@article{StrausKravanjaHribaretal., author = {Straus, Izidor and Kravanja, Gaia and Hribar, Luka and Kriegl, Raphael and Jezeršek, Matija and Shamonin (Chamonine), Mikhail and Drevenšek-Olenik, Irena and Kokot, Gašper}, title = {Surface Modification of Magnetoactive Elastomers by Laser Micromachining}, series = {Materials}, volume = {2024}, journal = {Materials}, number = {17 / 7}, publisher = {MDPI AG}, address = {Basel, Switzerland}, doi = {10.3390/ma17071550}, pages = {12}, abstract = {It has been recently demonstrated that laser micromachining of magnetoactive elastomers is a very convenient method for fabricating dynamic surface microstructures with magnetically tunable properties, such as wettability and surface reflectivity. In this study, we investigate the impact of the micromachining process on the fabricated material's structural properties and its chemical composition. By employing scanning electron microscopy, we investigate changes in size distribution and spatial arrangement of carbonyl iron microparticles dispersed in the polydimethylsiloxane (PDMS) matrix as a function of laser irradiation. Based on the images obtained by a low vacuum secondary electron detector, we analyze modifications of the surface topography. The results show that most profound modifications occur during the low-exposure (8 J/cm^2) treatment of the surface with the laser beam. Our findings provide important insights for developing theoretical models of functional properties of laser-sculptured microstructures from magnetoactive elastomers.}, language = {en} } @article{GlavanBelyaevaShamoninChamonine, author = {Glavan, Gašper and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail}, title = {Transient Response of Macroscopic Deformation of Magnetoactive Elastomeric Cylinders in Uniform Magnetic Fields}, series = {Polymers}, volume = {16}, journal = {Polymers}, number = {5, Special Issue Magnetic Polymer Composites: Design and Application II}, publisher = {MDPI}, address = {Basel, Schweiz}, issn = {2073-4360}, doi = {10.3390/polym16050586}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-71067}, pages = {17}, abstract = {Significant deformations of bodies made from compliant magnetoactive elastomers (MAE) in magnetic fields make these materials promising for applications in magnetically controlled actuators for soft robotics. Reported experimental research in this context was devoted to the behaviour in the quasi-static magnetic field, but the transient dynamics are of great practical importance. This paper presents an experimental study of the transient response of apparent longitudinal and transverse strains of a family of isotropic and anisotropic MAE cylinders with six different aspect ratios in time-varying uniform magnetic fields. The time dependence of the magnetic field has a trapezoidal form, where the rate of both legs is varied between 52 and 757 kA/(s·m) and the maximum magnetic field takes three values between 153 and 505 kA/m. It is proposed to introduce four characteristic times: two for the delay of the transient response during increasing and decreasing magnetic field, as well as two for rise and fall times. To facilitate the comparison between different magnetic field rates, these characteristic times are further normalized on the rise time of the magnetic field ramp. The dependence of the normalized characteristic times on the aspect ratio, the magnetic field slew rate, maximum magnetic field values, initial internal structure (isotropic versus anisotropic specimens) and weight fraction of the soft-magnetic filler are obtained and discussed in detail. The normalized magnetostrictive hysteresis loop is introduced, and used to explain why the normalized delay times vary with changing experimental parameters.}, language = {en} } @article{GlavanBelyaevaShamoninChamonine, author = {Glavan, Gašper and Belyaeva, Inna A. and Shamonin (Chamonine), Mikhail}, title = {Multiferroic Cantilevers Containing a Magnetoactive Elastomer: Magnetoelectric Response to Low-Frequency Magnetic Fields of Triangular and Sinusoidal Waveform}, series = {Sensors}, volume = {22}, journal = {Sensors}, number = {10}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s22103791}, pages = {1 -- 17}, abstract = {In this work, multiferroic cantilevers comprise a layer of a magnetoactive elastomer (MAE) and a commercially available piezoelectric polymer-based vibration sensor. The structures are fixed at one end in the horizontal plane and the magnetic field is applied vertically. First, the magnetoelectric (ME) response to uniform, triangle-wave magnetic fields with five different slew rates is investigated experimentally. Time and field dependences of the generated voltage, electric charge, and observed mechanical deflection are obtained and compared for four different thicknesses of the MAE layer. The ME responses to triangular and sinusoidal wave excitations are examined in contrast. Second, the ME response at low frequencies (≤3 Hz) is studied by the standard method of harmonic magnetic field modulation. The highest ME coupling coefficient is observed in the bias magnetic field strength of ≈73 kA/m and it is estimated to be about 3.3 ns/m (ME voltage coefficient ≈ 25 V/A) at theoretically vanishing modulation frequency (f→0 Hz). Presented results demonstrate that the investigated heterostructures are promising for applications as magnetic-field sensors and energy harvesting devices.