TY - JOUR A1 - van den Heede, Philip A1 - Thiel, Charlotte A1 - de Belie, Nele T1 - Natural and accelerated carbonation behaviour of high-volume fly ash (HVFA) mortar: Effects on internal moisture, microstructure and carbonated phase proportioning T2 - Cement and Concrete Composites N2 - Binders with large portions of carbon-intensive Portland cement replaced by supplementary cementitious materials (e.g. fly ash) are more susceptible to carbonation mainly due to their lower CO2 buffering capacity. This conclusion is usually drawn from accelerated experiments at elevated CO2 levels involving processes that seriously differ from natural carbonation. The resulting presence of H2O reactant in the pore system and the carbonated microstructure itself may be very different. In this paper, these phenomena were investigated for High-Volume Fly Ash (HVFA) mortar via carbonation tests at ±0.04% CO2 (natural carbonation), 1% CO2 and 10% CO2. Internal humidity sensor monitoring and 1H NMR relaxometry revealed the highest water vapour and liquid water contents after carbonation at 10% CO2. Carbonation at 10% CO2 results in a coarser pore structure than carbonation at 1% CO2, and this probably due to a higher degree of C–S–H carbonation. KW - 1H NMR relaxometry KW - Carbonation KW - Mercury intrusion porosimetry KW - Moisture sensors KW - Multi-ring electrodes KW - Thermogravimetric analysis Y1 - 2020 UR - https://opus4.kobv.de/opus4-oth-regensburg/frontdoor/index/index/docId/4389 VL - 113 IS - October PB - Elsevier ER -