@article{MennickenPeterKaulenetal., author = {Mennicken, Max and Peter, Sophia Katharina and Kaulen, Corinna and Simon, Ulrich and Karth{\"a}user, Silvia}, title = {Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes}, series = {Beilstein journal of nanotechnology}, volume = {13}, journal = {Beilstein journal of nanotechnology}, publisher = {Beilstein-Institut zur F{\"o}rderung der Chemischen Wissenschaften}, doi = {10.3762/bjnano.13.16}, pages = {219 -- 229}, abstract = {The performance of nanoelectronic and molecular electronic devices relies strongly on the employed functional units and their addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands of gold nanoparticles and contacted by nanoelectrodes. The resulting small-area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport mechanism, that is, thermally activated hopping conduction in the case of Ru-terpyridine wire devices or sequential tunneling in nanoparticle-based devices. Furthermore, the conductance switching of nanoparticle-based devices upon 530 nm irradiation was attributed to plasmon-induced metal-to-ligand charge transfer in the Ru-terpyridine complexes used as switching ligands. Finally, our results reveal a superior device performance of nanoparticle-based devices compared to molecular wire devices based on Ru-terpyridine complexes as functional units.}, language = {en} } @article{SchelsHerdlHausladenetal., author = {Schels, Andreas and Herdl, Florian and Hausladen, Matthias and Wohlfartsst{\"a}tter, Dominik and Edler, Simon and Bachmann, Michael and Pahlke, Andreas and Schreiner, Rupert and Hansch, Walter}, title = {Quantitative Field Emission Imaging for Studying the Doping-Dependent Emission Behavior of Silicon Field Emitter Arrays}, series = {Micromachines}, volume = {14}, journal = {Micromachines}, number = {11}, publisher = {MDPI}, doi = {10.3390/mi14112008}, abstract = {Field emitter arrays (FEAs) are a promising component for novel vacuum micro- and nanoelectronic devices, such as microwave power amplifiers or fast-switching X-ray sources. However, the interrelated mechanisms responsible for FEA degradation and failure are not fully understood. Therefore, we present a measurement method for quantitative observation of individual emission sites during integral operation using a low-cost, commercially available CMOS imaging sensor. The emission and degradation behavior of three differently doped FEAs is investigated in current-regulated operation. The measurements reveal that the limited current of the p-doped emitters leads to an activation of up to 55\% of the individual tips in the array, while the activation of the n-type FEA stopped at around 30\%. This enhanced activation results in a more continuous and uniform current distribution for the p-type FEA. An analysis of the individual emitter characteristics before and after a constant current measurement provides novel perspectives on degradation behavior. A burn-in process that trims the emitting tips to an integral current-specific ideal field enhancement factor is observed. In this process, blunt tips are sharpened while sharp tips are dulled, resulting in homogenization within the FEA. The methodology is described in detail, making it easily adaptable for other groups to apply in the further development of promising FEAs.}, language = {en} } @article{MuellerWeiglMuellerWilliamsetal., author = {M{\"u}ller, Max and Weigl, Stefan and M{\"u}ller-Williams, Jennifer and Lindauer, Matthias and R{\"u}ck, Thomas and Jobst, Simon and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Comparison of photoacoustic spectroscopy and cavity ring-down spectroscopy for ambient methane monitoring at Hohenpeißenberg}, series = {Atmospheric Measurement Techniques}, volume = {16}, journal = {Atmospheric Measurement Techniques}, number = {18}, publisher = {Copernicus Publications}, issn = {1867-8548}, doi = {10.5194/amt-16-4263-2023}, pages = {4263 -- 4270}, abstract = {With an atmospheric concentration of approximately 2000 parts per billion (ppbV, 10-9), methane (CH4) is the second most abundant greenhouse gas (GHG) in the atmosphere after carbon dioxide (CO2). The task of long-term and spatially resolved GHG monitoring to verify whether climate policy actions are effective is becoming more crucial as climate change progresses. In this paper we report the CH4 concentration readings of our photoacoustic (PA) sensor over a 5 d period at Hohenpeißenberg, Germany. As a reference device, a calibrated cavity ring-down spectrometer, Picarro