@article{SakoparnigGalanSteindletal., author = {Sakoparnig, Marlene and Galan, Isabel and Steindl, Florian Roman and Kusterle, Wolfgang and Juhart, Joachim and Grengg, Cyrill and Briendl, Lukas G. and Saxer, Andreas and Thumann, Maria and Mittermayr, Florian}, title = {Durability of clinker reduced shotcrete: Ca2+ leaching, sintering, carbonation and chloride penetration}, series = {Materials and structures}, volume = {54}, journal = {Materials and structures}, publisher = {Springer Nature}, doi = {10.1617/s11527-021-01644-7}, pages = {1 -- 23}, abstract = {The reduction of clinker use is mandatory to lower the negative environmental impact of concrete. In shotcrete mixes, similarly to the case of conventional concrete, the use of supplementary cementitious materials (SCMs) and proper mix design allow for the substitution of clinker without compromising the mechanical properties. However, the impact of the substitution on the durability of shotcrete needs to be further assessed and understood. The results from the present study, obtained from real-scale sprayed concrete applications, show a reduction of the Ca2+ leaching and sintering potential of clinker-reduced shotcrete mixes due to the presence of SCMs. This positive effect, crucial for low maintenance costs of tunnels, is mainly related to a reduced portlandite content, which on the other hand negatively affects the carbonation resistance of shotcrete. Additionally, the hydration of SCMs positively influences the chloride penetration resistance presumably due to a combination of microstructural changes and changes in the chloride binding capacity. Differences found in the pore size distribution of the various mixes have low impact on the determined durability parameters, in particular compared to the effect of inhomogeneities produced during shotcrete application.}, language = {en} } @inproceedings{SteindlGalanBaldermannetal., author = {Steindl, Florian and Galan, Isabel and Baldermann, Andre and Sakoparnig, Marlene and Dietzel, Martin and R{\"o}ck, Rudolf and Kusterle, Wolfgang and Mittermayr, Florian}, title = {Dauerhaftigkeitsuntersuchungen an Trocken- und Nassspritzbetonen mit mineralischen Zusatzstoffen - Investigations on the durability of dry- and wet-mix sprayed concrete with mineral additions}, series = {Spritzbeton-Tagung 2021, 21. + 22. J{\"a}nner 2021, Alpbach Tirol}, booktitle = {Spritzbeton-Tagung 2021, 21. + 22. J{\"a}nner 2021, Alpbach Tirol}, pages = {94 -- 111}, abstract = {Die Dauerhaftigkeit von Spritzbeton kann, insbesondere in seiner Verwendung als St{\"u}tz-und Ausbaumaterial im Tunnelbau, durch chemische Angriffe deutlich herabgesetzt werden. Im Forschungsprojekt "Entwicklung neuer dauerhafter und nachhaltiger Spritzbetone (ASSpC)" wurden Pr{\"u}fk{\"o}rper von Trocken-und Nassspritzbetonen in Großspritzversuchen hergestellt. Der Sulfatwiderstand und das L{\"o}sungsverhalten der Betone in sulfathaltigen w{\"a}ssrigen L{\"o}sungen wurden mit drei Testverfahren bestimmt und die Ergebnisse miteinander verglichen: Ein Pulvertestverfahren zeigt die Aufl{\"o}sung von Zementhydratphasen zugunsten der Neubildung von Calcit und Ettringit. Das Ausmaß der Sulfatdehnung an Bohrkernen, ermittelt im zweiten Testverfahren, korrespondiert mit dem chemischen Verhalten des gemahlenen Materials, insbesondere bez{\"u}glich der Reaktivit{\"a}t von calcium-und aluminium-haltigen Hydratphasen. Der Thaumasitwiderstand, ermittelt {\"u}ber Masseverlust von Pr{\"u}f-k{\"o}rpern, zeigte eine weitgehende {\"U}bereinstimmung mit den zuvor genannten Tests. Die Verwendung von hochreinen Metakaolinen (7-10 M-\% des Bindemittels) oder Feinstcalcit (5-10 M-\% des Bindemittels) allein f{\"u}hrte insgesamt zu deutlich geringerer Sulfatbest{\"a}ndigkeit. Hingegen konnten hohe Gehalte an H{\"u}ttensand oder Silikastaub auch in Kombination mit Metakaolin und Feinstcalcit den Sulfatwiderstand von Spritzbeton erh{\"o}hen. The durability of shotcrete can be degraded by chemical attacks, especially if used as ground support in tunnel construction. In the course of the research project "Advanced and Sustainable Sprayed Concrete (ASSpC)" test specimens of dry-mix and wet-mix shotcrete were sprayed in large-scale tests. The sulfate resistance and the leaching behaviour of these shotcretes were assessed in sulfate-bearing solutions. A test procedure based on the use of shotcrete powders shows that hydrated cement phases dissolve in favour of calcite and ettringite neo-formation. The sulfate expansion measured on drill cores in the second procedure corresponds to the behaviour of the powders, especially regarding the reactivity of calcium-and aluminium-bearing hydrated phases. The resistance against thaumasite attack, assessed by measuring the mass loss of prisms, coincides with the former test results. The exclusive use of high-purity metakaolin (7-10 wt-\% of binder) or fine calcium carbonate (5-10 wt-\% of binder) leads to a decrease in the sulfate durability. However, high amounts of blast furnace slag or silica fume can increase the sulfate resistance of shotcrete even when used in combination with metakaolin or fine calcium carbonate.}, language = {de} }