@article{SteiningerGadererDawoudetal., author = {Steininger, Peter and Gaderer, Matthias and Dawoud, Belal and Gaderer, Matthias}, title = {Experimental and numerical study on the solar gain and heat loss of typical existing and refurbished German buildings}, series = {iCRBE Procedia}, volume = {1}, journal = {iCRBE Procedia}, number = {1}, publisher = {Weentech}, doi = {10.32438/icrbe.202035}, pages = {75 -- 93}, abstract = {This communication introduces an experimental setup for investigating the effect of solar radiation on the reduction of transmission heat losses and the steady state thermal conductance of uninsulated and insulated multi-layer wall samples. The setup consists of two adjacent climatic chambers, which share a common wall, in which the multi-layer wall samples are mounted. A solar simulator is applied within the outdoor air climatic chamber, whose radiation spectrum and radiation intensity are approximately equivalent to those of the sun. The first tests have been carried out on a wall sample with a typical structure of existing buildings from the year 1930 in Germany. In addition, a high-performance insulating plaster layer has been applied on a basic test sample (with existing building structure) to replicate and assess the refurbished scenario. Furthermore, a numerical investigation on the transient heat transfer process is carried out by using the simulation software COMSOL Multiphysics®. The experimental results of both uninsulated and insulated wall samples are validated against 1D and 3D models. As seen, the uninsulated wall, whose thermal conductance was experimentally determined to be equal to 1.79 W/(m²K), absorbs a heat flux of 208 W/m² through its external wall surface over a period of 8 hours. A fraction of 9.8 \% of the absorbed heat arrives as a gain on the internal wall and reduces the transmission heat losses by 11.7 \% over a period of 55 hours. On the other hand, the thermal conductivity of the insulation layer of the refurbished wall sample with micro hollow glass spheres was estimated by a parameter estimation procedure using the 3D model and the obtained experimental data. Using the estimated thermal conductivity, a thermal conductance of 0.42 W/(m²K) has been obtained for the refurbished wall sample.}, language = {en} } @article{MikhaeilGadererDawoud, author = {Mikhaeil, Makram and Gaderer, Matthias and Dawoud, Belal}, title = {On the application of adsorber plate heat exchangers in thermally driven chillers}, series = {Applied Thermal Engineering}, volume = {220}, journal = {Applied Thermal Engineering}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2022.119713}, abstract = {The effect of both heat and mass transfer characteristic lengths (HTCL, MTCL) of two different adsorber plate heat exchangers (APHE), for application in an adsorption chiller, on the adsorption and desorption kinetics is investigated. Three representative test frames (TF1-TF3) are prepared to examine small-scale adsorbent samples of the microporous silica gel (Siogel of Oker-Chemie, Germany) applying the volumetric large-temperature-jump methodology at different operating conditions. Based on the obtained kinetic data, an analytical model has been developed to predict the specific cooling power (SCP) and the coefficient of performance (COP) of a single-bed adsorption chiller comprising the studied APHEs. It turned out that, within the tested range of HTCL and MTCL, it can be concluded that, the adsorption kinetics are mainly influenced by the MTCL, while the desorption kinetics are dominated by the HTCL of the adsorbent domain. Applying Siogel as loose pellets inside a newly introduced APHE results in of 423.3 and 182.7 W⋅kg-1, at the evaporator temperatures of 15 °C and 5 °C, respectively. Herein, the condenser and adsorber-end temperatures amount to 30 °C and the desorption-end temperature to 90 °C. The corresponding s amount to 0.50 and 0.40, respectively, which represent quite promising results for further design optimizations.}, language = {en} } @article{VerezBorriCrespoetal., author = {V{\´e}rez, David and Borri, Emiliano and Crespo, Alicia and Zsembinszki, Gabriel and Dawoud, Belal and Cabeza, Luisa F.