G2301, from the meteorological observatory of the German Weather Service (DWD) was employed. Trace gas measurements with photoacoustic instruments promise to provide low detection limits at comparably low costs. However, PA devices are often susceptible to cross-sensitivities related to fluctuating environmental conditions, e.g. ambient humidity. The obtained results show that for PA sensor systems non-radiative relaxation effects induced by varying humidity are a non-negligible factor. Applying algorithm compensation techniques, which are capable of calculating the influence of non-radiative relaxation effects on the photoacoustic signal, increase the accuracy of the photoacoustic sensor significantly. With an average relative deviation of 1.11 \% from the G2301, the photoacoustic sensor shows good agreement with the reference instrument.}, language = {en} } @article{GoldschmidtMoserNitzscheetal., author = {Goldschmidt, Jens and Moser, Elisabeth and Nitzsche, Leonard and Bierl, Rudolf and W{\"o}llenstein, J{\"u}rgen}, title = {Improving the performance of artificial neural networks trained on synthetic data in gas spectroscopy - a study on two sensing approaches}, series = {tm - Technisches Messen}, journal = {tm - Technisches Messen}, edition = {Online ver{\"o}ffentlicht}, publisher = {Oldenbourg Wissenschaftsverlag}, doi = {10.1515/teme-2023-0051}, abstract = {Artificial neural networks (ANNs) are used in quantitative infrared gas spectroscopy to predict concentrations on multi-component absorption spectra. Training of ANNs requires vast amounts of labelled training data which may be elaborate and time consuming to obtain. Additional data can be gained by the utilization of synthetically generated spectra, but at the cost of systematic deviations to measured data. Here, we present two approaches to train ANNs with a combination of comparatively small, measured data sets and synthetically generated data. For the first approach a neural network is trained hybridly with synthetically generated infrared absorption spectra of mixtures of N2O and CO and measured zero-gas spectra, taken with a mid-infrared dual comb spectrometer. This improves the mean absolute error (MAE) of the network predictions from 0.46 to 0.01 ppmV and 0.24 to 0.01 ppmV for the concentration predictions of N2O and CO respectively for zero-gas measurements which was previously observed for training with purely synthetic data. At the same time a similar performance on spectra from gas mixtures of 0-100 ppmV N2O and 0 to 60 ppmV CO was achieved. For the second approach an ANN pre-trained on synthetic infrared spectra of mixtures of acetone and ethanol is retrained on a small dataset consisting of 26 spectra taken with a mid-infrared photoacoustic spectrometer. In this case the MAE for the concentration predictions of ethanol and acetone are improved by 45 \% and 20 \% in comparison to purely synthetic training. This shows the capability of using synthetically generated data to train ANNs in combination with small amounts of measured data to further improve neural networks for gas sensing and the transferability between different sensing approaches.}, language = {en} } @article{ZifarelliCantatoreSampaoloetal., author = {Zifarelli, Andrea and Cantatore, Aldo Francesco Pio and Sampaolo, Angelo and Mueller, Max and Rueck, Thomas and Hoelzl, Christine and Rossmadl, Hubert and Patimisco, Pietro and Spagnolo, Vincenzo}, title = {Multivariate analysis and digital twin modelling: Alternative approaches to evaluate molecular relaxation in photoacoustic spectroscopy}, series = {Photoacoustics}, volume = {33}, journal = {Photoacoustics}, publisher = {Elsevier}, issn = {2213-5979}, doi = {10.1016/j.pacs.2023.100564}, abstract = {A comparative analysis of two different approaches developed to deal with molecular relaxation in photoacoustic spectroscopy is here reported. The first method employs a statistical analysis based on partial least squares regression, while the second method relies on the development of a digital twin of the photoacoustic sensor based on the theoretical modelling of the occurring relaxations. Methane detection within a gas matrix of synthetic air with variable humidity level is selected as case study. An interband cascade laser emitting at 3.345 µm is used to target methane absorption features. Two methane concentration ranges are explored targeting different absorptions, one in the order of part-per-million and one in the order of percent, while water vapor absolute concentration was varied from 0.3 \% up to 2 \%. The results achieved employing the detection techniques demonstrated the possibility to efficiently retrieve the target gas concentrations with accuracy > 95 \% even in the case of strong influence of relaxation effects.