}, language = {en} } @article{BelyaevaKramarenkoShamoninChamonine, author = {Belyaeva, Inna A. and Kramarenko, Elena Yu and Shamonin (Chamonine), Mikhail}, title = {Magnetodielectric effect in magnetoactive elastomers: Transient response and hysteresis}, series = {POLYMER}, volume = {127}, journal = {POLYMER}, publisher = {ELSEVIER}, doi = {10.1016/j.polymer.2017.08.056}, pages = {119 -- 128}, abstract = {Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000\%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SavelevGlavanBelanetal., author = {Savelev, Dmitrii V. and Glavan, Gašper and Belan, Viktoria O. and Belyaeva, Inna A. and Fetisov, Leonid Y. and Shamonin (Chamonine), Mikhail}, title = {Resonant Magnetoelectric Effect at Low Frequencies in Layered Polymeric Cantilevers Containing a Magnetoactive Elastomer}, series = {Applied Sciences}, volume = {12}, journal = {Applied Sciences}, number = {4}, publisher = {MPDI}, doi = {10.3390/app12042102}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-30637}, pages = {1 -- 13}, abstract = {In this work, the resonance enhancement of magnetoelectric (ME) coupling at the two lowest bending resonance frequencies was investigated in layered cantilever structures comprising a magnetoactive elastomer (MAE) slab and a commercially available piezoelectric polymer multilayer. A cantilever was fixed at one end in the horizontal plane and the magnetic field was applied horizontally. Five composite structures, each containing an MAE layer of different thicknesses from 0.85 to 4 mm, were fabricated. The fundamental bending resonance frequency in the absence of a magnetic field varied between roughly 23 and 55 Hz. It decreased with the increasing thickness of the MAE layer, which was explained by a simple theory. The largest ME voltage coefficient of about 7.85 V/A was measured in a sample where the thickness of the MAE layer was ≈2 mm. A significant increase in the bending resonance frequencies in the applied DC magnetic field of 240 kA/m up to 200\% was observed. The results were compared with alternative designs for layered multiferroic structures. Directions for future research were also discussed.}, language = {en} } @article{GlavanBelyaevaRuwischetal., author = {Glavan, Gašper and Belyaeva, Inna A. and Ruwisch, Kevin and Wollschlaeger, Joachim and Shamonin (Chamonine), Mikhail}, title = {Magnetoelectric Response of Laminated Cantilevers Comprising a Magnetoactive Elastomer and a Piezoelectric Polymer, in Pulsed Uniform Magnetic Fields}, series = {Sensors}, volume = {21}, journal = {Sensors}, number = {19}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s21196390}, pages = {1 -- 19}, abstract = {The voltage response to pulsed uniform magnetic fields and the accompanying bending deformations of laminated cantilever structures are investigated experimentally in detail. The structures comprise a magnetoactive elastomer (MAE) slab and a commercially available piezoelectric polymer multilayer. The magnetic field is applied vertically and the laminated structures are customarily fixed in the horizontal plane or, alternatively, slightly tilted upwards or downwards. Six different MAE compositions incorporating three concentrations of carbonyl iron particles (70 wt\%, 75 wt\% and 80 wt\%) and two elastomer matrices of different stiffness are used. The dependences of the generated voltage and the cantilever's deflection on the composition of the MAE layer and its thickness are obtained. The appearance of the voltage between the electrodes of a piezoelectric material upon application of a magnetic field is considered as a manifestation of the direct magnetoelectric (ME) effect in a composite laminated structure. The ME voltage response increases with the increasing total quantity of the soft-magnetic filler in the MAE layer. The relationship between the generated voltage and the cantilever's deflection is established. The highest observed peak voltage around 5.5 V is about 8.5-fold higher than previously reported values. The quasi-static ME voltage coefficient for this type of ME heterostructures is about 50 V/A in the magnetic field of approximate to 100 kA/m, obtained for the first time. The results could be useful for the development of magnetic field sensors and energy harvesting devices relying on these novel polymer composites.}, language = {en} } @article{BelyaevaKleppLemmeletal., author = {Belyaeva, Inna A. and Klepp, J{\"u}rgen and Lemmel, Hartmut and Shamonin (Chamonine), Mikhail}, title = {Feasibility of Probing the Filler Restructuring in Magnetoactive Elastomers by Ultra-Small-Angle Neutron Scattering}, series = {Applied Sciences}, volume = {11}, journal = {Applied Sciences}, number = {10}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/app11104470}, pages = {1 -- 9}, abstract = {Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 x 10(-5) and 1.85 x 10(-4) angstrom(-1). It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered.