Scanning electrochemical microscopy for the differentiation of radical-induced degradation mechanisms in polymer electrolyte membranes

  • In this work, a spatially resolved analytical method based on scanning electrochemical microscopy (SECM) to distinguish different degradation phenomena in polymer electrolyte membranes was developed. SECM was combined with a Franz diffusion cell to distinguish between radical-induced aging of a sulfonated tetrafluoroethylene based fluoropolymer-copolymer due to deactivation of the sulfonic acid groups followed by a decreased proton conductivity, and the radical-induced formation of cracks and holes in the polymer. The experiments were performed with ferrocyanide as redox mediator to detect holes and cracks, and protons (sulfuric acid) to determine the through-plane proton conductivity, respectively. A pristine Nafion™ membrane, a pristine Nafion™ membrane with an artificial pinhole and a Nafion™ membrane aged with Fenton's reagent were investigated to prove the measurement principle. It could be shown that holes and cracks can be reliably detected with this approach and discriminated from a change in proton conductivity. The presenceIn this work, a spatially resolved analytical method based on scanning electrochemical microscopy (SECM) to distinguish different degradation phenomena in polymer electrolyte membranes was developed. SECM was combined with a Franz diffusion cell to distinguish between radical-induced aging of a sulfonated tetrafluoroethylene based fluoropolymer-copolymer due to deactivation of the sulfonic acid groups followed by a decreased proton conductivity, and the radical-induced formation of cracks and holes in the polymer. The experiments were performed with ferrocyanide as redox mediator to detect holes and cracks, and protons (sulfuric acid) to determine the through-plane proton conductivity, respectively. A pristine Nafion™ membrane, a pristine Nafion™ membrane with an artificial pinhole and a Nafion™ membrane aged with Fenton's reagent were investigated to prove the measurement principle. It could be shown that holes and cracks can be reliably detected with this approach and discriminated from a change in proton conductivity. The presence of holes in the investigated aged membranes was confirmed by scanning electron microscopy, whereas the loss of sulfonate groups could be supported by infrared spectroscopy measurements.show moreshow less

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Metadaten
Author:Susanne ThielORCiD, Maik EichelbaumORCiD
DOI:https://doi.org/10.1039/d4ra02203c
ISSN:2046-2069
Parent Title (English):RSC Advances
Publisher:Royal Society of Chemistry (RSC)
Document Type:Article
Language:English
Reviewed:Begutachtet/Reviewed
Release Date:2024/07/10
Volume:14
Issue:20
Article Number:13748
Pagenumber:10
First Page:13748
Last Page:13757
institutes:Institut für Angewandte Wasserstoffforschung, Elektro- und Thermochemische Energiesysteme (H2Ohm)
Fakultät für Angewandte Chemie
Research Themes:Energie & Ressourcen
Licence (German):Creative Commons - CC BY-NC - Namensnennung - Nicht kommerziell 4.0 International
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