}, language = {en} } @article{JobstRecumEcijaArenasetal.2023, author = {Jobst, Simon and Recum, Patrick and {\´E}cija-Arenas, {\´A}ngela and Moser, Elisabeth and Bierl, Rudolf and Hirsch, Thomas}, title = {Semi-Selective Array for the Classification of Purines with Surface Plasmon Resonance Imaging and Deep Learning Data Analysis}, series = {ACS sensors}, volume = {8}, journal = {ACS sensors}, number = {9}, publisher = {American Chemical Society}, doi = {10.1021/acssensors.3c01114}, pages = {3530 -- 3537}, year = {2023}, abstract = {In process analytics or environmental monitoring, the real-time recording of the composition of complex samples over a long period of time presents a great challenge. Promising solutions are label-free techniques such as surface plasmon resonance (SPR) spectroscopy. They are, however, often limited due to poor reversibility of analyte binding. In this work, we introduce how SPR imaging in combination with a semi-selective functional surface and smart data analysis can identify small and chemically similar molecules. Our sensor uses individual functional spots made from different ratios of graphene oxide and reduced graphene oxide, which generate a unique signal pattern depending on the analyte due to different binding affinities. These patterns allow four purine bases to be distinguished after classification using a convolutional neural network (CNN) at concentrations as low as 50 μM. The validation and test set classification accuracies were constant across multiple measurements on multiple sensors using a standard CNN, which promises to serve as a future method for developing online sensors in complex mixtures.}, language = {en} } @article{ZahnerSchreinerStierstorferetal., author = {Zahner, Th and Schreiner, Rupert and Stierstorfer, R. and Kus, O. and Li, S. T. and Roessler, R. and Pedarnig, J. D. and B{\"a}uerle, D. and Lengfellner, H.}, title = {Off-diagonal Seebeck effect and anisotropic thermopower in Bi2Sr2CaCu2O8 thin films}, series = {Europhysics Letters}, volume = {40}, journal = {Europhysics Letters}, number = {6}, publisher = {IOP Sciences}, doi = {10.1209/epl/i1997-00521-4}, pages = {673 -- 678}, abstract = {The anisotropy ΔS of the thermopower in thin films of the high-Tc superconductor Bi2Sr2CaCu2O8 is investigated using off-c-axis epitaxial film growth and the off-diagonal Seebeck effect. The measurements represent a new method for the investigation of anisotropic transport properties in solids, taking advantage of the availability of oriented grown crystalline thin films instead of using bulk crystals. First results for the temperature dependence ΔS(T) in Bi2Sr2CaCu2O8 thin films are presented and described within a two-band model. Subjecting the films to heat treatments in different gases at relatively low temperatures, ΔS could reversibly be changed in a wide range.}, language = {en} } @article{SchreinerSchweizer, author = {Schreiner, Rupert and Schweizer, Heinz C.}, title = {High-frequency operation of 1.57-μm laterally coupled distributed feedback lasers with self-aligned ohmic contacts and nickel surface gratings}, series = {IEEE Journal of Selected Topics in Quantum Electronics}, volume = {9}, journal = {IEEE Journal of Selected Topics in Quantum Electronics}, number = {5}, publisher = {IEEE}, doi = {10.1109/JSTQE.2003.819469}, pages = {1179 -- 1182}, abstract = {Laterally coupled distributed feedback lasers with self-aligned ohmic contacts show the advantage of a considerably simplified fabrication process. These lasers exhibit superior spectral properties with full benefit from the gain coupling mechanism. Side-mode suppression ratios up to 55- and 3-dB bandwidths beyond 15 GHz were obtained for these devices.