simultaneous action of the external magnetic field and shear deformation. Striking similarities of the observed phenomena to the structural relaxation processes in glassy materials and to the jamming transition of granular materials are pointed out. The obtained results are important for fundamental understanding of material behavior in magnetic fields as well as for the development of devices on the basis of magnetoactive elastomeric materials.}, language = {en} } @article{BelyaevaKramarenkoShamoninChamonine, author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Shamonin (Chamonine), Mikhail}, title = {Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis}, series = {POLYMER}, volume = {127}, journal = {POLYMER}, publisher = {ELSEVIER}, doi = {10.1016/j.polymer.2017.08.056}, pages = {119 -- 128}, abstract = {Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000\%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SorokinBelyaevaShamoninChamonineetal., author = {Sorokin, Vladislav V. and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail and Kramarenko, Elena Yu}, title = {Magnetorheological response of highly filled magnetoactive elastomers from perspective of mechanical energy density: Fractal aggregates above the nanometer scale?}, series = {Physical Review E}, volume = {95}, journal = {Physical Review E}, number = {6}, publisher = {Amer Physical Soc}, doi = {10.1103/PhysRevE.95.062501}, abstract = {The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass \% of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles.}, language = {en} } @article{BelyaevaKleppLemmeletal., author = {Belyaeva, Inna A. and Klepp, J{\"u}rgen and Lemmel, Hartmut and Shamonin (Chamonine), Mikhail}, title = {Feasibility of Probing the Filler Restructuring in Magnetoactive Elastomers by Ultra-Small-Angle Neutron Scattering}, series = {Applied Sciences}, volume = {11}, journal = {Applied Sciences}, number = {10}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/app11104470}, pages = {1 -- 9}, abstract = {Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 x 10(-5) and 1.85 x 10(-4) angstrom(-1). It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered.}, language = {en} } @article{GlavanBelyaevaShamoninChamonine, author = {Glavan, Gašper and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail}, title = {On the Piezomagnetism of Magnetoactive Elastomeric Cylinders in Uniform Magnetic Fields: Height Modulation in the Vicinity of an Operating Point by Time-Harmonic Fields}, series = {Polymers}, volume = {16}, journal = {Polymers}, number = {19}, doi = {10.3390/polym16192706}, abstract = {Soft magnetoactive elastomers (MAEs) are currently considered to be promising materials for actuators in soft robotics. Magnetically controlled actuators often operate in the vicinity of a bias point. Their dynamic properties can be characterized by the piezomagnetic strain coefficient, which is a ratio of the time-harmonic strain amplitude to the corresponding magnetic field strength. Herein, the dynamic strain response of a family of MAE cylinders to the time-harmonic (frequency of 0.1-2.5 Hz) magnetic fields of varying amplitude (12.5 kA/m-62.5 kA/m), superimposed on different bias magnetic fields (25-127 kA/m), is systematically investigated for the first time. Strain measurements are based on optical imaging with sub-pixel resolution. It is found that the dynamic strain response of MAEs is considerably different from that in conventional magnetostrictive polymer composites (MPCs), and it cannot be described by the effective piezomagnetic constant from the quasi-static measurements. The obtained maximum values of the piezomagnetic strain coefficient (∼102 nm/A) are one to two orders of magnitude higher than in conventional MPCs, but there is a significant phase lag (35-60°) in the magnetostrictive response with respect to an alternating magnetic field. The experimental dependencies of the characteristics of the alternating strain on the amplitude of the alternating field, bias field, oscillation frequency, and aspect ratio of cylinders are given for several representative examples. It is hypothesized that the main cause of observed peculiarities is the non-linear viscoelasticity of these composite materials.}, language = {en} } @article{GlavanSalamonBelyaevaetal., author = {Glavan, Gašper and Salamon, Peter and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena}, title = {Tunable surface roughness and wettability of a soft magnetoactive elastomer}, series = {Journal of applied polymer science}, volume = {135}, journal = {Journal of applied polymer science}, number = {18}, publisher = {Wiley}, doi = {10.1002/app.46221}, abstract = {Surface topographical modifications of a soft magnetoactive elastomer (MAE) in response to variable applied magnetic field are investigated. The analysis is performed in situ and is based on optical microscopy, spread optical reflection and optical profilometry measurements. Optical profilometry analysis shows that the responsivity of magnetic field-induced surface roughness with respect to external magnetic field is in the range of 1 mu m/T. A significant hysteresis of surface modifications takes place for increasing and decreasing fields. Investigations of shape of sessile water droplets deposited on the MAE surface reveal that field-induced topographical modifications affect the contact angle of water at the surface. This effect is reversible and the responsivity to magnetic field is in the range of 20 degrees/T. Despite the increased surface roughness, the apparent contact angle decreases with increasing field, which is attributed to the field-induced protrusion of hydrophilic microparticles from the surface layer.