@article{KrieglKravanjaHribaretal., author = {Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Čoga, Lucija and Drevenšek-Olenik, Irena and Jezeršek, Matija and Kalin, Mitjan and Shamonin (Chamonine), Mikhail}, title = {Microstructured Magnetoactive Elastomers for Switchable Wettability}, series = {Polymers}, volume = {14}, journal = {Polymers}, number = {18}, publisher = {MDPI}, doi = {10.3390/polym14183883}, pages = {1 -- 21}, abstract = {We demonstrate the control of wettability of non-structured and microstructured magnetoactive elastomers (MAEs) by magnetic field. The synthesized composite materials have a concentration of carbonyl iron particles of 75 wt.\% (≈27 vol.\%) and three different stiffnesses of the elastomer matrix. A new method of fabrication of MAE coatings on plastic substrates is presented, which allows one to enhance the response of the apparent contact angle to the magnetic field by exposing the particle-enriched side of MAEs to water. A magnetic field is not applied during crosslinking. The highest variation of the contact angle from (113 ± 1)° in zero field up to (156 ± 2)° at about 400 mT is achieved in the MAE sample with the softest matrix. Several lamellar and pillared MAE structures are fabricated by laser micromachining. The lateral dimension of surface structures is about 50 µm and the depth varies between 3 µm and 60 µm. A systematic investigation of the effects of parameters of laser processing (laser power and the number of passages of the laser beam) on the wetting behavior of these structures in the absence and presence of a magnetic field is performed. In particular, strong anisotropy of the wetting behavior of lamellar structures is observed. The results are qualitatively discussed in the framework of the Wenzel and Cassie-Baxter models. Finally, directions of further research on magnetically controlled wettability of microstructured MAE surfaces are outlined. The obtained results may be useful for the development of magnetically controlled smart surfaces for droplet-based microfluidics.}, language = {en} } @article{JezeršekKrieglKravanjaetal., author = {Jezeršek, Matija and Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Drevenšek-Olenik, Irena and Unold, Heiko and Shamonin (Chamonine), Mikhail}, title = {Control of Droplet Impact through Magnetic Actuation of Surface Microstructures}, series = {Advanced Materials Interfaces}, volume = {10}, journal = {Advanced Materials Interfaces}, number = {11}, publisher = {Wiley}, doi = {10.1002/admi.202202471}, abstract = {An effective method for on-demand control over the impact dynamics of droplets on a magnetoresponsive surface is reported. The surface is comprised of micrometer-sized lamellas from a magnetoactive elastomer on a copper substrate. The surface itself is fabricated using laser micromachining. The orientation of the lamellae is switched from edge-on (orthogonal to the surface) to face-on (parallel to the surface) by changing the direction of a moderate (<250 mT) magnetic field. This simple actuation technique can significantly change the critical velocities of droplet rebound, deposition, and splashing. Rebound and deposition regimes can be switched up to Weber number We < 13 ± 3, while deposition and splashing can be switched in the range of 32 < We < 52. Because a permanent magnet is used, no permanent power supply is required for maintaining the particular regime of droplet impact. The presented technology is highly flexible and enables selective fabrication and actuation of microstructures on complex devices. It has great potential for applications in soft robotics, microfluidics, and advanced thermal management.}, language = {en} } @article{GlavanKettlBrunhuberetal., author = {Glavan, Gašper and Kettl, Wolfgang and Brunhuber, Alexander and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena}, title = {Effect of Material Composition on Tunable Surface Roughness of Magnetoactive Elastomers}, series = {Polymers}, volume = {11}, journal = {Polymers}, number = {4}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/polym11040594}, pages = {1 -- 13}, abstract = {We investigated magnetic-field-induced modifications of the surface roughness of magnetoactive elastomers (MAEs) with four material compositions incorporating two concentrations of ferromagnetic microparticles (70 wt\% and 80 wt\%) and exhibiting two shear storage moduli of the resulting composite material (about 10 kPa and 30 kPa). The analysis was primarily based on spread optical reflection