}, language = {en} } @article{CheongAwKarimovetal., author = {Cheong, Kuan Yew and Aw, Kean and Karimov, Khasan S. and Zhao, Feng and Mahroof-Tahir, Mohammad and Schreiner, Rupert}, title = {Advances in Smart Materials and Applications}, series = {Advances in Materials Science and Engineering}, journal = {Advances in Materials Science and Engineering}, publisher = {Hindawi}, doi = {10.1155/2014/517342}, abstract = {This is one of a series of special issues published in Advances in Materials Science and Engineering, focusing on the latest advances of smart materials and their applications. Evolution of engineering materials is strongly depending on the growing transformation of complexity in engineering products. New materials being designed are required to provide specific properties and demonstrate certain functional characteristics by manipulating their dimension, chemistry, and structure through various advanced technologies. Therefore, "smartness" of a material has become the topic of interest. Properties of smart materials may change accordingly to the applied external stimuli. Under the direction of the editorial team, we showcase advances of organic and inorganic based smart materials and their applications in areas of specific interest such as energy, environment, and health. A total of 9 articles are published in this special issue. Six articles are focused on production, synthesis, and optimization of smart materials; and the remaining are dedicated to application of smart materials.}, language = {en} } @article{SchreinerWiedmannCoenningetal., author = {Schreiner, Rupert and Wiedmann, J. and Coenning, W. and Porsche, J. and Gentner, Jean-Louis and Berroth, Manfred and Scholz, Ferdinand and Schweizer, H.}, title = {Fabrication approach for antiphase narrow linewidth complex coupled 1.55 μm DFB lasers}, series = {Electronics Letters}, volume = {35}, journal = {Electronics Letters}, number = {2}, publisher = {The Institution of Engineering and Technology IET}, issn = {0013-5194}, doi = {10.1049/el:19990132}, pages = {146 -- 148}, abstract = {A new method for fabricating narrow linewidth antiphase complex coupled MQW DFB lasers by periodically etching the active layer and quartemary InGaAsP overgrowth is reported. The minimum linewidth for a 375 µm long ridge waveguide laser is only 250 kHz at an optical output power of 4 mW.}, language = {en} } @article{SchreinerKoerblGraebeldingeretal., author = {Schreiner, Rupert and K{\"o}rbl, M. and Gr{\"a}beldinger, H. and Gentner, Jean-Louis and Schweizer, H.}, title = {Laterally gain-coupled 1.57 [micro sign]m DFB lasers with chromium surface grating and self-aligned Ti/Pt/Au ohmic contact}, series = {Electronics Letters}, volume = {36}, journal = {Electronics Letters}, number = {7}, publisher = {The Institution of Engineering and Technology, IET}, issn = {0013-5194}, doi = {10.1049/el:20000500}, pages = {636 -- 637}, abstract = {A simple method for fabricating gain coupled DFB lasers with lateral surface chromium Bragg gratings and self-aligned low capacitance ohmic contacts is reported. These InGaAsP/InP lasers show monomode emission with a sidemode suppression ratio of 40 dB. For 243 µm long devices a continuous wave threshold current of 17 mA was measured at room temperature.}, language = {en} } @article{SchreinerNaegeleKoerbletal., author = {Schreiner, Rupert and Naegele, Peter and K{\"o}rbl, M. and Groning, A. and Gentner, Jean-Louis and Schweizer, Heinz C.}, title = {Monolithically integrated tunable laterally coupled distributed-feedback lasers}, series = {Photonics Technology Letters}, volume = {13}, journal = {Photonics Technology Letters}, number = {12}, publisher = {IEEE}, doi = {10.1109/68.969880}, pages = {1277 -- 1279}, abstract = {A new method for fabrication of tunable InGaAsP-InP single-mode lasers without epitaxial overgrowth is reported. These devices show the advantage of a considerably simplified fabrication process compared to conventional tunable laser types. The lasers comprise an active Bragg reflector integrated with an uncorrugated separately pumped gain region. By adjusting the current through the Bragg reflector, the wavelength can be tuned between 1590.8 and 1595.2 nm.}, language = {en} } @article{DenkSchuengelWeberetal., author = {Denk, Alexander and Sch{\"u}ngel, Verena and Weber, Stefka and Kaulen, Corinna}, title = {Heimexperiment und Online-Dokumentation : Praktische Ausbildung in den MINT-F{\"a}chern}, series = {Chemie in unserer Zeit}, journal = {Chemie in unserer Zeit}, publisher = {Wiley-VCH}, doi = {10.1002/ciuz.202100018}, abstract = {Die Anleitung zum selbst{\"a}ndigen wissenschaftlichen Arbeiten ist ein fester Bestandteil in der naturwissenschaftlichen Ausbildung, der im letzten Jahr durch Distanz-Unterricht stark vernachl{\"a}ssigt wurde. Wir stellen hier einen Ansatz vor, bei dem Studierende zu Hause mit Alltagsgegenst{\"a}nden in Teilaufgaben die Aktivit{\"a}t von Hefe in Abh{\"a}ngigkeit von Temperatur und Substrat untersucht haben. Die Ergebnisse des gesamten Kurses wurden in einem Google-Dokument gesammelt und zentral ausgewertet. Gleichzeitig fand ein Erfahrungsaustausch unter den Lernenden statt und Probleme konnten {\"o}ffentlich diskutiert werden. Dar{\"u}ber hinaus wurden grundlegende F{\"a}higkeiten wie Beobachten, Protokollieren und detailgetreues Berichten ge{\"u}bt. Die Online-Dokumentation und -Erfassung der Ergebnisse stellt somit eine geeignete Methode dar, die Durchf{\"u}hrung von Heimexperimenten zu aktivieren und zu koordinieren.