}, language = {en} } @article{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Laser Micromachining of Magnetoactive Elastomers as Enabling Technology for Magnetoresponsive Surfaces}, series = {Advanced Materials Technologies}, volume = {7}, journal = {Advanced Materials Technologies}, number = {5}, publisher = {Wiley}, doi = {10.1002/admt.202101045}, pages = {1 -- 8}, abstract = {A simple method for structuring of the surface of a magnetoactive elastomer (MAE) on the tens of micrometers scale, which capabilities extend beyond conventional mold-based polymer casting, is reported. The method relies on the ablation of the material by absorption of nanosecond infrared pulses from a commercial laser. It is shown that it is possible to fabricate parallel lamellar structures with a high aspect ratio (up to 6:1) as well as structures with complex scanning trajectories. The method is fast (fabrication time for the 7 × 7 mm2 is about 60 s), and the results are highly reproducible. To illustrate the capabilities of the fabrication method, both orthogonal to the MAE surface and tilted lamellar structures are fabricated. These magnetosensitive lamellae can be easily bent by ±45° using an external magnetic field of about 230 mT. It is demonstrated that this bending allows one to control the sliding angle of water droplets in a great range between a sticky (>90°) and a sliding state (<20°). Perspectives on employing this fabrication technology for magnetosensitive smart surfaces in microfluidic devices and soft robotics are discussed.}, language = {en} } @article{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Jezeršek, Matija and Shamonin (Chamonine), Mikhail}, title = {Tunable Drop Splashing on Magnetoactive Elastomers}, series = {Advanced Materials Interfaces}, volume = {8}, journal = {Advanced Materials Interfaces}, number = {11}, publisher = {Wiley}, doi = {10.1002/admi.202100235}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-24504}, pages = {1 -- 7}, abstract = {The significant effect of an external dc magnetic field on the splashing behavior of ethanol drops impacting on the unstructured (flat) surface of soft magnetoactive elastomers (MAEs) is reported. The Weber number corresponding to the transition between the deposition and the splashing regime is reduced by ≈20\% in a moderate magnetic field of ≈300 mT. Alongside this effect, a two-fold increase of the initial deceleration of the ejection sheet is observed for the softest sample. The main underlying mechanism for the observed phenomena is believed to be the magnetic-field-induced stiffening of the MAEs. Further possible mechanisms are magnetically induced changes in the surface roughness and magnetic-field-induced plasticity (magnetic shape memory effect). The potential application areas are magnetically regulable wetting and magneto-responsive surfaces for controlling the drop splashing.}, language = {en} } @inproceedings{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Adaptive Magneto-Responsive Surfaces Fabricated by Laser-Based Microstructuring}, series = {Proceedings of the ASME 2022 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS 2022): September 12-14, 2022, Dearborn, Michigan}, booktitle = {Proceedings of the ASME 2022 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS 2022): September 12-14, 2022, Dearborn, Michigan}, publisher = {ASME}, isbn = {978-0-7918-8627-4}, doi = {10.1115/SMASIS2022-90742}, pages = {6}, abstract = {Adaptive surface microstructures are used extensively in nature to control various surface properties such as wettability, adhesion, self-cleaning, drag reduction, etc. Regulation of these properties can be achieved with the appropriate employment of a multitude of smart materials, whose characteristics/response can be controlled by noncontact stimuli, e.g., light, heat, or magnetic field. One of the very promising magneto-regulable smart materials are magnetoactive elastomers (MAEs). They are comprised of a compliant polymer matrix with embedded micrometer-sized ferromagnetic particles. The particles interact with each other and a magnetic field. This results in remarkable tunability of the physical properties of MAEs. This paper reports a fast, resilient, and tailored method for direct surface micromachining of MAEs that enables micro-structuring without mechanical contact between the tool and the material, bypassing the usual constraints of conventional fabrication methods. It is shown that it is possible to fabricate a large variety of different microstructure geometries whose precision is limited predominantly by the size of magnetic particles. Lamellar structures with a high aspect ratio (up to 6:1) oriented either perpendicularly to the surface, can be strongly bent by applying magnetic fields in the range of 0-250 mT.}, language = {en} }