@article{GamischEttengruberGadereretal., author = {Gamisch, Bernd and Ettengruber, Stefan and Gaderer, Matthias and Dawoud, Belal}, title = {Dynamic simulation of isothermal and non-isothermal reduction and oxidation reactions of iron oxide for a hydrogen storage process}, series = {Renewable and Sustainable Energy}, volume = {1}, journal = {Renewable and Sustainable Energy}, number = {1}, publisher = {ELSP, International Open Science Platform}, doi = {10.55092/rse20230004}, abstract = {This work aims first to develop a dynamic lumped model for the isothermal reactions of hydrogen/steam with a single iron oxide/iron pellet inside a tubular reactor and to validate the model results against the experimental reaction kinetic data with the help of our STA device. To describe the temporal change in mass, and consequently, the temporal heat of reaction, the shrinking core model, based on the geometrical contracting sphere, is applied. It turned out that, the simulation model can reproduce the experimental, temporal concentration and temperature-dependent conversion rates with a maximum deviation of 4.6\% during the oxidation reactions and 3.1\% during the reduction reactions. In addition, a measured isothermal storage process comprising one reduction and one oxidation phase with a holding phase in between on a single reacting pellet could be reproduced with a maximum absolute deviation in the conversion rate of 1.5\%. Moreover, a lumped, non-isothermal simulation model for a pelletized tubular redox-reactor including 2kg of iron oxide pellets has been established, in which the heat of reaction, heat transfer to the ambient and heat transfer between the solid and gas phases are considered. The temporal courses of the outlet gas concentration as well as the temperatures of the gas stream and the solid material at a constant input gas flow rate and a constant reacting gas inlet concentration but different input gas temperatures are estimated. Because of the endothermic nature of the reduction reaction, the inlet reacting gas temperature shall be kept high to prevent the severe temperature drop in the solid phase and, consequently, the significant reduction of the reaction rate. Contrary to that, the oxidation process requires lower input gas temperatures to avoid the excessive overheating of the reaction mass and, consequently, the sintering of the reacting pellets. Finally, five of the previous reactors have been connected in series to explore the influence of the changing inlet gas temperatures and concentrations on the dynamic performance of each storage mass.}, language = {en} } @article{GamischHuberGadereretal., author = {Gamisch, Bernd and Huber, Lea and Gaderer, Matthias and Dawoud, Belal}, title = {On the Kinetic Mechanisms of the Reduction and Oxidation Reactions of Iron Oxide/Iron Pellets for a Hydrogen Storage Process}, series = {Energies}, volume = {15}, journal = {Energies}, number = {21}, publisher = {MDPI}, doi = {10.3390/en15218322}, abstract = {This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90\% Fe2O3, 10\% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions' kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5\%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71\% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.}, language = {en} } @misc{AppelhansKampmannMottoketal., author = {Appelhans, Marie-Luise and Kampmann, Matthias and Mottok, J{\"u}rgen and Riederer, Michael and Nagl, Klaus and Steffens, Oliver and D{\"u}nnweber, Jan and Wildgruber, Markus and Roth, Julius and Stadler, Timo and Palm, Christoph and Weiß, Martin Georg and Rochholz, Sandra and Bierl, Rudolf and Gschossmann, Andreas and Haug, Sonja and Schmidbauer, Simon and Koch, Anna and Westner, Markus and Bary, Benedikt von and Ellermeier, Andreas and V{\"o}gele, Daniel and Maiwald, Frederik and Hierl, Stefan and Schlamp, Matthias and Ehrlich, Ingo and Siegl, Marco and H{\"u}ntelmann, Sven and Wildfeuer, Matthias and Br{\"u}ckl, Oliver and Sterner, Michael and Hofrichter, Andreas and Eckert, Fabian and Bauer, Franz and Dawoud, Belal and Rabl, Hans-Peter and Gamisch, Bernd and Schmidt, Ottfried and Heberl, Michael and Thema, Martin and Mayer, Ulrike and Eller, Johannes and Sippenauer, Thomas and Adelt, Christian and Haslbeck, Matthias and Vogl, Bettina and Mauerer, Wolfgang