}, language = {de} } @article{GeorgeAllertWeber, author = {George, Wolfgang Michael and Allert, R. and Weber, Karsten}, title = {Versorgung Sterbender im Krankenhaus Ein vom G-BA-Innovationsfonds gef{\"o}rdertes Projekt reduziert nicht indizierte Verlegungen}, series = {KU-Gesundheitsmanagement}, volume = {90}, journal = {KU-Gesundheitsmanagement}, publisher = {Mediengruppe Oberfranken - Fachverlage}, address = {Kulmbach}, issn = {2510-8409}, pages = {24 -- 27}, abstract = {W{\"u}rdevolles Sterben muss an jedem Ort m{\"o}glich sein, auch im Krankenhaus, und hier nicht nur auf einer Palliativstation. Immer noch kommt es am Lebensende zu unn{\"o}tigen, nicht dem Patientenwohl dienenden, Verlegungen vom Heim oder der eigenen Wohnung in das Krankenhaus, vom Krankenhaus bspw. in ein Hospiz oder innerhalb des Krankenhauses von einer Normal- auf die Intensivstation. Damit die Zahl vermeidbarer Verlegungen im Krankenhaus reduziert wird, wurden im Rahmen eines Projektes zur Versorgungsforschung (Avenue-Pal), gef{\"o}rdert {\"u}ber den Gemeinsamen Bundesausschuss aus dem Innovationsfonds des Bundes, Entscheidungshilfen erarbeitet.}, language = {de} } @article{BachmannDuesbergPahlkeetal., author = {Bachmann, Michael and D{\"u}sberg, Felix and Pahlke, Andreas and Edler, Simon and Schels, Andreas and Herdl, Florian and Hausladen, Matthias and Buchner, Philipp and Schreiner, Rupert}, title = {The "LED-version" of the electron gun: An electron source for operation in ambient pressure environments based on silicon field emitter arrays}, series = {Vakuum in Forschung und Praxis}, volume = {35}, journal = {Vakuum in Forschung und Praxis}, number = {3}, publisher = {Wiley}, doi = {10.1002/vipr.202300801}, pages = {32 -- 37}, abstract = {We report on our progress to develop and optimize electron sources for practical applications. A simple fabrication process is introduced based on a wafer dicing saw and a wet chemical etch step without the need for a clean room. Due to the formation of crystal facets the samples show a homogeneous geometry throughout the array. Characterization techniques are developed to systematically compare various arrays. A very defined measurement procedure based on current controlled IV-sweeps as well as lifetime measurements at various currents is proposed. To investigate the current distribution in the array a commercial CMOS detector is used and shows the potential for in depth analysis of the arrays. Finally, a compact hermetically sealed housing is presented enabling electron generation in atmospheric pressure environments.}, language = {en} } @article{PangerlMoserMuelleretal., author = {Pangerl, Jonas and Moser, Elisabeth and M{\"u}ller, Max and Weigl, Stefan and Jobst, Simon and R{\"u}ck, Thomas and Bierl, Rudolf and Matysik, Frank-Michael}, title = {A sub-ppbv-level Acetone and Ethanol Quantum Cascade Laser Based Photoacoustic Sensor- Characterization and Multi-Component Spectra Recording in Synthetic Breath}, series = {Photoacoustics}, volume = {30}, journal = {Photoacoustics}, publisher = {Elsevier}, issn = {2213-5979}, doi = {10.1016/j.pacs.2023.100473}, pages = {1 -- 12}, abstract = {Trace gas analysis in breath is challenging due to the vast number of different components. We present a highly sensitive quantum cascade laser based photoacoustic setup for breath analysis. Scanning the range between 8263 and 8270 nm with a spectral resolution of 48 pm, we are able to quantify acetone and ethanol within a typical breath matrix containing water and CO2. We photoacoustically acquired spectra within this region of mid-infra-red light and prove that those spectra do not suffer from non-spectral interferences. The purely additive behavior of a breath sample spectrum was verified by comparing it with the independently acquired single component spectra using Pearson and Spearman correlation coefficients. A previously presented simulation approach is improved and an error attribution study is presented. With a 3σ detection limit of 6.5 ppbv in terms of ethanol and 250 pptv regarding acetone, our system is among the best performing presented so far.