}, title = {Experimental Study of a Small-Size Vacuum Insulated Water Tank for Building Applications}, series = {Sustainability}, volume = {13}, journal = {Sustainability}, number = {10}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/su13105329}, pages = {1 -- 11}, abstract = {Insulation of thermal energy storage tanks is fundamental to reduce heat losses and to achieve high energy storage efficiency. Although water tanks were extensively studied in the literature, the enhancement of the insulation quality is often overlooked. The use of vacuum insulation has the potential to significantly reduce heat losses without affecting the dimension of the storage system. This paper shows for the first time the results of the heat losses tests done for a 0.535 m3 water tank for residential building applications built with a double wall vacuum insulation. The different tests show that the rate of heat losses strictly depends on the temperature distribution inside the tank at the beginning of the experiment. Compared to a conventional water tank insulated with conventional materials, the U-value of the lateral surface was reduced by almost three times (from 1.05 W/K·m2 to 0.38 W/K·m2) using vacuum insulation. However, the bottom part, which is usually used to place the support parts and the piping, is the critical design part of those tanks acting as a thermal bridge with the ambient and enhancing heat losses.}, language = {en} } @article{FreniFrazzicaDawoudetal., author = {Freni, Angelo and Frazzica, Andrea and Dawoud, Belal and Chmielewski, Stefanie and Calabrese, Luigi and Bonaccorsi, Lucio Maria}, title = {Adsorbent coatings for heat pumping applications: Verification of hydrothermal and mechanical stabilities}, series = {Applied Thermal Engineering}, volume = {50}, journal = {Applied Thermal Engineering}, number = {2}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2011.07.010}, pages = {1658 -- 1663}, abstract = {This paper presents novel experimental methods for verification of both hydrothermal and mechanical stabilities of adsorbent coatings. Experiments have been carried out on zeolite-based coatings over aluminum substrates, prepared by a dip-coating technique developed at CNR-ITAE. Hydrothermal aging of several adsorbent coatings is ongoing. Adsorption and structural stability of some samples under test was successfully verified after 35000 aging cycles by isobars measurement and XRD analysis. Mechanical properties of coatings have been evaluated by applying different typologies of static and dynamic mechanical stresses. Results obtained have been compared with those achieved by subjecting adsorbent coatings prepared by Mitsubishi Plastic Incorporation (MPI) to the same characterization protocol. The comparison between the two types of coating returned that MPI coatings posses similar thermal stability and better mechanical strength than CNR-ITAE coatings.}, language = {en} } @article{FrazzicaPalombaDawoudetal., author = {Frazzica, Andrea and Palomba, Valeria and Dawoud, Belal and Gull{\`i}, Giuseppe and Brancato, Vincenza and Sapienza, Alessio and Vasta, Salvatore and Freni, Angelo and Costa, Fabio and Restuccia, Giovanni}, title = {Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair}, series = {Applied Energy}, volume = {174}, journal = {Applied Energy}, publisher = {Elsevier}, doi = {10.1016/j.apenergy.2016.04.080}, pages = {15 -- 24}, abstract = {In the present paper design, realization and testing of a novel small scale adsorption refrigerator prototype based on activated carbon/ethanol working pair is described. Firstly, experimental activity has been carried out for identification of the best performing activated carbon available on the market, through the evaluation of the achievable thermodynamic performance both under air conditioning and refrigeration conditions. Once identified the best performing activated carbon, the design of the adsorber was developed by experimental dynamic performance analysis, carried out by means of the Gravimetric-Large Temperature Jump (G-LTJ) apparatus available at CNR ITAE lab. Finally, the whole 0.5 kW refrigerator prototype was designed and built. First experimental results both under reference air conditioning and refrigeration cycles have been reported, to check the achievable performance. High Specific Cooling Powers (SCPs), 95 W/kg and 50 W/kg, for air conditioning and refrigeration respectively, were obtained, while the COP ranged between 0.09 and 0.11, thus showing an improvement of the current state of the art. (C) 2016 Elsevier Ltd. All rights reserved.}, language = {en} } @article{PalombaNowakDawoudetal., author = {Palomba, Valeria and Nowak, Sebastian and Dawoud, Belal and Frazzica, Andrea}, title = {Dynamic modelling of Adsorption systems: a comprehensive calibrated dataset for heat pump and storage applications}, series = {Journal of energy storage}, volume = {33}, journal = {Journal of energy storage}, publisher = {Elsevier}, doi = {10.1016/j.est.2020.102148}, abstract = {The growing efforts for the development of clean and efficient energy systems require the use of a multi-disciplinary approach and the integration of multiple generation appliances. Among the fields that can be considered enabling technologies, adsorption systems for air conditioning and thermal energy storages, are constantly increasing their maturity. However, for a proper design and integration of such systems, there is the need for a simulation framework that is reliable and computationally convenient. In the present paper, the implementation of a dynamic model for adsorption systems is presented, which includes different components (adsorber, phase changer, sorption materials) and is structured as a library. Modelica language and the commercial software Dymola (R) are used for the analysis. Data for different heat exchangers and working pairs are calibrated using experimental results and the calibrated model is subsequently used for the design of an adsorber based on a plate heat exchanger for thermal energy storage applications. The results proved that the model is fast and can reproduce experimental results with good accuracy, thus being a useful tool for the design and optimization of the different components of sorption systems.