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    <title language="eng">CNT/alumina-composites as electrically conductive ceramics</title>
    <abstract language="eng">CNT-reinforced alumina ceramics are an interesting option for the production of electrically conductive ceramics. It is shown that high electrical conductivity can be achieved with only 0.25 wt.-% of CNTs in the alumina matrix. These small amounts added enable the production of dense ceramics with very good mechanical properties, although CNTs massively inhibit densification of the ceramics during the sintering process, especially at higher concentrations. The article also describes the manufacturing process, the mechanical and thermal properties achieved and possible applications.</abstract>
    <parentTitle language="eng">cfi ceramic forum international</parentTitle>
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    <author>Hannes Kühl</author>
    <author>Christian Bechteler</author>
    <author>Ralf Girmscheid</author>
    <author>Achim Rübling</author>
    <collection role="institutes" number="">Fakultät Werkstofftechnik</collection>
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    <title language="eng">Development of pressureless sintered and hot‐pressed CNT/alumina composites including mechanical characterization</title>
    <abstract language="eng">AbstractA process for the production of carbon nanotube (CNT)/alumina composites on the basis of an aqueous suspension and without any extensive pretreatment was developed. Pressureless sintering and hot‐pressing of the nanocomposites were extensively researched and optimized. The influence of varying CNT contents, different alumina powders, sintering temperature and pressure on mechanical properties were investigated. Optimal hot‐pressing conditions are specified at 1550°C, 15 min dwell time, and 80 MPa applied pressure. Dense nanocomposites up to 3 wt.% and 0.5 wt.% CNT content were achieved by hot‐pressing and pressureless sintering, respectively. Furthermore, a 20% increase in hardness for CNT contents below 1.0 wt.% was detected, which is independent from the applied force and the alumina matrix. A highly anisotropic fracture toughness at increased CNT contents was detected by an indentation‐based method. The developed process provides a possibility to produce CNT/alumina composites with improved mechanical properties under reasonable effort, which could also be used for industrial production.</abstract>
    <parentTitle language="eng">International Journal of Ceramic Engineering &amp; Science</parentTitle>
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    <author>Christian Bechteler</author>
    <author>Achim Rübling</author>
    <author>Ralf Girmscheid</author>
    <author>Hannes Kühl</author>
    <collection role="institutes" number="">Fakultät Werkstofftechnik</collection>
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    <title language="eng">Electrical and thermal conductivity of CNT/alumina‐nanocomposite ceramics</title>
    <abstract language="eng">AbstractIn the present work, carbon nanotube (CNT)‐reinforced alumina nanocomposite ceramics were investigated about their electrical and, for the first time in such detail, thermal conductivity. Therefore, two different alumina powders with varying CNT‐contents were processed by pressureless sintering and hot pressing to achieve CNT/alumina composite ceramics with varying porosity and CNT‐content between 0 and 5 wt.% CNTs. A significant influence of the grain size on percolation threshold of the electrical conductivity was detected. The coarser CT 3000 SG‐based ceramic showed a threshold of &amp;lt;0.25 wt.%, which is the lowest reported threshold in literature. Pore orientation in the hot‐pressed materials shows a significant influence on the electrical and thermal conductivity of the composite, causing anisotropic properties. Both, electrical and thermal conductivity are higher parallel to the pore structure and perpendicular to the press‐direction, respectively, with electrical conductivity being up to three times and thermal conductivity up to 30% higher parallel to the pore structure. Unlike electrical conductivity, thermal conductivity decreases significantly with increasing CNT‐content. As two influences, CNT‐content and porosity, interact, each of them was analyzed separately in order to measure the isolated influence of CNT‐content on thermal conductivity at constant porosity. It was shown, that thermal conductivity decreases considerably with increasing CNT‐content even at constant porosity, because of a disturbed crystal structure due to a finer grain structure with more grain boundaries. This behavior is contrary to the expected, and sometimes reported, effect of CNTs. The combination of an increasing CNT‐content and the related increase in porosity causes a strongly decreasing thermal conductivity of the material from 35 W/m∙K for pure alumina to 10 W/m∙K for alumina with 5 wt.% CNTs. The presented results in this and other previously published investigations from the authors show that CNT/alumina‐nanocomposites have the potential of combining outstanding mechanical properties and electrical conductivity, which can be used as high performance electrically conductive ceramic material for a wide range of applications.</abstract>
    <parentTitle language="eng">International Journal of Ceramic Engineering &amp; Science</parentTitle>
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    <identifier type="doi">https://doi.org/10.1002/ces2.10167</identifier>