}, language = {en} } @article{BodnarukKalitaKulyketal., author = {Bodnaruk, Andrii V. and Kalita, Viktor M. and Kulyk, Mykola M. and Lozenko, Albert F. and Ryabchenko, Sergey M. and Snarskii, Andrei A. and Brunhuber, Alexander and Shamonin (Chamonine), Mikhail}, title = {Temperature blocking and magnetization of magnetoactive elastomers}, series = {Journal of Magnetism and Magnetic Materials}, volume = {471}, journal = {Journal of Magnetism and Magnetic Materials}, number = {February}, publisher = {Elsevier}, doi = {10.1016/j.jmmm.2018.10.005}, pages = {464 -- 467}, abstract = {The magnetization of a magnetoactive elastomer (MAE) with microparticles of soft magnetic carbonyl iron embedded in a highly elastic matrix has been studied. It is shown that at high temperatures its magnetization curve has the form of a specific hysteresis loop. This hysteresis is attributed to the influence of displacement of magnetized particles in the elastically soft elastomer matrix under the effect of magnetic forces, leading to the change of magnetic interaction between the particles. In this case, there is a maximum in the field dependence of the magnetic susceptibility, the occurrence of which has been associated with the competition between rearrangement of particles, when they are displaced in a magnetic field, and saturation of particles' magnetization. When the MAE is cooled below approximately 225 K, both the magnetic hysteresis and the maximum in the field dependence of the magnetic susceptibility disappear. When the MAE material is cooled below the solidification temperature of the elastomer matrix, the displacements of the magnetic particles during magnetization are blocked by the rigid matrix. The magnetization reversal of the MAE is reversible. This means that the shape of subsequent magnetization loops remains constant and the sample returns into the initial non-magnetized state after the magnetic field is turned off.}, language = {en} } @article{BodnarukAndriiVBrunhuberetal., author = {Bodnaruk, and Andrii V., and Brunhuber, Alexander and Kalita, Viktor M. and Kulyk, Mykola M. and Kurzweil, Peter and Snarskii, Andrei A. and Lozenko, Albert F. and Ryabchenko, Sergey M. and Shamonin (Chamonine), Mikhail}, title = {Magnetic anisotropy in magnetoactive elastomers, enabled by matrix elasticity}, series = {Polymer}, volume = {162}, journal = {Polymer}, number = {January}, publisher = {Elsevier}, doi = {10.1016/j.polymer.2018.12.027}, pages = {63 -- 72}, abstract = {Polydimethylsiloxane based magnetoactive elastomers demonstrate above the melting transition range (e.g. at room temperature) an induced uniaxial magnetic anisotropy, which grows with increasing magnetic field. By freezing a material down to 150 K, displaced iron microparticles are immobilized, so that the magnetic anisotropy can be measured. Magnetic anisotropy "constant" is a consequence of particle displacements and a characteristic of the energy of internal deformations in the polymer matrix. The maximum anisotropy constant of the filling is at least one order of magnitude larger than the shear modulus of the pure elastomer (matrix). In a magnetic field, the gain in the rigidity of the composite material is attributed to the magnetomechanical coupling, which is in turn a source of anisotropy. The concept of effective magnetic field felt by the magnetization allows one to explain the magnetization curve at room temperature from low-temperature measurements. The results can be useful for developing vibration absorbers and isolators.}, language = {en} } @article{BeckerRaikherStolbovetal., author = {Becker, Tatiana I. and Raikher, Yuriy L. and Stolbov, Oleg V. and B{\"o}hm, Valter and Zimmermann, Klaus}, title = {Magnetoactive elastomers for magnetically tunable vibrating sensor systems}, series = {Physical Sciences Reviews}, volume = {7}, journal = {Physical Sciences Reviews}, number = {10}, publisher = {de Gruyter}, issn = {2365-659X}, doi = {10.1515/psr-2019-0125}, pages = {1 -- 28}, abstract = {Magnetoactive elastomers (MAEs) are a special type of smart materials consisting of an elastic matrix with embedded microsized particles that are made of ferromagnetic materials with high or low coercivity. Due to their composition, such elastomers possess unique magnetic field-dependent material properties. The present paper compiles the results of investigations on MAEs towards an approach of their potential application as vibrating sensor elements with adaptable sensitivity. Starting with the model-based and experimental studies of the free vibrational behavior displayed by cantilevers made of MAEs, it is shown that the first bending eigenfrequency of the cantilevers depends strongly on the strength of an applied uniform magnetic field. The investigations of the forced vibration response of MAE beams subjected to in-plane kinematic excitation confirm the possibility of active magnetic control of the amplitude-frequency characteristics. With change of the uniform field strength, the MAE beam reveals different steady-state responses for the same excitation, and the resonance may occur at various ranges of the excitation frequency. Nonlinear dependencies of the amplification ratio on the excitation frequency are obtained for different magnitudes of the applied field. Furthermore, it is shown that the steady-state vibrations of MAE beams can be detected based on the magnetic field distortion. The field difference, which is measured simultaneously on the sides of a vibrating MAE beam, provides a signal with the same frequency as the excitation and an amplitude proportional to the amplitude of resulting vibrations. The presented prototype of the MAE-based vibrating unit with the field-controlled "configuration" can be implemented for realization of acceleration sensor systems with adaptable sensitivity. The ongoing research on MAEs is oriented to the use of other geometrical forms along with beams, e.g. two-dimensional structures such as membranes.}, language = {de} }