}, language = {en} } @article{Dawoud, author = {Dawoud, Belal}, title = {Water vapor adsorption kinetics on small and full scale zeolite coated adsorbers; A comparison}, series = {Applied thermal engineering}, volume = {50}, journal = {Applied thermal engineering}, number = {2}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2011.07.013}, pages = {1645 -- 1651}, abstract = {A possibility to enhance both heat and mass transfer characteristics of an adsorber heat exchanger is to apply the adsorbent directly to its surface in form of a consolidated layer. As the majority of the available publications on the effect of both coating technology and adsorbent layer thickness on the adsorption kinetics deals with small scale adsorbent samples, the results obtained can only represent the best case design of an adsorber heat exchanger. This article presents, therefore, a comparison between the adsorption kinetics of water vapour on small as well as two different full scale coated adsorber heat exchanger types with AQSOA-Z02 layers of Mitsubishi Plastics Incorporation under quasi isobaric conditions of adsorption heat pumps. The small scale coated samples have a zeolite dry mass of 200 mg and layer thicknesses of 200, 300 and 500 μm while the full scale adsorbers have a coated zeolite mass between 1.5 and 2.5 kg and layer thicknesses of 150, 200, 300, 400 and 500 μm. In the investigated adsorption heat pump module, up to 52.7 and 57.3\% of the equilibrium differential water loading measured with the small scale coated substrates have been obtained after an adsorption-evaporation times of 300 and 600 s, respectively.}, language = {en} } @article{FrazzicaPalombaDawoud, author = {Frazzica, Andrea and Palomba, Valeria and Dawoud, Belal}, title = {Thermodynamic Performance of Adsorption Working Pairs for Low-Temperature Waste Heat Upgrading in Industrial Applications}, series = {Applied Sciences}, volume = {11}, journal = {Applied Sciences}, number = {8}, publisher = {MDPI}, doi = {10.3390/app11083389}, abstract = {The present work aims at the thermodynamic analysis of different working pairs in adsorption heat transformers (AdHT) for low-temperature waste heat upgrade in industrial processes. Two different AdHT configurations have been simulated, namely with and without heat recovery between the adsorbent beds. Ten working pairs, employing different adsorbent materials and four different refrigerants, have been compared at varying working boundary conditions. The effects of heat recovery and the presence of a temperature gradient for heat transfer between sinks/sources and the AdHT components have been analyzed. The achieved results demonstrate the possibility of increasing the overall performance when internal heat recovery is implemented. They also highlight the relevant role played by the existing temperature gradient between heat transfer fluids and components, that strongly affect the real operating cycle of the AdHT and thus its expected performance. Both extremely low, i.e., 40-50 degrees C, and low (i.e., 80 degrees C) waste heat source temperatures were investigated at variable ambient temperatures, evaluating the achievable COP and specific energy. The main results demonstrate that optimal performance can be achieved when 40-50 K of temperature difference between waste heat source and ambient temperature are guaranteed. Furthermore, composite sorbents demonstrated to be the most promising adsorbent materials for this application, given their high sorption capacity compared to pure adsorbents, which is reflected in much higher achievable specific energy.