and Ramsauer, Ralf and Lohmann, Daniel and Sax, Irmengard and Gabor, Thomas and Feld, Sebastian and Linnhoff-Popien, Claudia and Ławrowski, Robert Damian and Langer, Christoph and Schreiner, Rupert and Sellmair, Josef}, title = {Forschung 2019}, editor = {Baier, Wolfgang}, address = {Regensburg}, organization = {Ostbayerische Technische Hochschule Regensburg}, isbn = {978-3-9818209-7-3}, doi = {10.35096/othr/pub-789}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-7890}, pages = {72}, abstract = {Bericht mit Forschungsprojekten aus verschiedenen Bereichen der OTH Regensburg mit dem Schwerpunktthema "K{\"u}nstliche Intelligenz" und einem Gespr{\"a}ch zur "Medizin der Zukunft"}, subject = {Forschung}, language = {de} } @article{MikhaeilNowakPalombaetal., author = {Mikhaeil, Makram and Nowak, Sebastian and Palomba, Valeria and Frazzica, Andrea and Gaderer, Matthias and Dawoud, Belal}, title = {Experimental and analytical investigation of applying an asymmetric plate heat exchanger as an evaporator in a thermally driven adsorption appliance}, series = {Applied Thermal Engineering}, journal = {Applied Thermal Engineering}, number = {228}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2023.120525}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-61115}, abstract = {This communication presents an experimental and analytical study on the evaporation mechanism in a closed-structured asymmetric plate heat exchanger (PHE) employed as a stagnant water evaporator for the application in an adsorption heat transformation appliance. To this aim, an experimental unit is constructed, which comprises two identical PHEs, one acting as an vaporator/condenser and the second, as an adsorber/desorber. Two endoscopes are mounted inside the investigated evaporator to visualize the evaporation mechanism when performing adsorption-evaporation processes under different boundary conditions. It turned out that the evaporation mechanism is a partially covered, thin film evaporation. A heat transfer analysis is performed to evaluate the heat transfer coefficient of the thin film evaporation () inside the investigated evaporator, resulting in -values between 1330 and 160 [W∙m-2∙K-1] over the investigated adsorption-evaporation time. Correlating the obtained () to the film thickness and the wetted area results in -values between 0.34 and 0.78 [mm] and wetted to total area ratios of 0.78 to 0.16. Besides, an analytical model has been developed and introduced to correlate the overall evaporator heat transfer coefficient with the adsorption potential and the time rate of change of the water uptake.}, language = {en} } @article{GaertnerRankHeberletal., author = {G{\"a}rtner, Sebastian and Rank, Daniel and Heberl, Michael and Gaderer, Matthias and Dawoud, Belal and Haumer, Anton and Sterner, Michael}, title = {Simulation and Techno-Economic Analysis of a Power-to-Hydrogen Process for Oxyfuel Glass Melting}, series = {Energies}, volume = {14}, journal = {Energies}, number = {24}, publisher = {MDPI}, doi = {10.3390/en14248603}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-22713}, abstract = {As an energy-intensive industry sector, the glass industry is strongly affected by the increasingly stringent climate protection targets. As established combustion-based production systems ensure high process stability and glass quality, an immediate switch to low greenhouse gas emission processes is difficult. To approach these challenges, this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study indicate, that the proposed system can reduce specific carbon dioxide emissions by up to 60\%, while increasing specific energy demand by a maximum of 25\%. Investigations of the impact of altered combustion and furnace properties like adiabatic flame temperature (+25 °C), temperature efficiency (∆ξ = -0.003) and heat capacity flow ratio (∆zHL = -0.009) indicate that pure hydrogen-oxygen combustion has less impact on melting properties than assumed so far. Within the case study, high CO2 abatement costs of 295 €/t CO2-eq. were determined. This is mainly due to the insufficient performance of renewable energy sources. The correlations between process scaling and economic parameters presented in this study show promising potential for further economic optimization of the proposed energy system in the future.