measurements. The surfaces of all four materials were found to be very smooth in the absence of magnetic field (RMS roughness below 50 nm). A maximal field-induced roughness modification (approximately 1 m/T) was observed for the softer material with the lower filler concentration, and a minimal modification (less than 50 nm/T) was observed for the harder material with the higher filler concentration. All four materials showed a significant decrease in the total optical reflectivity with an increasing magnetic field as well. This effect is attributed to the existence of a distinct surface layer that is depleted of microparticles in the absence of a magnetic field but becomes filled with particles in the presence of the field. We analyzed the temporal response of the reflective properties to the switching on and off of the magnetic field and found switching-on response times of around 0.1 s and switching-off response times in the range of 0.3-0.6 s. These observations provide new insight into the magnetic-field-induced surface restructuring of MAEs and may be useful for the development of magnetically reconfigurable elastomeric optical surfaces.}, language = {en} } @article{GlavanSalamonBelyaevaetal., author = {Glavan, Gašper and Salamon, Peter and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail and Drevensek-Olenik, Irena}, title = {Tunable surface roughness and wettability of a soft magnetoactive elastomer}, series = {Journal of applied polymer science}, volume = {135}, journal = {Journal of applied polymer science}, number = {18}, publisher = {Wiley}, doi = {10.1002/app.46221}, abstract = {Surface topographical modifications of a soft magnetoactive elastomer (MAE) in response to variable applied magnetic field are investigated. The analysis is performed in situ and is based on optical microscopy, spread optical reflection and optical profilometry measurements. Optical profilometry analysis shows that the responsivity of magnetic field-induced surface roughness with respect to external magnetic field is in the range of 1 mu m/T. A significant hysteresis of surface modifications takes place for increasing and decreasing fields. Investigations of shape of sessile water droplets deposited on the MAE surface reveal that field-induced topographical modifications affect the contact angle of water at the surface. This effect is reversible and the responsivity to magnetic field is in the range of 20 degrees/T. Despite the increased surface roughness, the apparent contact angle decreases with increasing field, which is attributed to the field-induced protrusion of hydrophilic microparticles from the surface layer.}, language = {en} } @article{LovšinBrandlGlavanetal., author = {Lovšin, Matija and Brandl, Dominik and Glavan, Gašper and Belyaeva, Inna A. and Cmok, Luka and Coga, Lucija and Kalin, Mitjan and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena}, title = {Reconfigurable Surface Micropatterns Based on the Magnetic Field-Induced Shape Memory Effect in Magnetoactive Elastomers}, series = {Polymers}, volume = {13}, journal = {Polymers}, number = {24}, publisher = {MDPI}, doi = {10.3390/polym13244422}, abstract = {A surface relief grating with a period of 30 mu m is embossed onto the surface of magnetoactive elastomer (MAE) samples in the presence of a moderate magnetic field of about 180 mT. The grating, which is represented as a set of parallel stripes with two different amplitude reflectivity coefficients, is detected via diffraction of a laser beam in the reflection configuration. Due to the magnetic-field-induced plasticity effect, the grating persists on the MAE surface for at least 90 h if the magnetic field remains present. When the magnetic field is removed, the diffraction efficiency vanishes in a few minutes. The described effect is much more pronounced in MAE samples with larger content of iron filler (80 wt\%) than in the samples with lower content of iron filler (70 wt\%). A simple theoretical model is proposed to describe the observed dependence of the diffraction efficiency on the applied magnetic field. Possible applications of MAEs as magnetically reconfigurable diffractive optical elements are discussed. It is proposed that the described experimental method can be used as a convenient tool for investigations of the dynamics of magnetically induced plasticity of MAEs on the micrometer scale.