}, language = {en} } @article{PalombaDawoudSapienzaetal., author = {Palomba, Valeria and Dawoud, Belal and Sapienza, Alessio and Vasta, Salvatore and Frazzica, Andrea}, title = {On the impact of different management strategies on the performance of a two-bed activated carbon/ethanol refrigerator: An experimental study}, series = {Energy conversion and management}, volume = {142}, journal = {Energy conversion and management}, publisher = {Elsevier}, doi = {10.1016/j.enconman.2017.03.055}, pages = {322 -- 333}, abstract = {In the present work, an experimental study on a lab-scale adsorption refrigerator, based on activated carbon/ethanol working pair is reported. An extensive testing campaign has been carried out at the CNR ITAE laboratory, with multiple aims. First, the performance has been evaluated in terms of both COP and Specific Cooling Power (SCP), under different boundary conditions, including both air conditioning and refrigeration applications. Attractive SCPs, up to 180 W/kg and 70 W/kg for air conditioning and refrigeration, respectively, were measured. Under the same conditions, COP between 0.17 and 0.08 were obtained. In addition, different management strategies, namely, heat recovery between adsorbers and re-allocation of phase durations, were evaluated to identify their influence on the system. Both strategies confirmed the possibility of increasing COP and SCP up to 40\% and 25\%, respectively. Moreover, a design analysis based on the experimental results has been carried out, to suggest possible improvements of the system. The obtained results demonstrated the possibility of employing a non-toxic refrigerant like ethanol reaching performance comparable with other harmful refrigerants like ammonia and methanol. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{Dawoud, author = {Dawoud, Belal}, title = {On the development of an innovative gas-fired heating appliance based on a zeolite-water adsorption heat pump; system description and seasonal gas utilization efficiency}, series = {Applied Thermal Engineering}, volume = {72}, journal = {Applied Thermal Engineering}, number = {2}, publisher = {Elsevier}, doi = {10.1016/j.applthermaleng.2014.09.008}, pages = {323 -- 330}, abstract = {The main objective of this work is to introduce an innovative hybrid heating appliance incorporating a gas condensing boiler and a zeolite-water adsorption heat pump. The condensing boiler is applied to drive the zeolite-water heat pump for the heating base-load and to assist the heat pump in the so called "mixed operation" mode, in which both the heat pump and the condensing boiler are working in series to cover medium heating demands. Peak heating demands are covered by the condensing boiler in the so called "direct heating" mode. The three operation modes of the hybrid heating appliance have been technically described. In addition, the laboratory test conditions for estimating the seasonal heating performance according to the German Guideline VDI 4650-2 have been introduced. For both heating systems 35/28 °C and 55/45 °C, which represent the typical operating conditions of floor and high temperature radiating heating systems in Europe, seasonal heating gas utilization efficiencies of 1.34 and 1.26 have been measured, respectively with a ground heat source. In two field test installations in one-family houses in Germany, the introduced heating appliance showed 27\% more seasonal gas utilization efficiency for heating and domestic hot water production, which is equivalent to a CO2-emission reduction of 20\% compared to the gas condensing boiler technology.}, language = {en} } @book{FreniDawoudBonaccorsietal., author = {Freni, Angelo and Dawoud, Belal and Bonaccorsi, Lucio Maria and Chmielewski, Stefanie and Frazzica, Andrea and Calabrese, Luigi and Restuccia, Giovanni}, title = {Characterization of Zeolite-Based Coatings for Adsorption Heat Pumps}, publisher = {Springer}, address = {Berlin}, doi = {10.1007/978-3-319-09327-7}, pages = {96 S.}, abstract = {This book proposes a radically new approach for characterizing thermophysical and mechanical properties of zeolite-based adsorbent coatings for Adsorptive Heat Transformers (AHT). It presents a developed standard protocol for the complete characterization of advanced coated adsorbers. Providing an in-depth analysis of the different procedures necessary for evaluating the performance of adsorbers, it also presents an analysis of their stability under the hydrothermal and mechanical stresses during their entire life cycle. Adsorptive Heat Transformers (AHT), especially adsorption chillers and heat pumps, are considered to be promising technologies to increase thermal energy efficiency. Nevertheless, an overall increase in performance of this apparatus is necessary for them to be considered a mature technology to be used commercially. Development of innovative coated adsorbers can be perceived as a key issue for the enhancement of AHT technology. This procedure relies on the deposition, either by means of a binder or by direct crystallization, of the adsorbent material over a metallic heat exchanger, aiming at the improvement of the heat transfer between the external heat source and the adsorbent itself. This book offers a valuable resource to those working on the development of novel adsorbent materials and advanced adsorbent beds for heating and cooling applications. It is also intended for researchers interested in renewable energy and energy efficiency.}, language = {en} }