Metastability in reversible diffusion processes I. Sharp asymptotics for capcities and exit times
(2004)
We develop a potential theoretic approach to the problem of metastability for reversible diffusion processes with generators of the form +rF ( )r on R or subsets of , where F is a smooth function with finitely many local minima. In analogy to previous work in discrete Markov chains, we show that metastable exit times from the attractive domains of the minima of F can be related, up to multiplicative errors that tend to one as # 0, to the capacities of suitably constructed sets. We show that this capacities can be computed, again up to multiplicative errors that tend to one, in terms of local characteristics of F at the starting minimum and the relevant saddle points. As a result, we are able to give the first rigorous proof of the classical Eyring-Kramers formula in dimension larger than 1. The estimates on capacities make use of their variational representation and monotonicity properties of Dirichlet forms. The methods developed here are extensions of our earlier work on discrete Markov chains to continuous diffusion processes.
We continue the analysis of the problem of metastability for reversible diffusion processes,
initiated in [BEGK3], with a precise analysis of the low-lying spectrum of the generator.
Recall that we are considering processes with generators of the form 1+rF()r on Rd or subsets
of Rd , where F is a smooth function with finitely many local minima. Here we consider only
the generic situation where the depths of all local minima are different. We show that in general
the exponentially small part of the spectrum is given, up to multiplicative errors tending to one, by
the eigenvalues of the classical capacity matrix of the array of capacitors made of balls of radius
centered at the positions of the local minima of F. We also get very precise uniform control on the
corresponding eigenfunctions. Moreover, these eigenvalues can be identified with the same precision
with the inverse mean metastable exit times from each minimum. In [BEGK3] it was proven
that these mean times are given, again up to multiplicative errors that tend to one, by the classical
Eyring–Kramers formula.