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    <title language="eng">Solar Urea: Towards a Sustainable Fertilizer Industry</title>
    <abstract language="eng">Urea, an agricultural fertilizer, nourishes humanity. The century‐old Bosch–Meiser process provides the world's urea. It is multi‐step, consumes enormous amounts of non‐renewable energy, and has a large CO2 footprint. Thus, developing an eco‐friendly synthesis for urea is a priority. Herein we report a single‐step Pd/LTA‐3A catalyzed synthesis of urea from CO2 and NH3 under ambient conditions powered solely by solar energy. Pd nanoparticles serve the dual function of catalyzing the dissociation of NH3 and providing the photothermal driving force for urea formation, while the absorption capacity of LTA‐3A removes by‐product H2O to shift the equilibrium towards urea production. The solar urea conversion rate from NH3 and CO2 is 87 μmol g−1 h−1. This advance represents a first step towards the use of solar energy in urea production. It provides insights into green fertilizer production, and inspires the vision of sustainable, modular plants for distributed production of urea on farms.</abstract>
    <parentTitle language="eng">Angewandte Chemie</parentTitle>
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The century\u2010old Bosch\u2013Meiser process provides the world's urea. It is multi\u2010step, consumes enormous amounts of non\u2010renewable energy, and has a large CO&lt;jats:sub&gt;2&lt;\/jats:sub&gt; footprint. Thus, developing an eco\u2010friendly synthesis for urea is a priority. Herein we report a single\u2010step Pd\/LTA\u20103A catalyzed synthesis of urea from CO&lt;jats:sub&gt;2&lt;\/jats:sub&gt; and NH&lt;jats:sub&gt;3&lt;\/jats:sub&gt; under ambient conditions powered solely by solar energy. Pd nanoparticles serve the dual function of catalyzing the dissociation of NH&lt;jats:sub&gt;3&lt;\/jats:sub&gt; and providing the photothermal driving force for urea formation, while the absorption capacity of LTA\u20103A removes by\u2010product H&lt;jats:sub&gt;2&lt;\/jats:sub&gt;O to shift the equilibrium towards urea production. 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    <author>Meikun Xia</author>
    <author>Chengliang Mao</author>
    <author>Alan Gu</author>
    <author>Athanasios A. Tountas</author>
    <author>Chenyue Qiu</author>
    <author>Thomas E. Wood</author>
    <author>Young Feng Li</author>
    <author>Ulrich Ulmer</author>
    <author>Yangfan Xu</author>
    <author>Camilo J. Viasus</author>
    <author>Jessica Ye</author>
    <author>Chenxi Qian</author>
    <author>Geoffrey Ozin</author>
    <collection role="institutes" number="">Fakultät Verfahrenstechnik</collection>
    <collection role="institutes" number="">Institut für Angewandte Wasserstoffforschung, Elektro- und Thermochemische Energiesysteme (H2Ohm)</collection>
    <collection role="Forschungsschwerpunkt" number="1">Energie &amp; Ressourcen</collection>
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