}, language = {en} } @article{ChatzitakisSafarovOpferkuchetal., author = {Chatzitakis, Paris and Safarov, Javid and Opferkuch, Frank and Dawoud, Belal}, title = {Experimental investigation of an absorption heat pump with organic working pairs}, series = {Applied Thermal Engineering}, volume = {163}, journal = {Applied Thermal Engineering}, number = {December}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2019.114311}, abstract = {As part of a systematic approach towards the search for alternative absorption heat pump (AHP) working pairs that could potentially provide comparable performance to conventional ones, a previous work performed a detailed theoretical cycle analysis and simulation that revealed concrete correlations between key working fluid thermophysical properties and AHP performance indicators. Following this work, targeted combinations of two organic refrigerants, 2,2,2-trifluoroethanol (TFE) and 2,2,3,3,3-pentafluoropropanol (5FP) and two organic absorbents, 1,3-dimethyl-2-imidazolidinone (DMI) and 2-pyrrolidone (PYR) were tested in a prototype 5 kW AHP, based on a highly compact plate heat exchanger design, which has been previously introduced. The purpose of this effort was to test the findings of the previous work with experimental measurements. The working pair combinations were also subjected to vapor liquid equilibrium (VLE) and viscosity measurements, in order to determine reliable activity coefficient and improve the accuracy of the simulations. The experimental performance data agree well with the COP simulations and show to be consistent with the conclusions derived from the previous theoretical work.}, language = {en} } @misc{BroserFalterŁawrowskietal., author = {Broser, Christian and Falter, Thomas and Ławrowski, Robert Damian and Altenbuchner, Amelie and V{\"o}gele, Daniel and Koss, Claus and Schlamp, Matthias and Dunnweber, Jan and Steffens, Oliver and Heckner, Markus and Jaritz, Sabine and Schiegl, Thomas and Corsten, Sabine and Lauer, Norina and Guertler, Katherine and Koenig, Eric and Haug, Sonja and Huber, Dominik and Birkenmaier, Clemens and Krenkel, Lars and Wagner, Thomas and Justus, Xenia and Saßmannshausen, Sean Patrick and Kleine, Nadine and Weber, Karsten and Braun, Carina N. and Giacoppo, Giuliano and Heinrich, Michael and Just, Tobias and Schreck, Thomas and Schnabl, Andreas and Gilmore, Amador T{\´e}ran and Roeslin, Samuel and Schmid, Sandra and Wellnitz, Felix and Malz, Sebastian and Maurial, Andreas and Hauser, Florian and Mottok, J{\"u}rgen and Klettke, Meike and Scherzinger, Stefanie and St{\"o}rl, Uta and Heckner, Markus and Bazo, Alexander and Wolff, Christian and Kopper, Andreas and Westner, Markus and Pongratz, Christian and Ehrlich, Ingo and Briem, Ulrich and Hederer, Sebastian and Wagner, Marcus and Schillinger, Moritz and G{\"o}rlach, Julien and Hierl, Stefan and Siegl, Marco and Langer, Christoph and Hausladen, Matthias and Schreiner, Rupert and Haslbeck, Matthias and Kreuzer, Reinhard and Br{\"u}ckl, Oliver and Dawoud, Belal and Rabl, Hans-Peter and Gamisch, Bernd and Schmidt, Ottfried and Heberl, Michael and G{\"a}nsbauer, Bianca and Bick, Werner and Ellermeier, Andreas and Monkman, Gareth J. and Prem, Nina and Sindersberger, Dirk and Tschurtschenthaler, Karl and Aurbach, Maximilian and Dendorfer, Sebastian and Betz, Michael A. and Szecsey, Tamara and Mauerer, Wolfgang and Murr, Florian}, title = {Forschung 2018}, editor = {Baier, Wolfgang}, address = {Regensburg}, organization = {Ostbayerische Technische Hochschule Regensburg}, isbn = {978-3-9818209-5-9}, doi = {10.35096/othr/pub-1382}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-13826}, pages = {98}, subject = {Forschung}, language = {de} } @article{WeindlerLehnerEcksteinetal., author = {Weindler, Jeremy and Lehner, Hannes and Eckstein, J. and Dawoud, Belal}, title = {Performance assessment of a green hydrogen-based household energy system supported by a battery storage at different resolutions of the electrical load profile}, series = {International Journal of Hydrogen Energy}, volume = {144}, journal = {International Journal of Hydrogen Energy}, publisher = {Elsevier}, issn = {0360-3199}, doi = {10.1016/j.ijhydene.2025.04.431}, pages = {30 -- 41}, abstract = {Hydrogen deems quite suitable for medium- and long-term energy storage of