}, language = {en} } @article{GlavanBelyaevaDrevenšekOleniketal., author = {Glavan, Gašper and Belyaeva, Inna A. and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail}, title = {Experimental study of longitudinal, transverse and volume strains of magnetoactive elastomeric cylinders in uniform magnetic fields}, series = {Journal of Magnetism and Magnetic Materials}, volume = {579}, journal = {Journal of Magnetism and Magnetic Materials}, publisher = {Elsevier}, issn = {0304-8853}, doi = {10.1016/j.jmmm.2023.170826}, abstract = {Magnetoactive elastomers (MAEs) are promising materials for realization of magnetic field-controlled soft actuators. Herein, a systematic investigation of magnetic field-induced macroscopic deformations of soft MAE cylinders with a diameter of 15 mm in uniform quasi-static magnetic fields directed parallel to the cylinder's axis is reported. The measurements were based on image processing. Thirty-six MAE samples differing in the weight fraction of the iron filler (70 wt\%, 75 wt\% and 80 wt\%), alignment of filling particles, and the aspect ratio (0.2, 0.4, 0.6, 0.8, 1.0 and 1.2) were fabricated. MAE cylinders exhibited high relative change in height (up to 35\% in the field of 485 kA/m) and lateral contraction. The dependence of the maximum extensional strain on the aspect ratio was obtained and compared with theoretical considerations. A concave dent was formed on the free circular base in magnetic fields. This concavity was characterized experimentally. A significant volumetric strain of the order of magnitude of 10\% was calculated in MAEs for the first time. In consequently repeated magnetization cycles, the remanent extensional strain significantly increased after each cycle. The results are qualitatively discussed in the framework of the modern views on the magnetically induced macroscopic deformations of MAEs. The directions of further research are outlined.}, language = {en} } @misc{KrieglKravanjaHribaretal., author = {Kriegl, Raphael and Kravanja, Gaia and Hribar, Luka and Jezeršek, Matija and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail}, title = {Characterization of Wetting Properties of Magnetoactive Elastomer Surfaces}, series = {Proceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS) - 2023, September 11-13, 2023 Austin, Texas, USA}, journal = {Proceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS) - 2023, September 11-13, 2023 Austin, Texas, USA}, publisher = {The American Society of Mechanical Engineers}, address = {New York, USA}, isbn = {978-0-7918-8752-3}, doi = {10.1115/SMASIS2023-110998}, abstract = {Commercially available contact angle (CA) measuring devices usually do not allow for the application of magnetic fields to the sample under test. A setup for measuring the CA of liquids on magnetosensitive surfaces has been developed specifically for investigating the surfaces of magnetoactive elastomers (MAEs). The addition of a programmable linear stage, which moves a permanent magnet, allows for fine control of the magnetic field applied to the MAE without the need for large and power-consuming electromagnets. Paired with a custom control and evaluation software, this measurement setup operates semiautomatically, limiting operator error and increasing precision, speed, as well as repeatability of static and dynamic CA measurements for different magnetoactive materials. The software is equipped with robust droplet fitting algorithms to avoid experimental challenges arising with soft magnetoactive materials, such as the curling of sample edges or diffuse non-reflective surfaces. Several application examples on MAE surfaces, both processed and unprocessed, are presented.}, language = {en} } @article{KravanjaKrieglHribaretal., author = {Kravanja, Gaia and Kriegl, Raphael and Hribar, Luka and Glavan, Gašper and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Magnetically Actuated Surface Microstructures for Efficient Transport and Tunable Separation of Droplets and Solids}, series = {Advanced Engineering Materials}, volume = {25}, journal = {Advanced Engineering Materials}, number = {22}, publisher = {Wiley-VCH}, issn = {1527-2648}, doi = {10.1002/adem.202301000}, pages = {1 -- 11}, abstract = {Efficient transportation of droplets (∽10 ¹ ̶̶̶̶ 10 ² µl) and small solid objects (∽10 ¹ ̶ 10 ² mm ³ ) have important applications in many fields, such as microfluidics, lab-on-a-chip devices, drug delivery, etc. A novel multifunctional surface consisting of a periodic array of micro-lamellae from a soft magnetoactive elastomer (MAE) on a plastic substrate is reported for these purposes. The physical origin of the propulsion is the bending of soft magnetic lamellae