}, language = {en} } @article{SchmidtDenkerDashielletal., author = {Schmidt, Oliver G. and Denker, Ullrich and Dashiell, Michael W. and Jin-Phillipp, Neng Yun and Eberl, Karl and Schreiner, Rupert and Gr{\"a}beldinger, Hedwig and Schweizer, Heinz C. and Christiansen, Silke H. and Ernst, Frank}, title = {Laterally aligned Ge/Si islands: a new concept for faster field-effect transistors}, series = {Materials Science and Engineering B}, volume = {89}, journal = {Materials Science and Engineering B}, number = {1-3}, publisher = {Elsevier}, address = {New York, NY}, issn = {1873-4944}, doi = {10.1016/S0921-5107(01)00810-8}, pages = {101 -- 105}, abstract = {Self-assembled and coherently strained Ge dots were grown on a Si/SiGe superlattice, which was deposited on a flat Si(001) substrate surface patterned with a regular array of straight trenches. The superlattice translates the surface modulation of the substrate into a strain-field modulation, which causes the Ge dots on its surface to form along straight lines above the buried trenches. This approach provides self-assembled Ge dots with excellent lateral periodicity, which might be useful for fabricating dot-based field-effect-transistors (DotFETs). Here, we propose the concept of a modulation-doped p-channel DotFET (p-MOD-DotFET). The p-MOD-DotFET relies on embedded Ge-rich nanostructures, which provide p-channels through the Ge-rich dots. A high Ge concentration in the dots is desirable in order to exploit the high hole mobility of Ge-rich material. We show that the commonly observed Si-Ge intermixing during Si capping of Ge dots can be suppressed by overgrowing the islands at low temperature.}, language = {en} } @article{RueckMuellerJobstetal., author = {R{\"u}ck, Thomas and M{\"u}ller, Max and Jobst, Simon and Weigl, Stefan and Pangerl, Jonas and Bierl, Rudolf and Matysik, Frank-Michael}, title = {Digital Twin of a Photoacoustic Trace Gas Sensor for Monitoring Methane in Complex Gas Compositions}, series = {Sensors and Actuators B: Chemical}, journal = {Sensors and Actuators B: Chemical}, number = {378}, doi = {10.1016/j.snb.2022.133119}, abstract = {The digitalization of industrial processes requires smart sensor systems. Photoacoustic spectroscopy is well suited for this purpose as it allows for small-sized and low-cost trace gas analysis. However, the method is susceptible to changes in measurement conditions and standard calibration routines often fail to correct for all changes. We therefore created a Digital Twin (DT) of a photoacoustic trace gas sensor for methane and evaluated it regarding variations in gas composition (CH4, N2, O2, CO2, H2O), temperature and pressure. With a mean absolute percentage error of 0.8 \% the accuracy of the sensor after DT compensation significantly exceeds the 24 \% achieved based on standard calibration in nitrogen. For the first time, we can fully analytically compute the photoacoustic signal under moderate ambient conditions with an error in the ppbV range by taking a holistic approach. Assuming knowledge of the underlying energy transfer processes, the model of this Digital Twin can be adapted to any microphone based photoacoustic sensor for monitoring any analyte species.}, language = {en} } @article{ReinkerBlaesingBierletal., author = {Reinker, Lukas and Bl{\"a}sing, Dominic and Bierl, Rudolf and Ulbricht, Sabina and Dendorfer, Sebastian}, title = {Correlation of Acceleration Curves in Gravitational Direction for Different Body Segments during High-Impact Jumping Exercises}, series = {sensors}, volume = {23}, journal = {sensors}, number = {4}, publisher = {MDPI}, address = {Basel}, doi = {10.3390/s23042276}, url = {http://nbn-resolving.de/urn:nbn:de:bvb:898-opus4-58217}, abstract = {Osteoporosis is a common disease of old age. However, in many cases, it can be very well prevented and counteracted with physical activity, especially high-impact exercises. Wearables have the potential to provide data that can help with continuous monitoring of patients during therapy phases or preventive exercise programs in everyday life. This study aimed to determine the accuracy and reliability of measured acceleration data at different body positions compared to accelerations at the pelvis during different jumping exercises. Accelerations at the hips have been investigated in previous studies with regard to osteoporosis prevention. Data were collected using an IMU-based motion capture system (Xsens) consisting of 17 sensors. Forty-nine subjects were included in this study. The analysis shows the correlation between impacts and the corresponding drop height, which are dependent on the respective exercise. Very high correlations (0.83-0.94) were found between accelerations at the pelvis and the other measured segments at the upper body. The foot sensors provided very weak correlations (0.20-0.27). Accelerations measured at the pelvis during jumping exercises can be tracked very well on the upper body and upper extremities, including locations where smart devices are typically worn, which gives possibilities for remote and continuous monitoring of programs.