surplus renewable electricity. Nowadays, all-in-one solutions consisting of an electrolyzer, a compressor, pressurized hydrogen storage tanks, a fuel cell (FC) and the necessary peripheral components are available for single family houses. This work presents a comparative assessment of the system's key performance indicators in a household system with three market available FCs with the nominal powers of 0.8, 1.4 and 7.8 kW. The design tool developed for the assessment of the hybrid energy system along with two energy management system configurations are introduced. An electrochemical and thermal model widely applied in the literature is used to model the FCs, which is validated against the available experimental data in the literature for all three FCs. The influence of the FCs' nominal power, their power dynamic operation range, the use of a battery storage with different capacities and the load profile's resolution have been technically assessed regarding the system's self-sufficiency (SS), the FC's efficiency, full-load operating hours, and number of on/off cycles. It turned out that, the system performance is strongly dependent on the nominal power of the FC and its power dynamic operation range. If no battery-storage is applied, the complete grid independence is not possible, and a high resolution of the load profile is indispensable in the assessment of the system design. A hybrid energy system comprising the 1.4 kW FC, a PV system of 10 kW peak power and a battery of 15 kW storage capacity showed a degree of SS of 98\%. The number of the full-load operating hours and on/off cycles of that FC amount to 768 and 116 cycles, respectively. Such promising results are referred to the high dynamic operation range of the battery, and its high discharge power capacity, which makes it more suitable to cover a remarkably higher fraction of the load deficit, if compared to a system without a battery.}, language = {en} } @article{WeindlerDawoud, author = {Weindler, Jeremy and Dawoud, Belal}, title = {Experimental investigation of a small-scale continuous flow ohmic heating reactor for a highly effective conversion of renewable electricity surpluses into heat}, series = {Applied Thermal Engineering}, volume = {242}, journal = {Applied Thermal Engineering}, publisher = {Elsevier}, issn = {1359-4311}, doi = {10.1016/j.applthermaleng.2024.122401}, pages = {15}, abstract = {Sector coupling is expected to play a decisive role as a key technology to realize the energy transition towards green energy supply. This work introduces, therefore, a comprehensive experimental study on a new power-to-heat system based on the continuous-flow, ohmic heating principle, which aims at utilizing renewable electricity in green processes. The ohmic heating technology, which is widely applied in the food industry, has been adapted and evaluated for delivering heat and domestic hot water to a single-family house. The introduced prototype is designed to convert renewable electricity into heat in the power range between 1000 and 3000 W with a typical electrical household installation (230 V, 50 Hz and 16 A fuse). A dedicated test rig has been developed and a comprehensive experimental campaign has been carried out to investigate the performance of the introduced system under typical operating conditions of a single-family house. Both the conversion efficiency and the dynamics of the thermal response of the introduced system have been assessed. It turned out that, the temperature lift between the return and supply of the reactor, and consequently, the conversion efficiency of electrical into thermal energy, are independent on the return temperature, for a fixed value of the volume flow rate of the electrolyte solution. A remarkable steady-state conversion efficiency of 97.5\% has been measured. In addition, the dynamic response of the ohmic heating system has been found to be strongly dependent on the desired temperature lift. By an implemented controller, 95\% of the steady state temperature lift of 44.5 K can be realized in 50 s, which marks an exceptionally rapid thermal response. The obtained results pave the way towards a field test study of the developed technology in a real household installation as well as to extend the focus on new fields such as green chemical processes.}, language = {en} }