in non-uniform magnetic fields, which is also observed in uniform magnetic fields. The magnetoactive surface is fabricated using a facile and rapid method of laser ablation. The propulsion of items is realized using a four-pole rotating magnet. This results in a cyclic lamellar fringe motion over the micro-structured surface and brings an advantage of easy reciprocation of transport by rotation reversal. Two modes of object transportation are identified: "pushing" mode for precise control of droplet and solid positioning and "bouncing" mode for heavier solid objects transportation. A water droplet of 5 μl or a glass sphere with a 2.1 mm diameter can be moved at a maximum speed of 60 mm s ⁻¹ . The multifunctionality of the proposed mechatronic platform is demonstrated on the examples of selective solid-liquid separation and droplet merging.}, language = {en} } @article{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Laser Micromachining of Magnetoactive Elastomers as Enabling Technology for Magnetoresponsive Surfaces}, series = {Advanced Materials Technologies}, volume = {7}, journal = {Advanced Materials Technologies}, number = {5}, publisher = {Wiley}, doi = {10.1002/admt.202101045}, pages = {1 -- 8}, abstract = {A simple method for structuring of the surface of a magnetoactive elastomer (MAE) on the tens of micrometers scale, which capabilities extend beyond conventional mold-based polymer casting, is reported. The method relies on the ablation of the material by absorption of nanosecond infrared pulses from a commercial laser. It is shown that it is possible to fabricate parallel lamellar structures with a high aspect ratio (up to 6:1) as well as structures with complex scanning trajectories. The method is fast (fabrication time for the 7 × 7 mm2 is about 60 s), and the results are highly reproducible. To illustrate the capabilities of the fabrication method, both orthogonal to the MAE surface and tilted lamellar structures are fabricated. These magnetosensitive lamellae can be easily bent by ±45° using an external magnetic field of about 230 mT. It is demonstrated that this bending allows one to control the sliding angle of water droplets in a great range between a sticky (>90°) and a sliding state (<20°). Perspectives on employing this fabrication technology for magnetosensitive smart surfaces in microfluidic devices and soft robotics are discussed.}, language = {en} } @article{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Jezeršek, Matija and Shamonin (Chamonine), Mikhail}, title = {Tunable Drop Splashing on Magnetoactive Elastomers}, series = {Advanced Materials Interfaces}, volume = {8}, journal = {Advanced Materials Interfaces}, number = {11}, publisher = {Wiley}, doi = {10.1002/admi.202100235}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-24504}, pages = {1 -- 7}, abstract = {The significant effect of an external dc magnetic field on the splashing behavior of ethanol drops impacting on the unstructured (flat) surface of soft magnetoactive elastomers (MAEs) is reported. The Weber number corresponding to the transition between the deposition and the splashing regime is reduced by ≈20\% in a moderate magnetic field of ≈300 mT. Alongside this effect, a two-fold increase of the initial deceleration of the ejection sheet is observed for the softest sample. The main underlying mechanism for the observed phenomena is believed to be the magnetic-field-induced stiffening of the MAEs. Further possible mechanisms are magnetically induced changes in the surface roughness and magnetic-field-induced plasticity (magnetic shape memory effect). The potential application areas are magnetically regulable wetting and magneto-responsive surfaces for controlling the drop splashing.}, language = {en} } @article{StrausKokotKravanjaetal., author = {Straus, Izidor and Kokot, Gašper and Kravanja, Gaia and Hribar, Luka and Kriegl, Raphael and Shamonin (Chamonine), Mikhail and Jezeršek, Matija and Drevenšek-Olenik, Irena}, title = {Dynamically tunable lamellar surface structures from magnetoactive elastomers driven by a uniform magnetic field}, series = {Soft Matter}, volume = {Vol. 19}, journal = {Soft Matter}, publisher = {Royal Society of Chemistry}, doi = {10.1039/D3SM00012E}, pages = {3357 -- 3365}, abstract = {Stimuli responsive materials are key ingredients for any application that requires dynamically tunable or on-demand responses. In this work we report experimental and theoretical investigation of magnetic-field driven modifications of soft-magnetic elastomers whose surface was processed by laser ablation into lamellar microstructures that can be manipulated by a uniform magnetic field. We present a minimal hybrid model that elucidates the associated deflection process of the lamellae and explains the lamellar structure frustration in terms of dipolar magnetic forces arising from the neighbouring lamellae. We experimentally determine the magnitude of the deflection as a function of magnetic flux density and explore the dynamic response of lamellae to fast changes in a magnetic field. A relationship between the deflection of lamellae and modifications of the optical reflectance of the lamellar structures is resolved.