}, language = {en} } @article{PirkerŁawrowskiSchreineretal., author = {Pirker, Luka and Ławrowski, Robert Damian and Schreiner, Rupert and Remškar, Maja and Višić, Bojana}, title = {MoₓWₓ₋₁S₂ Nanotubes for Advanced Field Emission Application}, series = {Advanced Functional Materials}, journal = {Advanced Functional Materials}, publisher = {Wiley}, issn = {1616-3028}, doi = {10.1002/adfm.202213869}, pages = {1 -- 8}, abstract = {Transition metal dichalcogenide (TMDC) nanotubes complement the field of low-dimensional materials with their quasi-1D morphology and a wide set of intriguing properties. By introducing different transition metals into the crystal structure, their properties can be tailored for specific purpose and applications. Herein, the characterization and a subsequent preparation of single-nanotube field emission devices of MoxWx-1S2 nanotubes prepared via the chemical vapor transport reaction is presented. Energy-dispersive X-ray spectroscopy, Raman spectroscopy, and X-ray diffraction indicate that the molybdenum and tungsten atoms are randomly distributed within the crystal structure and that the material is highly crystalline. High resolution transmission electron microscopy and electron diffraction (ED) patterns further corroborate these findings. A detailed analysis of the ED patterns from an eight-layer nanotube reveal that the nanotubes grow in the 2H structure, with each shell consists of one bilayer. The work function of the nanotubes is comparable to that of pure MoS2 and lower of pure WS2 NTs, making them ideal candidates for field emission applications. Two devices with different geometrical setup are prepared and tested as field emitters, showing promising results for single nanotube field emission applications.}, language = {en} } @article{BornmannMingelsDamsetal., author = {Bornmann, Benjamin and Mingels, Stephan and Dams, Florian and Prommesberger, Christian and Schreiner, Rupert and L{\"u}tzenkirchen-Hecht, Dirk and M{\"u}ller, G{\"u}nter}, title = {Electron spectrometer in adjustable triode configuration for photo-induced field emission measurements}, series = {The Review of scientific instruments}, volume = {83}, journal = {The Review of scientific instruments}, number = {1}, publisher = {American Institute of Physics}, address = {Melville, NY}, doi = {10.1063/1.3673475}, abstract = {We have constructed a new ultrahigh vacuum apparatus with a triode configuration for the systematic investigation of photo-induced field emission (PFE) from metallic or semiconducting cathodes. These are exposed to electric fields up to 400 MV∕m and laser irradiation by means of hole or mesh gates. Cathodes and gates are in situ exchangeable and adjustable with high precision to ensure a homogeneous extraction of electrons which are partially transmitted to the fixed electron spectrometer. Its hemispherical sector analyzer provides an energy resolution limit of 8 meV. The commissioning of the measurement system has been performed with a tungsten needle. Its temperature showed up in the high-energy tail of the electron spectrum, while its work function was derived from the spectral low-energy part combined with the integral current-voltage curve. First PFE measurements on B-doped Si-tip arrays yielded a small field emission current increase under green laser illumination. A shift and splitting of the energy spectra was observed which revealed different emission regimes as well as the photosensitivity of the cathode due to carrier excitation into the conduction band. For the full exploitation of the PFE system, a tunable laser over a wide eV-range is required.}, language = {en} } @article{TanYeapChowetal., author = {Tan, Pi Lin and Yeap, Guan Yeow and Chow, Wen Shyang and Schreiner, Rupert and Cheong, Kuan Yew}, title = {Effect of Thickness of Porphyrin on Electrical Properties of Organic Devices}, series = {Advanced Materials Research (AMR)}, volume = {1024}, journal = {Advanced Materials Research (AMR)}, publisher = {Trans Tech Publications Ltd.