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Therefore, two different alumina powders with varying CNT\u2010contents were processed by pressureless sintering and hot pressing to achieve CNT\/alumina composite ceramics with varying porosity and CNT\u2010content between 0 and 5 wt.% CNTs. A significant influence of the grain size on percolation threshold of the electrical conductivity was detected. The coarser CT 3000 SG\u2010based ceramic showed a threshold of &amp;lt;0.25 wt.%, which is the lowest reported threshold in literature. Pore orientation in the hot\u2010pressed materials shows a significant influence on the electrical and thermal conductivity of the composite, causing anisotropic properties. Both, electrical and thermal conductivity are higher parallel to the pore structure and perpendicular to the press\u2010direction, respectively, with electrical conductivity being up to three times and thermal conductivity up to 30% higher parallel to the pore structure. Unlike electrical conductivity, thermal conductivity decreases significantly with increasing CNT\u2010content. As two influences, CNT\u2010content and porosity, interact, each of them was analyzed separately in order to measure the isolated influence of CNT\u2010content on thermal conductivity at constant porosity. It was shown, that thermal conductivity decreases considerably with increasing CNT\u2010content even at constant porosity, because of a disturbed crystal structure due to a finer grain structure with more grain boundaries. This behavior is contrary to the expected, and sometimes reported, effect of CNTs. The combination of an increasing CNT\u2010content and the related increase in porosity causes a strongly decreasing thermal conductivity of the material from 35 W\/m\u2219K for pure alumina to 10 W\/m\u2219K for alumina with 5 wt.% CNTs. The presented results in this and other previously published investigations from the authors show that CNT\/alumina\u2010nanocomposites have the potential of combining outstanding mechanical properties and electrical conductivity, which can be used as high performance electrically conductive ceramic material for a wide range of applications.&lt;\/jats:p&gt;","DOI":"10.1002\/ces2.10167","type":"journal-article","created":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T15:24:15Z","timestamp":1668785055000},"update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Electrical and thermal conductivity of CNT\/alumina\u2010nanocomposite ceramics"],"prefix":"10.1002","volume":"5","author":[{"ORCID":"http:\/\/orcid.org\/0000-0003-0706-9863","authenticated-orcid":false,"given":"Christian","family":"Bechteler","sequence":"first","affiliation":[{"name":"Technische Hochschule N\u00fcrnberg Georg Simon Ohm  N\u00fcrnberg Germany"},{"name":"Department of Materials University of Oxford  Oxford UK"}]},{"given":"Lisa","family":"Machuj","sequence":"additional","affiliation":[{"name":"Technische Hochschule N\u00fcrnberg Georg Simon Ohm  N\u00fcrnberg Germany"}]},{"given":"Kilian","family":"Hebendanz","sequence":"additional","affiliation":[{"name":"Technische Hochschule N\u00fcrnberg Georg Simon Ohm  N\u00fcrnberg Germany"}]},{"given":"Achim","family":"R\u00fcbling","sequence":"additional","affiliation":[{"name":"Technische Hochschule N\u00fcrnberg Georg Simon Ohm  N\u00fcrnberg Germany"}]},{"given":"Ralf","family":"Girmscheid","sequence":"additional","affiliation":[{"name":"Rauschert Heinersdorf\u2010Pressig GmbH  Pressig Germany"}]},{"given":"Hannes","family":"K\u00fchl","sequence":"additional","affiliation":[{"name":"Technische Hochschule N\u00fcrnberg Georg Simon Ohm  N\u00fcrnberg Germany"}]}],"member":"311","published-online":{"date-parts":[[2022,11,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/SCIENCE.268.5212.845"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/SCIENCE.270.5239.1179"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0008\u20106223(95)00017\u20108"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/381678a0"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2357920"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/J.OCERAM.2021.100166"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/CES2.10103"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compscitech.2009.01.015"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2014.01.020"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1744\u20107402.2004.tb00166.x"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2008.10.005"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2013.07.008"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2013.12.092"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1551\u20102916.2006.01232.x"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.actamat.2003.10.038"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compscitech.2008.04.001"},{"key":"e_1_2_8_18_1","volume-title":"Oxford classic texts in the physical sciences","author":"Maxwell JC","year":"2002"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1702301"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1151\u20102916.1935.tb19340.x"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1080\/14786449208620364"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1151\u20102916.2003.tb03285.x"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/j.1538\u20107305.1958.tb03883.x"}],"container-title":["International Journal of Ceramic Engineering &amp;amp; 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    <author>Christian Bechteler</author>
    <author>Lisa Machuj</author>
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