}, language = {en} } @inproceedings{KravanjaBelyaevaHribaretal., author = {Kravanja, Gaia and Belyaeva, Inna A. and Hribar, Luka and Drevenšek-Olenik, Irena and Shamonin (Chamonine), Mikhail and Jezeršek, Matija}, title = {Adaptive Magneto-Responsive Surfaces Fabricated by Laser-Based Microstructuring}, series = {Proceedings of the ASME 2022 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS 2022): September 12-14, 2022, Dearborn, Michigan}, booktitle = {Proceedings of the ASME 2022 Conference on Smart Materials, Adaptive Structures and Intelligent Systems (SMASIS 2022): September 12-14, 2022, Dearborn, Michigan}, publisher = {ASME}, isbn = {978-0-7918-8627-4}, doi = {10.1115/SMASIS2022-90742}, pages = {6}, abstract = {Adaptive surface microstructures are used extensively in nature to control various surface properties such as wettability, adhesion, self-cleaning, drag reduction, etc. Regulation of these properties can be achieved with the appropriate employment of a multitude of smart materials, whose characteristics/response can be controlled by noncontact stimuli, e.g., light, heat, or magnetic field. One of the very promising magneto-regulable smart materials are magnetoactive elastomers (MAEs). They are comprised of a compliant polymer matrix with embedded micrometer-sized ferromagnetic particles. The particles interact with each other and a magnetic field. This results in remarkable tunability of the physical properties of MAEs. This paper reports a fast, resilient, and tailored method for direct surface micromachining of MAEs that enables micro-structuring without mechanical contact between the tool and the material, bypassing the usual constraints of conventional fabrication methods. It is shown that it is possible to fabricate a large variety of different microstructure geometries whose precision is limited predominantly by the size of magnetic particles. Lamellar structures with a high aspect ratio (up to 6:1) oriented either perpendicularly to the surface, can be strongly bent by applying magnetic fields in the range of 0-250 mT.}, language = {en} } @article{KrieglJezeršekKravanjaetal., author = {Kriegl, Raphael and Jezeršek, Matija and Kravanja, Gaia and Hribar, Luka and Mukhi, Soham and Kokot, Gašper and Drevenšek-Olenik, Irena and Shamonin, Mikhail}, title = {Tunable rebound of millimeter-sized rigid balls by magnetic actuation of elastomer-based surface microstructures}, series = {Smart Materials and Structures}, volume = {33}, journal = {Smart Materials and Structures}, number = {6}, publisher = {IOP Science}, doi = {10.1088/1361-665X/ad41a9}, abstract = {A novel method for controlling the rebound behavior of small balls made of Al2O3 with a radius of 2.381 mm is presented. It uses different types of micro-structured surfaces of soft magnetoactive elastomers. These surfaces were fabricated via laser micromachining and include fully ablated surfaces as well as micrometer-sized lamellas with a fixed width of 90 µm, height of 250 µm and three different gap sizes (15, 60 and 105 µm). The lamellas can change their orientation from edge-on to face-on configuration according to the direction of the external magnetic field from a permanent magnet. The orientation of the external magnetic field significantly influences the rebound behavior of the balls, from a coefficient of restitution e of to < 0.1. The highest relative change in the coefficient of restitution between zero field and face-on configuration of is observed for lamellas with a gap of 60 µm. Other characteristics of the ball rebound such as the penetration depth into an Magnetoactive elastomer and the maximum deceleration are investigated as well. The proposed method does not require a constant power supply due to the use of permanent magnets. It may find novel applications in the field of impact engineering.}, language = {en} }