}, address = {Baech}, issn = {1662-8985}, doi = {10.4028/www.scientific.net/AMR.1024.381}, pages = {381 -- 384}, abstract = {The study on electrical properties for both 2,3,7,8,12,13,17,18-octaethyl-21,23H-porphine Cu (II) (Cu-porphyrin) and 2,3,7,8,12,13,17,18-octaethyl-21,23H-porphine (porphyrin) thin film, which were fabricated using spin coating method was conducted. Porphyrins were diluted with chloroform of various concentrations (0.05 mg/ml, 0.1 mg/ml, 0.5 mg/ml, 2.0 mg/ml and 3.0 mg/ml). The solution was spin coated on top of glass substrates. A layer of aluminum was evaporated on top of the organic thin film through thermal evaporation and shadow mask was placed on top of the organic thin film where two electrodes with a gap of 50 μm were formed. Surface morphology of the organic thin film was observed by scanning electron microscope (SEM) and profilometer. Different concentrations of organic solutions greatly affected the molecular packing and arrangement order of the organic thin film and thickness of the organic layer and eventually affected electrical properties of the devices.}, language = {en} } @article{DamsNavitskiPrommesbergeretal., author = {Dams, Florian and Navitski, Aliaksandr and Prommesberger, Christian and Serbun, Pavel and Langer, Christoph and M{\"u}ller, G{\"u}nter and Schreiner, Rupert}, title = {Homogeneous Field Emission Cathodes With Precisely Adjustable Geometry Fabricated by Silicon Technology}, series = {IEEE Transactions on Electron Devices}, volume = {59}, journal = {IEEE Transactions on Electron Devices}, number = {10}, publisher = {IEEE}, issn = {0018-9383}, doi = {10.1109/TED.2012.2206598}, pages = {2832 -- 2837}, abstract = {Silicon-based cathodes with precisely aligned field emitter arrays of sharp tips applicable for miniaturized electron sources were successfully fabricated and characterized. This was made possible by an improved fabrication process using wet thermal oxidation, wet etching, and reactive-ion etching steps with adjustable anisotropy. As substrate materials, both p-doped silicon and n-doped silicon were used. The cathode chips contain about 3 × 10 5 Si tips/cm 2 in a triangular array with tip heights of 2.5 μm, tip radii of less than 30 nm, and spacing of 20 μm. Well-aligned field emission (FE) and excellent homogeneity from all tips (i.e., 100\% efficiency) and maximum stable currents of typically 0.1 μA (0.6 μA) for p (n)-type Si were reproducibly achieved. The current-voltage characteristics of the p-Si tips exhibit the expected saturation at around 10 nA with around ten times better current stability, whereas the n-Si tips show the usual Fowler-Nordheim behavior. Additional coating of the Si tips with 5-nm Cr and 10-nm Au layers resulted in improved stability and at least five times higher average FE current limits (about 3 μA) at about 30\% higher operation voltage.}, language = {en} } @article{ŁawrowskiPrommesbergerLangeretal., author = {Ławrowski, Robert Damian and Prommesberger, Christian and Langer, Christoph and Dams, Florian and Schreiner, Rupert}, title = {Improvement of Homogeneity and Aspect Ratio of Silicon Tips for Field Emission by Reactive-Ion Etching}, series = {Advances in Materials Science and Engineering. Special issue: Advances in Smart Materials and Applications}, volume = {2014}, journal = {Advances in Materials Science and Engineering. Special issue: Advances in Smart Materials and Applications}, publisher = {Hindawi}, issn = {1687-8442}, doi = {10.1155/2014/948708}, pages = {1 -- 6}, abstract = {The homogeneity of emitters is very important for the performance of field emission (FE) devices. Reactive-ion etching (RIE) and oxidation have significant influences on the geometry of silicon tips. The RIE influences mainly the anisotropy of the emitters. Pressure has a strong impact on the anisotropic factor. Reducing the pressure results in a higher anisotropy, but the etch rate is also lower. A longer time of etching compensates this effect. Furthermore an improvement of homogeneity was observed. The impact of uprating is quite low for the anisotropic factor, but significant for the homogeneity. At low power the height and undercut of the emitters are more constant over the whole wafer. The oxidation itself is very homogeneous and has no observable effect on further variation of the homogeneity. This modified fabrication process allows solving the problem of inhomogeneity of previous field emission arrays.}, language = {en} }