@article{WolfgrammAbbSampetal., author = {Wolfgramm, Alex and Abb, Valerius and Samp, Artur and Samp, Rafal and Hoffmann, Jens Christoph and M{\"u}ller, Rainer and Kammler, Martin}, title = {Structural and functional evolution of HKUST-1 nanoparticles induced by ball milling}, series = {Next Materials}, volume = {10}, journal = {Next Materials}, publisher = {Elsevier}, doi = {10.1016/j.nxmate.2025.101544}, pages = {7}, abstract = {In this study, the effect of post-synthetic ball milling on the structural and functional properties of as-synthesized nanoparticles of the copper-based metal-organic framework (MOF) HKUST-1 was investigated for the first time. Nanoparticles were synthesized using sodium formate as a capping agent. The crystalline particles were subjected to a controlled ball milling process, which induced significant structural changes. Powder X-ray diffraction (PXRD) revealed a reduction in crystallite size from 91 nm to 21 nm and the introduction of microstrain, partially disrupting the MOF's long-range crystalline order, as evidenced by peak broadening and the diminished intensity of high-angle reflections. Particle morphology pre- and post-milling was further studied with scanning electron microscopy (SEM) imaging, verifying a narrow particle size distribution of ± 22 nm after milling. Fourier-transform infrared spectroscopy (FTIR) indicated protonation of carboxylate groups in the larger pores of the framework, likely due to moisture incorporation during milling. Brunauer-Emmett-Teller (BET) surface area analysis showed a substantial decrease in specific surface area from 521 m²/g to 226 m²/g, suggesting a partial collapse of the porous framework. We discuss the applicability of ball milling as a versatile means of post-synthetic approach to reduce MOF particle sizes, a key element in the preparation of MOF-based thin films using inks or polymers.}, language = {en} } @inproceedings{MelekhovAbbLechneretal., author = {Melekhov, Evgeny and Abb, Valerius and Lechner, Alfred and Kammler, Martin}, title = {Development of a glass-fiber-based spectrometer for the determination of drug residues in groundwater}, series = {Tagungsband 2. Symposium Elektronik und Systemintegration ESI 2020 "Intelligente Systeme und ihre Komponenten: Forschung und industrielle Anwendung"}, booktitle = {Tagungsband 2. Symposium Elektronik und Systemintegration ESI 2020 "Intelligente Systeme und ihre Komponenten: Forschung und industrielle Anwendung"}, editor = {Ivanov, Artem and Bicker, Marc and Patzelt, Peter}, isbn = {978-3-9818439-4-1}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:860-opus4-2174}, pages = {101 -- 109}, abstract = {Within the scope of this project, a portable measuring device has been developed which enables a cost-effective analysis of organic substances from ppm to sub-ppm range, such as drug residues in groundwater. The measurement is carried out by means of a surface-enhanced Raman scattering effect (SERS effect) and an exchangeable sensor head. The sensor head used is a nanostructured optical glass fiber glued into a fiber cannula. The tip of the fiber has been processed to act as a SERS cell. The fiber cannula is connected to a freely movable patch cable by using an adapter. Para-thiocresol is used to characterize the SERS cells.}, language = {en} } @misc{MelekhovAbbWeidaueretal., author = {Melekhov, Evgeny and Abb, Valerius and Weidauer, Tobias and Kammler, Martin and Lechner, Alfred}, title = {Tunable Nanopillars as Surface Enhanced Raman Scattering (SERS) Active Structure for Optical Quartz Glass Fiber}, series = {SMSI 2021 - Sensors and Instrumentation}, journal = {SMSI 2021 - Sensors and Instrumentation}, publisher = {AMA Association for Sensors and Measurement}, isbn = {978-3-9819376-4-0}, doi = {10.5162/SMSI2021/B8.2}, pages = {153 -- 154}, abstract = {In this work, a simple cost effective method to create tunable self-assembled three-dimensional nanostructure array-like nanoantennas on a tip of an optical quartz glass fiber is described. The structures are prepared using lithography-less dry etching. Gold nanoparticles are used as an etching mask using a thin metal-film thermal dewetting technique. The structures are applied as sensor for label-free analysis of organic substances in ppb range, such as drug residues in groundwater. The measurements are carried out by means of a Surface-enhanced Raman scattering (SERS) effect, an exchangeable sensor head, and a portable Raman device. This method allows in situ applications. Parathiocresol is used as a model substance to characterize the SERS cells. For metallization, gold and silver are compared. Reproducible SERS enhancement factors up to 10 7 are evaluated.}, language = {en} } @article{MelekhovPennWeidaueretal., author = {Melekhov, Evgeny and Penn, Tatjana and Weidauer, Tobias and Abb, Valerius and Kammler, Martin and Lechner, Alfred}, title = {Tunable nanopillar array on a quartz-fiber tip for surface enhanced Raman scattering (SERS) detection}, series = {tm - Technisches Messen}, volume = {89}, journal = {tm - Technisches Messen}, number = {1}, publisher = {de Gruyter}, doi = {10.1515/teme-2021-0093}, pages = {70 -- 81}, abstract = {In this work, a simple two-step method to create tunable self-assembled three-dimensional nanostructure array-like nanoantennas directly on the tip of an optical quartz glass fiber is described. The structures are prepared by using dry etching of the fiber tip. For the etching process, gold nanoparticles fabricated by thermal dewetting technique were used as template. The structures are applied as sensors for label-free analysis of organic substances in ppb range, such as drug residues in liquid solutions. The measurements are carried out by a portable Raman device with an exchangeable sensor head utilizing the SERS-effect. This method allows in situ applications. In order to characterize the SERS cells, para-thiocresol and diclofenac sodium are used as model substances. For optimization of the substrate performance, different thicknesses of the dewetting-layer (6, 9, 12 nm), different etching times for formation of the pillars (6, 8, 10 and 12 min), and different thicknesses of SERS-metallization (25, 50, 75 nm) of gold and silver are compared. In order to show the applicability of the structure on the tip of a fiber, measurements from the upper side and from the underside of the substrate on quartz plates are compared. Reproducible SERS enhancement factors up to 10 7 {10^{7}} were achieved.}, language = {en} }